氧化铝对Pd/CZLA催化氧化甲醇性能的影响
详细信息 查看官网全文
- 英文论文题名：Effect of aluminum on Catalytic Performance of the Pd/CZLA Catalysts for the oxidation of methanol
- 论文作者：张雪乔 ; 刘建英 ; 刘洁 ; 王丽莎 ; 黎坤
- 英文论文作者：Xueqiao Zhang ; Jianying Liu ; Jie Liu ; College of Resources and Environment ; Chengdu University of Information Technology
- 年：2016
- 作者机构：成都信息工程大学;
- 论文关键词：氧化铝 ; 钯 ; 甲醇 ; 催化氧化
- 英文论文关键词：aluminum ; palladium ; methanol ; catalytic oxidation
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第十五分会：表界面结构调控与催化
- 语种：中文
- 分类号：O643.36
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第十五分会 ; 表界面结构调控与催化
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：411k
- 原文格式：D
- 会议级别：全国
摘要
采用等体积浸渍法制备一系列不同Al_2O_3含量的Pd/CeO_2-ZrO_2-La_2O_3-Al_2O_3催化剂。分别运用N2吸脱附、H2程序升温还原(H2-TPR)等方法对催化剂进行表征,并考察其对甲醇的催化氧化性能。结果表明,添加Al_2O_3可改善催化剂的织构性能和还原性能,同时调变催化剂活性中心的种类,进而提高甲醇的催化氧化活性[1-3]。活性测试结果显示,当Al_2O_3含量为70%时,T50、T90以及ΔT分别为125℃,153℃和28℃,具有较好的应用前景。
Pd/CeO_2-ZrO_2-La_2O_3-Al_2O_3 catalysts with different content of aluminum were prepared by the impregnation method.And the catalytic activities of these catalysts for the oxidation of methanol were investigated.The results of catalytic activity indicate that the presence of Al_2O_3 significantly improves catalytic performance for methanol oxidation.And the higher content of Al_2O_3,the better activity of methanol catalytic oxidation.
Pd/CeO_2-ZrO_2-La_2O_3-Al_2O_3 catalysts with different content of aluminum were prepared by the impregnation method.And the catalytic activities of these catalysts for the oxidation of methanol were investigated.The results of catalytic activity indicate that the presence of Al_2O_3 significantly improves catalytic performance for methanol oxidation.And the higher content of Al_2O_3,the better activity of methanol catalytic oxidation.
引文
[1]Zhou Li Ping.Industrial Catalysis.2004,8(12):42.
[2]Wang Jianqiang,Shen Meiqing,Yuan An et al.Catalysis Communications.2008,10:103.
[3]Abbas Khaleel,Muhammad Nawaz.Journal of Environmental Sciences.2015,29:199.
[2]Wang Jianqiang,Shen Meiqing,Yuan An et al.Catalysis Communications.2008,10:103.
[3]Abbas Khaleel,Muhammad Nawaz.Journal of Environmental Sciences.2015,29:199.