加热不燃烧卷烟烟草材料的热分析研究
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- 英文论文题名：Investigation of thermogravimetry and pyrolysis behavior of tobacco material in two heat-not-burn cigarette brands
- 论文作者：杨继 ; 杨帅 ; 段沅杏 ; 田永峰 ; 赵伟 ; 杨柳 ; 汤建国 ; 朱东来 ; 陈永宽 ; 缪明明
- 英文论文作者：YANG Ji ; YANG Shuai ; DUAN Yuanxing ; TIAN Yongfeng ; ZHAO Wei ; YANG Liu ; TANG Jianguo ; ZHU Donglai ; CHEN Yongkuan ; MIAO Mingming ; R&D Center ; China Tobacco Yunnan Industrial Co. ; Ltd.
- 年：2016
- 作者机构：云南中烟工业有限责任公司技术中心;
- 论文关键词：加热不燃烧卷烟 ; 热重/差示扫描量热 ; 热裂解 ; 烟草材料
- 英文论文关键词：heat-not-burn cigarette ; TG/DSC ; pyrolysis ; tobacco materials
- 会议召开时间：2016-12-01
- 会议录名称：中国烟草学会2016年度优秀论文汇编——烟草工业主题
- 语种：中文
- 分类号：TS42
- 学会代码：ZGYG
- 学会名称：中国烟草学会
- 页数：7
- 文件大小：1948k
- 原文格式：D
摘要
利用热重/差示扫描量热法和热裂解分析研究了空气氛围下典型电加热和炭加热新型卷烟烟草材料热行为。结果表明:①两种典型的加热不燃烧卷烟烟草材料的热失重都分为四个阶段,碳加热型卷烟A主失重阶段发生在133-270℃,电加热型卷烟B主失重阶段发生在232-347℃;②两种烟草材料在前两个阶段失重量均要明显高于传统卷烟,主要是相对高比例的料香及烟雾生成剂的使用及较高的含水量;③两种典型的烟草材料在350℃热裂解,主要检出物质均为甘油、丙二醇和烟碱,其他主要物质还有乙酸、酮、醛和长链烷烃。
The thermogravimetry(TG) and pyrolysis behavior in tobacco materials of two typical heat-not-burn cigarettes,including charcoal heating cigarettes(A) and electric heating cigarettes(B),were investigated by TG/DSC and Py-GC/MS.Results showed that ① TG in tobacco materials of two typical heat-not-burn cigarettes could be divided into four stages. The main weight loss stage of A was 133-270℃ but that of B was 232-347℃. ② The weight loss of tobacco materials of two typical heat-not-burn cigarettes in the first and the second stage was significantly higher than that of conventional cigarettes as there were relatively high proportion of flavor component, smoke generator and high water content. ③ The pyrolysis reaction of two typical tobacco materials were performed by Py-GC/MS at 350℃. The main detection substances were glycerol, propylene glycol and nicotine, as well as acetic acid, ketones, aldehydes, and longchain alkanes.
The thermogravimetry(TG) and pyrolysis behavior in tobacco materials of two typical heat-not-burn cigarettes,including charcoal heating cigarettes(A) and electric heating cigarettes(B),were investigated by TG/DSC and Py-GC/MS.Results showed that ① TG in tobacco materials of two typical heat-not-burn cigarettes could be divided into four stages. The main weight loss stage of A was 133-270℃ but that of B was 232-347℃. ② The weight loss of tobacco materials of two typical heat-not-burn cigarettes in the first and the second stage was significantly higher than that of conventional cigarettes as there were relatively high proportion of flavor component, smoke generator and high water content. ③ The pyrolysis reaction of two typical tobacco materials were performed by Py-GC/MS at 350℃. The main detection substances were glycerol, propylene glycol and nicotine, as well as acetic acid, ketones, aldehydes, and longchain alkanes.
引文
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[17]刘珊,张军涛,胡军,等.裙带菜多糖的热裂解产物分析及卷烟应用研究[J].中国烟草学报,2013,19(5):10-15.
[18]杨柳,缪明明,吴亿勤,等.TGA和Py-GC/MS研究琥珀酸单薄荷酯的热失重和热裂解行为[J].中国烟草学报,2008,4:1-7.
[19]G o m e z-S i u r a n a A,M a r c i l l a A,B e l t r a n M,e t al.Thermogravimetric study of the pyrolysis of tobacco and several ingredients used in the fabrication of commercial c i g a r e t t e s:E ff e c t o f t h e p r e s e n c e o f M C M-4 1[J].Thermochimica Acta.2011,523:161-169.
[20]白晓莉,霍红,蒙延峰,等.几种烟草薄片的热性能分析[J].北京师范大学学报:自然科学版,2010,46(6):696-699.
[21]黄玉惠,李卓美,马志艺.取代度和金属平衡离子对羧甲基纤维素热行为的影响[J].高等学校化学学报,1990,11(8):882-886.
[22]钟庆辉.烟草化学基本知识[M].北京:轻工业出版社,1985:3-4.
[23]Burdick D,Benner J F,Burton H R.Thermal decomposition of tobacco.IV.Apparent correlations between thermogravimetric data and certain constituents in smoke from chemically-treated tobaccos[J].Tobacco New York,1969:21-24.
[24]Baker R R,Oburn S,Liu C,et al.Pyrolysis of saccharide tobacco ingredients:a TGA–FTIR investigation[J].Journal of Analytical and Applied Pyrolysis,2005,74(1):171-180.
[25]王洪波,郭军伟,夏巧玲,等.部分国产烟草样品的热重分析[J].烟草科技,2009,9:47-49.
[26]Wang W S,Wang Y,Yang L J,et al.Studies on thermal behavior of reconstituted tobacco sheet[J].Thermochim.Acta,2005,437:7-11.
[27]Torikai K,Yoshida S,Takahashi H,et al.Effects of temperature,atmosphere and p H on the generation of smoke compounds during tobacco pyrolysis[J].Food and Chemical Toxicology,2004,42(9):1409-1417.
[2]Pryor W A,Church D F,Evans M D,et al.A comparison of the free radical chemistry of tobacco-burning cigarettes and cigarettes that only heat tobacco[J].Free Radical Biology and Medicine,1990.8(3):275-279.
[3]Bethizy J D,Borgerding M F,Doolittle D J,et al.Chemical and biological studies of a cigarette that heats rather than burns tobacco[J].The Journal of Clinical Pharmacology,1990.30(8):755-763.
[4]菲利普莫里斯公司.传送烟香的电吸烟系统和烟卷:中国,CN1131676C[P],1996-06-06.
[5]菲利普莫里斯公司.带有烟雾检测用内置总管装置的电热吸烟系统:中国,CN101637308A[P],2003-11-7.
[6]R.J.雷诺兹烟草公司.香烟及其制造方法:中国,CN1086407A[P],1994-5-11.
[7]Baker R R,Bevan M A J.Studies on the Eclipse Cigarette:Studies on the Eclipse Cigarette:Project Report Number P94.Project Report Number P94.http://legacy.library.ucsf.edu/tid/lmv24a99.
[8]菲利普莫里斯公司.基于蒸馏的发烟制品:中国,CN101778578A[P],2010-7-14.
[9]菲利普莫里斯公司.电加热的发烟系统:中国,CN102438470A[P],2012-5-2.
[10]Borgerding M F,Bodnar J A,Chung H L,et al.Chemical and biological studies of a new cigarette that primarily heats tobacco.Part 1.Chemical composition of mainstream smoke[J].Food and Chemical Toxicology,1998,36,169.
[11]Bombick B R,Murli H,Avalos J T,et al.Chemical and biological studies of a new cigarette that primarily heats tobacco.Part 2.In vitro toxicology of mainstream smoke condensate[J].Food and Chemical Toxicology,1998,36,183.
[12]Bombick D W,Ayres P H,Putnam K,et al.Chemical and biological studies of a new cigarette that primarily heats tobacco.Part 3.In vitro toxicity of whole smoke[J].Food and Chemical Toxicology,1998,36,191.
[13]Gardner D E.A safer cigarette?A comparative study.A consensus report,Eclipse expert panel.Inhalation Toxicology,2000,12(S5),1.
[14]Foy J W D,Bombick B R,Bombick D W,et al.A comparison of in vitro toxicities of cigarette smoke condensate from“Eclipse”cigarettes and four commercially available ultralow-“tar”cigarettes[J]Food Chem.Toxicol,2004,42(2):237-243.
[15]陆昌伟,奚同庚.热分析质谱法[M].上海:上海科学技术文献出版社,2002:155-175.
[16]卢岚,杨柳,吴亿勤等,等.剑桥滤片捕集装置-热重-气相色谱-质谱法研究低温下纤维热解形成苯并[a]芘的过程[J].中国烟草学报,2012,18(30):1-5.
[17]刘珊,张军涛,胡军,等.裙带菜多糖的热裂解产物分析及卷烟应用研究[J].中国烟草学报,2013,19(5):10-15.
[18]杨柳,缪明明,吴亿勤,等.TGA和Py-GC/MS研究琥珀酸单薄荷酯的热失重和热裂解行为[J].中国烟草学报,2008,4:1-7.
[19]G o m e z-S i u r a n a A,M a r c i l l a A,B e l t r a n M,e t al.Thermogravimetric study of the pyrolysis of tobacco and several ingredients used in the fabrication of commercial c i g a r e t t e s:E ff e c t o f t h e p r e s e n c e o f M C M-4 1[J].Thermochimica Acta.2011,523:161-169.
[20]白晓莉,霍红,蒙延峰,等.几种烟草薄片的热性能分析[J].北京师范大学学报:自然科学版,2010,46(6):696-699.
[21]黄玉惠,李卓美,马志艺.取代度和金属平衡离子对羧甲基纤维素热行为的影响[J].高等学校化学学报,1990,11(8):882-886.
[22]钟庆辉.烟草化学基本知识[M].北京:轻工业出版社,1985:3-4.
[23]Burdick D,Benner J F,Burton H R.Thermal decomposition of tobacco.IV.Apparent correlations between thermogravimetric data and certain constituents in smoke from chemically-treated tobaccos[J].Tobacco New York,1969:21-24.
[24]Baker R R,Oburn S,Liu C,et al.Pyrolysis of saccharide tobacco ingredients:a TGA–FTIR investigation[J].Journal of Analytical and Applied Pyrolysis,2005,74(1):171-180.
[25]王洪波,郭军伟,夏巧玲,等.部分国产烟草样品的热重分析[J].烟草科技,2009,9:47-49.
[26]Wang W S,Wang Y,Yang L J,et al.Studies on thermal behavior of reconstituted tobacco sheet[J].Thermochim.Acta,2005,437:7-11.
[27]Torikai K,Yoshida S,Takahashi H,et al.Effects of temperature,atmosphere and p H on the generation of smoke compounds during tobacco pyrolysis[J].Food and Chemical Toxicology,2004,42(9):1409-1417.