NVF-DADMAC共聚物的合成及其在造纸中的初步应用研究
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摘要
为了开发多功能造纸助剂,以偶氮二异丁脒二盐酸盐(AIBA·2HCl)为引发剂,在水溶液中合成了N-乙烯基甲酰胺(NVF)与二甲基二烯丙基氯化铵(DADMAC)的共聚物(PNVF-DA).采用重量法、胶体滴定法、粘度法,详细讨论了诸反应因素包括引发剂质量分数、单体总质量分数及其配比、反应温度和时间对聚合过程及其产物性质的影响,较优的聚合条件为：n (NVF)/n (DADMAC)=7/3、ω(单体)=20%、θ=60℃、ω(引发剂)=0.1%。FTIR、DSC表征说明聚合产物已引入单体NVF、DADMAC,采用激光散射法测定了共聚物的分子量；着重讨论了聚合物质量浓度、温度、有机物含量、小分子盐含量及聚合物分子结构对PNVF-DA水溶液粘度的影响；最后,探讨了PNVF-DA在抄纸过程中的助滤助留效果以及在模拟造纸白水中的絮凝效果。
In order to develop multi-functional paper-making additives, a series of copolymers of N-vinylformamide(NVF) and diallyldimethylammonium chloride (DADMAC) were synthesized with 2,2'-azobis(isobutyramidine) dihydrochloride (AIBA-2HCl) as the initiator in aqueous solution。The effects of various reaction factors such as initiator concentration, mass fraction of monomers and their ratio, reaction temperature and time on the polymerization process and the properties of the products were discussed in detail by the weight method, colloid titration and viscosity method. The preferable polymerization conditions were:n(NVF)/n(DADMAC)-7/3、ω(monomers)=20%、θ=60℃、ω(initiator)=0.1%. The product was characterized by FTIR and DSC, the results indicated the polymerization of NVF and DADMAC. The weight-average molecular weight of some copolymers were determined by laser light scattering method. The influence of polymer concentration, temperature, organic content, salt content and structure of the copolymer on the viscosity of PNVF-DA aqueous solution were investigated. Finally, the effect of drainage and retention of the copolymers in the papermaking process and the flocculation in simulated white water were discussed.
In order to develop multi-functional paper-making additives, a series of copolymers of N-vinylformamide(NVF) and diallyldimethylammonium chloride (DADMAC) were synthesized with 2,2'-azobis(isobutyramidine) dihydrochloride (AIBA-2HCl) as the initiator in aqueous solution。The effects of various reaction factors such as initiator concentration, mass fraction of monomers and their ratio, reaction temperature and time on the polymerization process and the properties of the products were discussed in detail by the weight method, colloid titration and viscosity method. The preferable polymerization conditions were:n(NVF)/n(DADMAC)-7/3、ω(monomers)=20%、θ=60℃、ω(initiator)=0.1%. The product was characterized by FTIR and DSC, the results indicated the polymerization of NVF and DADMAC. The weight-average molecular weight of some copolymers were determined by laser light scattering method. The influence of polymer concentration, temperature, organic content, salt content and structure of the copolymer on the viscosity of PNVF-DA aqueous solution were investigated. Finally, the effect of drainage and retention of the copolymers in the papermaking process and the flocculation in simulated white water were discussed.
引文
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