中低压直接碳化法制备形貌可控的纳微级碱土碳酸盐
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- 英文论文题名：Preparation of Morphology Controllable Nano-micron Alkaline Earth Carbonates via Direct Middle-high Pressure Carbonization
- 论文作者：沙峰 ; 洪海龙 ; 张飞 ; 乔宪书 ; 张建斌
- 英文论文作者：Feng Sha ; Hai-long Hong ; Fei Zhang ; Xian-shu Qiao ; Jian-bin Zhang ; Chemical Engineering College ; Inner Mongolia University of Technology
- 年：2016
- 作者机构：内蒙古工业大学化工学院;
- 论文关键词：纳微米级碱土碳酸盐 ; 形貌控制 ; 二氧化碳
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十三分会：绿色化学
- 语种：中文
- 分类号：TQ127.13
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十三分会 ; 绿色化学
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：237k
- 原文格式：D
- 会议级别：全国
摘要
纳微级碱土碳酸盐(碳酸钙、碳酸锶、碳酸钡)因广泛应用于日常生活中的无机-有机复合材料领域及在其他工业领域而倍受关注~([1-3])。本文利用简单、快速的直接碳化法,在中低压下利用CO_2,以乙二醇类多元醇-乙二胺为导向剂,实现了纳微级碱土碳酸盐形貌、结构、粒度分布的可控制备。在此过程中,金属离子浓度、CO_2压力、温度、时间等参数得到了系统地考察,不同形貌、结构、粒度分布的纳微级碱土碳酸盐的最佳工艺条件得到了确定。图1为控制反应条件得到的形貌、粒度均一的碱土碳酸盐。
Nano-micron alkaline earth carbonates, including calcium carbonate, strontium carbonate and barium carbonate, were intensively researched owing to its wide application in inorganic-organic hybrid composite fields and other industrial areas. In this work, the nano-micron alkaline earth carbonate with specific morphology, structure and size distribution dioxide were prepared via a simple and fast direct reaction method. In this process, metal ion concentration, CO_2 pressure, temperature and time experimental parameters were systematically investigated, and the optimum conditions were confirmed. The bundle-like calcium carbonate, ellipsoid-like strontium carbonate and spindle-like barium carbonate were obtained, as shown in Figure 1.
Nano-micron alkaline earth carbonates, including calcium carbonate, strontium carbonate and barium carbonate, were intensively researched owing to its wide application in inorganic-organic hybrid composite fields and other industrial areas. In this work, the nano-micron alkaline earth carbonate with specific morphology, structure and size distribution dioxide were prepared via a simple and fast direct reaction method. In this process, metal ion concentration, CO_2 pressure, temperature and time experimental parameters were systematically investigated, and the optimum conditions were confirmed. The bundle-like calcium carbonate, ellipsoid-like strontium carbonate and spindle-like barium carbonate were obtained, as shown in Figure 1.
引文
[1]金宏,吴亚丽,王志平等.碳酸钙的形貌控制及表面改性探究[J].广州化工,2015,43(23):111-114.
[2]朱仁志,张欢,王淞等.碳酸钡纳米棒的合成与表征[J].材料研究与应用,2014,8(2):108-111.
[3]胡育,张元勤,李晓燕等.一种新的离子液体表面活性剂软模板法合成碳酸锶纳米棒[J].化学研究与应用,2011,23(10):1374-1377.
[2]朱仁志,张欢,王淞等.碳酸钡纳米棒的合成与表征[J].材料研究与应用,2014,8(2):108-111.
[3]胡育,张元勤,李晓燕等.一种新的离子液体表面活性剂软模板法合成碳酸锶纳米棒[J].化学研究与应用,2011,23(10):1374-1377.