高压放电与乙二胺合钴协同脱除烟气NO传质机制模型
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- 英文论文题名：Modelling of corona discharge combined with cobalt ethylenediamine solutions for the removal of NO from simulated flue gas
- 论文作者：王淑媛 ; 唐志鹏 ; 李济吾
- 英文论文作者：Wang Shu-yuan ; Tang Zhi-peng ; Li Ji-wu ; College of Environmental Science and Engineering ; Zhejiang Gongshang University
- 年：2015
- 作者机构：浙江工商大学环境学院;
- 论文关键词：高压放电 ; 乙二胺合钴 ; NO ; 效率模型 ; 脱硝效率
- 英文论文关键词：corona discharge ; cobalt ethylenediamine ; NO ; NO removal efficiency
- 会议召开时间：2015-08-12
- 会议录名称：静电放电：从地面新技术应用到空间卫星安全防护—中国物理学会第二十届全国静电学术会议论文集
- 语种：中文
- 分类号：X701
- 学会代码：WLJD
- 会议名称：静电放电 ; 从地面新技术应用到空间卫星安全防护—中国物理学会第二十届全国静电学术会议
- 会议地点：中国河北石家庄
- 主办单位：中国物理学会静电专业委员会
- 学会名称：中国物理学会静电专业委员会
- 页数：6
- 文件大小：617k
- 原文格式：D
- 会议级别：全国
摘要
建立与验证高压电晕放电与乙二胺合钴协同脱除烟气中NO的传质机理模型,指导烟气脱硝的实际应用。结合双模理论与实验研究,探究了NO在电场作用下的迁移过程和液相中的化学反应,探讨放电电压、水流量、乙二胺合钴浓度对NO脱除效率的影响。结果表明,NO脱除效率随着放电电压,乙二胺合钴浓度的增加而增加,NO脱除效率随着水流量的增加而缓慢增加,与模型公式计算出的结果基本相一致。建立了高压放电与乙二胺合钴协同脱除模拟烟气中NO传质模型,实验验证了电压、水流量、乙二胺合钴浓度等参数对脱除NO的影响。实验结果与模型公式计算出的结果基本相一致。
The aim of this research was to study the modelling of corona discharge combined with cobalt ethylenediamine solutions for the removal of NO from simulated flue gas.Based on the double film theory,a novelty formula was established to describe the mass-transfer process for the NO removal efficiency from simulated flue gas by corona discharge combined with cobalt ethylenediamine solution.The effect of discharge voltage,concentration of cobalt ethylenediamine and water flow on the removal efficiency of NO were investigated.It was seen that NO removal efficiency increased with the increasing of discharge voltage and the concentration of ethylenediamine solution,slightly increased with the increase in the water flow rate,which were fit to the calculated results of theoretical model.The novelty formula was established to describe a mass-transfer process for the NO removal efficiency from simulated flue gas by corona discharge combined with cobalt ethylenediamine solution.It was seen that the parameters of model had been tested experimentally and the experimental data were well in accord with the calculated results of theoretical model on the whole.
The aim of this research was to study the modelling of corona discharge combined with cobalt ethylenediamine solutions for the removal of NO from simulated flue gas.Based on the double film theory,a novelty formula was established to describe the mass-transfer process for the NO removal efficiency from simulated flue gas by corona discharge combined with cobalt ethylenediamine solution.The effect of discharge voltage,concentration of cobalt ethylenediamine and water flow on the removal efficiency of NO were investigated.It was seen that NO removal efficiency increased with the increasing of discharge voltage and the concentration of ethylenediamine solution,slightly increased with the increase in the water flow rate,which were fit to the calculated results of theoretical model.The novelty formula was established to describe a mass-transfer process for the NO removal efficiency from simulated flue gas by corona discharge combined with cobalt ethylenediamine solution.It was seen that the parameters of model had been tested experimentally and the experimental data were well in accord with the calculated results of theoretical model on the whole.
引文
[1]Man C K,Gibbins J R,Witkamp J G,et al.Coal characterization for NOx prediction in air-staged combustion of pulverized coals,Fuel,2005,84(17):2190-2195.
[2]Streets D G,Hao J M,Wu Y,et al.Anthropogenic mercury emissions in China[J],Atmos.Environ,2005,39(40):7789-7806.
[3]Irfan M F,Mjalli F S,Kim,S D.Modeling of NH3-NO-SCR reaction over Cu O/γ-Al2O3catalyst in a bubbling fluidized bed reactor using artificial intelligence techniques[J].Fuel,2012,93:245-251
[4]Jiang Y,Gao X,Zhang Y B,et al.Effects of Pb Cl2on selective catalytic reduction of NO with NH3over vanadia-based catalysts[J].J.Hazard.Mater,2014,274(15):270-278.
[5]Masuda S,Nakao H.Control of NOx by positive and negative pulsed corona discharge[J].IEEE/IASAnnu.Conf.1986,26(2):173-182.
[6]Wang R Y,Zhang B A,Sun B,et al.Apparent energy yield of a high efficiency pulse generator with respect to SO2 and NOx removal[J].J.Electrostat,1995,34(4):355-366.
[7]Mok Y S,Ham S W.Conversion of NO to NO2 in air by a pulsed corona discharge process[J].Chem.Eng.Sci,1998,53(9):1667-1678.
[8]Sun H,Felix H,Nasciuti A,et al.Reduction of NO/NO2&SO2 and destruction of VOCs&PCDD/F in industrial flue gas by electrical discharge[J].Chemosphere,1998,37(9-12):2351-2359.
[9]Kim Y S,Peek M S,Yoo J S,et al.Development of demonstration plant using non-thermal plasma process to remove SO2 and NOx from flue gas[J].J.Adv.Oxid.Technol,2006,6:35-40.
[10]聂勇,汪晶毅,钟侃,等.等离子体辅助催化还原NOX系统的优化[J].高压电技术,2008,34(2):359-362.
[11]王晓臣,商克峰.应用脉冲放电等离子体氧化NO、SO2的影响因素[J].高电压技术,2009,35(5):1122-1126.
[12]Kaczur J J.Oxidation chemistry of chloric acid in NOx/SOx and air toxic metal removal from gas streams[J].Environ.Prog,1996,15(4):245-254.
[13]Martinez A I,Deshpande B K.Kinetic modeling of H2O2 enhanced oxidation of flue gas elemental mercury[J].Fuel Proc.Technol,2007,88(10):982-987.
[14]Zhao Y,Guo T X,Chen Z Y,et al.Simultaneous removal of SO2 and NO using M/Na Cl O2 complex absorbent[J].Chem.Eng.J,2010,160(1):42-47.
[15]Zhang L L,Wang J X,Sun Q,et al.Removal of nitric oxide in rotating packed bed by ferrous chelate solution[J].Chem.Eng.J,2012,181-182:624-629.
[16]Ding J,Zhong Q,Zhang S L,et al.Simultaneous removal of NOX and SO2 from coal-fired flue gas by catalytic oxidation-removal Process with H2O2[J].Chem.Eng.J,2014,243:176-182.
[17]Long X L,Xiao W D,Yuan W K.Removal of sulfur dioxide and nitric oxide using cobalt ethylenediamine solution[J].Ind.Eng.Chem.Res,2005,44(4):686-691.
[18]Long X L,Xin Z L,Chen M B,et al.Nitric oxide absorption into cobalt ethylenediamine solution[J].Sep.Puri.Technol,2007,55(2):226-231.
[19]Liu F,Wang W C,Zheng W,et al.Optical study of radicals(OH,O,H,N)in a needle-plate negative pulsed streamer corona discharge[J].Plasma.Chem.Plasma.Process,2006,26(5):469-480.
[20]Yu C J,Xu F,Luo Z Y,et al.Influences of water vapor and fly ash addition on NO and SO2 gas conversion efficiencies enhanced by pulsed corona discharge[J].J.Electrostat,2009,67(6):829-834.
[21]Kim H,Jun H,Sakaguchi Y,et al.Simultaneous oxidization of NOx and SO2 by a new non-thermal plasma reactor enhanced by catalyst and additive[J].Plasma Sci.Technol,2008,10:53-56.
[22]Lonyi F,Solt H E,Valyon J,et al.The SCR of NOwith methane over In,H-and Co,In,H-ZSM-5catalysts:The promotional effect of cobalt[J].Appl.Catal.B-Environ,2012,117-118:212-223.
[23]Sun W,Pashaie B,Dhali S K,et al.Non-thermal plasma remediation of SO2/NO using a dielectric-barrier discharge[J].J.Appl.Phys,1996,79(7),3438.
[24]Mok Y S,Nam I S.Modeling of pulsed corona discharge process for the removal of nitric oxide and sulfur dioxide[J].Chem.Eng.J,2002,85(11):87-97.
[25]Derakhshesh M,Abedi J,Omidyeganeh M.Modeling of hazardous air pollutant removal in the pulsed corona discharge[J].Phys.Lett.A,2009,373(11):1051-1057.
[26]李济吾,俞杰,樊磊.高压电晕液膜放电产生OH·的检测技术研究[J].高电压技术,2012,38(7):20896-20900.
[27]Li J W,Fan L.Modeling of corona discharge combined with Mn2+catalysis for the removal of SO2 from simulated flue gas[J].Chemosphere,2013,91(9):1374-2379.
[28]Levenspiel O.Godfrey J H.A gradientless contactor for experimental study of interphase mass transfer with/without reaction[J].Chem.Eng.Sci,1974,29(8):1723-1730.
[2]Streets D G,Hao J M,Wu Y,et al.Anthropogenic mercury emissions in China[J],Atmos.Environ,2005,39(40):7789-7806.
[3]Irfan M F,Mjalli F S,Kim,S D.Modeling of NH3-NO-SCR reaction over Cu O/γ-Al2O3catalyst in a bubbling fluidized bed reactor using artificial intelligence techniques[J].Fuel,2012,93:245-251
[4]Jiang Y,Gao X,Zhang Y B,et al.Effects of Pb Cl2on selective catalytic reduction of NO with NH3over vanadia-based catalysts[J].J.Hazard.Mater,2014,274(15):270-278.
[5]Masuda S,Nakao H.Control of NOx by positive and negative pulsed corona discharge[J].IEEE/IASAnnu.Conf.1986,26(2):173-182.
[6]Wang R Y,Zhang B A,Sun B,et al.Apparent energy yield of a high efficiency pulse generator with respect to SO2 and NOx removal[J].J.Electrostat,1995,34(4):355-366.
[7]Mok Y S,Ham S W.Conversion of NO to NO2 in air by a pulsed corona discharge process[J].Chem.Eng.Sci,1998,53(9):1667-1678.
[8]Sun H,Felix H,Nasciuti A,et al.Reduction of NO/NO2&SO2 and destruction of VOCs&PCDD/F in industrial flue gas by electrical discharge[J].Chemosphere,1998,37(9-12):2351-2359.
[9]Kim Y S,Peek M S,Yoo J S,et al.Development of demonstration plant using non-thermal plasma process to remove SO2 and NOx from flue gas[J].J.Adv.Oxid.Technol,2006,6:35-40.
[10]聂勇,汪晶毅,钟侃,等.等离子体辅助催化还原NOX系统的优化[J].高压电技术,2008,34(2):359-362.
[11]王晓臣,商克峰.应用脉冲放电等离子体氧化NO、SO2的影响因素[J].高电压技术,2009,35(5):1122-1126.
[12]Kaczur J J.Oxidation chemistry of chloric acid in NOx/SOx and air toxic metal removal from gas streams[J].Environ.Prog,1996,15(4):245-254.
[13]Martinez A I,Deshpande B K.Kinetic modeling of H2O2 enhanced oxidation of flue gas elemental mercury[J].Fuel Proc.Technol,2007,88(10):982-987.
[14]Zhao Y,Guo T X,Chen Z Y,et al.Simultaneous removal of SO2 and NO using M/Na Cl O2 complex absorbent[J].Chem.Eng.J,2010,160(1):42-47.
[15]Zhang L L,Wang J X,Sun Q,et al.Removal of nitric oxide in rotating packed bed by ferrous chelate solution[J].Chem.Eng.J,2012,181-182:624-629.
[16]Ding J,Zhong Q,Zhang S L,et al.Simultaneous removal of NOX and SO2 from coal-fired flue gas by catalytic oxidation-removal Process with H2O2[J].Chem.Eng.J,2014,243:176-182.
[17]Long X L,Xiao W D,Yuan W K.Removal of sulfur dioxide and nitric oxide using cobalt ethylenediamine solution[J].Ind.Eng.Chem.Res,2005,44(4):686-691.
[18]Long X L,Xin Z L,Chen M B,et al.Nitric oxide absorption into cobalt ethylenediamine solution[J].Sep.Puri.Technol,2007,55(2):226-231.
[19]Liu F,Wang W C,Zheng W,et al.Optical study of radicals(OH,O,H,N)in a needle-plate negative pulsed streamer corona discharge[J].Plasma.Chem.Plasma.Process,2006,26(5):469-480.
[20]Yu C J,Xu F,Luo Z Y,et al.Influences of water vapor and fly ash addition on NO and SO2 gas conversion efficiencies enhanced by pulsed corona discharge[J].J.Electrostat,2009,67(6):829-834.
[21]Kim H,Jun H,Sakaguchi Y,et al.Simultaneous oxidization of NOx and SO2 by a new non-thermal plasma reactor enhanced by catalyst and additive[J].Plasma Sci.Technol,2008,10:53-56.
[22]Lonyi F,Solt H E,Valyon J,et al.The SCR of NOwith methane over In,H-and Co,In,H-ZSM-5catalysts:The promotional effect of cobalt[J].Appl.Catal.B-Environ,2012,117-118:212-223.
[23]Sun W,Pashaie B,Dhali S K,et al.Non-thermal plasma remediation of SO2/NO using a dielectric-barrier discharge[J].J.Appl.Phys,1996,79(7),3438.
[24]Mok Y S,Nam I S.Modeling of pulsed corona discharge process for the removal of nitric oxide and sulfur dioxide[J].Chem.Eng.J,2002,85(11):87-97.
[25]Derakhshesh M,Abedi J,Omidyeganeh M.Modeling of hazardous air pollutant removal in the pulsed corona discharge[J].Phys.Lett.A,2009,373(11):1051-1057.
[26]李济吾,俞杰,樊磊.高压电晕液膜放电产生OH·的检测技术研究[J].高电压技术,2012,38(7):20896-20900.
[27]Li J W,Fan L.Modeling of corona discharge combined with Mn2+catalysis for the removal of SO2 from simulated flue gas[J].Chemosphere,2013,91(9):1374-2379.
[28]Levenspiel O.Godfrey J H.A gradientless contactor for experimental study of interphase mass transfer with/without reaction[J].Chem.Eng.Sci,1974,29(8):1723-1730.