聚吡咯/碲纳米复合物的制备及其电容性质
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- 英文论文题名：Preparation and Capacitive Behavior of Polypyrrole/Tellurium Nanocomposite
- 论文作者：王家佳 ; 殷海霞 ; 乔雪娇 ; 张胜义
- 英文论文作者：Wang Jiajia ; Yin Haixia ; Qiao Xuejiao ; Zhang Shengyi ; Chemistry and Chemical Engineering ; Anhui University
- 年：2016
- 作者机构：安徽大学化学化工学院;
- 论文关键词：聚吡咯 ; 碲 ; 纳米复合物 ; 电容性质
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十六分会：纳米材料合成与组装
- 语种：中文
- 分类号：TB33
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十六分会 ; 纳米材料合成与组装
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：216k
- 原文格式：D
- 会议级别：全国
摘要
在酸性条件下,以二氧化碲为氧化剂氧化吡咯,制备了聚吡咯/碲纳米复合物。在制备过程中,加入的碳量子点增加了聚合物的导电性,反应剩余的二氧化碲与生成的单质碲组成Te/Te~(4+)电对,增加了复合物的比电容。探讨了聚合条件及溶液组成对产物性能的影响。采用扫描电镜、透射电镜、红外光谱等手段对复合物的结构与形貌进行了表征,研究了所得复合物的电容性质。结果表明,在最佳条件下,所得复合物的比电容高达1576 F/g。
Polypyrrole/tellurium(PPy/Te) nanocomposite was prepared using TeO_2 as the oxidant to pyrrole in acidic aqueous phase. In process, carbon quantum dots were added in order to enhance the conductivity of nanocomposite, and the remainder TeO_2 increased the specific capacitance of nanocomposite due to the formation of Te/Te~(4+) redox couple. The effect of reaction conditions and the solution composition on the property of nanocomposite was explored. The composition and morphology of nanocomposite were characterized by scanning electron microscope, transmission electron microscopy and fourier transform infrared spectrometer. Significantly, the capacitive property of the nanocomposite was studied, and the results show that the PPy/Te nanocomposite obtained optimum condition put up high specific capacitance(1576 F/g).
Polypyrrole/tellurium(PPy/Te) nanocomposite was prepared using TeO_2 as the oxidant to pyrrole in acidic aqueous phase. In process, carbon quantum dots were added in order to enhance the conductivity of nanocomposite, and the remainder TeO_2 increased the specific capacitance of nanocomposite due to the formation of Te/Te~(4+) redox couple. The effect of reaction conditions and the solution composition on the property of nanocomposite was explored. The composition and morphology of nanocomposite were characterized by scanning electron microscope, transmission electron microscopy and fourier transform infrared spectrometer. Significantly, the capacitive property of the nanocomposite was studied, and the results show that the PPy/Te nanocomposite obtained optimum condition put up high specific capacitance(1576 F/g).
引文
[1]Keskinen J.;Tuurala S.;Sj?din M.;Kiri K.;Nyholm L.;Flyktman T.;Str?mme M.;Smolander M.Synthetic Metals.2015,203:192.