Eu(Tb)配合物及配合物/SiO_2复合发光材料的制备及荧光性能研究
|
摘要
由于稀土元素特殊的电子构型及多种多样的电子能级,因此含稀土的配合物表现出许多独特的化学性质和物理性质。稀土配合物具有发射光谱呈线性,激发和发射波长理想,荧光寿命长,特征发射波长不受基质影响等特点,使其在发光领域广泛应用。稀土有机荧光配合物具有优良的发光性能,但其致命的弱点,光和热的不稳定性限制了它们的应用空间。实践表明,将稀土配合物引入到无机基质中,能提高其光和热的稳定性,所以研究稀土配合物/SiO_2杂化发光材料对稀土配合物的应用有着十分重要的意义。
本论文采用水热法,液相法成功制备出不同形貌的稀土配合物纳米粒子。通过溶胶-凝胶法把稀土配合物掺入SiO_2基质中,制备稀土配合物/SiO_2复合发光球及纳米管,来提高稀土配合物对光和热的稳定性。采用TEM、SEM、XRD、FTIR和PL等测试手段对产物进行了表征,获得了一些有意义的新结果,对进一步研究稀土配合物及其复合物的性质奠定了基础。该复合材料在生物示踪、光子晶体、发光与显示、微腔激光、数据存储、纳米传感器等多种领域具有潜在的应用价值。
The rare earth complexes present many unique chemical and physical properties because the rare earth elements have special electronic configuration and a variety of electronic energy levels. Rare earth complexes have the characteristic of linear emission spectra, ideal excitation and emission wavelength, longer fluorescent lifetime, and the characteristic emission wavelength is not be affected by the host, so they are widely used in luminescence fields. Rare-earth organic fluorescent complexes have an excellent luminescence properties, but its fatal weakness is light and heat instability, which limits their use space. It is practiced that the introducing the rare earth complexes into inorganic matrix can enhance its stability, so study of rare earth complexe / SiO_2 hybrid luminescence materials is very important for the application of rare earth complexes.
In this thesis, rare earth complex nanoparticles with different morphologies were prepared by hydrothermal and liquid phase method, the complex/SiO_2 nanospheres and nanotubes were synthesized by sol-gel method, in order to enhance the stability of heat and light. TEM, SEM, XRD, FTIR and PL measurements were used to characterize the samples, and some new results have been obtained, which will laid the foundation for further studies on the properties of rare earth complexes. The composite materials have potential application value in the biological track, photonic crystals, luminescence and display, micro-cavity lasers, data storage, nano-sensors and other fields.
本论文采用水热法,液相法成功制备出不同形貌的稀土配合物纳米粒子。通过溶胶-凝胶法把稀土配合物掺入SiO_2基质中,制备稀土配合物/SiO_2复合发光球及纳米管,来提高稀土配合物对光和热的稳定性。采用TEM、SEM、XRD、FTIR和PL等测试手段对产物进行了表征,获得了一些有意义的新结果,对进一步研究稀土配合物及其复合物的性质奠定了基础。该复合材料在生物示踪、光子晶体、发光与显示、微腔激光、数据存储、纳米传感器等多种领域具有潜在的应用价值。
The rare earth complexes present many unique chemical and physical properties because the rare earth elements have special electronic configuration and a variety of electronic energy levels. Rare earth complexes have the characteristic of linear emission spectra, ideal excitation and emission wavelength, longer fluorescent lifetime, and the characteristic emission wavelength is not be affected by the host, so they are widely used in luminescence fields. Rare-earth organic fluorescent complexes have an excellent luminescence properties, but its fatal weakness is light and heat instability, which limits their use space. It is practiced that the introducing the rare earth complexes into inorganic matrix can enhance its stability, so study of rare earth complexe / SiO_2 hybrid luminescence materials is very important for the application of rare earth complexes.
In this thesis, rare earth complex nanoparticles with different morphologies were prepared by hydrothermal and liquid phase method, the complex/SiO_2 nanospheres and nanotubes were synthesized by sol-gel method, in order to enhance the stability of heat and light. TEM, SEM, XRD, FTIR and PL measurements were used to characterize the samples, and some new results have been obtained, which will laid the foundation for further studies on the properties of rare earth complexes. The composite materials have potential application value in the biological track, photonic crystals, luminescence and display, micro-cavity lasers, data storage, nano-sensors and other fields.
引文
1 李建宇.稀土发光材料及其应用[M].北京,化学工业出版社,2003,300
2 符连社,张洪杰,邵华,等.溶胶-凝胶法制备无机/有机杂化材料研究进展[J].材料科学与工程,1999,17(1):84-88
3 K.Tadanaga,H.Yoshida,A.Matsuda,etal.Prepapration of Proton Conductive Inorganic-Organic Hybrid Films from 3-Glycidoxylpropyltriethoxysilane and Orthophosphoric Acid[J].Chemistry of Materials,2003,15,1910-1912
4 Q.M.Wang,B.Yan.Novel luminescent terbium molecular-based hybrids with modified meta aminobenzoic acid covalently bonded with silica[J].Mater.Chem,2004,14,2450-2454
5 P.Lenaerts,E.Ryckebosch,K.Driesen,etal.Study of the luminescence of tris(2-thenoyltrifluoroacetonato)lanthanide(Ⅲ)complexes covalently linked to 1,10-phen anthroline-functionalised hybrid sol-gel materials[J].Lumin,2005,114,77-84
6 D.W.Dong,Y.S.Yang,B.Z.Jiang,Sol-gel approach to the novel complex covalently bonded with silica matrix Mater[J].Chem.Phys.2006,95,89-93
7 P.Lenaerts,A.Storms,J.Mullens,e tal.Thin films of highly luminescent lanthanide complexes covalently linked to an organic-inorganic hybrid material via 2-substituted imidazo[4,5-f]-1,10-phenanthroline groups[J].Chem.Mater.2005,17,5194-5201
8 D.W.Dong,S.C.Jiang,Y.F.Men,e tal.complex films produced in situ via a sol-gel approach[J].Adv.Mater,2000,12,646-649
9 P.P.Lima,R.A.Sa Ferreira,R.O.Freire,F.A.Almeida Paz,L.S.Fu,L.D.Carlos,O.L.Malta,Spectroscopic Study of UV-Photostable Organic-Inorganic Hybrids Incorporating a New Eu~(3+) β-Diketonate Complex[J].Chem.Phys.Chem,2006,7,735-746
10 Q.M.Wang,B.Yan,e tal.Molecular assembly of novel luminescent terbium hybrid materials with modified 5-ethylpyridine-2,3-dicarboxylic acid as a functional bridge through an in situ sol-gel process[J].Opt.Mater,2007,29,510-515
11 P.Lenaerts,C.Gorller-Walrand,K.Binnemans,et al.Luminescent europium(Ⅲ) and terbium(Ⅲ) nicotinate complexes covalently linked to a 1,10-phenanthroline functionalised sol-gel glass[J].Joumal of Luminescence,2006,117,163-169
12宋春风,杨萍,吕孟凯,等.制备工艺条件对SiO_2干凝胶发光性质的影响[J].硅酸盐通报,2003,(2):89-92
13韩银花,林君.SiO_2干凝胶光致发光性质的研究[J].发光学报,2002,23(3):296-300
14 Junfang guo,Lianshe Fu,Huanrong Li,et al.Preparation and luminescence properties of ormosil hybrid materials doped with Tb(Tfacac)_3 phen complex via a sol-gel process[J].Mater Lett,2003,57,3899-3903
15 K.Driesen,R.V.Deun,C.Gorller-Walrand,et al.Near-infrared luminescence of lanthanide-calcein complexes doped into a silica-PEG hybrid material[J].Chem.Mater,2004,16,1531-1535
16 P.Lenaerts,K.Driesen,R.V.Deun,et al.Covalent coupling of luminescent tris(2-thenoyltrifluoroacetonato)lanthanide(Ⅲ)complexes on a Merrifield resin[J].Chem.Mater.2005,17,2148-2154
17 Q.M.Wang,B.Yan,X.H.Zhang.Lanthanide molecular-based hybrids covalently bonded with silica:Photoluminescence and control of micromorphology[J].Non-Cryst.Solids,2006,352,4136-4141
18安保礼,刘晓风.铕与苯甲酰丙酮、邻菲哕啉和丙烯酸四元配合物及其SiO_2复合材料的制备和光致发光性能[J].中山大学学报,2001,40(7)61-65
19 Baldo M A,O'Brien D F,You Y,et al.I-lighly efficient phosphorescent emission form organic Electro luminescent devices[J].Nature,1998,395:151-153
20 Cao Y,Parker I D,Yu G.Improved quantum efficiency for electroluminescence In semiconducting polymers[J].Nature,1999,397:414-416
21 Kido J,Nagai K,Chashi Y.Electroluminescence in terbium complex[J].Chem.Lett.,1990,657-660
22 Albery W J.Development of photogalvanic cells for solar energy conversion ACC[J].Chem.Res.,1982,15:142-150
23赵水亮,安晓萍,赵凤英,燕来,宝金荣.稀土(铕-铽)-18冠6-对苯二甲酸配合物的荧光性能[J].发光学报,2004,25(3):551
24 A.Beatrice,L.J.Maric,M.Gerard.Energy transfer luminescence of Europium(Ⅲ)and Terbium(Ⅲ) cryptates of macrobicyclic polypyridine ligands[J].Angew Chem Int,EdEngl.1987,26(3):266
25 D.B.Bolshoi,S.B.Meshkova,Z.M.Topilova.Luminescence from ytterbium(Ⅲ) and its complexes in solution[J].Opt.Sepectrosc,1997,1401
26 A.Beeby,R.S.Dickins,S.Faulkner,et al.Luminescence from ytterbium(Ⅲ)and its complexes in solution[J].Chem.Commun.,1997,1401-1402
27 W.D.Horrocks,M.Albin,Lanthanide ion luminescence in coordination chemistry and biochemistry[J].Prog.Inorg.Chem,1984,31
28 W.T.Carnall.The absorption and fluorescence spectra of rare earth ions in solution[J].Handbook of the Physics and Chmistry of Rare Northholland Amsterdam,1979,3:171
29 W.F.Sager,N.Filipescu,F.A.Serafin.Substituent etfects on intramolecular,energy transfer[J].Phys.Chem.,1964,68:3324
30 O.L.Malta,H.F.Brito,J.F.S.Menezes,F.R.Goncavese Silva,S.Aives Jr.,F.S.Farias Jr.,A.V.M.deAndrade[J].Lumin,1997,75:255
31 H.J.Batista,Av.Mde Andrade,R.L.Longo,et al.The Luminescence Properties of Diketonato-Europium Complexes[J].Inorg.Chem,1998,37:35-42
32杨士姚.钴、镍、铜、锌离子与芳香羧酸配位聚合物的组装、结构和性质[J].[厦门大学博士学位论文],2002
33任鹏.新型无机及无机-有机杂化二阶非线性光学材料的设计、合成和性能[J].[武汉大学博士学位论文],2003
34施而畏,夏长泰,王步国,仲维卓.水热法的应用与发展[J].无机材料学业报.1996,11(2),193
35 M.Eddaoudi,D.B.Moler,H.L.Li,B.L.Chen,T.M.Reineke,M.O'Keeffe,O.M.Yaghi,Modular chemistry:secondary building units as a basis for the design of highly porous and robudt metai-organic carboxylate frameworks[J].Acc.Chem.Res.,2001,34:319
36 S.S.Y Chui,S.M.F.Lo,J.P.H.Charmant,A.G.Orpen,LD.Williams,A chemically functionalizable nanoporous material[Cu3(TMA)2(H2O)3][J].Science,1999,283:1148
37林君,庞茂林,韩银花,于敏,张洪杰.溶胶-凝胶工艺制备法光薄膜研究进展[J].无机化学学报,2001,17(2):153
38 Q.Q Meng,H.J.Zhang,S.B.Wang,L.S.Fu,YX.Zheng,K.Y.Yang,Preparation and characterization of luminescent thin films doped with rare earth(Tb3+,Eu3+) complexes derived from a sol-gel process[J].Mater.Lett.2000.45:213
39林君,苏锵.溶胶-凝胶法及其在稀土发光材料合成中的应用[J].稀土学报,1994,15(1):42
40 T.Jin,S.Tsutsumi,Y.Deguchi,K.Machida,G.Adachi,Luminescent property of the terbium bipyridyl complex incorporated in silica matrix by a sol-gel method[J].Electrochem.Soc.,1995,142(10):L195
41 G.Qian,M.J.Wang,Preparation and fluorescence properties of nanocomposites of armorphous silica glasses doped with lanthanidet(Ⅲ)benzoates[J].Phys.Chem.Solid.1997.58(3):375
42王金龙.用流变相反应制备芳族羧酸盐单晶和镍酸盐正极材料[J].[武汉大学硕士学位论文],2003
43袁良杰.流变相合成法及其应用研究[J].[武汉大学博士学位论文],2003
44李文连.稀土有机配合物的发光研究的新进展[J].化学能报,1991,7(1):1-9
45 Janos,ErostyaAk~*,Andrea Buzady,Istvan Hornyak,Laszlo Kozma,Sensitized luminescence of Eu~(3+)/Gd~(3+)/cinnamic acid mixed complex[J].Journal of Photochemistry and Photobiology,1998,A:Chemistry 115,21
46 H.Samdson,Appl.phys.,1964,5:73
47 M.L.Bhaumik,J.Chem.Phys.,1965,42:787
48 M.Kleinerman,Dipyridine adduct of tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(Ⅲ)produces relatively large concentration-dependent paramagnetic shifts incholesterol monohydrate without serious peak broadening [J].Am.Chem.Soc.,1969,91:5160
49 P.K.Gallagher,A.Heller,E.Wasserman.A Two Step Energy Transfer in Solution[J].Chem.Phys.,1964,41(12):3921
50 C.F Meares,T.CzWensel,Acc.Chem.Res.,1984,17:202
51 PKolodner and J.A.Tyson,Appl.Phys.Lett.,1986,9:306
52 L.R.Matthews,E.T.Knobbe,Luminescence behavior of europium complexes in sol-gel derived host materials [J].Chem.Mater.,1993,5:1697
53 M.L.Bhaumik,C.L.Telk,J.Opt.Soc.Am.,1964,54(10):1211
54 M.L.Bhaumik.Laser Emission from a Europium Benzoylacetonate Alcohol Solution[J].Phys.Chem.,1964,68,1400
55 T.Jin,CzTsutsumi,Y,Deguchi,K.Machida,CxAdachi,J.Electrochem[J].Soc.,1995,42:195
56 K.Z.Wang,C.H.Huang,CxX.Xu.,Optical Properties of Langmuir-Blodgett Filin of Hemicyanine Containing the Rare Earth Complex Anion Dy(BPMPHD)_2[J].Thin Solid Films,1994,252:L39
57 D.J.zhou,C.H.Huang,C}X.Xu.,Langmuir-Blodgett Generation of an Europium Film and Second Harmonic
Hemicyanine Complex[J].Langmuir,1994,10:1910
58 J.Kido,K.Nagai,Y Okamoto,T.Skotheim,Electroluminescence from polysilane film doped with europium
complex[J].Chem.Lett.,1991:1267
59 J.Kido,H.Hayase,K.Hongawa,K.Nagaiand K.Okuyama,Bright red light-emit-ting organic electro luminescent devices
having a euronium complex as an emitter[J].Phvs.Lett.,1994,65:2124
60 王则民,余锡宾,杨海峰.苯甲酸镝、钇、镨掺杂配合物的光谱研究[J].光谱实验室,2001,18(2):151-154
61 吕国伟,李勇,李卫华.苯甲酸及其一氯代衍生物与邻菲哕啉或联吡啶的稀土铕三元配合物的荧光性质[J].光谱
学与光谱分析,2003,23(2):307-310
62 连锡山,盛慧,刘占梅.苯甲酸稀土(Eu,La)配合物的红外和荧光光谱研究[J].光谱学与光谱分析.1999,19
(4):562-565
63 王颖,李文先,孙元洪.苯甲酸稀土甲基亚砜配合物的合成与光致发光[J].内蒙古大学学报,2003,34(3):280-283
64 付忠实,赵凤英,薛珍.镧对铕配合物的发光影响[J].内蒙古石油化工,2001,27:16-17
65 赵永亮,赵凤英.铕铜苯甲酸a,a'联吡啶配合物的合成及性质研究[J].光谱学与光谱分析,2002,22(6):987-989
66 赵永亮,赵凤英.邻氨基苯甲酸2,2'-联吡啶铕镧混合稀土配合物的红外及荧光研究[J].光谱学与光谱分析,2000,
20(6):822-824
67 王正祥,舒万良,周忠诚.铕-芳香族有机羧酸-邻菲哕啉配合物的合成和荧光性能的研究[J].稀有金属,2002,26
(4):281-283
68 周忠诚.光致发光稀土(铕、铽)配合物的合成、荧光性能及理论研究[J].[博士论文],2002,48-51
69 Li Y.H.,Zhang H.J.,Wang S.B.,Synthesis arxi luminescence properties of organic-inorganic hybrid thin films doped
with Eu~(3+)[J].Thin Solid Films,2001,385:205-208
70 Meng Qingguo,Zhang Hongjie,Wang Shubin,etal.Preparation and characterization of luminescent thin films doped with rare earth Eu~(3+) and Tb~(3+) complexes derived from a sol-gel process[J].Materials Letters,2000,45:213-216
71 Yang bing,Zhang hong jie,Wang shu-bin.Luminescence properties of rare earth Eu~(3+) and Tb~(3+) complexes with conjugated carboxylic acid and 1,10-phenanthroline incorporated in silica matrix[J].Journal of photochemistry and photobiology,1998,112:231-238
72 Zhang H.J,Fu L.S,Wang S.B.,etal.Luminescence characteristics of europium and terbium complexes with 1,10-phenanthroline in-situ synthesized in a silica matrix by a two-step sol-gel process[J].Materials Letters,1999(38):260-264
73 王瑞芬,张建军,王淑萍.对硝基苯甲酸铕与2,2'-联吡啶配合物的合成及热分解的研究[J].稀有金属,2000,24(5):352-355
74 王宝兰,李建平,段聂晶.部分稀土与邻苯二甲酸及邻菲哕啉三元配合物的合成与表征[J].湖北大学学报,1996,18(2):375-378
75 赵永亮,赵凤英.二元羧酸-联吡啶稀土双核配合物中镧、铽对铕发光的增强作用[J].发光学报,2000,21(6):150-155
76 杨丽敏,翁诗甫,章菲.邻苯二甲酸铕锶络合物体系荧光的增强[J].光谱学与光谱分析,2000,20(5):727-729
77 李文先,张东凤.氯化稀土与苯基羧甲基亚砜配合物的合成、表征及Eu~(3+)配合物的发光[J].应用化学,2002,(2):140-143
78 张卫芳,刘德文.稀土配合物发光研究及其在生物化学中的应用[J].北京轻工业学院学报,1999,12(2):60-64
79 Albin Michael,Horrocks William.Europium(Ⅲ) luminescence excitation spectroscopy.Quantitative correlation between the total charge on the ligands and the ~7F_0-~5D_0 transition frequency in europium(Ⅲ) complexes[J].Inorg chem.,1985,24(6):895-900
80 Wu Ronghu,Zhao Huazhang,Su Qingde.Photoaeaustic and fluorescence studies of silica gels doted with rare earth salicylic acid complexes[J].Journal of Non-Crystalline Solids,2000,278:223-227
81 Chum X:H:;Zhang H.J,Li F.Sh..Luminesce properties of Eu(phen)2C13 doped in sol-gel-derived SiO_2-PEG mairix[J].Materials Letters,2000,46:244-247
82 Yan B,Zhang H.J,Ni J.Z.Luminescence properties of the rare earth(Eu~(3+) and Tb~(3+))complexes with 1,10-phenanthroline incorporated in silica matrix by a sol-gel method[J].Materials Science and Engineering,1998(B52):123-128
83 Silva F.R.G,Menezes J.F.S,Rocha G.B.,et al.Emission quantum yield of europium(Ⅲ) mixed complexes with thenoyltrfluoroacetonate and some aromatic ligands[J].Journal of Alloys and Compounds,2000.303:364-370
84 thong Guo-Lun,Wang Yong-Hong,Wang Cun-Kuan,et al.Assemblies of luminescent organized molecular films based on the intermolecular energy transfer between rare earth complexes[J].Thin Solid Fiims,2001,385:234-238
85Yang Yuetao,Su Qingde,Zhao Guiwen,et al.Photoacoustic spectroscopy study on lanthanide ternary complexes with dibenzoylmethide and phenanthroline[J].Specfiochimica Acts,1999,55:1527-1533
86Huang Ling,Wang Ke-Zhi,Huang Chun-Hui,et al.Synthetic and electroluminescent properties of two novel europium complexes with benzimidazole derivatives as second ligands[J].Synthetic Metals,2002,128:241-245
87范希智,陈君,凌启谈等.用稀士金属铽的有机配合物Tb(acac)_2(AA)phen做发光层的电致发光薄膜的研究[J].光子学报,2001,30(3):304
88R.J.Zhang,K.Z.Yang.Fluorescence Character of Rare Earth Complex with High Efficient Green Light in Ordered Molecular Films[J].Langmuir,1997,(13):7141-7150
89赵佳,刘霞,冯长根.稀土金属有机电致发光器件研究进展[J].稀有金属,2005,29(6):908-913
90张霞,张庆礼,苏静等.稀士激光晶体研究进展[J].人工晶体学报,2005,34(4):693-700
91雷光东,卢志云,朱卫国等.有机荧光防伪材料的制备[J].化学研究与应用,1999,11(3):208-311
92田君,尹敬辉.稀土荧光防伪油墨的制备[J].精细化工,1999,16(2):31-33
93何宜,龚盂镰,李源英等.稀土荧光塑料的研究[J].塑料工业,1988(6):44-47
94Auslander Judith D.,Berson William.Ink composition for bar code printing and scanning using wax-based invisible fluorescent inks.US5693693,1998
95Wang K Z,Li L J,Liu W M,et al.Vacuum-vaporized films fluorescent europium complex and their device application[J].Mater.Res.Bull.,1996,31(8):993
96Edards A,Chu T Y,Claude C,et al.Synthesis and characterization of electroluminescent organic-lanthanide(Ⅲ)complexes[J].Synth.Metals.,1997,84:433.
97黄春辉.稀土配位化学[M].北京科学出版社,1997,379
98杨武,高锦章.镧系(Eu~(3+)、Tb(3+))β-二酮-醋酸纤维素荧光膜的制备与性质[J].稀土,1998(1):10-13
99顾宜.材料科学与工程基础[M].北京科学出版社,2002,4
100李玲,何航.功能材料与纳米技术[M].北京化学工业出版社,2002
101X.P.Fan,M.Q.Wang,G H.Xiong.Spectroscopic Studies of Rare Earth Ions Insilica Glass Prepared by The Sol-Gel Process[J].Mater.Lett.1996,27:177-181
102H.Schmidt,G Philipp.Preparation of Gels in the CaO-Al_2O_3-SiO_2 System Filmmetal Alkoxides[J].Non-Cryst.Solids,1984,63:83-91
103R.Reisfeld.Prospects of Sol-Gel Technology Towards Luminescent Materials[J].Opt Mater,2001,16:17-29
104乔俊鹃,袁坚.溶胶-凝胶法制备有机-无机复合材料[J].佛山陶瓷,2002,4:1-4
105符连社,张洪杰,邵华等.溶胶-凝胶制备无机-有机杂化材料的研究进展[J].材料科学与工程,1999,17(1):84-88
106Fu Lianshe,Zhang Hongjie,Wamg Shubin,et al..Preparation and luminescence properties of ternary europium comploxs in-situ synthesized in silica/polymer hybrid matrix by a two-step sol-gel process[J],chemical research,1999,10(1):15
107陈建春.无机基质酞菁掺杂复合光限幅材料的研究[J].[福州大学学位论文],2003
108安保礼,刘晓岚,叶剑清等.铕(Ⅲ)与苯甲酰丙酮、邻菲哕啉和丙烯酸四元配合物及其复合材料的制备及其光致发光性能[J].中山大学学报,2001,40(4):61-65
109任杰,刘艳,唐小真.聚合物有机-无机纳米复合材料研究及应用前景[J].材料导报,2003,17(2):58-62
110杨勇,朱子勇,漆宗能.有机无机纳米复合材料的研究进展[J].上海交通大学学报,1998,23(9):131-135
111 殷亚东,张志成,徐相凌等.纳米材料辐射合成法制备[J].化学通报,1998,12:21-25
112朱连超,彭红瑞,张志馄.无机纳米粒子/聚合物复合材料研究进展[J].青岛化工学院学报,2002,(2):27-30
113 L.S.Fu,H.J.Zhang,S.B.Wang et al.Preparation and Luminescence Properties of Ternary Europium Complexes in-Situ Synthesized in Silica/Polymer Hybrid Matrix by a Two-Step Sol-Gel Process[J].Chemical Researches.1999,10(1):1-5
114钱国栋,王民权.原位合成配合Eu(DBM)_3.2H_2O在凝胶玻璃基质中的发光性能[J].硅酸盐学报,2003,31(1):47-50
115钱国栋,王民权等.凝胶玻璃中Eu(3+)和Tb(3+)与1,10-邻菲啰啉配合物的原位化学合成及其荧光和热学性能[J].材料研究学报,1998,8:352-357
116钱国栋,王民权.凝胶玻璃中Eu(3+)和Tb(3+)芳香羧酸配合物原位合成及其荧光性质[J].硅酸盐学报,1998,6:331-336
117孙莉,钟明强.无机纳米粒子于聚合物基材料的研究进展[J].化工科技,2002,10(3):50-53
118李海艳,李强.有机染料-层状硅酸盐光活性纳米复合材料[J].化学进展,2003,15(2):135-140
119蔡利芳,张永忠,席明哲等.原位合成法在材料制备中的应用及进展[J].金属热处理:2005,30(10):1-6
120 肖明艳,陈建敏.有机-无机杂化材料研究进展[J].高分子材料科学与工程,2001,17(5):6-12
121 黄小卫,庄卫东,李红卫.稀土功能材料研究开发现状和发展趋势[J].稀有金属.2004,28(4):711-715
122 倪永红,葛学武,徐相凌等.纳米材料制各研究的若干新进展[J].无机材料学报,2000,(1):9-15
123 张喜梅,陈玲,李琳等.纳米材料制备研究现状及其发展方向[J].现代化工,2000,20(7):13-16
124 陶栋梁,章婷,徐怡庄,等.稀土配合物发光中的能量传递研究[J].中国稀土学报,2001,19(6):543
125 杨武,陈淼,高锦章,等.镧系配合物的荧光光谱[J].光谱学与光谱分析,1999,19(2):227-229.
126 伍荣护,宋慧宇,苏庆德.稀土配合物分子内能量传递和弛豫过程的光声和荧光光谱研究[J].光谱学与光谱分析,2001,21(1):119-121
127 汪联辉,王文,章文贡.铽多元配合物的合成及其性质研究[J].中国稀土学报,2001,19(1):91-94
128 马建方,倪嘉缵.稀士羧酸配合物的结构[J].化学进展,1996,8(4):259-276
129 ZHAO Yong-liang,YANG Xiao-hua,MO Ri-gen.Spect roscopy and Spect ral Analysis,2002,22(2):223
130 ZHAO Yong-liang,ZHAO Feng-ying.Chinese Journal of Luminescence,2000,21(2):150
131 Yang Yuetao,Zhang Shuyi.Spect rochimica Acta Part A,2004,60:2065
132 Yang Yuetao,Su Qingde,Zhao Guiwen.Spect rochimica Acta Part A,1999,5:1527
133 REN Hui-juan,HONG Guang-yan,SONG Xin-yuan,et al.Journal of Functional Material,2004,35(2):228
134 L B Guo-wei,LI Yong,L I Wei-hua,et al.Spectroscopy and Spect ral Analysis,2003,23(2):307
135 LIAN Xi-shan,SHENG Hui,LIU Zhan-mei.Spectroscopy and Spect ral Analysis,1999,19(4):562
136 任慧娟 洪广言 宋心远,等.均苯四甲酸铕发光配合物的合成与表征[J].稀有金属材料与工程,2005,34(6):943-944
137 任慧娟 洪广言 宋心远,等.均苯三甲酸铕发光配合物的合成与表征[J].功能材料,2004,35(2):228-229
138 任慧娟 洪广言 宋心远,等.均苯四甲酸铽发光配合物的合成与表征[J].稀土,2004,25(6):48-49
139 杨念华,周丽荣,王芬.等.均苯三甲酸铽铵配合物的合成及其荧光特性研究[J].化学与生物工程,2007,24(2):12-14
140 C.J.Liang,D.Zhao,Z.R.Hong,D.X.Zhao,X.Y Liu,W.L.Li,Improved performance of electroluminescent devices based on an europium complex[J].Appl.Phys.Lett.,2000,76:67-69
141 J.Kido,Y Okamoto,Organic lanthanide metal complexes for electroluminescent materials[J].Chem.Rev,2002,102:2357-2368
142 K.Licha,Contrast agents for optical imaging[J].In Topics in Current Chemistry,Springer-Verlag Berlin Heidelberg,2002
143 M.Tan,Z..Ye,G Wang,J.Yuan,Preparation and time-resolved fluorometric application of Luminescent Europium Nanoparticles[J].Chem.Mater,2004m,16:2494-2498
144 Dan Zhao,Weiping Qin,Changfeng Wu,Guanshi Qin,Jisen Zhang,Shaozhe Lu,Laser selective spectroscopy of europium complex embedded in colloidal silica spheres[J].Chem.Phys.Lett.,2004,388:400-405
145 Z.Ye,M.Tan,G Wang,J.Yuan,.Preparation,characterization,and time-resolved fluorometric application of silicacoated terbium fluorescent nanoparticles[J].Anal.Chem.,2004,76:513-518
146 朱复红,杨冬亚,邱凤仙,等.稀土铈-草酸-邻菲哕啉配合物的合成、表征及荧光性能[J].应用化工,2008,37(3):257-259
147 苏义斌,谷学新,邹洪,等.稀土元素发光特性及其应用[J].化学研究,2001,12(4):55-59
148 杨瑞娜,王冬梅,金斗满等.利用铜和过氧化苯甲酰的氧化加成反应合成铜(Ⅱ)配合物及其晶体结构[J].河南科学,1992,4:48-51
149 王坤杰,宋玉民.稀土甘氨酸丁二酮肟配合物的制备和表征[J].中国科技论文在线.2008,04,17
2 符连社,张洪杰,邵华,等.溶胶-凝胶法制备无机/有机杂化材料研究进展[J].材料科学与工程,1999,17(1):84-88
3 K.Tadanaga,H.Yoshida,A.Matsuda,etal.Prepapration of Proton Conductive Inorganic-Organic Hybrid Films from 3-Glycidoxylpropyltriethoxysilane and Orthophosphoric Acid[J].Chemistry of Materials,2003,15,1910-1912
4 Q.M.Wang,B.Yan.Novel luminescent terbium molecular-based hybrids with modified meta aminobenzoic acid covalently bonded with silica[J].Mater.Chem,2004,14,2450-2454
5 P.Lenaerts,E.Ryckebosch,K.Driesen,etal.Study of the luminescence of tris(2-thenoyltrifluoroacetonato)lanthanide(Ⅲ)complexes covalently linked to 1,10-phen anthroline-functionalised hybrid sol-gel materials[J].Lumin,2005,114,77-84
6 D.W.Dong,Y.S.Yang,B.Z.Jiang,Sol-gel approach to the novel complex covalently bonded with silica matrix Mater[J].Chem.Phys.2006,95,89-93
7 P.Lenaerts,A.Storms,J.Mullens,e tal.Thin films of highly luminescent lanthanide complexes covalently linked to an organic-inorganic hybrid material via 2-substituted imidazo[4,5-f]-1,10-phenanthroline groups[J].Chem.Mater.2005,17,5194-5201
8 D.W.Dong,S.C.Jiang,Y.F.Men,e tal.complex films produced in situ via a sol-gel approach[J].Adv.Mater,2000,12,646-649
9 P.P.Lima,R.A.Sa Ferreira,R.O.Freire,F.A.Almeida Paz,L.S.Fu,L.D.Carlos,O.L.Malta,Spectroscopic Study of UV-Photostable Organic-Inorganic Hybrids Incorporating a New Eu~(3+) β-Diketonate Complex[J].Chem.Phys.Chem,2006,7,735-746
10 Q.M.Wang,B.Yan,e tal.Molecular assembly of novel luminescent terbium hybrid materials with modified 5-ethylpyridine-2,3-dicarboxylic acid as a functional bridge through an in situ sol-gel process[J].Opt.Mater,2007,29,510-515
11 P.Lenaerts,C.Gorller-Walrand,K.Binnemans,et al.Luminescent europium(Ⅲ) and terbium(Ⅲ) nicotinate complexes covalently linked to a 1,10-phenanthroline functionalised sol-gel glass[J].Joumal of Luminescence,2006,117,163-169
12宋春风,杨萍,吕孟凯,等.制备工艺条件对SiO_2干凝胶发光性质的影响[J].硅酸盐通报,2003,(2):89-92
13韩银花,林君.SiO_2干凝胶光致发光性质的研究[J].发光学报,2002,23(3):296-300
14 Junfang guo,Lianshe Fu,Huanrong Li,et al.Preparation and luminescence properties of ormosil hybrid materials doped with Tb(Tfacac)_3 phen complex via a sol-gel process[J].Mater Lett,2003,57,3899-3903
15 K.Driesen,R.V.Deun,C.Gorller-Walrand,et al.Near-infrared luminescence of lanthanide-calcein complexes doped into a silica-PEG hybrid material[J].Chem.Mater,2004,16,1531-1535
16 P.Lenaerts,K.Driesen,R.V.Deun,et al.Covalent coupling of luminescent tris(2-thenoyltrifluoroacetonato)lanthanide(Ⅲ)complexes on a Merrifield resin[J].Chem.Mater.2005,17,2148-2154
17 Q.M.Wang,B.Yan,X.H.Zhang.Lanthanide molecular-based hybrids covalently bonded with silica:Photoluminescence and control of micromorphology[J].Non-Cryst.Solids,2006,352,4136-4141
18安保礼,刘晓风.铕与苯甲酰丙酮、邻菲哕啉和丙烯酸四元配合物及其SiO_2复合材料的制备和光致发光性能[J].中山大学学报,2001,40(7)61-65
19 Baldo M A,O'Brien D F,You Y,et al.I-lighly efficient phosphorescent emission form organic Electro luminescent devices[J].Nature,1998,395:151-153
20 Cao Y,Parker I D,Yu G.Improved quantum efficiency for electroluminescence In semiconducting polymers[J].Nature,1999,397:414-416
21 Kido J,Nagai K,Chashi Y.Electroluminescence in terbium complex[J].Chem.Lett.,1990,657-660
22 Albery W J.Development of photogalvanic cells for solar energy conversion ACC[J].Chem.Res.,1982,15:142-150
23赵水亮,安晓萍,赵凤英,燕来,宝金荣.稀土(铕-铽)-18冠6-对苯二甲酸配合物的荧光性能[J].发光学报,2004,25(3):551
24 A.Beatrice,L.J.Maric,M.Gerard.Energy transfer luminescence of Europium(Ⅲ)and Terbium(Ⅲ) cryptates of macrobicyclic polypyridine ligands[J].Angew Chem Int,EdEngl.1987,26(3):266
25 D.B.Bolshoi,S.B.Meshkova,Z.M.Topilova.Luminescence from ytterbium(Ⅲ) and its complexes in solution[J].Opt.Sepectrosc,1997,1401
26 A.Beeby,R.S.Dickins,S.Faulkner,et al.Luminescence from ytterbium(Ⅲ)and its complexes in solution[J].Chem.Commun.,1997,1401-1402
27 W.D.Horrocks,M.Albin,Lanthanide ion luminescence in coordination chemistry and biochemistry[J].Prog.Inorg.Chem,1984,31
28 W.T.Carnall.The absorption and fluorescence spectra of rare earth ions in solution[J].Handbook of the Physics and Chmistry of Rare Northholland Amsterdam,1979,3:171
29 W.F.Sager,N.Filipescu,F.A.Serafin.Substituent etfects on intramolecular,energy transfer[J].Phys.Chem.,1964,68:3324
30 O.L.Malta,H.F.Brito,J.F.S.Menezes,F.R.Goncavese Silva,S.Aives Jr.,F.S.Farias Jr.,A.V.M.deAndrade[J].Lumin,1997,75:255
31 H.J.Batista,Av.Mde Andrade,R.L.Longo,et al.The Luminescence Properties of Diketonato-Europium Complexes[J].Inorg.Chem,1998,37:35-42
32杨士姚.钴、镍、铜、锌离子与芳香羧酸配位聚合物的组装、结构和性质[J].[厦门大学博士学位论文],2002
33任鹏.新型无机及无机-有机杂化二阶非线性光学材料的设计、合成和性能[J].[武汉大学博士学位论文],2003
34施而畏,夏长泰,王步国,仲维卓.水热法的应用与发展[J].无机材料学业报.1996,11(2),193
35 M.Eddaoudi,D.B.Moler,H.L.Li,B.L.Chen,T.M.Reineke,M.O'Keeffe,O.M.Yaghi,Modular chemistry:secondary building units as a basis for the design of highly porous and robudt metai-organic carboxylate frameworks[J].Acc.Chem.Res.,2001,34:319
36 S.S.Y Chui,S.M.F.Lo,J.P.H.Charmant,A.G.Orpen,LD.Williams,A chemically functionalizable nanoporous material[Cu3(TMA)2(H2O)3][J].Science,1999,283:1148
37林君,庞茂林,韩银花,于敏,张洪杰.溶胶-凝胶工艺制备法光薄膜研究进展[J].无机化学学报,2001,17(2):153
38 Q.Q Meng,H.J.Zhang,S.B.Wang,L.S.Fu,YX.Zheng,K.Y.Yang,Preparation and characterization of luminescent thin films doped with rare earth(Tb3+,Eu3+) complexes derived from a sol-gel process[J].Mater.Lett.2000.45:213
39林君,苏锵.溶胶-凝胶法及其在稀土发光材料合成中的应用[J].稀土学报,1994,15(1):42
40 T.Jin,S.Tsutsumi,Y.Deguchi,K.Machida,G.Adachi,Luminescent property of the terbium bipyridyl complex incorporated in silica matrix by a sol-gel method[J].Electrochem.Soc.,1995,142(10):L195
41 G.Qian,M.J.Wang,Preparation and fluorescence properties of nanocomposites of armorphous silica glasses doped with lanthanidet(Ⅲ)benzoates[J].Phys.Chem.Solid.1997.58(3):375
42王金龙.用流变相反应制备芳族羧酸盐单晶和镍酸盐正极材料[J].[武汉大学硕士学位论文],2003
43袁良杰.流变相合成法及其应用研究[J].[武汉大学博士学位论文],2003
44李文连.稀土有机配合物的发光研究的新进展[J].化学能报,1991,7(1):1-9
45 Janos,ErostyaAk~*,Andrea Buzady,Istvan Hornyak,Laszlo Kozma,Sensitized luminescence of Eu~(3+)/Gd~(3+)/cinnamic acid mixed complex[J].Journal of Photochemistry and Photobiology,1998,A:Chemistry 115,21
46 H.Samdson,Appl.phys.,1964,5:73
47 M.L.Bhaumik,J.Chem.Phys.,1965,42:787
48 M.Kleinerman,Dipyridine adduct of tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(Ⅲ)produces relatively large concentration-dependent paramagnetic shifts incholesterol monohydrate without serious peak broadening [J].Am.Chem.Soc.,1969,91:5160
49 P.K.Gallagher,A.Heller,E.Wasserman.A Two Step Energy Transfer in Solution[J].Chem.Phys.,1964,41(12):3921
50 C.F Meares,T.CzWensel,Acc.Chem.Res.,1984,17:202
51 PKolodner and J.A.Tyson,Appl.Phys.Lett.,1986,9:306
52 L.R.Matthews,E.T.Knobbe,Luminescence behavior of europium complexes in sol-gel derived host materials [J].Chem.Mater.,1993,5:1697
53 M.L.Bhaumik,C.L.Telk,J.Opt.Soc.Am.,1964,54(10):1211
54 M.L.Bhaumik.Laser Emission from a Europium Benzoylacetonate Alcohol Solution[J].Phys.Chem.,1964,68,1400
55 T.Jin,CzTsutsumi,Y,Deguchi,K.Machida,CxAdachi,J.Electrochem[J].Soc.,1995,42:195
56 K.Z.Wang,C.H.Huang,CxX.Xu.,Optical Properties of Langmuir-Blodgett Filin of Hemicyanine Containing the Rare Earth Complex Anion Dy(BPMPHD)_2[J].Thin Solid Films,1994,252:L39
57 D.J.zhou,C.H.Huang,C}X.Xu.,Langmuir-Blodgett Generation of an Europium Film and Second Harmonic
Hemicyanine Complex[J].Langmuir,1994,10:1910
58 J.Kido,K.Nagai,Y Okamoto,T.Skotheim,Electroluminescence from polysilane film doped with europium
complex[J].Chem.Lett.,1991:1267
59 J.Kido,H.Hayase,K.Hongawa,K.Nagaiand K.Okuyama,Bright red light-emit-ting organic electro luminescent devices
having a euronium complex as an emitter[J].Phvs.Lett.,1994,65:2124
60 王则民,余锡宾,杨海峰.苯甲酸镝、钇、镨掺杂配合物的光谱研究[J].光谱实验室,2001,18(2):151-154
61 吕国伟,李勇,李卫华.苯甲酸及其一氯代衍生物与邻菲哕啉或联吡啶的稀土铕三元配合物的荧光性质[J].光谱
学与光谱分析,2003,23(2):307-310
62 连锡山,盛慧,刘占梅.苯甲酸稀土(Eu,La)配合物的红外和荧光光谱研究[J].光谱学与光谱分析.1999,19
(4):562-565
63 王颖,李文先,孙元洪.苯甲酸稀土甲基亚砜配合物的合成与光致发光[J].内蒙古大学学报,2003,34(3):280-283
64 付忠实,赵凤英,薛珍.镧对铕配合物的发光影响[J].内蒙古石油化工,2001,27:16-17
65 赵永亮,赵凤英.铕铜苯甲酸a,a'联吡啶配合物的合成及性质研究[J].光谱学与光谱分析,2002,22(6):987-989
66 赵永亮,赵凤英.邻氨基苯甲酸2,2'-联吡啶铕镧混合稀土配合物的红外及荧光研究[J].光谱学与光谱分析,2000,
20(6):822-824
67 王正祥,舒万良,周忠诚.铕-芳香族有机羧酸-邻菲哕啉配合物的合成和荧光性能的研究[J].稀有金属,2002,26
(4):281-283
68 周忠诚.光致发光稀土(铕、铽)配合物的合成、荧光性能及理论研究[J].[博士论文],2002,48-51
69 Li Y.H.,Zhang H.J.,Wang S.B.,Synthesis arxi luminescence properties of organic-inorganic hybrid thin films doped
with Eu~(3+)[J].Thin Solid Films,2001,385:205-208
70 Meng Qingguo,Zhang Hongjie,Wang Shubin,etal.Preparation and characterization of luminescent thin films doped with rare earth Eu~(3+) and Tb~(3+) complexes derived from a sol-gel process[J].Materials Letters,2000,45:213-216
71 Yang bing,Zhang hong jie,Wang shu-bin.Luminescence properties of rare earth Eu~(3+) and Tb~(3+) complexes with conjugated carboxylic acid and 1,10-phenanthroline incorporated in silica matrix[J].Journal of photochemistry and photobiology,1998,112:231-238
72 Zhang H.J,Fu L.S,Wang S.B.,etal.Luminescence characteristics of europium and terbium complexes with 1,10-phenanthroline in-situ synthesized in a silica matrix by a two-step sol-gel process[J].Materials Letters,1999(38):260-264
73 王瑞芬,张建军,王淑萍.对硝基苯甲酸铕与2,2'-联吡啶配合物的合成及热分解的研究[J].稀有金属,2000,24(5):352-355
74 王宝兰,李建平,段聂晶.部分稀土与邻苯二甲酸及邻菲哕啉三元配合物的合成与表征[J].湖北大学学报,1996,18(2):375-378
75 赵永亮,赵凤英.二元羧酸-联吡啶稀土双核配合物中镧、铽对铕发光的增强作用[J].发光学报,2000,21(6):150-155
76 杨丽敏,翁诗甫,章菲.邻苯二甲酸铕锶络合物体系荧光的增强[J].光谱学与光谱分析,2000,20(5):727-729
77 李文先,张东凤.氯化稀土与苯基羧甲基亚砜配合物的合成、表征及Eu~(3+)配合物的发光[J].应用化学,2002,(2):140-143
78 张卫芳,刘德文.稀土配合物发光研究及其在生物化学中的应用[J].北京轻工业学院学报,1999,12(2):60-64
79 Albin Michael,Horrocks William.Europium(Ⅲ) luminescence excitation spectroscopy.Quantitative correlation between the total charge on the ligands and the ~7F_0-~5D_0 transition frequency in europium(Ⅲ) complexes[J].Inorg chem.,1985,24(6):895-900
80 Wu Ronghu,Zhao Huazhang,Su Qingde.Photoaeaustic and fluorescence studies of silica gels doted with rare earth salicylic acid complexes[J].Journal of Non-Crystalline Solids,2000,278:223-227
81 Chum X:H:;Zhang H.J,Li F.Sh..Luminesce properties of Eu(phen)2C13 doped in sol-gel-derived SiO_2-PEG mairix[J].Materials Letters,2000,46:244-247
82 Yan B,Zhang H.J,Ni J.Z.Luminescence properties of the rare earth(Eu~(3+) and Tb~(3+))complexes with 1,10-phenanthroline incorporated in silica matrix by a sol-gel method[J].Materials Science and Engineering,1998(B52):123-128
83 Silva F.R.G,Menezes J.F.S,Rocha G.B.,et al.Emission quantum yield of europium(Ⅲ) mixed complexes with thenoyltrfluoroacetonate and some aromatic ligands[J].Journal of Alloys and Compounds,2000.303:364-370
84 thong Guo-Lun,Wang Yong-Hong,Wang Cun-Kuan,et al.Assemblies of luminescent organized molecular films based on the intermolecular energy transfer between rare earth complexes[J].Thin Solid Fiims,2001,385:234-238
85Yang Yuetao,Su Qingde,Zhao Guiwen,et al.Photoacoustic spectroscopy study on lanthanide ternary complexes with dibenzoylmethide and phenanthroline[J].Specfiochimica Acts,1999,55:1527-1533
86Huang Ling,Wang Ke-Zhi,Huang Chun-Hui,et al.Synthetic and electroluminescent properties of two novel europium complexes with benzimidazole derivatives as second ligands[J].Synthetic Metals,2002,128:241-245
87范希智,陈君,凌启谈等.用稀士金属铽的有机配合物Tb(acac)_2(AA)phen做发光层的电致发光薄膜的研究[J].光子学报,2001,30(3):304
88R.J.Zhang,K.Z.Yang.Fluorescence Character of Rare Earth Complex with High Efficient Green Light in Ordered Molecular Films[J].Langmuir,1997,(13):7141-7150
89赵佳,刘霞,冯长根.稀土金属有机电致发光器件研究进展[J].稀有金属,2005,29(6):908-913
90张霞,张庆礼,苏静等.稀士激光晶体研究进展[J].人工晶体学报,2005,34(4):693-700
91雷光东,卢志云,朱卫国等.有机荧光防伪材料的制备[J].化学研究与应用,1999,11(3):208-311
92田君,尹敬辉.稀土荧光防伪油墨的制备[J].精细化工,1999,16(2):31-33
93何宜,龚盂镰,李源英等.稀土荧光塑料的研究[J].塑料工业,1988(6):44-47
94Auslander Judith D.,Berson William.Ink composition for bar code printing and scanning using wax-based invisible fluorescent inks.US5693693,1998
95Wang K Z,Li L J,Liu W M,et al.Vacuum-vaporized films fluorescent europium complex and their device application[J].Mater.Res.Bull.,1996,31(8):993
96Edards A,Chu T Y,Claude C,et al.Synthesis and characterization of electroluminescent organic-lanthanide(Ⅲ)complexes[J].Synth.Metals.,1997,84:433.
97黄春辉.稀土配位化学[M].北京科学出版社,1997,379
98杨武,高锦章.镧系(Eu~(3+)、Tb(3+))β-二酮-醋酸纤维素荧光膜的制备与性质[J].稀土,1998(1):10-13
99顾宜.材料科学与工程基础[M].北京科学出版社,2002,4
100李玲,何航.功能材料与纳米技术[M].北京化学工业出版社,2002
101X.P.Fan,M.Q.Wang,G H.Xiong.Spectroscopic Studies of Rare Earth Ions Insilica Glass Prepared by The Sol-Gel Process[J].Mater.Lett.1996,27:177-181
102H.Schmidt,G Philipp.Preparation of Gels in the CaO-Al_2O_3-SiO_2 System Filmmetal Alkoxides[J].Non-Cryst.Solids,1984,63:83-91
103R.Reisfeld.Prospects of Sol-Gel Technology Towards Luminescent Materials[J].Opt Mater,2001,16:17-29
104乔俊鹃,袁坚.溶胶-凝胶法制备有机-无机复合材料[J].佛山陶瓷,2002,4:1-4
105符连社,张洪杰,邵华等.溶胶-凝胶制备无机-有机杂化材料的研究进展[J].材料科学与工程,1999,17(1):84-88
106Fu Lianshe,Zhang Hongjie,Wamg Shubin,et al..Preparation and luminescence properties of ternary europium comploxs in-situ synthesized in silica/polymer hybrid matrix by a two-step sol-gel process[J],chemical research,1999,10(1):15
107陈建春.无机基质酞菁掺杂复合光限幅材料的研究[J].[福州大学学位论文],2003
108安保礼,刘晓岚,叶剑清等.铕(Ⅲ)与苯甲酰丙酮、邻菲哕啉和丙烯酸四元配合物及其复合材料的制备及其光致发光性能[J].中山大学学报,2001,40(4):61-65
109任杰,刘艳,唐小真.聚合物有机-无机纳米复合材料研究及应用前景[J].材料导报,2003,17(2):58-62
110杨勇,朱子勇,漆宗能.有机无机纳米复合材料的研究进展[J].上海交通大学学报,1998,23(9):131-135
111 殷亚东,张志成,徐相凌等.纳米材料辐射合成法制备[J].化学通报,1998,12:21-25
112朱连超,彭红瑞,张志馄.无机纳米粒子/聚合物复合材料研究进展[J].青岛化工学院学报,2002,(2):27-30
113 L.S.Fu,H.J.Zhang,S.B.Wang et al.Preparation and Luminescence Properties of Ternary Europium Complexes in-Situ Synthesized in Silica/Polymer Hybrid Matrix by a Two-Step Sol-Gel Process[J].Chemical Researches.1999,10(1):1-5
114钱国栋,王民权.原位合成配合Eu(DBM)_3.2H_2O在凝胶玻璃基质中的发光性能[J].硅酸盐学报,2003,31(1):47-50
115钱国栋,王民权等.凝胶玻璃中Eu(3+)和Tb(3+)与1,10-邻菲啰啉配合物的原位化学合成及其荧光和热学性能[J].材料研究学报,1998,8:352-357
116钱国栋,王民权.凝胶玻璃中Eu(3+)和Tb(3+)芳香羧酸配合物原位合成及其荧光性质[J].硅酸盐学报,1998,6:331-336
117孙莉,钟明强.无机纳米粒子于聚合物基材料的研究进展[J].化工科技,2002,10(3):50-53
118李海艳,李强.有机染料-层状硅酸盐光活性纳米复合材料[J].化学进展,2003,15(2):135-140
119蔡利芳,张永忠,席明哲等.原位合成法在材料制备中的应用及进展[J].金属热处理:2005,30(10):1-6
120 肖明艳,陈建敏.有机-无机杂化材料研究进展[J].高分子材料科学与工程,2001,17(5):6-12
121 黄小卫,庄卫东,李红卫.稀土功能材料研究开发现状和发展趋势[J].稀有金属.2004,28(4):711-715
122 倪永红,葛学武,徐相凌等.纳米材料制各研究的若干新进展[J].无机材料学报,2000,(1):9-15
123 张喜梅,陈玲,李琳等.纳米材料制备研究现状及其发展方向[J].现代化工,2000,20(7):13-16
124 陶栋梁,章婷,徐怡庄,等.稀土配合物发光中的能量传递研究[J].中国稀土学报,2001,19(6):543
125 杨武,陈淼,高锦章,等.镧系配合物的荧光光谱[J].光谱学与光谱分析,1999,19(2):227-229.
126 伍荣护,宋慧宇,苏庆德.稀土配合物分子内能量传递和弛豫过程的光声和荧光光谱研究[J].光谱学与光谱分析,2001,21(1):119-121
127 汪联辉,王文,章文贡.铽多元配合物的合成及其性质研究[J].中国稀土学报,2001,19(1):91-94
128 马建方,倪嘉缵.稀士羧酸配合物的结构[J].化学进展,1996,8(4):259-276
129 ZHAO Yong-liang,YANG Xiao-hua,MO Ri-gen.Spect roscopy and Spect ral Analysis,2002,22(2):223
130 ZHAO Yong-liang,ZHAO Feng-ying.Chinese Journal of Luminescence,2000,21(2):150
131 Yang Yuetao,Zhang Shuyi.Spect rochimica Acta Part A,2004,60:2065
132 Yang Yuetao,Su Qingde,Zhao Guiwen.Spect rochimica Acta Part A,1999,5:1527
133 REN Hui-juan,HONG Guang-yan,SONG Xin-yuan,et al.Journal of Functional Material,2004,35(2):228
134 L B Guo-wei,LI Yong,L I Wei-hua,et al.Spectroscopy and Spect ral Analysis,2003,23(2):307
135 LIAN Xi-shan,SHENG Hui,LIU Zhan-mei.Spectroscopy and Spect ral Analysis,1999,19(4):562
136 任慧娟 洪广言 宋心远,等.均苯四甲酸铕发光配合物的合成与表征[J].稀有金属材料与工程,2005,34(6):943-944
137 任慧娟 洪广言 宋心远,等.均苯三甲酸铕发光配合物的合成与表征[J].功能材料,2004,35(2):228-229
138 任慧娟 洪广言 宋心远,等.均苯四甲酸铽发光配合物的合成与表征[J].稀土,2004,25(6):48-49
139 杨念华,周丽荣,王芬.等.均苯三甲酸铽铵配合物的合成及其荧光特性研究[J].化学与生物工程,2007,24(2):12-14
140 C.J.Liang,D.Zhao,Z.R.Hong,D.X.Zhao,X.Y Liu,W.L.Li,Improved performance of electroluminescent devices based on an europium complex[J].Appl.Phys.Lett.,2000,76:67-69
141 J.Kido,Y Okamoto,Organic lanthanide metal complexes for electroluminescent materials[J].Chem.Rev,2002,102:2357-2368
142 K.Licha,Contrast agents for optical imaging[J].In Topics in Current Chemistry,Springer-Verlag Berlin Heidelberg,2002
143 M.Tan,Z..Ye,G Wang,J.Yuan,Preparation and time-resolved fluorometric application of Luminescent Europium Nanoparticles[J].Chem.Mater,2004m,16:2494-2498
144 Dan Zhao,Weiping Qin,Changfeng Wu,Guanshi Qin,Jisen Zhang,Shaozhe Lu,Laser selective spectroscopy of europium complex embedded in colloidal silica spheres[J].Chem.Phys.Lett.,2004,388:400-405
145 Z.Ye,M.Tan,G Wang,J.Yuan,.Preparation,characterization,and time-resolved fluorometric application of silicacoated terbium fluorescent nanoparticles[J].Anal.Chem.,2004,76:513-518
146 朱复红,杨冬亚,邱凤仙,等.稀土铈-草酸-邻菲哕啉配合物的合成、表征及荧光性能[J].应用化工,2008,37(3):257-259
147 苏义斌,谷学新,邹洪,等.稀土元素发光特性及其应用[J].化学研究,2001,12(4):55-59
148 杨瑞娜,王冬梅,金斗满等.利用铜和过氧化苯甲酰的氧化加成反应合成铜(Ⅱ)配合物及其晶体结构[J].河南科学,1992,4:48-51
149 王坤杰,宋玉民.稀土甘氨酸丁二酮肟配合物的制备和表征[J].中国科技论文在线.2008,04,17