~(19)F-NMR法测定聚醚多元醇伯羟基含量样品预处理方法研究
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- 英文论文题名：Study on the Pretreatment of Polyether Polyol for Determination of Primary Hydroxyl Using ~(19)F-NMR Method
- 论文作者：袁燕妮 ; 郭辉
- 英文论文作者：YUAN Yanni ; GUO Hui ; Shandong Bluestar Dongda chemical Co.Ltd
- 年：2016
- 作者机构：山东蓝星东大化工有限责任公司;
- 论文关键词：聚醚多元醇 ; 伯羟基 ; ~(19)F-NMR ; 三氟醋酸酯
- 英文论文关键词：polyether polyol ; primary hydroxyl ; ~(19)F-NMR ; trifluoroacetate
- 会议召开时间：2016-07-30
- 会议录名称：中国聚氨酯工业协会第十八次年会论文集
- 语种：中文
- 分类号：TQ326.5;O657.2
- 学会代码：JAZG
- 会议名称：中国聚氨酯工业协会第十八次年会
- 会议地点：中国上海
- 主办单位：中国聚氨酯工业协会
- 学会名称：中国聚氨酯工业协会
- 页数：5
- 文件大小：1222k
- 原文格式：D
- 会议级别：全国
摘要
重点研究了利用~(19)F-NMR法测定聚醚多元醇中伯羟基的含量前酰化处理过程溶剂、酰化剂加入量、酰化反应时间等实验条件的选择,以及19F-NMR法准确度和精密度的评定。
Primary hydroxyl relative content of polyether polyol was determined by ~(19)F-NMR method,and experimental conditions containing the solvent,the amount of acylating agent added and the acylation reaction time.Furthermore,accuracy and precision of ~(19)F-NMR method were provided by this paper.
Primary hydroxyl relative content of polyether polyol was determined by ~(19)F-NMR method,and experimental conditions containing the solvent,the amount of acylating agent added and the acylation reaction time.Furthermore,accuracy and precision of ~(19)F-NMR method were provided by this paper.
引文
[1]冯指南,胡瑞江,王殿福.高分子量高活性聚醚多元醇的合成研究[J].精细化工,1990,1(1):46-48.
[2]SIGGIA S,HANNA J G.Use of differential reaction rates to analyze mixtures of organic materials containing the same functional group[J].Anal Chem,1961,33:896 900.
[3]陈耀祖,王昌益.近代有机定量分析[M].北京:科学出版社,1987:37,82-86,155,224.
[4]吉佩芳.单扫描示波极普法在测定聚醚伯羟基方面的应用[J].金陵石油化工,1993(3):15,20-24.
[5]MATHIAS A.The determination and estimation of the relative amount of primary and secondary hydroxyl groups using NMR[J].Anal Chim Acta,1964,31:598-601.
[2]SIGGIA S,HANNA J G.Use of differential reaction rates to analyze mixtures of organic materials containing the same functional group[J].Anal Chem,1961,33:896 900.
[3]陈耀祖,王昌益.近代有机定量分析[M].北京:科学出版社,1987:37,82-86,155,224.
[4]吉佩芳.单扫描示波极普法在测定聚醚伯羟基方面的应用[J].金陵石油化工,1993(3):15,20-24.
[5]MATHIAS A.The determination and estimation of the relative amount of primary and secondary hydroxyl groups using NMR[J].Anal Chim Acta,1964,31:598-601.