全氟化合物在岷江流域沉积物中的污染特征及生态风险评价
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- 论文作者：孙静 ; 方淑红
- 年：2016
- 作者机构：成都信息工程大学;
- 论文关键词：岷江流域 ; 全氟化合物 ; 沉积物 ; 生态风险评价
- 英文论文关键词：Minjiang River Basin ; Perfluoroalkyl Substances ; Sediments ; Ecological Risk Assessment
- 会议召开时间：2016-12-14
- 会议录名称：2016全国水环境污染控制与生态修复技术高级研讨会论文集
- 语种：中文
- 分类号：X52;X826
- 学会代码：HJKP
- 会议名称：2016全国水环境污染控制与生态修复技术高级研讨会
- 会议地点：中国云南腾冲
- 主办单位：中国环境科学学会、中国环境科学研究院
- 学会名称：中国环境科学学会
- 页数：8
- 文件大小：965k
- 原文格式：D
- 会议级别：全国
摘要
目前,国内针对沉积物中的全氟化合物(PFASs)的调查研究集中在东南沿海发达地区,西南地区还尚未开展调查研究。本研究采用超声辅助萃取前处理方法,超高效液相色谱串联质谱分析了西南地区岷江流域表层沉积物中的全氟化合物的浓度水平。结果显示,岷江流域PFASs总浓度范围为n.d.~0.769 ng/g,其中PFBA、PFPe A、PFOA和PFOS是主要污染物。与国内外不同流域对比发现:岷江流域表层沉积物中PFOA和PFOS的浓度水平并不高。计算了全氟化合物对岷江流域的生态风险,结果显示,其风险墒值<1,暴露浓度低于对生态环境造成风险的水平。
Geographic areas about the concentration levels about perfluorinated compounds(PFASs) in sedments of different watershelds in China were mainly in the Southeast China and South China. Few studies in Sourthwest China were concerned. In this study, the concentration levels of PFASs in surface sediments of Minjiang River watersheld were conducted using ultrasound-assisted extraction followed by ultra-performance liquid chromatography tandem mass spectrometry. The results showed that total PFASs concentration in surface sediments of Minjiang River watersheld ranged from n.d to 0.769 ng/g. PFBA, PFPeA, PFOA and PFOS were the main detected PFASs. It is also found out that the levels of PFOA and PFOS in Minjiang River are not high compared with other rivers in China. Furthermore, ecological risk assessment was carried out according to calculate the entropy(the ratio of measured concentrations to predicted no-effect concentration)of PFOA and PFOS, and the results showed that the exposure concentration in sediment did not arrive to the ecological environment risks level.
Geographic areas about the concentration levels about perfluorinated compounds(PFASs) in sedments of different watershelds in China were mainly in the Southeast China and South China. Few studies in Sourthwest China were concerned. In this study, the concentration levels of PFASs in surface sediments of Minjiang River watersheld were conducted using ultrasound-assisted extraction followed by ultra-performance liquid chromatography tandem mass spectrometry. The results showed that total PFASs concentration in surface sediments of Minjiang River watersheld ranged from n.d to 0.769 ng/g. PFBA, PFPeA, PFOA and PFOS were the main detected PFASs. It is also found out that the levels of PFOA and PFOS in Minjiang River are not high compared with other rivers in China. Furthermore, ecological risk assessment was carried out according to calculate the entropy(the ratio of measured concentrations to predicted no-effect concentration)of PFOA and PFOS, and the results showed that the exposure concentration in sediment did not arrive to the ecological environment risks level.
引文
[1]Wang T,Wang Y W,Liao C Y,et al.Perspectives on the inclusion of perfluorooctane sulfonate into the Stockholm Convention on Persistent Organic Pollutants[J].Environmental Science and Technology,2009,43(14):5171-5175.
[2]Higgins C P,Field J A,Criddle C S,et al.Quantitative determination of perfluorochemicals in sediments and domestic sludge[J].Environmental Science&Technology,2005,39(11):3946-3956.
[3]Clara M,Gans O,Weiss S,et al.Perfluorinated alkylated substances in the aquatic environment:an Austrian case study[J].Water Research,2009,43(18):4760-4768.
[4]Labadie P,Chevreuil M.Partitioning behaviour of per fluorinated alkyl contaminants between water,sediment and fish in the Orge River(nearby Paris,France)[J].Environmental Pollution,2011,159(2):391-397.
[5]Becker A M,Gerstmann S,Frank H.Perfluorooctanoic acid and perfluorooctane sulfonate in the sediment of the Roter Main river,Bayreuth,Germany[J].Environmental Pollution,2008,156(3):818-820.
[6]Zhao L Z,Zhu L Y,Yang L P,et al.Distribution and desorption of perfluorinated compounds in fractionated sediments[J].Chemosphere,2012,88(11):1390-1397.
[7]Ahrens L,Taniyasu S,Yeung LWY,et al.Distribution of polyfluoroalkyl compounds in water,suspended particulate matterandsedimentfrom Tokyo Bay,Japan[J].Chemosphere,2010,79(3):266-272.
[8]Zhang Y,Meng W,Guo C S,et al.Determination and partitioning behavior of perfluoroalkyl carboxylic acids and perfluorooctane sulfonate in water and sediment from Dianchi Lake,China[J].Chemosphere,2012,88(11):1292-1299.
[9]Nakata H,Kannan K,Nasu T,et al.Perfluorinated contaminants in sediments and aquatic organisms collected from shallow water and tidal flat areas of the Ariake Sea,Japan:environmental fate of perfluorooctane sulfonate in aquatic ecosystems[J].Environmental Science&Technology,2006,40(16):4916-4921.
[10]Zushi Y,Tamada M,Kanai Y,et al.Time trends of perfluorinated compounds from the sediment core of Tokyo Bay,Japan(1950-2004)[J].Environmental Pollution,2010(158)(3):756-763.
[11]Senthilkumar K,Ohi E,Sajwan K,et al.Perfluorinated compounds in river water,river sediment,market fish and wildlife samples from Japan[J].Bulletin of Environmental Contamination and Toxicology,2007,79(4):427-431.
[12]Bao J,Jin Y H,Liu W,et al.Perfluorinated compounds in sediments from the Daliao River system of northeast China[J].Chemosphere,2009,77(5):652-657.
[13]Bao J,Liu W,Liu L,et al.Perfluorinated compounds in urban river sediments from Guangzhou and Shanghai of China[J].Chemosphere,2010,80(2):123-130.
[14]Pan G,You C.Sediment-water distribution of perfluo rooctane sulfonate(PFOS)in Yangtze River Estuary[J].Environmental Pollution,2010,158(5):1363-1367.
[15]Pan Yuan-yuan,Shi Ya-li,Wang Jie-ming,et al.Pilot investigation of perfluorinated compounds in river water,sediment,soil and fish in Tianjin,China[J].Bulletin of Environmental Contamination and Toxicology,2011,87(2):152-157.
[16]Wang Tie-ya,Chen Chun-li,E Naile J,et al.Perfluorinated compounds in water,sediment and soil from Guanting Reservoir,China[J].Environmental Contamination and Toxicology,2011,87(1):74-79.
[17]Yang Li-ping,Zhu Ling-yan,Liu Zheng-tao.Occurrence and partition of perfluorinated compounds in water and sediment from Liao River and Taihu Lake,China[J].Chemosphere,2011,83(6):806-814.
[18]Pan G,You C.Sediment-water distribution of perfluo rooctanesulfonate(PFOS)in Yangtze River Estuary[J].Environmental Pollution,2010,158(5):1363-1367.
[19]彭立,苏春江,徐云,等.岷江上游生态环境现状、存在问题及治理对策[J].江西农业大学学报(社会科学版),2007,6(1):80-84.
[20]张亮,廖海清,郭建阳,等.成渝经济区表层沉积物中的多溴联苯醚的分布特征[J].环境科学研究,2011,26(8):844-849.
[21]汤智,廖海清,张亮,等.成渝经济区表层沉积物中多环芳烃的分布、来源及生态风险评价[J].环境科学,2011,32(9):2640-2644.
[22]魏明翠,钟文珏,赵丽霞,等.南方某氟化学工业园周围环境中全氟化合物的分布研究[J].环境科学学报,2013,33(7):1989-1995.
[23]巩秀贤,李斌,柳玉英,等.浑河-大辽河水系水体与沉积物中典型全氟化合物的污染水平及生态风险评价[J].环境科学学报,2015,35(7):2177-2184.
[2]Higgins C P,Field J A,Criddle C S,et al.Quantitative determination of perfluorochemicals in sediments and domestic sludge[J].Environmental Science&Technology,2005,39(11):3946-3956.
[3]Clara M,Gans O,Weiss S,et al.Perfluorinated alkylated substances in the aquatic environment:an Austrian case study[J].Water Research,2009,43(18):4760-4768.
[4]Labadie P,Chevreuil M.Partitioning behaviour of per fluorinated alkyl contaminants between water,sediment and fish in the Orge River(nearby Paris,France)[J].Environmental Pollution,2011,159(2):391-397.
[5]Becker A M,Gerstmann S,Frank H.Perfluorooctanoic acid and perfluorooctane sulfonate in the sediment of the Roter Main river,Bayreuth,Germany[J].Environmental Pollution,2008,156(3):818-820.
[6]Zhao L Z,Zhu L Y,Yang L P,et al.Distribution and desorption of perfluorinated compounds in fractionated sediments[J].Chemosphere,2012,88(11):1390-1397.
[7]Ahrens L,Taniyasu S,Yeung LWY,et al.Distribution of polyfluoroalkyl compounds in water,suspended particulate matterandsedimentfrom Tokyo Bay,Japan[J].Chemosphere,2010,79(3):266-272.
[8]Zhang Y,Meng W,Guo C S,et al.Determination and partitioning behavior of perfluoroalkyl carboxylic acids and perfluorooctane sulfonate in water and sediment from Dianchi Lake,China[J].Chemosphere,2012,88(11):1292-1299.
[9]Nakata H,Kannan K,Nasu T,et al.Perfluorinated contaminants in sediments and aquatic organisms collected from shallow water and tidal flat areas of the Ariake Sea,Japan:environmental fate of perfluorooctane sulfonate in aquatic ecosystems[J].Environmental Science&Technology,2006,40(16):4916-4921.
[10]Zushi Y,Tamada M,Kanai Y,et al.Time trends of perfluorinated compounds from the sediment core of Tokyo Bay,Japan(1950-2004)[J].Environmental Pollution,2010(158)(3):756-763.
[11]Senthilkumar K,Ohi E,Sajwan K,et al.Perfluorinated compounds in river water,river sediment,market fish and wildlife samples from Japan[J].Bulletin of Environmental Contamination and Toxicology,2007,79(4):427-431.
[12]Bao J,Jin Y H,Liu W,et al.Perfluorinated compounds in sediments from the Daliao River system of northeast China[J].Chemosphere,2009,77(5):652-657.
[13]Bao J,Liu W,Liu L,et al.Perfluorinated compounds in urban river sediments from Guangzhou and Shanghai of China[J].Chemosphere,2010,80(2):123-130.
[14]Pan G,You C.Sediment-water distribution of perfluo rooctane sulfonate(PFOS)in Yangtze River Estuary[J].Environmental Pollution,2010,158(5):1363-1367.
[15]Pan Yuan-yuan,Shi Ya-li,Wang Jie-ming,et al.Pilot investigation of perfluorinated compounds in river water,sediment,soil and fish in Tianjin,China[J].Bulletin of Environmental Contamination and Toxicology,2011,87(2):152-157.
[16]Wang Tie-ya,Chen Chun-li,E Naile J,et al.Perfluorinated compounds in water,sediment and soil from Guanting Reservoir,China[J].Environmental Contamination and Toxicology,2011,87(1):74-79.
[17]Yang Li-ping,Zhu Ling-yan,Liu Zheng-tao.Occurrence and partition of perfluorinated compounds in water and sediment from Liao River and Taihu Lake,China[J].Chemosphere,2011,83(6):806-814.
[18]Pan G,You C.Sediment-water distribution of perfluo rooctanesulfonate(PFOS)in Yangtze River Estuary[J].Environmental Pollution,2010,158(5):1363-1367.
[19]彭立,苏春江,徐云,等.岷江上游生态环境现状、存在问题及治理对策[J].江西农业大学学报(社会科学版),2007,6(1):80-84.
[20]张亮,廖海清,郭建阳,等.成渝经济区表层沉积物中的多溴联苯醚的分布特征[J].环境科学研究,2011,26(8):844-849.
[21]汤智,廖海清,张亮,等.成渝经济区表层沉积物中多环芳烃的分布、来源及生态风险评价[J].环境科学,2011,32(9):2640-2644.
[22]魏明翠,钟文珏,赵丽霞,等.南方某氟化学工业园周围环境中全氟化合物的分布研究[J].环境科学学报,2013,33(7):1989-1995.
[23]巩秀贤,李斌,柳玉英,等.浑河-大辽河水系水体与沉积物中典型全氟化合物的污染水平及生态风险评价[J].环境科学学报,2015,35(7):2177-2184.