TC4 ELI钛合金表面搪瓷涂层制备及其磨损性能
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- 英文论文题名：Preparation and Wear Behavior of Enamel Coating on TC4 ELI Titanium Alloy
- 论文作者：冯秋元 ; 张永强 ; 董志宏 ; 张平辉 ; 王鼎春 ; 高颀 ; 彭晓 ; 王福会
- 英文论文作者：FENG Qiuyuan ; ZHANG Yongqiang ; DONG Zhihong ; ZHANG Pinghui ; WANG Dingchun ; GAO Qi ; PENG Xiao ; WANG Fuhui ; Institute of Baoti ; Baoti Group Ltd ; Laboratory for Corrosion and Protection ; Institute of Metal Research ; Chinese Academy of Sciences ; School of Materials Science and Engineering ; Northeastern University
- 年：2016
- 作者机构：宝钛集团有限公司宝钛研究院;中国科学院金属研究所金属腐蚀与防护实验室;东北大学材料科学与工程学院;
- 论文关键词：钛合金 ; 搪瓷涂层 ; 硬度 ; 摩擦磨损 ; 磨损机制
- 英文论文关键词：titanium alloy ; enamel coating ; hardness ; friction and wear ; wear mechanism
- 会议召开时间：2016-11-18
- 会议录名称：第一届先进材料前沿学术会议论文集（《材料导报》2016年第30卷第Z1期）
- 语种：中文
- 分类号：TG174.4
- 学会代码：CLDB
- 会议名称：第一届先进材料前沿学术会议
- 会议地点：中国陕西西安
- 主办单位：《材料导报》杂志社
- 学会名称：材料导报编辑部
- 页数：5
- 文件大小：1026k
- 原文格式：O
- 会议级别：全国
摘要
采用料浆烧结法在TC4 ELI钛合金表面制备了搪瓷涂层,利用原子力显微镜(AFM)、扫描电镜(SEM)、显微硬度计、摩擦磨损试验机、热震法等对涂层的表面三维形貌、磨痕形貌、显微硬度、摩擦学行为及涂层与基体的结合强度进行表征,对比分析了涂层与基体磨损前后的微观形貌,并对磨损机制进行探讨。结果表明,涂层组织致密,与基体结合良好,厚度约30μm,且均匀平整;与基体相比,其硬度显著提高;在干摩擦磨损条件下,涂层的磨损量较小,仅为基体的1/4,磨损率为基体的29.6%,表现出优异的耐磨性能;TC4 ELI钛合金的磨损机制为粘着磨损和磨粒磨损,搪瓷涂层的磨损机制为磨粒磨损。
An enamel coating was prepared on TC4 ELI titanium alloy surface by using slurry sintering process,and the surface three-dimensional morphology,grinding crack morphology,microhardness and the tribological behavior of the coating and bonding strength between the coating and substrate were characterized by means of atomic force microscopy(AFM),scanning electron microscopy(SEM),microhardness test,friction and wear testing machine and thermal shock method,respectively.The morphology of the coating and matrix before and after wear was comparatively analyzed,and the wear mechanism was discussed.The results show that the structure of the coating is compact and well combine with matrix The thickness of the coating is about 30/am,and it is uniform and smooth.Compared to matrix,the hardness of the coating improves obviously.Under the condition of dry friction and wear,the wear mass loss of the coating is little,and is only one quarter of the base metal.The wear rate of the coating is about29.6%that of the matrix.The coating shows excellent wear-resistance.The wear mechanism of the TC4 ELI titanium alloy is the adhesive and abrasive wear,while the enamel coating is the abrasive wear.
An enamel coating was prepared on TC4 ELI titanium alloy surface by using slurry sintering process,and the surface three-dimensional morphology,grinding crack morphology,microhardness and the tribological behavior of the coating and bonding strength between the coating and substrate were characterized by means of atomic force microscopy(AFM),scanning electron microscopy(SEM),microhardness test,friction and wear testing machine and thermal shock method,respectively.The morphology of the coating and matrix before and after wear was comparatively analyzed,and the wear mechanism was discussed.The results show that the structure of the coating is compact and well combine with matrix The thickness of the coating is about 30/am,and it is uniform and smooth.Compared to matrix,the hardness of the coating improves obviously.Under the condition of dry friction and wear,the wear mass loss of the coating is little,and is only one quarter of the base metal.The wear rate of the coating is about29.6%that of the matrix.The coating shows excellent wear-resistance.The wear mechanism of the TC4 ELI titanium alloy is the adhesive and abrasive wear,while the enamel coating is the abrasive wear.
引文
1 Kenneth G B.Tribological properties of titanium alloys[J].Wear.1991,151(2):203.
2 Wu H Y,Zhang P Z,Xu J,et al.Current situations and applications of titanium alloys wear resistance coatings[J].Mater Rev,2006,20(4):74(in Chinese).吴红艳,张平则,徐江,等.钛合金表面耐磨涂层的研究现状及应用[J].材料导报,2006,20(4):74.
3屠振密,李宁,朱永明.钛及钛合金表面处理技术和应用[M].北京:国防工业出版社,2010.
4 Zhecheva A,Sha W,Malinov S,et al.Enhancing the microstructure and properties of titanium alloys through nitriding and other surface engineering methods[J].Surf Coat Technol,2005,200(7):2192.
5 Li X Y,Fan A L,Tan B,et al.Tribological behavior of molybdenum alloying layer on Ti6Al4V by double glow discharge technique[J].Tribology,2003,23(2):108(in Chinese).李秀燕,范爱兰,唐宾,等.Ti6Al4V表面双层辉光离子渗Mo及其摩擦学性能的研究[J].摩擦学学报,2003,23(2):108.
6 Qin L,Tang B,Zhao J X,et al.Friction and wear behavior of TiMo diffusion layer on Ti6Al4V alloy substrate in sliding against GCrl5[J].Chin J Nonferrous Metals,2006,13(3):570(in Chinese).秦林,唐宾,赵晋香,等.钛合金Ti6Al4V表面渗钼层的摩擦磨损性能[J].中国有色金属学报,2006,13(3):570.
7 Aliasghari S,Skeldon P,Thompson G E.Plasma electrolytic oxidation of titanium in phosphate/silicate electrolyte and tribological performance of the coatings[J].Appl Surf Sci,2014,316:463.
8 Zhao Lidong,Lugscheider Erich.Reactive plasma spraying of Ti6-A14V alloy[J].Wear,2002,253(ll-12):1214.
9赵树萍,吕双坤,郝文杰.钛合金及其表面处理[M].哈尔滨:哈尔滨工业大学出版社,2003.
10 Hui S X,Zhang Z,Xiao J S,et al.Influence of Nb implantation on oxidation behaviour of a high temperature titanium alloy at 650℃[J].Acta Metall Sin,1999,35(S):S127(in Chinese).惠松骁,张翥,萧今声,等.离子注入Nb对高温钛合金650℃抗氧化性能的影响[J].金属学报,1999,35(增刊1):S127.
11 Wu W L,Li X W.Research progress on laser cladding of titanliu alloys[J].Rare Metal Mater Eng,2006,35(6):850(in Chinese).武万良,李学伟.钛合金激光熔覆技术研究进展[J].稀有金属材料与工程,2006,35(6):850.
12 Fei Weng,Chuanzhong Chen,Huijun Yu.Research status of laser cladding on titanium and its alloys:A review[J].Mater Des,2014,58:412.
13 Tang Zhaolin,Wang Fuhui,Wu Weitao.Effect of Al_2O_3 and enamel coatings on 900℃oxidation and hot corrosion behaviors of gammaTiAl[J].Mater Sci Eng A,2000,276(1-2):70.
14 Rao X X,Hu S B,Qian D S.Preparation and property of enamel coating on titanium alloy[J].Electroplating&Finishing,2010,29(1):50(in Chinese).饶晓晓,胡树兵,钱得书.钛合金搪瓷涂层的制备与性能研究[J].电镀与涂饰,2010,29(1):50.
15 Guan C H,Tang Z L,Wang F H,et al.Effect of enamel coating on oxidation and hot corrosion resistance of Ti-24Al-14Nb-3V[J].Chin J Mater Res,2000,14(Sl)!75(in Chinese).关春红,唐兆麟,王福会,等.搪瓷涂层对Ti-24AL-14Nb-3V抗氧化及热腐蚀性能的影响[J].材料研究学报,2000,14(S1):75.
16 Xiong Y M,Zhu S L,Wang F H.Effect of ultrafine enamel coating on the oxidation and mechanical property of Ti60 alloy[J].Acta Metall Sin,2004,40(7):768(in Chinese).熊玉明,朱圣龙,王福会.超细搪瓷涂层对Ti60合金氧化及力学性能的影响[J].金属学报,2004,40(7):768.
17 Tang Z L,Wang F H,Wu W T.Effect of coatings on cyclic oxidation resistance of TiAl intermetallics[J].Chin J Nonferrous Metals,1998,8(l):56(in Chinese).唐兆麟,王福会,吴维弢.涂层对TiAl金属间化合物抗循环氧化性能的影响[J].中国有色金属学报,1998,8(1):56.
18 Tang Z,Wang F,Gao W.The effects of several coatings on cyclic oxidation resistance of TiAl intermetallics[J].Surf Coat Technol,1998,108-109:57.
19 Xie D B,Wang F H.Oxidation and hot corrosion behavior of a composite MCrAlY/enamel coating[J].Chin J Mater Res,2003,17(6):583(in Chinese).谢冬柏,王福会.MCrAlY/搪瓷复合涂层的抗高温氧化及热腐蚀性能[J].材料研究学报,2003,17(6):583.
20 Xiong Yuming,Zhu Shenglong,Wang Fuhui.The oxidation behavior and mechanical performance of Ti60 alloy with enamel coating[J].Surf Coat Technol,2005,190(2-3):195.
21 Xiong Y M,Zhu S L,Wang F H.Oxidation behaviors of TiAlNb with coatings at 800*C and 900*C respectively[J].Rare Metal Mater Eng,2006,35(2):213(in Chinese).熊玉明,朱圣龙,王福会.带涂层的TiAlNb合金高温氧化行为[J].稀有金属材料与工程,2006,35(2):213.
22 Zheng Deyou,Zhu Shenglong,Wang Fuhui.The influence of TiAIN and enamel coatings on the corrosion behavior of Ti6Al4V alloy in the presence of solid NaCl deposit and water vapor at 450℃[J].Surf Coat Technol,2007,201(12):5859.
23 Xiong Yuming,Zhu Shenglong,Wang Fuhui,et al.The effect of enamel coating on the oxidation behavior of Ti3Al-based intermetallics at 750℃in air[J].Mater Sci Eng A,2007,460-461,214.
24 Tao J,Huang Z D,Liu H B,et al.Preparation and characterization of anti-oxidation enamel coating for Ti-based alloys at high temperature[J].J Nanjing University of Aeronautics&Astroautics,2010,42(4):505(in Chinese).陶杰,黄镇东,刘红兵,等.钛基合金抗高温氧化搪瓷涂层制备及性能表征[J].南京航空航天大学学报,2010,42(4):505.
25 Zhang C H,Yang H G,Zhang S,et al.Effect of cerium oxide on the microstructure and friction and wear behavior of enamel coating[J].Tribology,2005,25(3):198(in Chinese).张春华,杨洪刚,张松,等.氧化铈对搪瓷涂层组织及摩擦磨损性能的影响[J].摩擦学学报,2005,25(3):198.
26 Liu W,Li W Z,Yang J B,et al.Current research status of enamel coatings on titanium alloys[J].Mater Rev:Res,2013,27(2):45(in Chinese).刘伟,李伟洲,杨剑冰,等.钛合金搪瓷涂层研究现状[J].材料导报:综述篇,2013,27(2):45.
27 Li J,Wu Y,Wang D,et al.The microstructure and wear resistance characteristics of electroformed nickel and partially stabilized zirconia composite coatings[J].J Mater Sci,2000,35(7):1751.
28 Mi Fengyi,Zhu Shenglong.Long-term high temperature oxidation and hot corrosion behavior of an enamel coating onγ-TiAl intermetallics at 700℃[J].Corros Sci Protection Technol,2015,27(3):254(in Chinese).米丰毅,朱圣龙.搪瓷涂层700℃长期抗高温氧化和热腐蚀行为研究[J].腐蚀科学与防护技术,2015,27(3):254.
29 Ocelik V,Matthews D,De Hosson J Th M Sliding wear resistance of metal matrix composite layers prepared by high power laser[J].Surf Coat Technol,2005,197(2-3):303.
30 Mao Yishu,Cui Xianghong,Wang Shuqi,et al.Wear and friction characteristics of Ti6A14V alloy[J].J Aeronautical Mater,2013,33(2):41(in Chinese).茅奕舒,崔向红,王树奇,等.Ti6Al4V合金的磨损行为和磨损机制[J].航空材料学报,2013,33(2):41.
31 Chen Kangmin,Zhang Qiuyang,Li Xinxing,et al.Dry sliding wear behavior of TC11 alloy/GCrl5 steel tribo-pair[J].Rare Metal Mater Eng,2015,44(6):1531(in Chinese).陈康敏,张秋阳,李新星,等.TC11合金/GCr15钢摩擦副的干滑动磨损行为[J].稀有金属材料与工程,2015,44(6):1531.
32 Yang Kai,Huang Jiewen,Fan Xinmin,et al.Preparation and properties of Al_2O_3/MoS_2 composite coatings on Ti6Al4V alloy by cathodic plasma electrolytic deposition[J].Trans Mater Heat Treatment,2016,37(2):164(in Chinese).杨凯,黄洁雯,樊新民,等.TifAl-4V表面Al_2O_3/MoS_2涂层的阴极等离子电解沉积及性能[J].材料热处理学报,2016,37(2):164.
33 Fu Yongqing,Nee Lam Loh,Andrew W Batchelor,et al.Improvement in fretting wear and fatigue resistance of Ti-6A1-4V by application of several surface treatments and coatings[J].Surf Coat Technol,1998,106(2-3):193.
34 Fu Yongqing,Du Hejun.Effects of the counterface materials on the tribological characteristics of CNX coating deposited on plasma-nitrided Ti-6A1-4V[J].Mater Sci Eng A,2001,298(1-2):16.
2 Wu H Y,Zhang P Z,Xu J,et al.Current situations and applications of titanium alloys wear resistance coatings[J].Mater Rev,2006,20(4):74(in Chinese).吴红艳,张平则,徐江,等.钛合金表面耐磨涂层的研究现状及应用[J].材料导报,2006,20(4):74.
3屠振密,李宁,朱永明.钛及钛合金表面处理技术和应用[M].北京:国防工业出版社,2010.
4 Zhecheva A,Sha W,Malinov S,et al.Enhancing the microstructure and properties of titanium alloys through nitriding and other surface engineering methods[J].Surf Coat Technol,2005,200(7):2192.
5 Li X Y,Fan A L,Tan B,et al.Tribological behavior of molybdenum alloying layer on Ti6Al4V by double glow discharge technique[J].Tribology,2003,23(2):108(in Chinese).李秀燕,范爱兰,唐宾,等.Ti6Al4V表面双层辉光离子渗Mo及其摩擦学性能的研究[J].摩擦学学报,2003,23(2):108.
6 Qin L,Tang B,Zhao J X,et al.Friction and wear behavior of TiMo diffusion layer on Ti6Al4V alloy substrate in sliding against GCrl5[J].Chin J Nonferrous Metals,2006,13(3):570(in Chinese).秦林,唐宾,赵晋香,等.钛合金Ti6Al4V表面渗钼层的摩擦磨损性能[J].中国有色金属学报,2006,13(3):570.
7 Aliasghari S,Skeldon P,Thompson G E.Plasma electrolytic oxidation of titanium in phosphate/silicate electrolyte and tribological performance of the coatings[J].Appl Surf Sci,2014,316:463.
8 Zhao Lidong,Lugscheider Erich.Reactive plasma spraying of Ti6-A14V alloy[J].Wear,2002,253(ll-12):1214.
9赵树萍,吕双坤,郝文杰.钛合金及其表面处理[M].哈尔滨:哈尔滨工业大学出版社,2003.
10 Hui S X,Zhang Z,Xiao J S,et al.Influence of Nb implantation on oxidation behaviour of a high temperature titanium alloy at 650℃[J].Acta Metall Sin,1999,35(S):S127(in Chinese).惠松骁,张翥,萧今声,等.离子注入Nb对高温钛合金650℃抗氧化性能的影响[J].金属学报,1999,35(增刊1):S127.
11 Wu W L,Li X W.Research progress on laser cladding of titanliu alloys[J].Rare Metal Mater Eng,2006,35(6):850(in Chinese).武万良,李学伟.钛合金激光熔覆技术研究进展[J].稀有金属材料与工程,2006,35(6):850.
12 Fei Weng,Chuanzhong Chen,Huijun Yu.Research status of laser cladding on titanium and its alloys:A review[J].Mater Des,2014,58:412.
13 Tang Zhaolin,Wang Fuhui,Wu Weitao.Effect of Al_2O_3 and enamel coatings on 900℃oxidation and hot corrosion behaviors of gammaTiAl[J].Mater Sci Eng A,2000,276(1-2):70.
14 Rao X X,Hu S B,Qian D S.Preparation and property of enamel coating on titanium alloy[J].Electroplating&Finishing,2010,29(1):50(in Chinese).饶晓晓,胡树兵,钱得书.钛合金搪瓷涂层的制备与性能研究[J].电镀与涂饰,2010,29(1):50.
15 Guan C H,Tang Z L,Wang F H,et al.Effect of enamel coating on oxidation and hot corrosion resistance of Ti-24Al-14Nb-3V[J].Chin J Mater Res,2000,14(Sl)!75(in Chinese).关春红,唐兆麟,王福会,等.搪瓷涂层对Ti-24AL-14Nb-3V抗氧化及热腐蚀性能的影响[J].材料研究学报,2000,14(S1):75.
16 Xiong Y M,Zhu S L,Wang F H.Effect of ultrafine enamel coating on the oxidation and mechanical property of Ti60 alloy[J].Acta Metall Sin,2004,40(7):768(in Chinese).熊玉明,朱圣龙,王福会.超细搪瓷涂层对Ti60合金氧化及力学性能的影响[J].金属学报,2004,40(7):768.
17 Tang Z L,Wang F H,Wu W T.Effect of coatings on cyclic oxidation resistance of TiAl intermetallics[J].Chin J Nonferrous Metals,1998,8(l):56(in Chinese).唐兆麟,王福会,吴维弢.涂层对TiAl金属间化合物抗循环氧化性能的影响[J].中国有色金属学报,1998,8(1):56.
18 Tang Z,Wang F,Gao W.The effects of several coatings on cyclic oxidation resistance of TiAl intermetallics[J].Surf Coat Technol,1998,108-109:57.
19 Xie D B,Wang F H.Oxidation and hot corrosion behavior of a composite MCrAlY/enamel coating[J].Chin J Mater Res,2003,17(6):583(in Chinese).谢冬柏,王福会.MCrAlY/搪瓷复合涂层的抗高温氧化及热腐蚀性能[J].材料研究学报,2003,17(6):583.
20 Xiong Yuming,Zhu Shenglong,Wang Fuhui.The oxidation behavior and mechanical performance of Ti60 alloy with enamel coating[J].Surf Coat Technol,2005,190(2-3):195.
21 Xiong Y M,Zhu S L,Wang F H.Oxidation behaviors of TiAlNb with coatings at 800*C and 900*C respectively[J].Rare Metal Mater Eng,2006,35(2):213(in Chinese).熊玉明,朱圣龙,王福会.带涂层的TiAlNb合金高温氧化行为[J].稀有金属材料与工程,2006,35(2):213.
22 Zheng Deyou,Zhu Shenglong,Wang Fuhui.The influence of TiAIN and enamel coatings on the corrosion behavior of Ti6Al4V alloy in the presence of solid NaCl deposit and water vapor at 450℃[J].Surf Coat Technol,2007,201(12):5859.
23 Xiong Yuming,Zhu Shenglong,Wang Fuhui,et al.The effect of enamel coating on the oxidation behavior of Ti3Al-based intermetallics at 750℃in air[J].Mater Sci Eng A,2007,460-461,214.
24 Tao J,Huang Z D,Liu H B,et al.Preparation and characterization of anti-oxidation enamel coating for Ti-based alloys at high temperature[J].J Nanjing University of Aeronautics&Astroautics,2010,42(4):505(in Chinese).陶杰,黄镇东,刘红兵,等.钛基合金抗高温氧化搪瓷涂层制备及性能表征[J].南京航空航天大学学报,2010,42(4):505.
25 Zhang C H,Yang H G,Zhang S,et al.Effect of cerium oxide on the microstructure and friction and wear behavior of enamel coating[J].Tribology,2005,25(3):198(in Chinese).张春华,杨洪刚,张松,等.氧化铈对搪瓷涂层组织及摩擦磨损性能的影响[J].摩擦学学报,2005,25(3):198.
26 Liu W,Li W Z,Yang J B,et al.Current research status of enamel coatings on titanium alloys[J].Mater Rev:Res,2013,27(2):45(in Chinese).刘伟,李伟洲,杨剑冰,等.钛合金搪瓷涂层研究现状[J].材料导报:综述篇,2013,27(2):45.
27 Li J,Wu Y,Wang D,et al.The microstructure and wear resistance characteristics of electroformed nickel and partially stabilized zirconia composite coatings[J].J Mater Sci,2000,35(7):1751.
28 Mi Fengyi,Zhu Shenglong.Long-term high temperature oxidation and hot corrosion behavior of an enamel coating onγ-TiAl intermetallics at 700℃[J].Corros Sci Protection Technol,2015,27(3):254(in Chinese).米丰毅,朱圣龙.搪瓷涂层700℃长期抗高温氧化和热腐蚀行为研究[J].腐蚀科学与防护技术,2015,27(3):254.
29 Ocelik V,Matthews D,De Hosson J Th M Sliding wear resistance of metal matrix composite layers prepared by high power laser[J].Surf Coat Technol,2005,197(2-3):303.
30 Mao Yishu,Cui Xianghong,Wang Shuqi,et al.Wear and friction characteristics of Ti6A14V alloy[J].J Aeronautical Mater,2013,33(2):41(in Chinese).茅奕舒,崔向红,王树奇,等.Ti6Al4V合金的磨损行为和磨损机制[J].航空材料学报,2013,33(2):41.
31 Chen Kangmin,Zhang Qiuyang,Li Xinxing,et al.Dry sliding wear behavior of TC11 alloy/GCrl5 steel tribo-pair[J].Rare Metal Mater Eng,2015,44(6):1531(in Chinese).陈康敏,张秋阳,李新星,等.TC11合金/GCr15钢摩擦副的干滑动磨损行为[J].稀有金属材料与工程,2015,44(6):1531.
32 Yang Kai,Huang Jiewen,Fan Xinmin,et al.Preparation and properties of Al_2O_3/MoS_2 composite coatings on Ti6Al4V alloy by cathodic plasma electrolytic deposition[J].Trans Mater Heat Treatment,2016,37(2):164(in Chinese).杨凯,黄洁雯,樊新民,等.TifAl-4V表面Al_2O_3/MoS_2涂层的阴极等离子电解沉积及性能[J].材料热处理学报,2016,37(2):164.
33 Fu Yongqing,Nee Lam Loh,Andrew W Batchelor,et al.Improvement in fretting wear and fatigue resistance of Ti-6A1-4V by application of several surface treatments and coatings[J].Surf Coat Technol,1998,106(2-3):193.
34 Fu Yongqing,Du Hejun.Effects of the counterface materials on the tribological characteristics of CNX coating deposited on plasma-nitrided Ti-6A1-4V[J].Mater Sci Eng A,2001,298(1-2):16.
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