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Highly efficient and stable planar perovskite solar cells with large-scale manufacture and low-cost SnO_2 layer towards commercialization viable
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摘要
The past five years have seen the remarkable rise of a new type of hybrid perovskite solar cells(PSCs).However, there still remain challenges for PSCs towards large-scale application and commercialization.The main reasons are the instability of the perovskite film and the lack of large-scale and low-cost manufacture techniques for electron transfer layer(ETL).Tin oxide(SnO_2) has emerged as a promising candidate for ETL, however, systematic exploration of its commercialized application in PSCs is still missing.Here, we prepared SnO_2 ETL through the electron beam evaporation(e-beam) technology,realizing large-scale,low-cost and uniform manufacture which would be available for industrial deployment.A Cs-containing blended perovskite absorber layer was introduced into the PSCs to effectively enhance the ambient stability.As a result, PSCs exhibit a high efficiency of 18.2% without any interface modification, and remarkable long-term stability, which remained 97% of its initial PCE after being stored over 34 days.Our result demonstrated the great potential of the PSCs based on SnO_2 ETL towards commercially viable.
The past five years have seen the remarkable rise of a new type of hybrid perovskite solar cells(PSCs).However, there still remain challenges for PSCs towards large-scale application and commercialization.The main reasons are the instability of the perovskite film and the lack of large-scale and low-cost manufacture techniques for electron transfer layer(ETL).Tin oxide(SnO_2) has emerged as a promising candidate for ETL, however, systematic exploration of its commercialized application in PSCs is still missing.Here, we prepared SnO_2 ETL through the electron beam evaporation(e-beam) technology,realizing large-scale,low-cost and uniform manufacture which would be available for industrial deployment.A Cs-containing blended perovskite absorber layer was introduced into the PSCs to effectively enhance the ambient stability.As a result, PSCs exhibit a high efficiency of 18.2% without any interface modification, and remarkable long-term stability, which remained 97% of its initial PCE after being stored over 34 days.Our result demonstrated the great potential of the PSCs based on SnO_2 ETL towards commercially viable.
引文
[1]F.Ye,H.Chen,F.Xie,W.Tang,M.Yin,J.He,E.Bi,Y.Wang,X.Yang,L.Han,Energy Environ.Sci.2016,9,2295.
    [2]W.Ke,G.Fang,Q.Liu,L.Xiong,P.Qin,H.Tao,J.Wang,H.Lei,B.Li,J.Wan,G.Yang,Y.Yan,Journal of the American Chemical Society2015,137,6730.

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