黑色圆珠笔油墨种类的研究
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摘要
由圆珠笔油墨形成的契约、合同、收据和借条等可疑文件的真伪及形成时间的鉴定是目前法庭科学经常遇到的问题,因此建立一种简便、灵敏和准确的检验圆珠笔油墨字迹色痕的异同及形成时间的方法是十分必要的。本论文对国内外不同厂家生产的130支黑色圆珠笔油墨进行了系统的分类研究,涉及到紫外可见分光光度法、极谱法、高效液相色谱法、高效液相色谱-质谱联用、系统聚类分析五种方法。
第一章详细评述了近年来有关圆珠笔油墨种类及其字迹色痕形成时间的研究进展。
第二章采用高效液相色谱法(HPLC)对黑色圆珠笔油墨的种类进行了研究,根据有色成分的不同对不同品牌的黑色圆珠笔进行分类,同时采用系统聚类分析的方法,对实验结果进行了化学计量学的分析。
第三章介绍了黑色圆珠笔油墨字迹色痕的高效液相色谱-质谱法(HPLC- MS)的研究情况。
第四章采用紫外可见分光光度法对黑色圆珠笔油墨的种类进行了研究,依据紫外可见光谱图中特征峰位置的不同进行种类的认定。
第五章介绍了极谱法在黑色圆珠笔油墨种类研究中的应用,根据不同染料还原峰电位的不同进行分类。
第六章总结了本论文的研究工作,指出了论文工作的不足之处,并对该研究工作的未来发展提出了设想。
As it is a frequently encountered problem of forensic science nowadays to distinguish whether the questioned documents, such as deeds, contracts and receipts, written in ballpoint pen inks are true or not, and identify the writing age of them, it is very essential to establish a simple, sensitive and accurate method to examine the similarities and differences of the ballpoint pen inks and identify the writing age. In this study, 130 different kinds of black ballpoint pen inks from different manufactures were studied, concerning five methods: UV-vis spectrophotometry, Oscillopolarography, High performance liquid chromatography, High performance liquid chromatogramphy-mass spectrometry and Hierarchical clustering analysis
Chapter one summarized the recent advance of the research to kinds and writing age of ballpoint pen inks.
In chapter two, A High performance liquid chromatography (HPLC) method was established to study black ballpoint pen inks, different kinds of black ballpoint pen inks from different trademarks were classified into different categories according to disparities of their dye components. Hierarchical clustering analysis was adopted to analyze data of HPLC.
In chapter three, High performance liquid chromatography-mass spectrometry (HPLC- MS) was used to studied black ballpoint pen inks.
In chapter four, the kinds of black ballpoint pen inks were studied by UV-vis spectrophotometry, different UV absorption peaks were used for kind analysis.
In chapter five, electrochemistry method was used to study the kinds of black ballpoint pen inks, different peak potentions were used for kind analysis.
In chapter six, the research work of the dissertation was summarized and the prospect of this research field was given.
第一章详细评述了近年来有关圆珠笔油墨种类及其字迹色痕形成时间的研究进展。
第二章采用高效液相色谱法(HPLC)对黑色圆珠笔油墨的种类进行了研究,根据有色成分的不同对不同品牌的黑色圆珠笔进行分类,同时采用系统聚类分析的方法,对实验结果进行了化学计量学的分析。
第三章介绍了黑色圆珠笔油墨字迹色痕的高效液相色谱-质谱法(HPLC- MS)的研究情况。
第四章采用紫外可见分光光度法对黑色圆珠笔油墨的种类进行了研究,依据紫外可见光谱图中特征峰位置的不同进行种类的认定。
第五章介绍了极谱法在黑色圆珠笔油墨种类研究中的应用,根据不同染料还原峰电位的不同进行分类。
第六章总结了本论文的研究工作,指出了论文工作的不足之处,并对该研究工作的未来发展提出了设想。
As it is a frequently encountered problem of forensic science nowadays to distinguish whether the questioned documents, such as deeds, contracts and receipts, written in ballpoint pen inks are true or not, and identify the writing age of them, it is very essential to establish a simple, sensitive and accurate method to examine the similarities and differences of the ballpoint pen inks and identify the writing age. In this study, 130 different kinds of black ballpoint pen inks from different manufactures were studied, concerning five methods: UV-vis spectrophotometry, Oscillopolarography, High performance liquid chromatography, High performance liquid chromatogramphy-mass spectrometry and Hierarchical clustering analysis
Chapter one summarized the recent advance of the research to kinds and writing age of ballpoint pen inks.
In chapter two, A High performance liquid chromatography (HPLC) method was established to study black ballpoint pen inks, different kinds of black ballpoint pen inks from different trademarks were classified into different categories according to disparities of their dye components. Hierarchical clustering analysis was adopted to analyze data of HPLC.
In chapter three, High performance liquid chromatography-mass spectrometry (HPLC- MS) was used to studied black ballpoint pen inks.
In chapter four, the kinds of black ballpoint pen inks were studied by UV-vis spectrophotometry, different UV absorption peaks were used for kind analysis.
In chapter five, electrochemistry method was used to study the kinds of black ballpoint pen inks, different peak potentions were used for kind analysis.
In chapter six, the research work of the dissertation was summarized and the prospect of this research field was given.
引文
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[1]王炳娟,马秋凤,邹洪.薄层色谱法鉴定蓝色圆珠笔中油墨的研究[J].分析试验室, 2007, 26.
[2] GRIM D M, SIEGEL J, ALLISON J. Dose ink age inside of a pen cartridge[J].Forensic Sci, 2002, 47(6).
[1]王岩,吕煜,王景翰等.紫外可见光谱法分析蓝色圆珠笔油墨[J].广东公安科技, 2002, 68(4): 18-21
[2] NG L K, LAFONTAINE P, BRAZEAU L. Ballpoint pen inks:Characterization by positive and negative ion-electrospray ionization mass spectrometry for the forensic examination of writing inks[J]. Forensic.Sci, 2002, 47(4):1238
[3] GRIM D M, SIEGEL J, ALLISON J. Dose ink age inside of a pen cartridge[J].Forensic Sci, 2002, 47(6)
[4]吴欣.最新实用印刷色彩[M].北京:中国轻工业出版社, 2006, 37
[5]王炳娟,马秋凤,邹洪.薄层色谱法鉴定蓝色圆珠笔中油墨的研究[J].分析试验室, 2007, 26,增刊
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[2]王彦吉等.光谱分析与色谱分析.北京大学出版社, 1995: 81-102
[2]王俭.傅立叶变换红外显微光谱法鉴别蓝色圆珠笔字迹色痕.光谱学与光谱分析, 1999, 19(6): 192-194
[3]王俭.蓝色圆珠笔字迹色痕ATR谱与模式识别研究.高等学校化学学报, 2001, 22(6): 925-927
[4]王俭.蓝色圆珠笔油墨紫外光照射变化的研究.分析化学, 2000, 28(9): 1107-1109
[5]冯计民. Micro-ATR技术对书写笔痕的鉴别.刑事技术, 1998, 2: 13-14
[6] Andrasko J.Microrefiectance FTIR techniques applied to materies encounterd in forensic examination of documents[J]. Forensic Sci, 1996, 41 (5): 812-823
[7] Merrill RA et al. Analysis of ballpoint pen ink by diffuse reflectance infrared spectrometry[J]. Forensic Sci, 1992, 37(2): 528-541
[8] Mazzella W D et al. Classification and identification of photocopying toner by DRIFTS: 1 Preliminary results[J]. Forensic Sci, 1991, 36(2): 449-465
[9] Mazzella W D et al. Classification and identification of photocopying toner by DRIFTS:I. Preliminary results[J]. Forensic Sci, 1991, 36(3): 820-837
[10] Harris J. A preliminary report on the nondestructive examination of question documents by FTIR spectroscopy[J]. Candian Society of forensic science journal, 1991, 24(1): 4-21
[11] Trzeinska B. Infrared spectroscopy of ballpen paste [J]. Forensic Sci, 1990, 46: 105-109
[12]潘家来.激光拉曼光谱在有机化学上的应用[M].化学出版社, 1986, 49
[13] Cheng C. In situ detection of trace explosives by Raman microscopy[J]. Forensic Sci, 1995, 40(1):31-37
[14] Hayward I P. Use of fiber optic probe the detection and identification of explosive by Raman spectroscopy[J]. Forensic Sci, 1995, 40(5): 883-884
[15] Sands H. UV-excited resonance Raman spectroscopy of narcotics and explosives[J]. Forensic Sci, 1998, 43(3): 509-513
[16] Suzuki E M. In situ identification and analysis of automotive paint pigments using line segment excitation Raman specrroscopy Inoganic topocoat pigments[J]. Forensic Sci, 2001, 46(5): 1053-1069
[17] White P C. SERRS Spectroscopy-A new technique for forensic science[J]. Science &Justice, 2000,40(2): 113-119
[18] Kuptsov A H. Application of fourier transform raman spectroscopy in forensic science[J]. Forensic Sci, 1994, 39(2): 305-318
[19] Mclaybourn. Using Raman spectroscopy to solve crime ink, questioned documents and faud[J]. Science & Justice, 2000, 40(4): 261-271
[20]徐彻.傅立叶拉曼光谱发鉴别黑色墨水的研究[J].医学杂志, 1998, 14(3): 146-148
[21]梁鲁宁.激光拉曼光谱区分黑色圆珠笔字迹初探[J].刑事技术, 2000, 3: 28-29
[22] Reza M. Applicability of surface enhanced resonance Raman scattering for the direct discrimination of ballpoint pen inks[J]. Analyst, 2001, 1418-1422
[23] Cantu A A. Analytical methods for detecting fraudulent documents[J]. Anal Chem, 1991, 63(17): 847-852
[24] Olson. Color comparison in questioned document examination using microspectrophotometry [J]. Forensic Sci, 1986, 31(4):1330-1340
[25] Pfefferli. Application of microspectrophotometry in document examination[J]. Forensic Sci, 1983, 23:129-136
[26] Hartshorne A W. The definition of colour for single textile fibres by microspectrophotometry[J]. Forensic Sci, 1987, 34:107-129
[27] Zeichner A. Transmission and reflectance microspectrophotometry of inks[J]. Forensic Sci, 1988, 33(5): 1171-1184
[28] Zeichner A. Some special observations regarding visible transmission spectra of ink and improved method for their discrimination by microspectrophotometry[J]. Forensic Sci, 1992, 37(3): 475-749
[29] Cantu A A. Comments on accelerated aging of inks[J]. Forensic Sci, 1988, 33(3): 744-750
[30]王岩,王俭,郝旺林,王彦吉.蓝色圆珠笔油墨薄层色谱扫描条件的选择[J].检验技术, 15-18
[31]李继民.薄层色谱及其扫描法鉴别蓝圆珠笔油墨的种类[J].中国人民公安大学学报(自然科学版), 2003, 38(6): 22-24
[32]李继民.常见黑色签字笔油墨种类鉴别研究[J].广东公安科技, 2002(3): 21-24
[33]任玲.薄层色谱鉴定黑色圆珠笔墨水[J].中国人民公安大学学报(自然科学版), 1999(3): 21-25
[34]谢朋,王晶,暴仁等.新型薄层色谱法鉴别钢笔墨水色料的研究[J].中国人民公安大学学报(自然科学版), 2002(3): 11-13
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