超短时间阳极氧化制备TiO_2纳米管阵列以及超声协助负载CdS量子点
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- 英文论文题名：Ultrafast anodized titania nanotube arrays and loading with CdS quantum dots by ultrasonication assistance
- 论文作者：曹春斌 ; 章国顺 ; 张苗 ; 孙兆奇
- 英文论文作者：CAO Chunbin ; ZHANG Guoshun ; ZHANG Miao ; SUN Zhaoqi ; School of Sciences ; Anhui Agricultural University ; School of Physics and Material Science ; Anhui University
- 年：2016
- 作者机构：安徽农业大学理学院;安徽大学物理与材料科学学院;
- 论文关键词：阳极氧化 ; TiO2纳米管阵列 ; CdS量子点 ; 光电响应。
- 英文论文关键词：Anodization ; TiO2 nanotube arrays ; Cd S quantum dots ; Photoelectric response
- 会议召开时间：2016-10-21
- 会议录名称：安徽省第四届（2016年）“卓凌杯”真空科技青年创新大赛暨学术研讨会论文集
- 语种：中文
- 分类号：TQ134.11;TB383.1
- 学会代码：AHZK
- 会议名称：安徽省第四届（2016年）“卓凌杯”真空科技青年创新大赛暨学术研讨会
- 会议地点：中国安徽安庆
- 主办单位：安徽省真空学会
- 学会名称：安徽省真空学会
- 页数：13
- 文件大小：11359k
- 原文格式：D
- 会议级别：地方
摘要
采用120 V电压,在含0.4 M F-电解液中阳极氧化Ti片制备了高度有序且结构紧凑的Ti O2纳米管阵列。与传统阳极氧化工艺(60 V,0.27 MF~-)相比,不仅制备时间从数小时缩短到数十秒,而且所得到的TiO_2纳米管阵列与Ti基底结合紧密,光电转化性能也有明显提高。在传统的连续离子层吸附反应法(SILAR)基础上,采用超声协助的U-SILAR方法在Ti O2纳米管阵列表面负载了Cd S量子点。结果表明,与传统SILAR方法相比,U-SILAR方法所负载的CdS量子点尺寸均匀、排列紧密且数量较多;量子点/纳米管阵列体系可见光吸收明显增强,带隙从2.29 eV(SILAR)减小到2.02 eV(U-SILAR);光电流密度显著提高,而且随着光照时间的延长,U-SILAR方法得到的体系光电转化性能稳定。本文工作在优化阳极氧化工艺、提高量子点/纳米管阵列体系光电转化效率和器件性能稳定性方面具有重要的参考价值。
Well-aligned titania nanotube arrays(TNAs) were fabricated by electrochemical anodization at high voltage of 120 V in an electrolyte containing high F-concentration of 0.4 M.Compared to the TNAs obtained by traditional anodic conditions(60 V,0.27 MF~-), the resulted samples show more uniform surface, firmer structure, and stronger adhesion to the Ti substrate.Importantly, the anodization time can be greatly reduced from several hours to tens of seconds.Moreover, based on the conventional method of successive ion layer absorption and reaction(SILAR), ultrasonic assistant successive ion layer absorption and reaction(U-SILAR) wasemployed to load Cd S quantum dots onto TNAs. The results show that the uniform and densely arranged Cd S quantum dots were obtained by U-SILAR method. Furthermore, the visible light absorption and photoelectric response of the quantum dots/TNAs system were obviously enhanced,and the band gap was red shift to 2.02 eV, compared with 2.29 eV by SILAR method. This work will have significant impact on the optimization of the anodization technique and improvement of the photoelectric conversion efficiency of the quantum dots/TNAs system.
Well-aligned titania nanotube arrays(TNAs) were fabricated by electrochemical anodization at high voltage of 120 V in an electrolyte containing high F-concentration of 0.4 M.Compared to the TNAs obtained by traditional anodic conditions(60 V,0.27 MF~-), the resulted samples show more uniform surface, firmer structure, and stronger adhesion to the Ti substrate.Importantly, the anodization time can be greatly reduced from several hours to tens of seconds.Moreover, based on the conventional method of successive ion layer absorption and reaction(SILAR), ultrasonic assistant successive ion layer absorption and reaction(U-SILAR) wasemployed to load Cd S quantum dots onto TNAs. The results show that the uniform and densely arranged Cd S quantum dots were obtained by U-SILAR method. Furthermore, the visible light absorption and photoelectric response of the quantum dots/TNAs system were obviously enhanced,and the band gap was red shift to 2.02 eV, compared with 2.29 eV by SILAR method. This work will have significant impact on the optimization of the anodization technique and improvement of the photoelectric conversion efficiency of the quantum dots/TNAs system.
引文
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[5]G.K.Mor,O.K.Varghese,M.Paulose,K.Shankar,C.A.Grimes,A review on highly ordered,vertically oriented Ti O2 nanotube arrays:Fabrication,material properties,and solar energy applications,Solar Energy Materials and Solar Cells 90(2006)2011-75.
[6]A.Ghicov,P.Schmuki,Self-ordering electrochemistry:a review on growth and functionality of Ti O2 nanotubes and other self-aligned MOx structures,Chemical Communications(2009)2791-808.
[7]Q.F.Gui,D.L.Yu,S.Y.Zhang,H.P.Xiao,C.Y.Yang,Y.Song,X.F.Zhu,Influence ofanodizing voltage mode on the nanostructure of Ti O2 nanotubes,Journal of Solid State Electrochemistry 18(2014)141-8.
[8]H.Wang,H.Li,J.Wang,J.Wu,M.Liu,Influence of Applied Voltage on Anodized Ti O2Nanotube Arrays and Their Performance on Dye Sensitized Solar Cells,Journal of Nanoscience and Nanotechnology 13(2013)4183-8.
[9]Y.Li,H.Yu,C.Zhang,W.Song,G.Li,Z.Shao,B.Yi,Effect of water and annealing temperature of anodized Ti O2 nanotubes on hydrogen production in photoelectrochemical cell,Electrochimica Acta 107(2013)313-9.
[10]J.C.Cardoso,T.M.Lizier,M.V.Boldrin Zanoni,Highly ordered Ti O2 nanotube arrays and photoelectrocatalytic oxidation of aromatic amine,Applied Catalysis B-Environmental 99(2010)96-102.
[11]H.Omidvar,S.Goodarzi,A.Seif,A.R.Azadmehr,Influence of anodization parameters on the morphology of Ti O2 nanotube arrays,Superlattices and Microstructures 50(2011)26-39.
[12]Q.Chen,H.Liu,Y.Xin,X.Cheng,J.Zhang,J.Li,P.Wang,H.Li,Controlled anodic growth of Ti O2 nanobelts and assessment of photoelectrochemical and photocatalytic properties,Electrochimica Acta 99(2013)152-60.
[13]A.F.Kanta,M.Poelman,A.Decroly,Electrochemical characterisation of Ti O2 nanotube array photoanodes for dye-sensitized solar cell application,Solar Energy Materials and Solar Cells133(2015)76-81.
[14]C.Chen,L.Wang,F.M.Li,L.Y.Ling,Improving conversion efficiency of Cd S quantum dots-sensitized Ti O2 nanotube arrays by doping with Zn2+and decorating with Zn O nanoparticles,Materials Chemistry and Physics 146(2014)531-7.
[15]R.Gakhar,Y.R.Smith,M.Misra,D.Chidambaram,Photoelectric performance of Ti O2nanotube array photoelectrodes sensitized with Cd S0.54Se0.46 quantum dots,Applied Surface Science 355(2015)1279-88.
[16]J.Zhang,J.Hu,Y.-F.Zhu,Q.Liu,H.Zhang,R.-G.Du,C.-J.Lin,Fabrication of Cd Te/Zn S core/shell quantum dots sensitized Ti O2 nanotube films for photocathodic protection of stainless steel,Corrosion Science 99(2015)118-24.
[17]D.S.Guan,P.J.Hymel,Y.Wang,Growth mechanism and morphology control of double-layer and bamboo-type Ti O2 nanotube arrays by anodic oxidation,Electrochimica Acta 83(2012)420-9.
[18]V.Nguyen,W.Li,V.Pham,L.Wang,P.Sheng,Q.Cai,C.Grimes,A Cd S/Zn Se/Ti O2nanotube array and its visible light photocatalytic activities,Journal of colloid and interface science 462(2016)389-96.
[19]A.Sarkar,A.K.Singh,D.Sarkar,G.G.Khan,K.Mandal,Three-Dimensional Nanoarchitecture of Bi Fe O3 Anchored Ti O2 Nanotube Arrays for Electrochemical Energy Storage and Solar Energy Conversion,Acs Sustainable Chemistry&Engineering 3(2015)2254-63.
[20]M.Ge,C.Cao,S.Li,S.Zhang,S.Deng,J.Huang,Q.Li,K.Zhang,S.S.Al-Deyab,Y.Lai,Enhanced photocatalytic performances of n-Ti O2 nanotubes by uniform creation of p-n heterojunctions with p-Bi2O3 quantum dots,Nanoscale 7(2015)11552-60.
[21]H.Li,L.Cao,W.Liu,G.Su,B.Dong,Synthesis and investigation of Ti O2 nanotube arrays prepared by anodization and their photocatalytic activity,Ceramics International 38(2012)5791-7.
[22]J.Yu,B.Wang,Effect of calcination temperature on morphology and photoelectrochemical properties of anodized titanium dioxide nanotube arrays,Applied Catalysis B-Environmental 94(2010)295-302.
[23]C.Gao,Z.Zhang,X.Li,L.Chen,Y.Wang,Y.He,F.Teng,J.Zhou,W.Han,E.Xie,Synergistic effects in three-dimensional Sn O2/Ti O2/Cd S multi-heterojunction structure for highly efficient photoelectrochemical hydrogen production,Solar Energy Materials and Solar Cells 141(2015)101-7.
[24]H.Sun,P.Zhao,F.Zhang,Y.Liu,J.Hao,Ag2S/Cd S/Ti O2 Nanotube Array Films with High Photocurrent Density by Spotting Sample Method,Nanoscale Research Letters 10(2015)382.
[25]S.Zhou,Y.Wang,M.Zhao,L.-P.Jiang,J.-J.Zhu,Cd Se Te@Cd S@Zn S Quantum-Dot-Sensitized Macroporous Tio(2)Film:A Multisignal-Amplified Photoelectrochemical Platform,Chemphyschem 16(2015)2826-35.
[26]C.Chen,Y.Xie,G.Ali,S.H.Yoo,S.O.Cho,Improved conversion efficiency of Cd S quantum dots-sensitized Ti O2 nanotube array using Zn O energy barrier layer,Nanotechnology 22(2011).
[27]H.J.Kim,S.W.Kim,C.Gopi,S.K.Kim,S.S.Rao,M.S.Jeong,Improved performance of quantum dot-sensitized solar cells adopting a highly efficient cobalt sulfide/nickel sulfide composite thin film counter electrode,Journal of Power Sources 268(2014)163-70.
[28]I.Lopez,I.Gomez,Improvement of the luminescent properties of cadmium sulfide quantum dots by a post-synthesis modification,Physica B-Condensed Matter 453(2014)81-5.
[29]Z.Liu,G.Ji,D.Guan,B.Wang,X.Wu,Enhanced charge-carrier transfer by Cd S and Ag2S quantum dots co-sensitization for Ti O2 nanotube arrays,Journal of Colloid and Interface Science457(2015)1-8.
[30]P.Wang,X.Li,J.Fang,D.Li,J.Chen,X.Zhang,Y.Shao,Y.He,A facile synthesis of Cd Se quantum dots-decorated anatase Ti O2 with exposed{001}facets and its superior photocatalytic activity,Applied Catalysis B-Environmental 181(2016)838-47.
[31]M.Zhang,Y.Xu,Z.Gong,J.Tao,Z.Sun,J.Lv,X.Chen,X.Jiang,G.He,P.Wang,F.Meng,Enhanced charge collection and photocatalysis performance of Cd S and Pb S nanoclusters co-sensitized Ti O2 porous film,Journal of Alloys and Compounds 649(2015)190-5.
[32]Z.Zou,Y.Qi,C.Xie,J.Xu,Y.Luo,C.Wang,H.Yan,Cd S/Ti O2 nanocomposite film and its enhanced photoelectric responses to dry air and formaldehyde induced by visible light at room temperature,Journal of Alloys and Compounds 645(2015)17-23.
[33]D.Esparza,I.Zarazua,T.Lopez-Luke,R.Carriles,A.Torres-Castro,E.De la Rosa,Photovoltaic Properties of Bi2S3 and Cd S Quantum Dot Sensitized Ti O2 Solar Cells,Electrochimica Acta 180(2015)486-92.
[34]X.Cheng,X.Yu,Z.Xing,Characterization and mechanism analysis of Mo–N-co-doped Ti O2 nano-photocatalyst and its enhanced visible activity,Journal of colloid and interface science 372(2012)1-5.
[35]Y.Yang,H.Zhong,C.Tian,Photocatalytic mechanisms of modified titania under visible light,Research on Chemical Intermediates 37(2011)91-102.
[36]F.Spadavecchia,G.Cappelletti,S.Ardizzone,C.L.Bianchi,S.Cappelli,C.Oliva,P.Scardi,M.Leoni,P.Fermo,Solar photoactivity of nano-N-Ti O 2 from tertiary amine:role of defects andparamagnetic species,Applied Catalysis B:Environmental 96(2010)314-22.
[37]C.-B.Cao,L.Xiao,X.-P.Song,Z.-Q.Sun,Influence of annealing and Ag doping on structural and optical properties of indium tin oxide thin films,Journal of Vacuum Science&Technology A 28(2010)48-53.
[38]X.Cheng,G.Pan,X.Yu,T.Zheng,Preparation of Cd S NCs decorated Ti O2 nano-tubes arrays photoelectrode and its enhanced photoelectrocatalytic performance and mechanism,Electrochimica Acta 105(2013)535-41.
[39]D.R.Baker,P.V.Kamat,Photosensitization of Ti O2Nanostructures with Cd S Quantum Dots:Particulate versus Tubular Support Architectures,Advanced Functional Materials 19(2009)805-11.
[2]M.Adachi,Y.Murata,M.Harada,S.Yoshikawa,Formation of titania nanotubes with high photo-catalytic activity,Chemistry Letters(2000)942-3.
[3]D.Regonini,C.R.Bowen,A.Jaroenworaluck,R.Stevens,A review of growth mechanism,structure and crystallinity of anodized Ti O2 nanotubes,Materials Science&Engineering R-Reports 74(2013)377-406.
[4]Q.Zhou,Z.Fang,J.Li,M.Wang,Applications of Ti O2 nanotube arrays in environmental and energy fields:A review,Microporous and Mesoporous Materials 202(2015)22-35.
[5]G.K.Mor,O.K.Varghese,M.Paulose,K.Shankar,C.A.Grimes,A review on highly ordered,vertically oriented Ti O2 nanotube arrays:Fabrication,material properties,and solar energy applications,Solar Energy Materials and Solar Cells 90(2006)2011-75.
[6]A.Ghicov,P.Schmuki,Self-ordering electrochemistry:a review on growth and functionality of Ti O2 nanotubes and other self-aligned MOx structures,Chemical Communications(2009)2791-808.
[7]Q.F.Gui,D.L.Yu,S.Y.Zhang,H.P.Xiao,C.Y.Yang,Y.Song,X.F.Zhu,Influence ofanodizing voltage mode on the nanostructure of Ti O2 nanotubes,Journal of Solid State Electrochemistry 18(2014)141-8.
[8]H.Wang,H.Li,J.Wang,J.Wu,M.Liu,Influence of Applied Voltage on Anodized Ti O2Nanotube Arrays and Their Performance on Dye Sensitized Solar Cells,Journal of Nanoscience and Nanotechnology 13(2013)4183-8.
[9]Y.Li,H.Yu,C.Zhang,W.Song,G.Li,Z.Shao,B.Yi,Effect of water and annealing temperature of anodized Ti O2 nanotubes on hydrogen production in photoelectrochemical cell,Electrochimica Acta 107(2013)313-9.
[10]J.C.Cardoso,T.M.Lizier,M.V.Boldrin Zanoni,Highly ordered Ti O2 nanotube arrays and photoelectrocatalytic oxidation of aromatic amine,Applied Catalysis B-Environmental 99(2010)96-102.
[11]H.Omidvar,S.Goodarzi,A.Seif,A.R.Azadmehr,Influence of anodization parameters on the morphology of Ti O2 nanotube arrays,Superlattices and Microstructures 50(2011)26-39.
[12]Q.Chen,H.Liu,Y.Xin,X.Cheng,J.Zhang,J.Li,P.Wang,H.Li,Controlled anodic growth of Ti O2 nanobelts and assessment of photoelectrochemical and photocatalytic properties,Electrochimica Acta 99(2013)152-60.
[13]A.F.Kanta,M.Poelman,A.Decroly,Electrochemical characterisation of Ti O2 nanotube array photoanodes for dye-sensitized solar cell application,Solar Energy Materials and Solar Cells133(2015)76-81.
[14]C.Chen,L.Wang,F.M.Li,L.Y.Ling,Improving conversion efficiency of Cd S quantum dots-sensitized Ti O2 nanotube arrays by doping with Zn2+and decorating with Zn O nanoparticles,Materials Chemistry and Physics 146(2014)531-7.
[15]R.Gakhar,Y.R.Smith,M.Misra,D.Chidambaram,Photoelectric performance of Ti O2nanotube array photoelectrodes sensitized with Cd S0.54Se0.46 quantum dots,Applied Surface Science 355(2015)1279-88.
[16]J.Zhang,J.Hu,Y.-F.Zhu,Q.Liu,H.Zhang,R.-G.Du,C.-J.Lin,Fabrication of Cd Te/Zn S core/shell quantum dots sensitized Ti O2 nanotube films for photocathodic protection of stainless steel,Corrosion Science 99(2015)118-24.
[17]D.S.Guan,P.J.Hymel,Y.Wang,Growth mechanism and morphology control of double-layer and bamboo-type Ti O2 nanotube arrays by anodic oxidation,Electrochimica Acta 83(2012)420-9.
[18]V.Nguyen,W.Li,V.Pham,L.Wang,P.Sheng,Q.Cai,C.Grimes,A Cd S/Zn Se/Ti O2nanotube array and its visible light photocatalytic activities,Journal of colloid and interface science 462(2016)389-96.
[19]A.Sarkar,A.K.Singh,D.Sarkar,G.G.Khan,K.Mandal,Three-Dimensional Nanoarchitecture of Bi Fe O3 Anchored Ti O2 Nanotube Arrays for Electrochemical Energy Storage and Solar Energy Conversion,Acs Sustainable Chemistry&Engineering 3(2015)2254-63.
[20]M.Ge,C.Cao,S.Li,S.Zhang,S.Deng,J.Huang,Q.Li,K.Zhang,S.S.Al-Deyab,Y.Lai,Enhanced photocatalytic performances of n-Ti O2 nanotubes by uniform creation of p-n heterojunctions with p-Bi2O3 quantum dots,Nanoscale 7(2015)11552-60.
[21]H.Li,L.Cao,W.Liu,G.Su,B.Dong,Synthesis and investigation of Ti O2 nanotube arrays prepared by anodization and their photocatalytic activity,Ceramics International 38(2012)5791-7.
[22]J.Yu,B.Wang,Effect of calcination temperature on morphology and photoelectrochemical properties of anodized titanium dioxide nanotube arrays,Applied Catalysis B-Environmental 94(2010)295-302.
[23]C.Gao,Z.Zhang,X.Li,L.Chen,Y.Wang,Y.He,F.Teng,J.Zhou,W.Han,E.Xie,Synergistic effects in three-dimensional Sn O2/Ti O2/Cd S multi-heterojunction structure for highly efficient photoelectrochemical hydrogen production,Solar Energy Materials and Solar Cells 141(2015)101-7.
[24]H.Sun,P.Zhao,F.Zhang,Y.Liu,J.Hao,Ag2S/Cd S/Ti O2 Nanotube Array Films with High Photocurrent Density by Spotting Sample Method,Nanoscale Research Letters 10(2015)382.
[25]S.Zhou,Y.Wang,M.Zhao,L.-P.Jiang,J.-J.Zhu,Cd Se Te@Cd S@Zn S Quantum-Dot-Sensitized Macroporous Tio(2)Film:A Multisignal-Amplified Photoelectrochemical Platform,Chemphyschem 16(2015)2826-35.
[26]C.Chen,Y.Xie,G.Ali,S.H.Yoo,S.O.Cho,Improved conversion efficiency of Cd S quantum dots-sensitized Ti O2 nanotube array using Zn O energy barrier layer,Nanotechnology 22(2011).
[27]H.J.Kim,S.W.Kim,C.Gopi,S.K.Kim,S.S.Rao,M.S.Jeong,Improved performance of quantum dot-sensitized solar cells adopting a highly efficient cobalt sulfide/nickel sulfide composite thin film counter electrode,Journal of Power Sources 268(2014)163-70.
[28]I.Lopez,I.Gomez,Improvement of the luminescent properties of cadmium sulfide quantum dots by a post-synthesis modification,Physica B-Condensed Matter 453(2014)81-5.
[29]Z.Liu,G.Ji,D.Guan,B.Wang,X.Wu,Enhanced charge-carrier transfer by Cd S and Ag2S quantum dots co-sensitization for Ti O2 nanotube arrays,Journal of Colloid and Interface Science457(2015)1-8.
[30]P.Wang,X.Li,J.Fang,D.Li,J.Chen,X.Zhang,Y.Shao,Y.He,A facile synthesis of Cd Se quantum dots-decorated anatase Ti O2 with exposed{001}facets and its superior photocatalytic activity,Applied Catalysis B-Environmental 181(2016)838-47.
[31]M.Zhang,Y.Xu,Z.Gong,J.Tao,Z.Sun,J.Lv,X.Chen,X.Jiang,G.He,P.Wang,F.Meng,Enhanced charge collection and photocatalysis performance of Cd S and Pb S nanoclusters co-sensitized Ti O2 porous film,Journal of Alloys and Compounds 649(2015)190-5.
[32]Z.Zou,Y.Qi,C.Xie,J.Xu,Y.Luo,C.Wang,H.Yan,Cd S/Ti O2 nanocomposite film and its enhanced photoelectric responses to dry air and formaldehyde induced by visible light at room temperature,Journal of Alloys and Compounds 645(2015)17-23.
[33]D.Esparza,I.Zarazua,T.Lopez-Luke,R.Carriles,A.Torres-Castro,E.De la Rosa,Photovoltaic Properties of Bi2S3 and Cd S Quantum Dot Sensitized Ti O2 Solar Cells,Electrochimica Acta 180(2015)486-92.
[34]X.Cheng,X.Yu,Z.Xing,Characterization and mechanism analysis of Mo–N-co-doped Ti O2 nano-photocatalyst and its enhanced visible activity,Journal of colloid and interface science 372(2012)1-5.
[35]Y.Yang,H.Zhong,C.Tian,Photocatalytic mechanisms of modified titania under visible light,Research on Chemical Intermediates 37(2011)91-102.
[36]F.Spadavecchia,G.Cappelletti,S.Ardizzone,C.L.Bianchi,S.Cappelli,C.Oliva,P.Scardi,M.Leoni,P.Fermo,Solar photoactivity of nano-N-Ti O 2 from tertiary amine:role of defects andparamagnetic species,Applied Catalysis B:Environmental 96(2010)314-22.
[37]C.-B.Cao,L.Xiao,X.-P.Song,Z.-Q.Sun,Influence of annealing and Ag doping on structural and optical properties of indium tin oxide thin films,Journal of Vacuum Science&Technology A 28(2010)48-53.
[38]X.Cheng,G.Pan,X.Yu,T.Zheng,Preparation of Cd S NCs decorated Ti O2 nano-tubes arrays photoelectrode and its enhanced photoelectrocatalytic performance and mechanism,Electrochimica Acta 105(2013)535-41.
[39]D.R.Baker,P.V.Kamat,Photosensitization of Ti O2Nanostructures with Cd S Quantum Dots:Particulate versus Tubular Support Architectures,Advanced Functional Materials 19(2009)805-11.