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CoNi@TiO_2核壳结构的合成制备及吸波性能的研究
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摘要
电磁波吸收材料的制备具有重要的理论意义和实际应用价值。理想的吸波材料要同时具备磁损耗与介电损耗并满足阻抗匹配条件,本文利用溶剂热的方法成功制备了磁性CoNi为核、介电TiO_2为壳的核壳结构,测试结果表明该结构具有一定的电磁波吸收性能(在5.5mm处的反射损耗RL=-25dB)。可能的原因如下,首先,由于内核和壳层其自身就具有特有的吸波频段和吸波强度.并且当两种不同的材料构成核壳结构以后,在电磁场的作用下,电子在界面之间的极化、磁的共振等一系列的因素会增强核壳结构材料的相关性能。
Synthesis of Electromagnetic wave(EM-wave) absorption material is significant theoritically and applicatively. An ideal EM-wave absorption material should meet impendence matching including dielectric loss and magnetic loss. In this paper, we have successfully synthesized magnetic Co Ni core and dielectric TiO_2 shell structure via solvothermal method, and this material presents efficient EM-wave absorption at some degree(refiction loss(RL)=-25 d B at the thickness of 5.5 mm). The reasons are as follows. Firstly, for the nature of core and shell materials, they can absorb EM-wave efficiently at certain frequencies, respectively. Secondly, Electronic polarization in the interface of core and shell, as well as magnetic resonance, happens in the present of external electromagentic field, promoting efficient EM-wave absorption.
引文
[1]Lin,Y.;Xu L.;Jiang,Z.;Li,H.;Xie,Z.;Zheng,L.RSC Adv.2015,5:70849.
    [2]Hu,M.;Lin,B.;Yu,S.Nano Res.2008,1:303.

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