混凝-Fenton试剂氧化法预处理高浓度油墨废水

详细信息    查看官网全文

• 英文论文题名：Pretreatment of High Concentrated Ink Printing Wastewater by Coagulation Coupling Fenton Reagent Oxidation
• 论文作者：陈亚利 ; 言海燕 ; 乔瑞平 ; 宋林啸 ; 斯克诚 ; 王艳 ; 宋杨 ; 田华 ; 汤权新 ; 刘豹
• 英文论文作者：Chen Yali ; Yan Haiyan ; Qiao Ruiping ; Song Linxiao ; Si Kecheng ; Wang Yan ; Song Yang ; Tian Hua ; Tang Quanxin ; Liu Bao ; Hunan Yonker Environmental Protection Research Institute Co. ; Ltd. ; Hunan Yonker Environmental Protection Co. ; Ltd. ; Hunan Yonker Water Affairs Co. ; Ltd.
• 年：2016
• 作者机构：湖南永清环保研究院有限责任公司;湖南永清环保股份有限公司;湖南永清水务有限公司;
• 论文关键词：油墨废水 ; 强化混凝 ; Fenton试剂氧化 ; 可生化性
• 英文论文关键词：ink printing wastewater ; coagulation sedimentation ; Fenton reagent oxidation ; biodegradability
• 会议召开时间：2016-10-25
• 会议录名称：2016中国水处理技术研讨会暨第36届年会论文集
• 语种：中文
• 分类号：X78
• 学会代码：GSCL
• 会议名称：2016中国水处理技术研讨会暨第36届年会
• 会议地点：中国江苏南京
• 主办单位：中国化工学会工业水处理专业委员会、中国石油学会海洋石油分会
• 学会名称：中国化工学会工业水处理专业委员会
• 页数：8
• 文件大小：906k
• 原文格式：D
• 会议级别：全国

摘要

采用强化混凝联用Fenton试剂氧化技术处理油墨废水,优化了混凝条件,考察了后续Fenton试剂氧化效果。强化混凝最佳条件为:p H5.62,PFS投加量2000mg/L,CPAM投加量5mg/L,混凝处理后CODCr和色度去除率分别为76.54%和95%;处理后上清液进行Fenton试剂氧化,在最经济的适用条件下CODCr去除率为55.43%。实验表明强化混凝与Fenton试剂联用可以有效预处理高浓度油墨废水,CODCr和色度总去除率分别达89.55%和98%以上,总BOD5/CODCr由0.025提高至0.350以上,废水可生化性显著提高,满足后续生化处理进水要求。
The combined coagulation and Fenton reagent oxidation process was adopted to pretreat ink printing wastewater,the coagulation condition was optimized, and the effect of the subsequent Fenton reagent oxidation was explored. The the optimum coagulation condition was: p H5.62, PFS dosage 2000mg/L, CPAM dosage 5mg/L. After coagulation treatment, CODCr and colority removal efficiency reached 76.54% and 95%, respectively. The supernatant after coagulation sedimentation was then treated by Fenton reagent oxidation,under the most economical condition, CODCr removal efficiency reached 55.43%. Research showed that the combined coagulation and Fenton reagent oxidation process is an effective pretreatment method for high concentration ink printing wastewater,the total removal efficiency of CODCr and colority reached 89.55% and 98%, respectively, and BOD5/CODCr was also raised from 0.025 up to 0.350,the biodegradability of the wastewater was improved greatly, and the treated effluent could meet the subsequent biological oxidation process.

引文

[1]蔡炎兴,张振家.混凝沉淀-生物接触氧化法处理水性油墨废水的研究[J].上海化工,2006,31(7):13-17.
    [2]Szabo.B.Application for printing inks,in Polymer dispersions and their industrial applications[M].(eds D.Urban and K.Takamura).Wiley-VCH,Germany,2002,103–104.
    [3]孙更民,潘建芳,顾军.物化—生化法处理油墨生产废水[J].苏州科技学院学报(工程技术版),2003,16(3):36-39.
    [4]杨鹏,王中琪,王军.酸析-电催化法处理水性油墨废水的试验研究[J].工业水处理,2013,33(6):51-54.
    [5]王顺,柳荣展,张宾等.混凝-热固化-微电解法处理高浓度水性油墨废水[J].水处理技术,2015,41(4):122-124.
    [6]唐璐,舒晓春.酸析+臭氧+MBR工艺处理手机显示屏厂废水[J].环境科学与技术,2011(s1):211-212.
    [7]杨鹏,王中琪,王军.酸析-电催化法处理水性油墨废水的试验研究[J].工业水处理,2013,33(6):51-54.
    [8]张金朝,张文晖.混凝-絮凝工艺处理水性油墨废水[J].中国造纸,2016,35(3):13-18.
    [9]Ma X,Xia H.Optimization of coagulation process for treatment of water-based printing ink wastewater[J].Bioinformatics&Biomedical Engineering International Conference on,2010,12(11):1-4.
    [10]朱乐辉,余保财,张玉等.混凝+厌氧+好氧组合工艺处理油墨废水的工程实例[J].环境工程,2011,29((2):51-54.
    [11]汤纯鹏,蔡凌,钮静等.颜料、油墨废水物化、生化法综合治理技术[J].城市环境与城市生态,1999,12(3):1-3.
    [12]李英.臭氧氧化法去除油墨废水色度的研究[J].工业用水与废水,2012,43(6):44-46.
    [13]Ma X J,Xia H L.Treatment of water-based printing ink wastewater by Fenton process combined with coagulation[J].Journal of Hazardous Materials,2009,162(1):86-390.
    [14]Gao A F,Liang X L,Zhang Y,et al.Optimization of printing-ink wastewater treatment by Fenton oxidation using response surface methodology[J].Environmental Science&Technology,2013,36(7):117-116.
    [15]赵忠强,芦小山,左卫雄.电氧化法处理水性油墨废水的研究[J].工业水处理,2015,35(7):72-75.
    [16]石键韵,陈欣义.微电解处理技术在PCB油墨废水预处理的试验研究[J].广东化工,2012,39(2):237-238.
    [17]刘鹏,李朝林,陆钢等.紫外催化湿式氧化工艺降解油墨废水[J].环境工程学报,2012,6(7):2265-2270.
    [18]M.A.El Khateeb.Treatment of ink wastewater via heterogeneous photocatalytic oxidation[J].Desalination&Water Treatment,2012,7(1):1-5.
    [19]韩芳,耿翠玉,乔瑞平等.混凝-臭氧联用技术深度处理煤气化废水的研究[J].工业给排水,2015,41(10):58-61.