偏高岭土基地聚合物吸附铜离子的行为研究
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- 英文论文题名：Study on the behavior of adsorption of Cu~(2+) to Geopolymers
- 论文作者：李海宇 ; 宋卫锋 ; 简静仪 ; 杨梓亨 ; 郑伟聪 ; 周思宇
- 英文论文作者：LI Hai-yu ; SONG Wei-feng ; JIAN Jing-yi ; YANG Zi-heng ; ZHENG Wei-cong ; ZHOU Si-yu ; College of Environmental Science and Engineering ; Guangdong University of Technology
- 年：2016
- 作者机构：广东工业大学环境科学与工程学院;
- 论文关键词：地聚合物 ; 吸附 ; 重金属 ; 动力学 ; 热力学
- 英文论文关键词：geopolymers ; adsorbent ; heavy metal ; dynamics ; thermodynamics
- 会议召开时间：2016-12-01
- 会议录名称：第六届重金属污染防治及风险评价研讨会暨重金属污染防治专业委员会2016年学术年会论文集
- 语种：中文
- 分类号：O647.33;X703
- 学会代码：HJKP
- 会议名称：第六届重金属污染防治及风险评价研讨会暨重金属污染防治专业委员会2016年学术年会
- 会议地点：中国福建厦门
- 主办单位：中国环境科学学会
- 学会名称：中国环境科学学会
- 页数：8
- 文件大小：11993k
- 原文格式：D
- 会议级别：全国
摘要
地聚合物是一类新兴的重金属吸附剂。为了更好的理解地聚合物对水中Cu~(2+)的吸附规律,本文以偏高岭土为原料,以硅酸钠和氢氧化钠为激活剂制备地聚合物,利用吸附等温式、动力学公式、热力学公式、Elovich公式和Weber-Morris公式,揭示地聚合物吸附Cu~(2+)的吸附方式及过程。结果表明:Cu~(2+)理论最大吸附量是40.161mg·g~(-1);吸附动力学满足表观二级动力学方程;Cu~(2+)吸附过程分为四步,在0min~0.5min内存在一个快速吸附的过程,0.5min~3min内Cu~(2+)出现了释放,3min~30min Cu~(2+)去除率随时间增加,并在30min后Cu~(2+)吸附逐渐达到平衡;地聚合物对Cu~(2+)的吸附属于物理吸附,吸附过程自发吸热。
The kinetics and thermodynamics of the adsorption isotherm of geopolymers on the Cu~(2+) adsorption process were studied in this paper. The results showed that the adsorption process was in accordance with the Freundlich adsorption isotherm equation. The adsorption capacity of Cu~(2+) was 40.161mg·g~(-1), and adsorption process meet the pseudo-second-order kinetics equation. Elovich formula, Weber-Morris formula and dynamic boundary formula showed that the adsorption process of Cu~(2+) was divided into four steps. The rapid adsorption of Cu~(2+) by geopolymers was appeared in first 0.5min. Gibbs free energy change indicate that the geopolymers of Cu~(2+) adsorption was a spontaneous process. Adsorption of Cu~(2+) was affected the electron cloud of silicon and aluminum, but do not changed the way they connection.
The kinetics and thermodynamics of the adsorption isotherm of geopolymers on the Cu~(2+) adsorption process were studied in this paper. The results showed that the adsorption process was in accordance with the Freundlich adsorption isotherm equation. The adsorption capacity of Cu~(2+) was 40.161mg·g~(-1), and adsorption process meet the pseudo-second-order kinetics equation. Elovich formula, Weber-Morris formula and dynamic boundary formula showed that the adsorption process of Cu~(2+) was divided into four steps. The rapid adsorption of Cu~(2+) by geopolymers was appeared in first 0.5min. Gibbs free energy change indicate that the geopolymers of Cu~(2+) adsorption was a spontaneous process. Adsorption of Cu~(2+) was affected the electron cloud of silicon and aluminum, but do not changed the way they connection.
引文
[1]D.Khale,R.Chaudhary.Mechanism of geopolymerization and factors influencing its development:a review[J].Journal of Materials Science,2007,42(3):729-746.
[2]P.Palmero,A.Formia,P.Antonaci,et al.Geopolymer technology for application-oriented dense and lightened materials.Elaboration and characterization[J].Ceramics International,2015,41(10):12967-12979.
[3]Z.Yunsheng,S.Wei,C.Qianli,et al.Synthesis and heavy metal immobilization behaviors of slag based geopolymer[J].J Hazard Mater,2007,143(1-2):206-213.
[4]郑娟荣,杨长利,陈有志.碱激发胶凝材料抗硫酸盐侵蚀机理的探讨[J].郑州大学学报,2012,33(03):1-5.
[5]M.Sarkar,K.Dana,S.Das.Microstructural and phase evolution in metakaolin geopolymers with different activators and added aluminosilicate fillers[J].Journal of Molecular Structure,2015,1098 110-118.
[6]F.J.López,S.Sugita,M.Tagaya,et al.Metakaolin-Based Geopolymers for Targeted Adsorbents to Heavy Metal Ion Separation[J].Journal of Materials Science and Chemical Engineering,2014,02(07):16-27.
[7]Z.H.Zhang,H.J.Zhu,C.H.Zhou,et al.Geopolymer from kaolin in China:An overview[J].Applied Clay Science,2016,119 31-41.
[8]X.Yao,Z.Zhang,H.Zhu,et al.Geopolymerization process of alkali–metakaolinite characterized by isothermal calorimetry[J].Thermochimica Acta,2009,493(1-2):49-54.
[9]J.W.Phair,J.S.J.v.Deventer.Characterization of fly-ash-based geopolymeric binders activated with sodium aluminate[J].Ind.Eng.Chem.Res.,2002,41 4242-4251.
[10]B.I.El-Eswed,R.I.Yousef,M.Alshaaer,et al.Stabilization/solidification of heavy metals in kaolin/zeolite based geopolymers[J].International Journal of Mineral Processing,2015,137 34-42.
[11]徐子芳,杨政,邹小童,等.煤系废物地聚合物稳定固化重金属离子效果研究[J].环境科学学报,2015,35(3):812-818.
[12]金漫彤,金赞芳,黄彩菊.地聚合物固化重金属Pb2+的研究[J].环境学科,2011,32(5):1448-1453.
[13]T.W.Cheng,M.L.Lee,M.S.Ko,et al.The heavy metal adsorption characteristics on metakaolin-based geopolymer[J].Applied Clay Science,2012,56 90-96.
[14]S.Andrejkovi?ová,A.Sudagar,J.Rocha,et al.The effect of natural zeolite on microstructure,mechanical and heavy metals adsorption properties of metakaolin based geopolymers[J].Applied Clay Science,2016,126 141-152.
[15]B.D.Williams,J.J.Neeway,M.M.V.Snyder,et al.Mineral assemblage transformation of a metakaolin-based waste form after geopolymer encapsulation[J].Journal of Nuclear Materials,2016,473320-332.
[16]C.Tippayasam,P.Balyore,P.Thavorniti,et al.Potassium alkali concentration and heat treatment affected metakaolin-based geopolymer[J].Construction and Building Materials,2016,104 293-297.
[17]曹征良,李伟文,陈玉伦.偏高岭土在混凝土中的应用[J].深圳大学学报,2004,21(02):183-186.
[18]M.N.Mu?ek,S.Svilovi?,M.Ugrina,et al.Removal of copper and cobalt ions by fly ash-based geopolymer from solutions-equilibrium study[J].Desalination and Water Treatment,2015,57(23):10689-10699.
[19]H.Javadian,F.Ghorbani,H.-a.Tayebi,et al.Study of the adsorption of Cd(II)from aqueous solution using zeolite-based geopolymer,synthesized from coal fly ash;kinetic,isotherm and thermodynamic studies[J].Arabian Journal of Chemistry,2015,8(6):837-849.
[20]J.Wang,Q.Li,M.M.Li,et al.Competitive adsorption of heavy metal by extracellular polymeric substances(EPS)extracted from sulfate reducing bacteria[J].Bioresour Technol,2014,163 374-6.
[21]Y.S.Ho,G.Mc Kay.Sorption of dye from aqueous solution by peat[J].Chemical Engineering Journal,1998,70 115-124.
[22]M.Arami,N.Y.Limaee,N.M.Mahmoodi,et al.Removal of dyes from colored textile wastewater by orange peel adsorbent:equilibrium and kinetic studies[J].J Colloid Interface Sci,2005,288(2):371-6.
[23]O.Gulnaz,A.Kaya,F.Matyar,et al.Sorption of basic dyes from aqueous solution by activated sludge[J].J Hazard Mater,2004,108(3):183-188.
[24]C.Tien,B.V.Ramarao.Further examination of the relationship between the Langmuir kinetics and the Lagergren and the second-order rate models of batch adsorption[J].Separation and Purification Technology,2014,136 303-308.
[25]R.-L.Tseng,F.-C.Wu,R.-S.Juang.Characteristics and applications of the Lagergren's first-order equation for adsorption kinetics[J].Journal of the Taiwan Institute of Chemical Engineers,2010,41(6):661-669.
[26]Y.S.Ho,G.Mc Kay.Pseudo-second order model for sorption processes[J].Process Biochemistry,1999,34451-465.
[27]H.Runtti,S.Tuomikoski,T.Kangas,et al.Chemically activated carbon residue from biomass gasification as a sorbent for iron(II),copper(II)and nickel(II)ions[J].Journal of Water Process Engineering,2014,412-24.
[28]王春峰,李健生,王连军,等.粉煤灰合成Na A型沸石对重金属离子的吸附动力学[J].中国环境科学,2009,29(1):36-41.
[29]T.Luukkonen,H.Runtti,M.Niskanen,et al.Simultaneous removal of Ni(II),As(III),and Sb(III)from spiked mine effluent with metakaolin and blast-furnace-slag geopolymers[J].J Environ Manage,2016,166579-88.
[30]林建伟,詹艳慧,陆霞.锆改性沸石对水中磷酸盐和铵的吸附特性[J].中国环境科学,2012,32(11):2023-2031.
[31]李克亮,仝玉萍.铜对地聚合物化学结构的影响[J].建筑材料学报,2014,17(4):711-714.
[32]T.Bakharev.Geopolymeric materials prepared using Class F fly ash and elevated temperature curing[J].Cement and Concrete Research,2005,35(6):1224-1232.
[33]C.K.Yip,G.C.Lukey,J.L.Provis,et al.Effect of calcium silicate sources on geopolymerisation[J].Cement and Concrete Research,2008,38(4):554-564.
[34]W.K.W.Lee,J.S.J.v.Deventer.Use of Infrared Spectroscopy to Study Geopolymerization of Heterogeneous Amorphous Aluminosilicates[J].Langmuir,2003,19 8726-8734.
[35]相波,李义久.吸附等温式在重金属吸附性能研究中的应用[J].有色金属,2007,59(1):77-80.
[36]Y.Yu,Y.-Y.Zhuang,Z.-H.Wang.Adsorption of Water-Soluble Dye onto Functionalized Resin[J].Journal of Colloid and Interface Science,2001,242(2):288-293.
[2]P.Palmero,A.Formia,P.Antonaci,et al.Geopolymer technology for application-oriented dense and lightened materials.Elaboration and characterization[J].Ceramics International,2015,41(10):12967-12979.
[3]Z.Yunsheng,S.Wei,C.Qianli,et al.Synthesis and heavy metal immobilization behaviors of slag based geopolymer[J].J Hazard Mater,2007,143(1-2):206-213.
[4]郑娟荣,杨长利,陈有志.碱激发胶凝材料抗硫酸盐侵蚀机理的探讨[J].郑州大学学报,2012,33(03):1-5.
[5]M.Sarkar,K.Dana,S.Das.Microstructural and phase evolution in metakaolin geopolymers with different activators and added aluminosilicate fillers[J].Journal of Molecular Structure,2015,1098 110-118.
[6]F.J.López,S.Sugita,M.Tagaya,et al.Metakaolin-Based Geopolymers for Targeted Adsorbents to Heavy Metal Ion Separation[J].Journal of Materials Science and Chemical Engineering,2014,02(07):16-27.
[7]Z.H.Zhang,H.J.Zhu,C.H.Zhou,et al.Geopolymer from kaolin in China:An overview[J].Applied Clay Science,2016,119 31-41.
[8]X.Yao,Z.Zhang,H.Zhu,et al.Geopolymerization process of alkali–metakaolinite characterized by isothermal calorimetry[J].Thermochimica Acta,2009,493(1-2):49-54.
[9]J.W.Phair,J.S.J.v.Deventer.Characterization of fly-ash-based geopolymeric binders activated with sodium aluminate[J].Ind.Eng.Chem.Res.,2002,41 4242-4251.
[10]B.I.El-Eswed,R.I.Yousef,M.Alshaaer,et al.Stabilization/solidification of heavy metals in kaolin/zeolite based geopolymers[J].International Journal of Mineral Processing,2015,137 34-42.
[11]徐子芳,杨政,邹小童,等.煤系废物地聚合物稳定固化重金属离子效果研究[J].环境科学学报,2015,35(3):812-818.
[12]金漫彤,金赞芳,黄彩菊.地聚合物固化重金属Pb2+的研究[J].环境学科,2011,32(5):1448-1453.
[13]T.W.Cheng,M.L.Lee,M.S.Ko,et al.The heavy metal adsorption characteristics on metakaolin-based geopolymer[J].Applied Clay Science,2012,56 90-96.
[14]S.Andrejkovi?ová,A.Sudagar,J.Rocha,et al.The effect of natural zeolite on microstructure,mechanical and heavy metals adsorption properties of metakaolin based geopolymers[J].Applied Clay Science,2016,126 141-152.
[15]B.D.Williams,J.J.Neeway,M.M.V.Snyder,et al.Mineral assemblage transformation of a metakaolin-based waste form after geopolymer encapsulation[J].Journal of Nuclear Materials,2016,473320-332.
[16]C.Tippayasam,P.Balyore,P.Thavorniti,et al.Potassium alkali concentration and heat treatment affected metakaolin-based geopolymer[J].Construction and Building Materials,2016,104 293-297.
[17]曹征良,李伟文,陈玉伦.偏高岭土在混凝土中的应用[J].深圳大学学报,2004,21(02):183-186.
[18]M.N.Mu?ek,S.Svilovi?,M.Ugrina,et al.Removal of copper and cobalt ions by fly ash-based geopolymer from solutions-equilibrium study[J].Desalination and Water Treatment,2015,57(23):10689-10699.
[19]H.Javadian,F.Ghorbani,H.-a.Tayebi,et al.Study of the adsorption of Cd(II)from aqueous solution using zeolite-based geopolymer,synthesized from coal fly ash;kinetic,isotherm and thermodynamic studies[J].Arabian Journal of Chemistry,2015,8(6):837-849.
[20]J.Wang,Q.Li,M.M.Li,et al.Competitive adsorption of heavy metal by extracellular polymeric substances(EPS)extracted from sulfate reducing bacteria[J].Bioresour Technol,2014,163 374-6.
[21]Y.S.Ho,G.Mc Kay.Sorption of dye from aqueous solution by peat[J].Chemical Engineering Journal,1998,70 115-124.
[22]M.Arami,N.Y.Limaee,N.M.Mahmoodi,et al.Removal of dyes from colored textile wastewater by orange peel adsorbent:equilibrium and kinetic studies[J].J Colloid Interface Sci,2005,288(2):371-6.
[23]O.Gulnaz,A.Kaya,F.Matyar,et al.Sorption of basic dyes from aqueous solution by activated sludge[J].J Hazard Mater,2004,108(3):183-188.
[24]C.Tien,B.V.Ramarao.Further examination of the relationship between the Langmuir kinetics and the Lagergren and the second-order rate models of batch adsorption[J].Separation and Purification Technology,2014,136 303-308.
[25]R.-L.Tseng,F.-C.Wu,R.-S.Juang.Characteristics and applications of the Lagergren's first-order equation for adsorption kinetics[J].Journal of the Taiwan Institute of Chemical Engineers,2010,41(6):661-669.
[26]Y.S.Ho,G.Mc Kay.Pseudo-second order model for sorption processes[J].Process Biochemistry,1999,34451-465.
[27]H.Runtti,S.Tuomikoski,T.Kangas,et al.Chemically activated carbon residue from biomass gasification as a sorbent for iron(II),copper(II)and nickel(II)ions[J].Journal of Water Process Engineering,2014,412-24.
[28]王春峰,李健生,王连军,等.粉煤灰合成Na A型沸石对重金属离子的吸附动力学[J].中国环境科学,2009,29(1):36-41.
[29]T.Luukkonen,H.Runtti,M.Niskanen,et al.Simultaneous removal of Ni(II),As(III),and Sb(III)from spiked mine effluent with metakaolin and blast-furnace-slag geopolymers[J].J Environ Manage,2016,166579-88.
[30]林建伟,詹艳慧,陆霞.锆改性沸石对水中磷酸盐和铵的吸附特性[J].中国环境科学,2012,32(11):2023-2031.
[31]李克亮,仝玉萍.铜对地聚合物化学结构的影响[J].建筑材料学报,2014,17(4):711-714.
[32]T.Bakharev.Geopolymeric materials prepared using Class F fly ash and elevated temperature curing[J].Cement and Concrete Research,2005,35(6):1224-1232.
[33]C.K.Yip,G.C.Lukey,J.L.Provis,et al.Effect of calcium silicate sources on geopolymerisation[J].Cement and Concrete Research,2008,38(4):554-564.
[34]W.K.W.Lee,J.S.J.v.Deventer.Use of Infrared Spectroscopy to Study Geopolymerization of Heterogeneous Amorphous Aluminosilicates[J].Langmuir,2003,19 8726-8734.
[35]相波,李义久.吸附等温式在重金属吸附性能研究中的应用[J].有色金属,2007,59(1):77-80.
[36]Y.Yu,Y.-Y.Zhuang,Z.-H.Wang.Adsorption of Water-Soluble Dye onto Functionalized Resin[J].Journal of Colloid and Interface Science,2001,242(2):288-293.