水性聚氨酯防霉涂料的功能设计与研究进展
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- 英文论文题名：The Latest Progress in Functional Design and Application of Waterborne Polyurethane Mildew Proof Coating
- 论文作者：夏峰 ; 杨建军
- 英文论文作者：XIA Feng ; YANG Jianjun ; School of Chemistry and Chemical Engineering of Anhui University & Key Laboratory of Environment-Friendly Polymer Materials of Anhui Province
- 年：2016
- 作者机构：安徽大学化学化工学院与安徽省绿色高分子材料重点实验室;
- 论文关键词：水性聚氨酯 ; 防霉涂料 ; 防霉机理 ; 功能设计
- 英文论文关键词：waterborne polyurethane ; mildew proof coating ; anti-mold mechanism ; functional design
- 会议召开时间：2016-07-30
- 会议录名称：中国聚氨酯工业协会第十八次年会论文集
- 语种：中文
- 分类号：TQ637
- 学会代码：JAZG
- 会议名称：中国聚氨酯工业协会第十八次年会
- 会议地点：中国上海
- 主办单位：中国聚氨酯工业协会
- 学会名称：中国聚氨酯工业协会
- 页数：7
- 文件大小：1002k
- 原文格式：D
- 会议级别：全国
摘要
综述了近几年来水性聚氨酯在防霉涂料中的功能化设计和研究性进展。首先分别阐述了合成路线中重要助剂和接枝改性聚氨酯发挥防霉作用的可能性机理,总结了国内外多种类型的防霉杀菌水性聚氨酯的合成工艺与最新成果,最后结合防霉工艺的研究现状展望了防霉涂料未来发展趋势,指出了防霉水性聚氨酯的功能化设计方向。
This paper reviewed the recent years' waterborne polyurethane(WPU)'s functional design and application on the mildew proof coating.Article firstly elaborated the important auxiliaries of synthetic route and grafting modified polyurethane playing mildew proof's role in likely mechanism,summarized the domestic and foreign various types of mold bactericidal waterborne polyurethane's synthetic process and the latest achievements.Finally,this paper,combined with the research status of anti-mold technology,prospected the trend of mildew proof coating's development and pointed out functional design's direction on waterborne polyurethane.
This paper reviewed the recent years' waterborne polyurethane(WPU)'s functional design and application on the mildew proof coating.Article firstly elaborated the important auxiliaries of synthetic route and grafting modified polyurethane playing mildew proof's role in likely mechanism,summarized the domestic and foreign various types of mold bactericidal waterborne polyurethane's synthetic process and the latest achievements.Finally,this paper,combined with the research status of anti-mold technology,prospected the trend of mildew proof coating's development and pointed out functional design's direction on waterborne polyurethane.
引文
[1]沈浩.防霉抗菌问题(概述)[R].上海:上海涂料染料行业协会年会暨第二届“绿色涂料发展论坛”第二届安全生态染料颜料发展论坛.2013.
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[3]NOREEN A,ZIAK M,ZUBER M,et al.Recent trends in environmentally friendly water-borne polyurethane coatings:A review[J].Korean Journal of Chemical Engineering,2016,33(2):388-400.
[4]CLEMANS D L,RHOADES S J,KENDZORSKI J J,et al.Smart CoatingsⅡ[M].America:ACS,2009.
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[6]杨忠敏.防水涂料助剂的功能特点及应用[J].化学工业,2015,33(2/3):33-37.
[7]朱明露,朱蕙岚,谢海娇,等.水性聚氨酯涂料的智能化发展[J].上海涂料,2015,53(7):23-28.
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[9]MANJUMEENA R,VENKATESAN R,DURAIBABU D,et al.Green nanosilver as reinforcing eco-friendly additive to epoxy coating for augmented anticorrosive and antimicrobial behavior[J].Springer Science+Business Media Dordrecht,2015.
[10]刘成楼,唐国军.调温调湿抗菌净味柔性内墙腻子的研制[J].上海涂料,2013,50(2):9-12.
[11]于艳,焦锋刚.改性水性聚氨酯涂料的研究进展[J].商洛学院学报,2013,27(2):40-44.
[12]赵曦.水性聚氨酯在涂料领域中的应用[J].化工中间体,2015(2):51-52.
[13]WOO G L Y,MITTELMAN MW,SANTERRE J P.Synthesis and characterization of a novel biodegradable antimicrobial polymer[J].Biomaterials,2000,21(19):1235-1246.
[14]PARK D,LARSON A M,KLIBANOV AM,et al.Antiviral and antibacterial polyurethanes of various modalities[J].Appl Biochem Biotechnol,2013,169:1134-1146.
[15]徐昊.水性聚氨酯涂料的研究进展[J].广州化工,2013,41(9):15-17.
[16]张玉,杨建军,吴庆云,等.水性聚氨酯涂料的应用及研究进展[J].聚氨酯工业,2015,30(2):6-10.
[17]LIU He,SONG Jie,SHANG Shibin,et al.Nanocrystal/silver nanoparticle composites as bifunctional nanofillers within waterborne polyurethane[J].ACS Appl Mater Interfaces,2012(4):2413-2419.
[18]YU Houyong,QIN Zongyi,SUN Bin,et al.One-pot green fabrication and antibacterial activity of thermally stable corn-like CNC/Ag nanocomposites[J].Springer Science/Business Media Dordrecht,2014.
[19]NAIK R B,RATNA D.Synthesis of silver nanoparticles embedded novel hyperbranched urethane alkyd-based nanocomposite for high solid antimicrobial coating application[J].American Coatings Association,2015.
[20]张然.纳米银水性抗菌木器涂料的研制与应用[D].广州:广东工业大学,2014.
[21]GAO Jingjing,QU Rongjun,TANG Bo,et al.Control of the aggregation behavior of silver nanoparticles in polyurethane matrix[J].Journal of Nanoparticle Research,2011,13(10):5289-5299.
[22]HAN J G,XIANG Y Q,ZHU Y.New antibacterial composites:waterborne polyurethane/gold nanocomposites synthesized via self-emulsifying method[J].J Inorg Organomet Polym,2014,24:283-290.
[23]王文毅.水性建筑涂料领域的防腐防霉抗藻剂及应用[J].涂料技术与文摘,2015,36(8):34-42.
[24]QIU Shan,DENG Fengxia,XU Shanwen,et al.Degradation of pollutant and antibacterial activity of waterborne polyurethane/doped TiO_2 nanoparticle hybrid films[J].Journal of Wuhan University of Technology-Mater,2015.
[25]XIONG Liang,ZHANG Weide,SHI QingShan,et al.Waterborne polyurethane/NiAl-LDH/ZnO composites with high antibacterial activity[J].Polym Adv Technol,2015,26:495-501.
[26]蔡劲树,魏育福,蔡英进.铝型材用抗菌防霉粉末涂料的研究[R].全国铝合金建筑型材用隔热条、粉、漆等关键辅助材料的选择和质量鉴别方法研讨会,2014.
[27]PEI Lijun,CAI Zhaosheng,SHANG Shibin,et al.Synthesis and performance of allyl dimethyl dehydroabietyl ammonium chloride[J].J Surfact Deterg,2014,17:279-286.
[28]ZHANG Yi,LI Yifan,LI Jiehua,et al.Synthesis and antibacterial characterization of waterborne polyurethanes with gemini quaternary ammonium salt[J].Sci Bull,2015,60(12):1114-1121.coatings from
[29]BAKHSHIH,YEGANEHI H,MEHDIPOUR-ATAEI S,et al.Synthesis and characterization of antibacterial polyurethane coatings from quaternary ammonium salts functionalized soybean oil based polyols[J].Materials Science and Engineering,2013,33(1):153-164.
[30]ZHAO Ruifang,WANG Hai,JI Tianjiao,et al.Biodegradable cationic e-poly-L-lysine-conjugated polymeric nanoparticles as a new effective antibacterial agent[J].Sci Bull,2015,60(2):216-226.
[2]LIU Hungli,A DAI Shenghong,FU Kengyen,et al.Antibacterial properties of silver nanoparticles in three different sizes and their nanocomposites with a new waterborne polyurethane[J].International Journal of Nanomedicine,2010(5):1017-1028.
[3]NOREEN A,ZIAK M,ZUBER M,et al.Recent trends in environmentally friendly water-borne polyurethane coatings:A review[J].Korean Journal of Chemical Engineering,2016,33(2):388-400.
[4]CLEMANS D L,RHOADES S J,KENDZORSKI J J,et al.Smart CoatingsⅡ[M].America:ACS,2009.
[5]张凡,杨建军,吴庆云,等.环保节能型水性聚氨酯建筑涂料研究进展[J].粘接,2014,75(5):75-79.
[6]杨忠敏.防水涂料助剂的功能特点及应用[J].化学工业,2015,33(2/3):33-37.
[7]朱明露,朱蕙岚,谢海娇,等.水性聚氨酯涂料的智能化发展[J].上海涂料,2015,53(7):23-28.
[8]杨建军,张建安,吴庆云,等.功能型水性聚氨酯涂料的设计与应用最新进展[J].涂料工业,2011,41(3):70-74.
[9]MANJUMEENA R,VENKATESAN R,DURAIBABU D,et al.Green nanosilver as reinforcing eco-friendly additive to epoxy coating for augmented anticorrosive and antimicrobial behavior[J].Springer Science+Business Media Dordrecht,2015.
[10]刘成楼,唐国军.调温调湿抗菌净味柔性内墙腻子的研制[J].上海涂料,2013,50(2):9-12.
[11]于艳,焦锋刚.改性水性聚氨酯涂料的研究进展[J].商洛学院学报,2013,27(2):40-44.
[12]赵曦.水性聚氨酯在涂料领域中的应用[J].化工中间体,2015(2):51-52.
[13]WOO G L Y,MITTELMAN MW,SANTERRE J P.Synthesis and characterization of a novel biodegradable antimicrobial polymer[J].Biomaterials,2000,21(19):1235-1246.
[14]PARK D,LARSON A M,KLIBANOV AM,et al.Antiviral and antibacterial polyurethanes of various modalities[J].Appl Biochem Biotechnol,2013,169:1134-1146.
[15]徐昊.水性聚氨酯涂料的研究进展[J].广州化工,2013,41(9):15-17.
[16]张玉,杨建军,吴庆云,等.水性聚氨酯涂料的应用及研究进展[J].聚氨酯工业,2015,30(2):6-10.
[17]LIU He,SONG Jie,SHANG Shibin,et al.Nanocrystal/silver nanoparticle composites as bifunctional nanofillers within waterborne polyurethane[J].ACS Appl Mater Interfaces,2012(4):2413-2419.
[18]YU Houyong,QIN Zongyi,SUN Bin,et al.One-pot green fabrication and antibacterial activity of thermally stable corn-like CNC/Ag nanocomposites[J].Springer Science/Business Media Dordrecht,2014.
[19]NAIK R B,RATNA D.Synthesis of silver nanoparticles embedded novel hyperbranched urethane alkyd-based nanocomposite for high solid antimicrobial coating application[J].American Coatings Association,2015.
[20]张然.纳米银水性抗菌木器涂料的研制与应用[D].广州:广东工业大学,2014.
[21]GAO Jingjing,QU Rongjun,TANG Bo,et al.Control of the aggregation behavior of silver nanoparticles in polyurethane matrix[J].Journal of Nanoparticle Research,2011,13(10):5289-5299.
[22]HAN J G,XIANG Y Q,ZHU Y.New antibacterial composites:waterborne polyurethane/gold nanocomposites synthesized via self-emulsifying method[J].J Inorg Organomet Polym,2014,24:283-290.
[23]王文毅.水性建筑涂料领域的防腐防霉抗藻剂及应用[J].涂料技术与文摘,2015,36(8):34-42.
[24]QIU Shan,DENG Fengxia,XU Shanwen,et al.Degradation of pollutant and antibacterial activity of waterborne polyurethane/doped TiO_2 nanoparticle hybrid films[J].Journal of Wuhan University of Technology-Mater,2015.
[25]XIONG Liang,ZHANG Weide,SHI QingShan,et al.Waterborne polyurethane/NiAl-LDH/ZnO composites with high antibacterial activity[J].Polym Adv Technol,2015,26:495-501.
[26]蔡劲树,魏育福,蔡英进.铝型材用抗菌防霉粉末涂料的研究[R].全国铝合金建筑型材用隔热条、粉、漆等关键辅助材料的选择和质量鉴别方法研讨会,2014.
[27]PEI Lijun,CAI Zhaosheng,SHANG Shibin,et al.Synthesis and performance of allyl dimethyl dehydroabietyl ammonium chloride[J].J Surfact Deterg,2014,17:279-286.
[28]ZHANG Yi,LI Yifan,LI Jiehua,et al.Synthesis and antibacterial characterization of waterborne polyurethanes with gemini quaternary ammonium salt[J].Sci Bull,2015,60(12):1114-1121.coatings from
[29]BAKHSHIH,YEGANEHI H,MEHDIPOUR-ATAEI S,et al.Synthesis and characterization of antibacterial polyurethane coatings from quaternary ammonium salts functionalized soybean oil based polyols[J].Materials Science and Engineering,2013,33(1):153-164.
[30]ZHAO Ruifang,WANG Hai,JI Tianjiao,et al.Biodegradable cationic e-poly-L-lysine-conjugated polymeric nanoparticles as a new effective antibacterial agent[J].Sci Bull,2015,60(2):216-226.
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