钛酸钡基无铅压电复合陶瓷性能的研究
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摘要
钛酸钡（BaTiO_3）是一种钙钛矿结构压电材料，其居里温度为120℃，具有较高的压电常数。针对无铅压电陶瓷的发展现状，本论文将对钛酸钡基无铅压电陶瓷进行研究。
通过建立基体--颗粒物理模型讨论应力对居里温度和压电系数的影响。讨论了存在内应力的情况下，BaTiO_3--ZrO_2复合陶瓷材料的居里温度和压电系数随着ZrO_2体积百分比的变化。
采用溶胶--凝胶法合成了粒径细小的ZnO-B_2O_3-SiO_2（ZBS）玻璃粉，通过添加ZBS玻璃，实现了陶瓷在1100℃低温下致密烧结。研究了玻璃添加量对陶瓷密度的影响。分析了液相烧结时，用不同颗粒尺寸的BaTiO_3初始粉末制备的陶瓷的密度、相结构、微观形貌和介电性能。通过掺杂MnCO_3，提高了陶瓷的密度，降低了介电损耗，得到较好压电性能的BaTiO_3陶瓷。
利用Pechini法成功合成了1mol%Y_2O_3--ZrO_2纳米粉，并制备了BaTiO_3--ZrO_2复合陶瓷。研究了烧结温度对陶瓷密度、物相和介电性能的影响。通过在BaTiO_3陶瓷中添加ZrO_2，实现了BaTiO_3陶瓷居里温度的提高。烧结温度为1050℃时，BaTiO_3--10vol%ZrO_2复合陶瓷的介电常数最高，居里温度提高到143℃。通过Raman光谱证明内应力是使居里温度提高的原因，随着ZrO_2含量的增加，居里温度向高温方向移动。
分别用固相法和液相法制备Bi、Cu共掺杂的BaTiO_3陶瓷。研究了Bi和Cu的掺杂量对固相法制备的(Ba_(1-2x)Bi_(2x))(CuxTi_(1-x))O_3陶瓷的微观结构、形貌、介电和压电性能的影响。研究分析了溶胶-凝胶自燃烧法制备(Ba_(1-2x)Bi_(2x))(CuxTi_(1-x))O_3粉体的具体工艺条件。研究了烧结工艺对液相法制备的(Ba_(1-2x)Bi_(2x))(CuxTi_(1-x))O_3陶瓷的微观形貌、物相和介电压电性能的影响。在T1=1300℃，T2=1150℃保温10h，x=0.005样品的居里温度为140℃，压电常数d_(33)=100pC/N，d_(31)=-18.44pC/N，K_p=17.62%；x=0.01样品的居里温度为150℃，压电常数d_(33)=80pC/N，d_(31)=-9.88pC/N，K_p=13.88%。并且压电系数d_(31)和机电耦合系数K_p的温度稳定性较好。最后，制备并研究了(Ba_(1-2x)Bi_(2x))(CuxTi_(1-x))O_3--ZrO_2复合陶瓷。
Barium titanate (BaTiO3) as a kind of perovskite type dielectric materials, has high dielectric constant. The Curie temperature of BaTiO3is120℃. According to the development station of lead-free piezoelectric ceramics, this paper will ascertain the study of the BaTiO3ceramics.
We build up a matrix-particle theoretical model to analyze that the internal stress affects the Curie temperature and piezoelectric coefficient. The Curie temperature and piezoelectric coefficient of BaTiO3--ZrO2ceramic was investigated as a function of volume percentage of ZrO3.
ZnO-B2O3-SiO2(ZBS) glass powder with small grain size was synthesized by a sol-gel method. Low temperature sintering at1100℃of high density ceramic was realized through ZBS glass powder adding. The influence of density with amount of glass powder was investigated. In liquid sintering, we study the density, crystal lattice, microstructure and dielectric properties of ceramic prepared using different particle size of raw powders. The ceramic with good piezoelectric property was obtained by adding MnCO3, which increase density and reduce the dielectric loss of ceramic.
lmol%Y2O3--ZrO3nanopowder was synthesized by a Pechini method, and BaTiO3--ZrO2composite ceramic was prepared. The effects of density, phase and dielectric properties of ceramic with sintering temperature was researched. The Curie temperature of BaTiO3ceramic is increased by adding ZrO2. BaTiO3--10vol%ZrO2composite ceramic has the highest dielectric constant and a Curie temperature (Tc=143℃) at sintering temperature of1050℃. The internal stress is the reason for the increase of the Curie temperature by Raman spectroscopy. With the increase of ZrO2content, the Curie temperature moves to high temperature.
Bi and Cu co-doped BaTiO3ceramics were prepared through solid-state reaction and liquid method respectively. The influence of microstructure, morphology, dielectric and piezoelectric properties of (Ba1-2xBi2X)(CuxTi1-x)O3ceramic with the amount of Bi and Cu doping was investigated. The process conditions has been analyzed to prepare (Ba1-2xBi2X)(CuxTi1-x)O3by self-combustion method. The effects of sintering condition on the microstructure, phase, dielectric and piezoelectric properties of (Ba1-2XBi2X)(CuxTi1-x)O3ceramics was investigated. The x=0.005sample has the Curie temperature (Tc=140℃), piezoelectric constant d33=100pC/N, d31=-18.44pC/N, and Kp=17.62%at temperature of Ti=1300℃, T2=1150℃. While the x=0.01sample has the Curie temperature (Tc=150℃), piezoelectric constant d33=80pC/N,d31=-9.88pC/N and Kp=13.88%at same condition. In addition, the piezoelectric constant d31and electromechanical coupling facor Kp have a good temperature stable property. Finally,(Ba1-2xBi2x)(CuxTi1-x)O3--ZrO2composite ceramics have prepared and investigated.
通过建立基体--颗粒物理模型讨论应力对居里温度和压电系数的影响。讨论了存在内应力的情况下，BaTiO_3--ZrO_2复合陶瓷材料的居里温度和压电系数随着ZrO_2体积百分比的变化。
采用溶胶--凝胶法合成了粒径细小的ZnO-B_2O_3-SiO_2（ZBS）玻璃粉，通过添加ZBS玻璃，实现了陶瓷在1100℃低温下致密烧结。研究了玻璃添加量对陶瓷密度的影响。分析了液相烧结时，用不同颗粒尺寸的BaTiO_3初始粉末制备的陶瓷的密度、相结构、微观形貌和介电性能。通过掺杂MnCO_3，提高了陶瓷的密度，降低了介电损耗，得到较好压电性能的BaTiO_3陶瓷。
利用Pechini法成功合成了1mol%Y_2O_3--ZrO_2纳米粉，并制备了BaTiO_3--ZrO_2复合陶瓷。研究了烧结温度对陶瓷密度、物相和介电性能的影响。通过在BaTiO_3陶瓷中添加ZrO_2，实现了BaTiO_3陶瓷居里温度的提高。烧结温度为1050℃时，BaTiO_3--10vol%ZrO_2复合陶瓷的介电常数最高，居里温度提高到143℃。通过Raman光谱证明内应力是使居里温度提高的原因，随着ZrO_2含量的增加，居里温度向高温方向移动。
分别用固相法和液相法制备Bi、Cu共掺杂的BaTiO_3陶瓷。研究了Bi和Cu的掺杂量对固相法制备的(Ba_(1-2x)Bi_(2x))(CuxTi_(1-x))O_3陶瓷的微观结构、形貌、介电和压电性能的影响。研究分析了溶胶-凝胶自燃烧法制备(Ba_(1-2x)Bi_(2x))(CuxTi_(1-x))O_3粉体的具体工艺条件。研究了烧结工艺对液相法制备的(Ba_(1-2x)Bi_(2x))(CuxTi_(1-x))O_3陶瓷的微观形貌、物相和介电压电性能的影响。在T1=1300℃，T2=1150℃保温10h，x=0.005样品的居里温度为140℃，压电常数d_(33)=100pC/N，d_(31)=-18.44pC/N，K_p=17.62%；x=0.01样品的居里温度为150℃，压电常数d_(33)=80pC/N，d_(31)=-9.88pC/N，K_p=13.88%。并且压电系数d_(31)和机电耦合系数K_p的温度稳定性较好。最后，制备并研究了(Ba_(1-2x)Bi_(2x))(CuxTi_(1-x))O_3--ZrO_2复合陶瓷。
Barium titanate (BaTiO3) as a kind of perovskite type dielectric materials, has high dielectric constant. The Curie temperature of BaTiO3is120℃. According to the development station of lead-free piezoelectric ceramics, this paper will ascertain the study of the BaTiO3ceramics.
We build up a matrix-particle theoretical model to analyze that the internal stress affects the Curie temperature and piezoelectric coefficient. The Curie temperature and piezoelectric coefficient of BaTiO3--ZrO2ceramic was investigated as a function of volume percentage of ZrO3.
ZnO-B2O3-SiO2(ZBS) glass powder with small grain size was synthesized by a sol-gel method. Low temperature sintering at1100℃of high density ceramic was realized through ZBS glass powder adding. The influence of density with amount of glass powder was investigated. In liquid sintering, we study the density, crystal lattice, microstructure and dielectric properties of ceramic prepared using different particle size of raw powders. The ceramic with good piezoelectric property was obtained by adding MnCO3, which increase density and reduce the dielectric loss of ceramic.
lmol%Y2O3--ZrO3nanopowder was synthesized by a Pechini method, and BaTiO3--ZrO2composite ceramic was prepared. The effects of density, phase and dielectric properties of ceramic with sintering temperature was researched. The Curie temperature of BaTiO3ceramic is increased by adding ZrO2. BaTiO3--10vol%ZrO2composite ceramic has the highest dielectric constant and a Curie temperature (Tc=143℃) at sintering temperature of1050℃. The internal stress is the reason for the increase of the Curie temperature by Raman spectroscopy. With the increase of ZrO2content, the Curie temperature moves to high temperature.
Bi and Cu co-doped BaTiO3ceramics were prepared through solid-state reaction and liquid method respectively. The influence of microstructure, morphology, dielectric and piezoelectric properties of (Ba1-2xBi2X)(CuxTi1-x)O3ceramic with the amount of Bi and Cu doping was investigated. The process conditions has been analyzed to prepare (Ba1-2xBi2X)(CuxTi1-x)O3by self-combustion method. The effects of sintering condition on the microstructure, phase, dielectric and piezoelectric properties of (Ba1-2XBi2X)(CuxTi1-x)O3ceramics was investigated. The x=0.005sample has the Curie temperature (Tc=140℃), piezoelectric constant d33=100pC/N, d31=-18.44pC/N, and Kp=17.62%at temperature of Ti=1300℃, T2=1150℃. While the x=0.01sample has the Curie temperature (Tc=150℃), piezoelectric constant d33=80pC/N,d31=-9.88pC/N and Kp=13.88%at same condition. In addition, the piezoelectric constant d31and electromechanical coupling facor Kp have a good temperature stable property. Finally,(Ba1-2xBi2x)(CuxTi1-x)O3--ZrO2composite ceramics have prepared and investigated.
引文
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