基于N-烷基吡啶和1，3-二烷基咪唑类离子液体为溶剂和模板剂的金属磷酸盐的离子热合成、结构与表征
|
摘要
近年来,人们对微孔化合物进行了系统的研究,合成得到了大量的开放式框架金属磷酸盐和亚磷酸盐,且它们在催化、分离和离子交换等领域表现出了潜在的应用价值。这些化合物一般都是在水热或溶剂热(反应介质完全为分子溶剂)反应条件下来制备的,实验中经常被使用的模板剂包括有机胺、碱土金属阳离子和金属络合物等。2004年,Morris等人报道了一种全新的微孔材料合成方法-离子热合成法。这种方法以室温离子液体或低共熔混合物为反应溶剂和模板剂,完全摆脱了原来分子溶剂的约束,化学反应环境完全是离子的。离子液体本身的优良溶解性能,低蒸汽压、高热力学稳定性和作为绿色反应溶剂的可循环性,使这种合成方法倍受化学工作者的关注。更为重要的是,离子液体同时作为反应溶剂和模板剂,有效的消除了传统微孔材料合成中不可避免的溶剂-框架和模板剂-框架之间的竞争问题。离子热体系特殊的化学反应环境,为具有新颖结构和特殊性质的新型微孔材料的合成设计带来了新的契机。
本论文在离子热条件下,合成得到十一种金属(亚)磷酸盐化合物,并通过单晶X-射线衍射、粉末X-射线衍射、ICP和元素分析、红外光谱及热重分析等手段对化合物的结构和性质进行了表征。研究成果主要包括以下四个方面:
(1)以N-甲基吡啶碘离子液体为反应溶剂和模板剂,合成得到具有低框架密度的手性三维开放式框架磷酸锌NIS-1(NENU Ionothermal Synthesis-1)及具有二维层结构的磷酸锌NIS-2;以N-乙基吡啶溴离子液体为反应溶剂和模板剂,合成得到二维层结构的磷酸锌NIS-3;以N-丙基吡啶溴离子液体为反应溶剂和模板剂,合成得到二维层结构的磷酸锌NIS-4。
(2)以1,3-二甲基咪唑碘离子液体为反应溶剂和模板剂,合成得到二维层结构的磷酸锌NIS-5;以1-乙基-3-甲基咪唑溴离子液体为反应溶剂和模板剂,合成得到具有非心空间群和超低框架密度结构的三维开放式框架磷酸锌NIS-6和一维链状结构的磷酸铝NIS-7,及与其同构的一维链状磷酸镓NIS-8。
(3)以1-乙基-3-甲基咪唑溴离子液体和咪唑的适量比混合物为反应溶剂和模板剂,合成得到与咪唑配位的零维钒磷酸盐簇NIS-9和手性三维开放式框架磷酸镓NIS-10。
(4)以1-乙基-3-甲基咪唑溴离子液体为反应溶剂和模板剂,合成得到具有低框架密度和螺旋结构的三维开放式框架亚磷酸锌NIS-11。
In recent years, microporous materials have been intensively studied. Among these microporous materials, metal phosphates and phosphites are quite attractive due to their rich structural chemistry and potential applications in catalysis, separation, adsorption, and ion-exchanging. These materials have been synthesized under hydrothermal or solvothermal conditions, by using organic amine, alkali metallic cations, metalic complexes as structure-directing agents. In 2004, Morris and coworkers reported a new type of solvothermal synthesis in which an ionic liquid or eutectic mixture was used as both the solvent and structure-directing agent in the preparation of zeotype aluminum phosphates. This new synthetic method has been termed ionothermal synthesis and the reactional media is completely ionic circumstance. To date, more and more attention has been paid to the ionothermal method due to the excellent solvating properties, vanishingly small vapor pressure, high thermal stability, and recyclability of ionic liquids as“green”solvent. Furthermore, the application of an ionic liquid as solvent and template can effectively remove the competition between template-framework and solvent-framework interactions that occurs inevitably in traditional preparation. The different chemistry of ionothermal solvent system produces conditions under which novel structures may be accessible.
In this dissertation, we focus our study on the synthesis of metal phosphate and phosphite by ionothermal reactions. Eleven new compounds have been ionothermally prepared by using N-alkyl pyridinium- and 1, 3-dialkyl imidazolium-based ionic liquids as solvents and templates. These compounds have been characterized by single crystal X-ray diffractions, PXRD, elemental analyses, ICP analyses, IR spectra and TG analyses. These results will be introduced from the following four issues:
1. A novel 3D chiral open-framework zinc phosphate, NIS-1 (Northeast Normal Univesity Ionothermal Synthesis-1), with low framework density and fascinating helical channels, has been ionothermally synthesized by using N-methyl pyridinium iodide as solvent and template. Meanwhile, three 2D layered zinc phosphates, NIS-2, NIS-3, NIS-4, have been ionothermally prepared in N-methyl pyridinium iodide, N-ethyl pyridinium bromide, N-propyl pyridinium bromide, respectively.
2. A new layered zinc phosphate, NIS-5, was synthesized by using 1, 3-dimethyl imidazolium iodide as solvent and template. Meanwhile, a novel 3D non-centrosymmetric open-framework zinc phosphate, NIS-6, which exhibits remarkably low framework density and interesting helical channels, has been ionothermally synthesized by using 1-ethyl-3-methyl imidazolium bromide as solvent and template. Furthermore, a 1D aluminum phosphate, NIS-7,and its isostructural gallium phosphate,NIS-8,have been both prepared in 1-ethyl 3-methyl imidazolium bromide.
3. A vanadium-phosphorus oxide cluster,NIS-9 and a novel 3D chiral open-framework gallium phosphate,NIS-10,have been ionothermally synthesized in the presence of metal oxide,phosphoric acid, imidazole and 1-ethyl-3-methyl imidazolium bromide. For NIS-9, each V atom is chelated by one imidazole molecule, the negative charge of framework is balanced by three ionic liquid cations; while for NIS-10, only Ga(3) atom is chelated by one imidazole molecule, the negative charge of framework is balanced by one protonated imidazole and half of an ionic liquid cation.
4. A novel 3D open-framework zinc phosphite, NIS-11, possessing low framework density and helices, has been ionothermally synthesized and characterized by using 1-ethyl-3-methyl imidazolium bromide as solvent and template.
本论文在离子热条件下,合成得到十一种金属(亚)磷酸盐化合物,并通过单晶X-射线衍射、粉末X-射线衍射、ICP和元素分析、红外光谱及热重分析等手段对化合物的结构和性质进行了表征。研究成果主要包括以下四个方面:
(1)以N-甲基吡啶碘离子液体为反应溶剂和模板剂,合成得到具有低框架密度的手性三维开放式框架磷酸锌NIS-1(NENU Ionothermal Synthesis-1)及具有二维层结构的磷酸锌NIS-2;以N-乙基吡啶溴离子液体为反应溶剂和模板剂,合成得到二维层结构的磷酸锌NIS-3;以N-丙基吡啶溴离子液体为反应溶剂和模板剂,合成得到二维层结构的磷酸锌NIS-4。
(2)以1,3-二甲基咪唑碘离子液体为反应溶剂和模板剂,合成得到二维层结构的磷酸锌NIS-5;以1-乙基-3-甲基咪唑溴离子液体为反应溶剂和模板剂,合成得到具有非心空间群和超低框架密度结构的三维开放式框架磷酸锌NIS-6和一维链状结构的磷酸铝NIS-7,及与其同构的一维链状磷酸镓NIS-8。
(3)以1-乙基-3-甲基咪唑溴离子液体和咪唑的适量比混合物为反应溶剂和模板剂,合成得到与咪唑配位的零维钒磷酸盐簇NIS-9和手性三维开放式框架磷酸镓NIS-10。
(4)以1-乙基-3-甲基咪唑溴离子液体为反应溶剂和模板剂,合成得到具有低框架密度和螺旋结构的三维开放式框架亚磷酸锌NIS-11。
In recent years, microporous materials have been intensively studied. Among these microporous materials, metal phosphates and phosphites are quite attractive due to their rich structural chemistry and potential applications in catalysis, separation, adsorption, and ion-exchanging. These materials have been synthesized under hydrothermal or solvothermal conditions, by using organic amine, alkali metallic cations, metalic complexes as structure-directing agents. In 2004, Morris and coworkers reported a new type of solvothermal synthesis in which an ionic liquid or eutectic mixture was used as both the solvent and structure-directing agent in the preparation of zeotype aluminum phosphates. This new synthetic method has been termed ionothermal synthesis and the reactional media is completely ionic circumstance. To date, more and more attention has been paid to the ionothermal method due to the excellent solvating properties, vanishingly small vapor pressure, high thermal stability, and recyclability of ionic liquids as“green”solvent. Furthermore, the application of an ionic liquid as solvent and template can effectively remove the competition between template-framework and solvent-framework interactions that occurs inevitably in traditional preparation. The different chemistry of ionothermal solvent system produces conditions under which novel structures may be accessible.
In this dissertation, we focus our study on the synthesis of metal phosphate and phosphite by ionothermal reactions. Eleven new compounds have been ionothermally prepared by using N-alkyl pyridinium- and 1, 3-dialkyl imidazolium-based ionic liquids as solvents and templates. These compounds have been characterized by single crystal X-ray diffractions, PXRD, elemental analyses, ICP analyses, IR spectra and TG analyses. These results will be introduced from the following four issues:
1. A novel 3D chiral open-framework zinc phosphate, NIS-1 (Northeast Normal Univesity Ionothermal Synthesis-1), with low framework density and fascinating helical channels, has been ionothermally synthesized by using N-methyl pyridinium iodide as solvent and template. Meanwhile, three 2D layered zinc phosphates, NIS-2, NIS-3, NIS-4, have been ionothermally prepared in N-methyl pyridinium iodide, N-ethyl pyridinium bromide, N-propyl pyridinium bromide, respectively.
2. A new layered zinc phosphate, NIS-5, was synthesized by using 1, 3-dimethyl imidazolium iodide as solvent and template. Meanwhile, a novel 3D non-centrosymmetric open-framework zinc phosphate, NIS-6, which exhibits remarkably low framework density and interesting helical channels, has been ionothermally synthesized by using 1-ethyl-3-methyl imidazolium bromide as solvent and template. Furthermore, a 1D aluminum phosphate, NIS-7,and its isostructural gallium phosphate,NIS-8,have been both prepared in 1-ethyl 3-methyl imidazolium bromide.
3. A vanadium-phosphorus oxide cluster,NIS-9 and a novel 3D chiral open-framework gallium phosphate,NIS-10,have been ionothermally synthesized in the presence of metal oxide,phosphoric acid, imidazole and 1-ethyl-3-methyl imidazolium bromide. For NIS-9, each V atom is chelated by one imidazole molecule, the negative charge of framework is balanced by three ionic liquid cations; while for NIS-10, only Ga(3) atom is chelated by one imidazole molecule, the negative charge of framework is balanced by one protonated imidazole and half of an ionic liquid cation.
4. A novel 3D open-framework zinc phosphite, NIS-11, possessing low framework density and helices, has been ionothermally synthesized and characterized by using 1-ethyl-3-methyl imidazolium bromide as solvent and template.
引文
[1]徐如人,庞文琴.《分子筛与多孔材料化学》[M].北京:科学出版社,2004.
[2]Everett D H.IUPAC manual of symbols and terminology [J]. Pure Appl Chem,1972,31(4):577-638.
[3]Francis R J,O’Hare D.The kinetics and mechanisms of the crystallisation of microporous materials [J]. J Chem Soc,Dalton Trans,1998(19):3133-3148.
[4]Di Renzo F,Cambon H,Dutartre R.A 28-year-old synthesis of micelle-templated mesoporous silica [J]. Micropor Mater,1997,10(4-6):283-286.
[5]Yanagisawa T,Shimizu T,Kuroda K,et al. Synthesis,characterization of mesoporous Al-Mg composite oxide and catalytic performance for oxyethylation of fatty alcohol [J]. Bull Chem Soc Jpn,1990,63(5):988-992.
[6]徐如人.科学,1998,50 (1):12-15.
[7]Sayari A,Karra V R,Reddy J S,et al. Synthesis of mesostructured lamellar aluminophosphates [J]. Chem Commun,1996(3):411-412.
[8]Bagshaw S A,Pinnavain T J. Mesoporous alumina molecular sieves [J]. Angew Chem Int Ed Engl,1996,35(10):1102-1105.
[9]Braun P V,Osenar P,Stupp S I.Semiconducting superlattices templated by molecular assemblies [J]. Nature,1996,380(6572):325-327.
[10]Attard G S,Corker J M,G?ltner C G,et al. Liquid-crystal templates for nanostructured metals [J]. Angew Chem Int Ed Engl,1997,36(12):1315-1317.
[11]Ryoo R,Joo S H,Kruk M,et al. [J]. Ordered mesoporous carbons [J]. Adv Mater,2001,13(9):677-681.
[12]Huo Q S,Margolese D I,Stucky G D. Surfactant control of phases in the synthesis of mesoporous silica-Based materials [J]. Chem Mater,1996,8(5):1147-1160.
[13]Velev O D,Jede T A,Lobo R F,et al. Microstructured porous silica obained via colloidal crystal template [J]. Chem Mater,1998 10(11):3597-3602.
[14]Davis M E,Saldarriaga C,Montes C,et al.A molecular sieve with eighteen-membered rings [J]. Nature,1988,331(6158):698-699.
[15]Davis S A,Burkett S L,Mendelson N H,et al. Bacterial templating of ordered macrostructures in silica and silica-surfactant mesophases [J]. Nature,1997,385(6615):420-423.
[16]Imhof A,Pine D J.Ordered macroporous materials by emulsion templating [J]. Nature,1997,389(6654):948-951.
[17]Choi K , Gardner D , Hilbrandt N , et al. Combinatorial Methods for the Synthesis of Aluminophosphate Molecular Sieves [J]. Angew Chem Int Ed,1999,38(19):2891-2894.
[18]Flanigen E M,Lok B M,Patton R L,et al. Aluminophosphate Molecular Sievesand the periodic Table.Proc.Of the 7th Intl.Zeolite Conf.Kodansha-Elsevier,Murakam Y,Lijima A,Ward J W(Eds),1986,103-112.
[19]Yu J,Xu R.Rich structure chemistry in the aluminophosphate family [J]. Acc Chem Res,2003,36(7):481-490.
[20]Yu J,Li J,Xu R. Structural diversity of a family of aluminophosphates with Al/P ratio of non-unity [J].Solid State Sci,2000,2(2):181-192.
[21]Chen J,Pang W,Xu R. Mixed-bonded open-framework aluminophosphates and related layered materials [J]. Top Catal,1999,9(1-2):93-103.
[22]Wang K,Yu J,Miao P,et al. A new layered aluminophosphate [C4H12N2][Al2P2O8(OH)2] templated by piperazine [J]. J Mater Chem,2001,11(7):1898-1902.
[23]Kongshaug K O,Fjellvag H,Lillerud K P. Layered aluminophosphates I.crystal structure of two novel layered aluminophosphates solved ab initio from powder diffraction data [J]. Micropor Mesopor Mater,1999,32(1-2):17-28.
[24]Kongshaug K O,Fjellvag H,Lillerud K P. Layered aluminophosphates II.crystal structure and thermal behaviour of the layered aluminophosphate UiO-15 and its high temperature variants [J]. J Mater Chem,1999,9(7):1591-1598.
[25]Maeda K,Tuel A,Baerlocher C. Synthesis and characterization of a new layered aluminophosphate templated with 1,3-diaminopropane:[H3N(CH2)3NH3]0.5[AlPO4(OH)(OH2)]·H2O [J]. J Chem Soc,Dalton Trans,2000(14):2457-2462.
[26]Riou D , Loiseau T , Férey G. Structure determination of(N2C2H10)4(NH4)AlP4O16 : a new aluminophosphate templated by ethylenediamine [J]. J Solid State Chem,1992,99(2):414-418.
[27]Yan W,Yu J,Shi Z,et al. A novel open-framework aluminophosphate [AlP2O6(OH)2][H3O] containing propeller-like chiral motifs [J]. Chem Commun,2000(15):1431-1432.
[28]Yu J,Williams I D.Two unusual layer aluminophosphates templated by imidazolium ions:[N2C3H5][AlP2O8H2·2H2O] and 2[N2C3H5][Al3P4O16H] [J]. J Solid State Chem,1998,136(1):141-144.
[29]Yu J,Terasaki O,Williams I D,et al. Solvothermal synthesis and characterization of new aluminophosphate layers templated by imidazolium ions [J]. Supramol Sci,1998,5(3-4):297-302.
[30]Morgan K R , Gainsford G J , Milestone N B. A new type of layered aluminiumphosphate[NH4]3[Co(NH3)6]3[Al2(PO4)4]2 assembled about a cobalt(III) hexammine complex [J]. Chem Commun,1997(1):61-62.
[31]Leech M A,Cowley A R,Prout K,et al. Ambient-temperature synthesis of new layered AlPOs and GaPOs in silica gels [J]. Chem Mater,1998,10(1):451-456.
[32]Jones R H,Thomas J M,Xu R,et al. Synthesis and structure of a one-dimensionally extended aluminium phosphate Et3NH+(H2AlP2O8)- [J]. J Chem Soc,Chem Commun,1990(17):1170-1172.
[33]Williams I D,Yu J,Gao Q,et al. New chain architecture for a one-dimensional aluminophosphate,[H3NCH2CH2NH3][AlP2O8H] [J]. Chem Commun,1997(14):1273-1274.
[34]Gao Q,Chen J,Li S,et al. Synthesis and structure of a chain aluminophosphate filled with [NH4]+and[H3NCH2CH2NH3]2+cations [J]. J Solid State Chem,1996,127(2):145-150.
[35]Ayi A A,Choudhury A,Natarajan S. Linear-chain AlPOs obtained by the reaction of amine phosphates with Al3+ions [J]. J Solid State Chem,2001,156(1):185-193.
[36]Wei B,Yu J,Shi Z,et al. A new layered aluminophosphate [Al2P4O16][C6H22N4][C2H10N2] with 4.12-net porous sheets [J]. J Chem Soc,Dalton Trans,2000(13):1979-1980.
[37]Bircsak Z,Harrison W T A.Template cooperation effect leading to the new layered aluminophosphate CN3H6·Al(HPO4)2·2H2O [J]. Chem Mater,1998,10(10):3016-3019.
[38]Sugiyama K,Hiraga K,Yu J,et al. A one-dimensionally extended chain aluminophosphate [J]. Acta Cryst,1999,C55(10):1615-1617.
[39]Wei B,Zhu G,Yu J,et al. Solvothermal synthesis and characterization of a new 3-D open-frameworkaluminophosphate [Al2P3O12][C4N3H16] [J]. Chem Mater,1999,11(12):3417-3419.
[40]Yu J,Sugiyama K,Togashi N,et al. Synthesis and characterization of a new two-dimensional aluminophosphate layer and structural diversity in anionic aluminophosphates with Al2P3O123- stoichiometry [J]. Chem Mater,1998,10(11):3636-3642.
[41]Chippindale A M,Powell A V,Bull L M,et al. Synthesis and characterization of 2 layered aluminophosphates,(T)2HAl2P3O12(T=2-BuNH3+) and (T)H2Al2P3O12(T=PyH+) [J]. J Solid State Chem,1992,96(1):199-210.
[42]Oliver S,Kuperman A,Lough A,et al. Aluminophosphate chain-to-layer transformation [J].Chem Mater,1996,8(9):2391-2398.
[43]Oliver S,Kuperman A,Lough A,et al.The synthesis and structure oftwo novel layered aluminophosphates containing interlamellar cyclohexylammonium[J].Chem Commun,1996(15):1761-1762.
[44]Chippindale A M,Walton R I.[C9H20N][Al2(HPO4)2(PO4)]:An aluminium phosphate with a new layer topology[J].J Solid State Chem,1999,145(2):731-738.
[45]Xu Y,Zhang B,Chen X,et al.An open frameworkaluminophosphate with unique 12-membered ring channels:Al9(PO4)12(C24H91N16)17·H2O [J].J Solid State Chem,1999,145(1):220-226.
[46]Jones R H,Thomas J M,Xu R,et al.Synthesis and structure of a novel aluminum phosphate anion-(Al3P4O16)3-[J].J Chem Soc,Chem Commun,1991(18):1266-1268.
[47]Gao Q,Li B,Chen J,et al. Nonaqueous synthesis and charaterization of a new 2-dimensional layered aluminophosphate [Al3P4O16]·3[CH3CH2NH3] [J].J Solid State Chem,1997,129(1):37-44.
[48]Thomas J M , Jones R H , Xu R , et al. A novel porous sheet aluminophosphate (Al3P4O16)3-·1.5[NH3(CH2)4NH3]2+ [J].J Chem Soc,Chem Commun,1992(13):929-931.
[49]Chippindale A M,Cowley A R,Huo Q,et al.Synthesis and structure of a new layered aluminium phosphate: [BuNH3]3[Al3P4O16][J].J Chem Soc,Dalton Trans,1997,15:2639-2643.
[50]Williams I D,Gao Q,Chen J,et al.Organic-template controlof inorganic structure: a low-symmetry two-dimensional sheet aluminophosphate 3[NH3CHMeCH2NH3][Al6P8O32]·H2O [J].Chem Commun,1996(15):1781-1782.
[51]Yu J , Li J , Sugiyama K , et al. Formation of a new layered aluminophosphate [Al3P4O16][C5N2H9]2[NH4] [J].Chem Mater,1999,11(7):1727-1732.
[52]Jones R H,Chippindale A M,Natarajan S,et al. A reactive template in the synthesis of a novel layered aluminum phosphate(Al3P4O16)3-[NH3(CH2)5NH3]2+(C5H10NH2)+ [J].J Chem Soc,Chem Commun,1994(5):565-566.
[53]Barrett P A,Jones R H.The pore-size modification of a layered aluminophosphate [Al3P4O16C9H24N3] by rational selection of the intercalated template cation [J].J Chem Soc,Chem Commun,1995(19):1979-1980.
[54] Oliver S,Kuperman A,Lough A,et al. Synthesis and crystal structures of two novel anionic aluminophosphates: a one-dimensional chain,UT-7([Al3P5O20H]5-[C7H13NH3+]5),and a layer containing two cycli amines,UT-8([Al3P4O16]3-[C4H7NH3+]2[C5H10NH2+]) [J].Inorg Chem,1996,35(22):6373-6380.
[55] Togashi N,Yu J,Zheng S,et al. Synthesis and structure of a 2-D layer Al3P4O16 center dot 3CH3CH2CH2NH3 [J].J Mater Chem,1998,8(12):2827-2830.
[56] Yao Y,Natarajan S,Chen J,et al.Synthesis and structural characterization of a new layered aluminophosphate intercalated with triply-protonated triethylenetetramine [C6H21N4][Al3P4O16] [J].JSolid State Chem,1999,146(2):458-463.
[57] Vidal L,Gramlich V,Patarin J,et al. Synthesis,characterization and structure of Mu-7,a new layered aluminophosphate with a 4×8 network [J]. Chem Lett,1999,3:201-202.
[58] Yu J,Williams I D.Two unusual layer aluminophosphates templated by imidazolium ions: [N2C3H5][AlP2O8H2·2H2O] and 2[N2C3H5][Al3P4O16H] [J]. J Solid State Chem,1998,136(1):141-144.
[59] Oliver S,Kuperman A,Lough A,et al. Aluminophosphate chain-to-layer transformation [J].Chem Mater,1996,8(9):2391-2398.
[60] Zhang M , Zhou D , Li J Y , et al. Synthesis and characterization of a new layered fluoroaluminophosphate (C4H11NOH)3.5[Al4(PO4)5F]·0.5H3O with extra-large 16-rings [J]. Inorg Chem 2007,46(1):136-140.
[61] Yu J,Sugiyama K,Zheng S,et al. Al16P20O80H44C6H18N2: A new microporous aluminophosphate containing intersecting 12- and 8-membered ring channels [J]. Chem.Mater,1998,10(5):1208-1211.
[62] Vidal L,Gramlich V,Patarin J,et al. Synthesis and structure of Mu-4,the new layered aluminophosphate [(C2H5)2NH2]4[Al8P10O40H2][H2O]2.5 [J]. Eur J Solid State Chem,1998,35(8-9):545-563.
[63] Jones R H , Thomas J M , Chen J , et al.Structure of anunusual aluminium phosphate ([Al5P6O24H]2-2[N(C2H5)3H]+·2H2O) JDF-20 with large elliptical apertures [J]. J Solid State Chem,1993,102(1):204-208.
[64] Wang K , Yu J , Shi Z , et al.Synthesis and characterization ofa new three-dimensional aluminophosphate [Al11P12O48][C4H12N2][C4H11N2] with an Al/P ratio of 11/12 [J]. J Chem Soc,Dalton Trans,2001(12):1809-1812.
[65] Yan W,Yu J,Shi Z,et al.An anionic framework aluminophosphate vertical bar (CH2)6N4H3·H2O center dot H2O vertical bar [Al11P12O48] and computer simulation of the template positions [J]. Microporous and Mesoporous Mater,2001,50(2-3):151-158.
[66] Yan W,Yu J,Xu R,et al. [Al12P13O52]3-[(CH2)6N4H3]3+: An anionic aluminophosphate molecular sieve with bronsted acidity [J]. Chem Mater,2000,12(9):2517-2519.
[67] Feng P,Bu X,Stucky G D. Control of structural ordering in crystalline lamellar aluminophosphates with periodicity from 51 to 62 angstrom [J]. Inorg Chem,2000,39(1):2-3.
[68] Huo Q,Xu R,Li S,et al. Syntehesis and characterization of a novel extra large ring of aluminophasphate JDF-20 [J]. J Chem Soc,Chem Commun,1992(12):875-876.
[69] Parise J B. Preparation and structural characterization of 2 metallophosphate frameworks clathrating diprotonated ethylenediamine:AlPO4-12(en) and GaPO4-12(en) [J]. Inorg Chem,1985,24(25):4312-4316.
[70] Feng S,Xu R,Yang G,et al.Chem J Chin Univ,1988(4):1.
[71]冯守华. [D]:[博士学位论文].长春:吉林大学化学学院,1986.
[72] Estermann M E,McCusker L B,Boelocher C,et al.A synthetic gallophosphate molecular-sieve with a 20-tetrahedral-atom pore opening [J]. Nature,1991,352: 320-323.
[73] Kan Q,Glasser F P,Xu R. Synthesis and characterization of 2 galliophosphates with occluded methylamine [J]. J Mater Chem,1993,3(9):983.
[74] Chippindale A M,Walton R I,Turner C. Synthesis and structure of a novel open-framework gallium phosphate [Me2NH(CH2)2NHMe2]2+[Ga4P5O20H]2-·H2O [J]. J Chem Soc,Chem Commun,1995(12):1261-1262
[75] Lin C,Wang S. [(1S,2S)-H2DACH][Ga2(1S,2S-DACH)(HPO4)(PO4)2]: A layered chiral gallophosphate containing chiral ligand and chiral template [J]. Inorg Chem,2001,40(12):2918-2921.
[76] Loiseau T,Ferey G. Oxyfluorinated microporous compounds,VII. synthesis and crystal structure of ULM-5,a new fluorinated gallophosphate Ga16(PO4)14(HPO4)2(OH)2F7,[H3N(CH2)6NH3]4,6H2O with 16-membered rings and both bonding and encapsulated F- [J]. J Solid State Chem ,1994,111(2):403-415.
[77] Loiseau T,Ferey G. Synthesis and crystal structure of ULM-16,a new open-framework fluorinated gallium phosphate with 16-ring channels: Ga4(PO4)4F2-·1.5NC6H14·0.5H2O·0.5H3O [J]. J Mater Chem,1996,6(6):1073-1074.
[78] Sassoye C,Loiseau T,Taulelle F,et al. A new open-framework fluorinated gallium phosphate with large 18-ring channels(MIL-31)[J] .Chem Commun,2000,11: 943-944.
[79] Sassoye C,Marrot J,Loiseau T,et al. Utilization of cyclopentylamine as structure-directing agent for the formation of fluorinated gallium phosphates exhibiting extra-large-pore open frameworks with 16-ring (ULM-16) and 18-ring channels (MIL-46) [J]. Chem Mater,2002,14(3):1340-1347.
[80] Beitone L,Marrot J,Loiseau T,et al. MIL-50,an open-framework GaPO with a periodic pattern of small water ponds and dry rubidium atoms:a combined XRD,NMR,and computational study[J]. J Am Chem Soc,2003,125(7):1912-1922.
[81] Walton R I,Millange F,Loiseau T,et al. Crystallization of a large-pore three-dimensional gallium fluorophosphate under mild conditions [J].Angew Chem Int Ed,2000,39(24):4552-4555.
[82] Chippindale A M,Peacock K J,Cowley A R.Synthesis and characterization of a large-pore,open-framework gallium phosphate,[NH3(CH2)4NH3]2[Ga4(HPO4)2(PO4)3(OH)3]·yH2O,and its vanadium-gallium phosphate analogue , [NH3(CH2)4NH3]2[Ga4-xVx(HPO4)2(PO4)3(OH)3]·yH2O (x≈0.4,y≈0.6) [J]. J Solid State Chem,1999,145(2):379-386.
[83] Lin C-H,Wang S-N,Lii K-H.[Ga2(DETA)(PO4)2]·2H2O (DETA=diethylenetriamine): A novel porous gallium phosphate containing 24-ring channels [J]. J Am Chem Soc,2001,123(19): 4649-4650.
[84] Schuth F,Schmidt W. Advanced materials progess repot on microporous and mesoporous material [J]. Adv Mater. 2002,14(9): 629-638.
[85] Yang Y L,Liu Y,Chen C. Hydrothermal synthesis and characterization of an organically templated gallophosphate JGP-5 [J]. Polyhedron,2004,23(9): 1535-1539
[86]杨玉林.稀反应体系下开放骨架结构的磷酸镓(亚磷酸镓)微孔晶体的水热合成研究[D]:[博士学位论文].长春:吉林大学化学学院,2004.
[87]杨磊.具有开放骨架结构磷酸镓(亚磷酸镓)微孔晶体的水热合成与研究[D]:[博士学位论文].长春:吉林大学化学学院,2005.
[88]高源.新型骨架结构的磷酸镓类微孔晶体材料的水热合成[D]: [硕士学位论文].哈尔滨:哈尔滨工业大学应用化学系,2006.
[89]马晶.开放骨架结构磷酸镓微孔晶体的水热合成与表征[D]: [硕士学位论文].哈尔滨:哈尔滨工业大学应用化学系,2007.
[90] Dhingra S S , Haushalter R C. Hydrothermal Synthesis and Crystal Structure of H3NCH2CH2NH3[In2(HPO4)4]-A Novel Octahedral-Trahedral Framework Indium Phosphate with Occluded Organic Cations [J]. J Chem Soc,Chem Comm,1993,21: 1665-1667.
[91]伊卓.新型磷酸铟(亚磷酸铟)微孔晶体的水热合成研究[D]:[硕士学位论文].长春:吉林大学化学学院,2005.
[92]陈超.具有开放骨架结构的磷酸铟,磷酸钛微孔晶体的水热合成研究[D]:[博士学位论文].长春:吉林大学化学学院,2006.
[93]刘成站.微孔亚磷酸铟和磷酸铟晶体的水热合成研究[D]:[博士学位论文].长春:吉林大学化学学院,2007.
[94] Harrison W T A,Gier T E,Stucky G D,et al. Structure and Properties of New Zeolite X-Type Zincophosphate and Beryllophosphate Molecular-Sieves [J]. Chem.Mater,1991,3(1): 27-29.
[95] Nenoff T M,Harrison W T A,Gier T E,et al. Room-temperature synthesis and characterization of new ZnPO and ZnAsO sodalite open frameworks [J]. J Am Chem Soc,1991,113(1) 378-379.
[96] Yang G Y,Sevov S C. Zinc Phosphate with Gigantic Pores of 24 Tetrahedra [J]. J Am Chem Soc,1999,121(36): 8389-8390.
[97] Zhu J,Bu X H,Feng P Y,et al. An Open-Framework Material with Dangling Organic Functional Groups in 24-Ring Channels [J]. J Am Chem Soc,2000,122(46): 11563-11564.
[98] Rao C N R,Natarajan S,Choudhury A,et al. Aufbau Princople of Complex Open-Framework Strutures of Metal Phosphates with Different Dimensionalities [J]. Acc Chem Res,2001,34(1): 80-87.
[99] Harrison W T A,Gier T E,Stucky G D,et al. NaZnPO4·H2O,an Open-Framework Sodium Zincophosphate with a New Chiral Tetrahedral Framework Topology [J]. Chem Mater,1996,8(1): 145-151.
[100] Neeraj S,Natarajan S,Rao C N R. A Novel Open-Framework Zinc Phosphate with Intersecting Helical Channels [J]. Chem Commun,1999(2):165-166.
[101] Lin Z E,Yao Y W,Zhang J,et al. Synthesis and Structure of a Novel Open-Framework Zincophosphate with Intersecting Three-Dimensional Helical Channels [J]. J Chem Soc,Dalton Trans,2002,24:4527-4528.
[102]Fan J,Slebodnick C,Angel R,et al. New Zinc Phosphates decorated by imidazole-containing Ligands [J]. Inorg.Chem,2005,44(3):552-558.
[103] Soghomonian V,Chen Q,Haushalter R C,et al. An inorganic double helix: hydrothermal synthesis,structure,and magnetism of chiral [(CH3)2NH2]K4[V10O10(H2O)2(OH)4(PO4)7]·4H2O [J]. Science,1993,259(5101):1596-1599.
[104]Shi Z , Feng S H , Gao S , et al. Inorganic-organic hybrid materials constructed from [(VO2)(HPO4)](infinity) helical chains and [M(4,4`-bpy)2]2+ (M = Co,Ni) fragments [J]. Angew Chem,Int Ed,2000,39(13):2325-2327.
[105] Khan M I,Meyer L M,Haushalter R C,et al. Giant voids in the hydrothermally synthesized microporous square pyramidal tetrahedral framework vanadium phosphates [HN(CH2CH2)3NH]K1.35[V5O9(PO4)2]·xH2O and Cs3[V5O9(PO4)2]·xH2O [J]. Chem Mater,1996,8(1):43-53.
[106]Escobal J,Pizarro J L,Mesa J L,et al. A New Manganese(II) Phosphate Templated by Ethylenediamine: (C2H10N2)[Mn2(HPO4)3(H2O)]. Hydrothermal Synthesis,Crystal Structure,and Spectroscopic and Magnetic Properties [J]. Chem Mater,2000,12(2),376-382.
[107] Kongshaug K O,Fjellvag H,Lillerud K F. The Synthesis and Characterization of a New Manganese Phosphate Templated by Piperazine [J]. J Solid State Chem,2001,156(1):32-36.
[108] Chippindale A M,Gaslain F O M,Cowley A R,et al. Synthesis and Characterisation of a Layered Organically-Templated Manganese Phosphate,[Mn2(HPO4)3]·(NH3(CH2)2NH3)3/2·H2PO4,and Its Reaction with Water [J]. J Mater Chem,2001,11(12):3172-3179.
[109]石磊. Mn(II)取代磷酸铝和磷酸锰微孔化合物的水热合成与表征[D]:[博士学位论文].长春:吉林大学化学学院,2005.
[110] Wloka M,Trojanov S I,Kemnitz E. New zirconium phosphate fluorides: Hydrothermal synthesis and crystal structures [J]. J Solid State Chem,1998,135(2):293-301.
[111] Natarajan S,Attfield M P,Cheetham A K. [H3N(CH2)2NH3]0.52+[Sn4P3O12]-: An open-framework Tin(II) phosphate [J]. Angew Chem Int Ed Engl,1997,36(9):978-980.
[112] Natarajan S,Ayyappan S,Cheetham A K,et al. Novel open-framework tin(II) phosphate materials containing Sn-O-Sn linkages and three-coordinated oxygens [J]. Chem Mater,1998,10(6): 1627-1631.
[113] Serre C,Guillou N,Férey G. Hydrothermal synthesis and ab initio structure determination from powder data of a new three-dimensional mixed valence oxyfluorinated titanium phosphate with an open structure: (TiTiF)-Ti-III-F-IV(PO4)2·2H2O or MIL-15 [J]. J Mater Chem,1999,9(5): 1185-1189.
[114]刘云凌.新型钛硅酸盐及磷酸盐分子筛的合成研究[D]:[博士学位论文].长春:吉林大学化学学院,2005.
[115] Fan J,Yee G T,Wang G B,et al. Syntheses,structures,and magnetic properties of inorganic-organic hybrid cobalt(II) phosphites containing bifunctional ligands [J]. Inorg Chem,2006,45(2):599-608.
[116] Liu X,Xing Y,Liu X. Solvothermal synthesis and magnetic properties of cobalt(II) phosphite structures of varying dimensionality [J]. CrystEngComm,2010,12(2):383-386.
[117] Fernandez S,Mesa J L,Pizarro J L,et al. (C2H10N2)[Cr(HPO3)F3]: The first organically templated fluorochromium(III) phosphite [J]. Angew Chem Int Ed,2002,41(19):3683-3685.
[118] Fernández S, Mesa J L,Pizarro J L,et al. A new organically templated gallium (III)-doped chromium(III) fluorophosphite,(C2H10N2)[Ga0.98Cr0.02(HPO3)F3] hydrothermal synthesis, crystal structure and spectroscopic properties [J]. J Solid State Chem,2004,177(3):765-771.
[119] Fernandez S,Mesa J L,Pizarro J L,et al. A new layered inorganic-organic hybrid manganese(II) phosphite:(C2H10N2)[Mn3(HPO3)4]. Hydrothermal synthesis,crystal structure,and spectroscopic and magnetic properties [J]. Chem Mater,2000,12(8):2092-2098.
[120] Fernandez S,Pizarro J L,Mesa J L,et al. Hydrothermal synthesis and structural characterization of the (CnH2n+6N2)[Mn3(HPO3)4)] (n=3-8) new layered inorganic-organic hybrid manganese(II) phosphites. Crystal structure and spectroscopic and magnetic properties of (C3H12N2)[Mn3(HPO3)4] [J]. Inorg Chem,2001,40(14):3476-3483.
[121] Chung U C,Mesa J L,Pizarro J L,et al. Mn(HPO3): A new manganese (II) phosphite with a condensed structure [J]. J Solid State Chem,2005,178(9):2913-2921.
[122] Fernandez S,Mesa J L,Pizarro J L,et al. Two new three-dimensional vanadium(III) and iron(III) phosphites templated by ethylenediamine : (C2H10N2)0.5[M(HPO3)2].Ab initio structure determination,spectroscopic,and magnetic properties [J]. Chem Mater,2002,14(5):2300-2307.
[123]刘成站,朱广山,方千荣,等. [In2(HPO3)4]·(NH3CH2CH2NH3)的水热合成与晶体结构[J].高等学校化学学报,2007,28(9):1637-1639.
[124] Mandal S,Pati S K,Green M A,et al. Inorganic-organic hybrid compounds: Synthesis,structure,and magnetic properties of the first organically templated iron oxalate-phosphite ,[C4N2H12[Fe4(II)(HPO3)2(C2O4)3],possessing infinite Fe-O-Fe chains [J]. Chem Mater,2005,17(11):2912-2917.
[125] Shi Z,Li G H,Zhang D,et al. A vanadium(IV) phosphite with a pillared layered structure: Hydrothermal synthesis and characterization of (VO)4(4,4’-bpy)2(HPO3)4 [J]. Inorg Chem,2003,42(7):2357-2361.
[126] Harrison W T A. (CN3H6)2·(VO)3(H2O)3(HPO3)4·3H2O,a guanidinium vanadium phosphite hydrate based on a (3,4) connected net: an "Orthogonal Templating" effect [J]. Solid State Sci,2003,5(2):297-302.
[127] Chiang R K,Chuang N T. Hydrothermal synthesis and structure characterization of a new 3D vanadium hydrogen phosphite with 14-ring channels: (C5N2H14)[VO(H2O)]3(HPO3)4·H2O [J]. J Solid State Chem,2005,178(10):3040-3045.
[128] Shi S H,Wang L,Yuan H M,et al. Hydrothermal synthesis and characterization of a new 3D vanadium (III) phosphite (C4H8N2H4)0.5(C4H8N2H3)[V4(HPO3)7(H2O)3]·1.5H2O [J]. J Solid State Chem,2004,177(11):4183-4187.
[129] Chen L,Bu X. (3,4)-Connected zincophosphites as structural analogues of zinc hydrogen phosphate [J]. Inorg Chem,2006,45(12):4654-4660.
[130] Liang J,Li J,Yu J,et al. [(C4H12N)2][Zn3(HPO3)4]: an open-framework zinc phosphite containing extra-large 24-ring channels [J]. Angew Chem Int Ed,2005,45(16):2546-2548.
[131] Li J,Li L,Chen P,et al. Template-designed syntheses of open-framework zinc phosphites with extra-large 24-ring channels [J]. Cryst Growth Des,2008,8(7):2318-2323.
[132] Liang J,Wang Y,Yu J,et al. Synthesis and structure of a new layered zinc phosphite (C5H6N2)Zn(HPO3) containing helical chains [J]. Chem Commun,2003(7):882-883.
[133] Yu J,Xu R. Insight into the construction of open-framework aluminophosphates [J]. Chem Soc Rev,2006,35(7):593-604.
[134] Fu W S , Wang L , Shi Z , et al. The first organically templated beryllium phosphite [NH3(CH2)3NH3]·Be3(HPO3)4: Hydrothermal synthesis and X-ray crystal structure [J]. Crystal Growth&Design,2004,4(2):297-300.
[135] Feng P Y,Bu X H,Stucky G D. Hydrothermal syntheses and structural characterization of zeolite analogue compounds based on cobalt phosphate [J]. Nature,1997,388(6644):735-741.
[136] Balkus K J J,Gabrielov A G,Zones S I,et al. Synthesis of porous materials[M],Occelli M,Kessler H(Eds). Marcel Dekker,NY 1996,77.
[137] Based on a 14 Membered Rings System.Stu Balkus K J,Jr.Biscotto M,Gabrielov A G. The Synthesis and Characterization of UTD-1: The First Large Pore Zeolite. Surf Sci Catal,1997 105A,415-421.
[138] Seddon K R.Ionic liquids for clean technology [J]. Chem Biotechnol,1997,68(4):351-356.
[139] Wasserscheid P,Keim W. Ionic liquids-new“solution”for transition metal catalysis [J]. Angew Chem Int Ed,2000,39(21):3773-3789.
[140] Tait S,Osteryoung R A.Infrared study of ambient–temperature chloroaluminates as a function of melt acidity [J]. Inorg Chem,1984,23(25):4352-4360.
[141] Wilkes J S. A short history of ionic liquid–from molten salts to neoteric solvents [J]. Green Chem,2002,4(2):73-80.
[142] Chum H L,Koch V R,Miller L L,et al. Electrochemical scrutiny of organometallic iron complexes and hexamethylbenzene in a room temperature molten salt [J]. J Am Chem Soc,1975,97(11):3264-3265.
[143] Wilkes J S,Levisky J A,Wilson R A,et al. Dialkylimidazolium chloroaluminate metals: a new class of room–temperature ionic liquids for electrochemistry,spectroscopy,and synthesis [J]. Inorg Chem,1982,21(3):1263-1264.
[144] Hussey C L. Room temperature haloaluminate ionic liquids–novel solvents for transition metal solution chemistry [J]. Pure Appl Chem,1988,60(12):1763-1772.
[145] Wilkes J S,Zaworotko M J. Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids [J]. J Chem Soc,Chem Commun,1992,(13):965-966.
[146]杨雅立,王晓化,寇元等.不断壮大的离子液体家族[J].化学进展,2003,15(6):471-476.
[147] Cola A C,Jensen J L,Ntai I,et al. Novel bronsted acidic ionic liquids and their use as dual solvent–catalysts [J]. J Am Chem Soc,2002,124(21):5962-5963.
[148] Bao W L,Wang Z M,Li Y X. Synthesis of chiral ionic liquids from natural amino acids [J]. J Org Chem,2003,68(2):591-593.
[149] Zhao D B,Fei Z F,Geldbach T J,et al. Nitrile–functionalized pyridinium ionic liquids: synthesis,characterization,and their application in carbon-carbon coupling reactions [J]. J Am Chem Soc,2004,126(48):876-882.
[150] Paul A,Mandal P K,Samanta A. On the optical properties of the imidazolium ionic liquids [J]. J Phys Chem B,2005,109(18):9148-9153.
[151] Paul A,Samanta A. Photoinduced electron transfer reaction in room temperature ionic liquids: a combined laser flash photolysis and fluorescence study [J]. J Phys Chem B,2007,111(8): 1957-1962.
[152] Leone A M,Weatherly S C,Williams M E,et al. An ionic liquid form of DNA: redox–active molten salts of nucleic acids [J]. J Am Chem Soc,2001,123(2):218-222.
[153] Huang J,Jiang T,Gao H X,et al. Pd nanoparticles immobilized on molecular sieves by ionic liquids: Heterogeneous catalysts for solvent-free hydrogenation [J]. Angew Chem Int Ed,2004,43(11):1397-1399.
[154] Dai L Y,Yu S Y,Shan Y K,et al. Novel room temperature inorganic ionic liquids [J]. Eur J Inorg Chem,2004,(2): 237-241.
[155]顾彦龙,石峰,邓有全.室温离子液体:一类新型的软介质和功能材料[J].科学通报,2004,49(6):515-521.
[156]王均凤,张锁江,陈慧萍等.离子液体的性质及其在催化反应中的应用[J].过程工程学报,2003,3(2):177-185.
[157] Zhang S,Sun N,Zhang X,et al. Periodicity and map for discovery of new ionic liquids [J].Sci China Ser B,2006,49(2): 103-115.
[158] Zhang J,Zhang S,Dong K,et al. Supported absorption of CO2 by tetrabutylphosphonium amino acids ionic liquids [J]. Chem Eur J,2006,12(15):4021-4026.
[159]刘鹰,刘植昌,徐春明等.室温离子液体催化异丁烷-丁烯烷基化的中试研究[J].化工进展,2005,24(6):656-660.
[160] Holbery J D,Seddon K R.The phase behavior of 1-alkyl-3-methylimidazolium tetrafluoroborates: ionic liquids and ionic liquid crystals [J]. J Chem Soc,Dalton Trans,1999(13):2133-2139.
[161]李汝雄.绿色溶剂—离子液体的合成与应用[M].北京:化学工业出版社,2004,10-31
[162]张锁江,吕兴梅.离子液体—从基础研究到工业应用[M].北京:科学出版社,2006,1-2
[163] Decastro C,Sauvage E,Valkenberg M H,et al. Immobilised ionic liquids as lewis acid catalysts forthe alkylation of aromatic compounds with dodecene [J]. J Catal,2000,196(1):86-94.
[164] Valkenberg M H,deCastro C,Holderich W F. Friedel-Crafts acylation of aromatics catalysed by supported ionic liquids [J]. Appl Catal A-General,2001,215(1-2):185-190.
[165] Fadeev A G,Meagher M M. Opportunities for ionic liquids in recovery of biofuels [J]. Chem Commun,2001(3):295-296.
[166] Visser A E,Swatloski R P,Reichert W M,et al. Task-specific ionic liquids for the extraction of metal ions from aqueous solutions [J]. Chem Commun,2001,(1):135-136.
[167] Dai S,Ju Y H,Barnes C E. Solvent extraction of strontium nitrate by a crown ether using room-temperature ionic liquids [J]. J Chem Soc,Dalton Trans,1999,8:1201-1202.
[168] Blanchard L A,Hancu D,Beckman E J,et al. Green processing using ionic liquids and CO2 [J]. Nature,1999,399(6731):28-29.
[169] Armstrong D W,He L F,Liu Y S. Examination of ionic liquids and their interaction with molecules,when used as stationary phases in gas chromatography [J]. Ana Chem,1999,71(17):3873-3876.
[170] He L J,Zhang W Z,Zhao L,et al. Effect of 1-alkyl-3-methylimidazolium-based ionic liquids as the eluent on the separation of ephedrines by liquid chromatography [J]. J Chromatogr A,2003,1007(1-2):39-45.
[171] Mikoshiba S,Murai S,Sumino H,et al. Ionic liquid type dye-sensitized solar cells: Increase in photovoltaic performances by adding a small amount of water [J]. Cur Appl Phys,2005,5(2):152-158.
[172] Antonietti M,Kuang D B,Smarsly B,et al. Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures [J]. Angew Chem Int Ed,2004,43(38):4988-4992.
[173] Zhou Y,Antonietti M. Synthesis of very small TiO2 nanocrystals in a room-temperature ionic liquid and their self-assembly toward mesoporous spherical aggregates [J]. J Am Chem Soc,2003,125(49):14960-14961.
[174] Zhou Y,Schattka J H,Antonietti M. Room-temperature ionic liquids as template to monolithic mesoporous silica with wormlike pores via a sol-gel nanocasting technique [J]. Nano Lett,2004,4(3):477-481.
[175] Scheeren C W,Machado G,Dupont J,et al. Nanoscale Pt(0) particles prepared in imidazolium room temperature ionic liquids: Synthesis from an organometallic precursor,characterization,and catalytic properties in hydrogenation reactions [J]. Inorg Chem,2003,42(15):4738-4742.
[176] Zones S I. Synthesis of pentasil zeolites from sodium-silicate solutions in the presence of quaternary imidazole compounds [J]. Zeolites,1989,9(6):458-467.
[177] Adams C J,Bradley A E,Seddon K R. The synthesis of mesoporous materials using novel ionic liquid templates in water [J]. Aust J Chem,2001,54(11):679-681.
[178] Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[179] Parnham E R,Morris R E.Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[180] Morris R E.Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[181] Morris R E.Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21):2990-2998.
[182] Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesisusing ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[183] Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[184] Parnham E R,Wheatley P S,Morris R E.The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[185] Parnham E R,Morris R E.1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[186] Parnham E R,Morris R E.Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[187] Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[188] Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[189] Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[190] Parnham E R,Morris R E.The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[191] Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[192] Wang L , Xu Y P , Wang B C , et al. Ionothermal synthesis of magnesium-containing aluminophosphate molecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[193] Harrison W T A.C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[194] Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Micropor Mesopor Mater,2008,115(3):624-628.
[195] Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[196] Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[197] Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Micropor Mesopor Mater,2009,120(3):278-284.
[198] Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[199] Lin Z,Wragg D S,Morris R E. Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[200] Parnham E R,Slawin A M Z,Morris R E.Ionothermal synthesis of b-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[201] Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[202] Lin Z,Slawin A M Z,Morris R E.Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[203] Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[204] Zhang J,Chen S,Bu X.Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[205] Chen S,Zhang J,Bu X.Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[206] Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[207] Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[208] Liao J H,Wu P C,Bai Y H. Eutectic mixture of choline chloride/urea as a green solvent in synthesis of a coordination polymer:[Zn(O3PCH2CO2)]·NH4 [J]. Inorg Chem Commun,2005,8(4):390-392.
[1]Cheetham A K,Férey G,Loiseau T. Open-framework inorganic materials [J]. Angew Chem Int Ed,1999,38(22):3268-3292.
[2]Davis M E. Ordered porous materials for emerging applications [J]. Nature,2002,417(6891):813-821.
[3]Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[4]Parnham E R,Morris R E. Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[5]Morris R E. Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[6]Morris R E. Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21),2990-2998.
[7]Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesis using ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[8]Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[9]Parnham E R,Wheatley P S,Morris R E. The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[10]Parnham E R,Morris R E. 1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[11]Parnham E R,Morris R E. Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[12]Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[13]Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[14]Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[15]Parnham E R,Morris R E. The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[16]Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[17]Wang L,Xu Y P,Wang B C,et al. Ionothermal synthesis of magnesium-containing aluminophosphatemolecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[18]Harrison W T A. C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[19]Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Microporous Mesoporous Mater,2008,115(3):624-628.
[20]Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[21]Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[22]Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Microporous Mesoporous Mater,2009,120(3):278-284.
[23]Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[24]Lin Z,Wragg D S,Morris R E.Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[25]Parnham E R,Slawin A M Z,Morris R E. Ionothermal synthesis ofβ-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[26]Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[27]Lin Z,Slawin A M Z,Morris R E.Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[28]Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[29]Zhang J,Chen S,Bu X. Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[30]Chen S,Zhang J,Bu X. Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[31]Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[32]Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[33]Wang Y,Yu J,Guo M,et al. [{Zn2(HPO4)4}{Co(dien)2}]·H3O: a zinc phosphate with multidirectional intersecting helical channels [J]. Angew Chem Int Ed,2003,42(34):4089-4092.
[34]Lin Z E,Yao Y W,Zhang J,et al. Synthesis and structure of a novel open-framework zincophosphate with intersecting three-dimensional helical channels [J]. J Chem Soc,Dalton Trans,2002(24):4527-4528.
[35]Harrison W T A,Phillips M L F.Hydrothermal syntheses and single-crystal structures of some novel guanidinium-zinc-phosphates [J]. Chem Mater,1997,9(8):1837-1846.
[36]Harrison W T A,Gier T E,Stucky G D,et al. NaZnPO4·H2O,an open-framework sodium zincophosphate with a new chiral tetrahedral framework topology [J]. Chem Mater,1996,8(1):145-151.
[37]Neeraj S,Forster P M,Rao C N R,et al. A new route for the synthesis of open-framework metal phosphates using organophosphates [J]. Chem Commun,2001(24):2716-2717.
[38]Zhang J,Chen S,Bu X. Nucleotide-catalyzed conversion of racemic zeolite-type zincophosphate into enantioenriched crystals [J]. Angew Chem Int Ed,2009,48(33):6049-6051.
[39]Sheldrick G M.Program for crystal structure solution and refinement[CP]. SHELXL-97,University of G?ttingen,1997.
[40]Brese N E,O’Keeffe M. Bond-valence parameters for solids [J]. Acta Cryst,1991,B47(2):192-197.
[41]Khan M I,Meyer L M,Haushalter R C,et al. Giant voids in the hydrothermally synthesized microporous square pyramidal-tetrahedral framework vanadium phosphates [HN(CH2CH2)3NH]K1.35[V5O9(PO4)2]·xH2O and Cs3[V5O9(PO4)2]·xH2O [J]. Chem Mater,1996,8(1):43-53.
[42]Spek A L. Single-crystal structure validation with the program PLATON [J]. J Appl Crystallogr,2003,36(1):7-13.
[43]Yu J,Xu R. Chiral zeolitic materials:structural insights and synthetic challenges [J]. J Mater Chem,2008,18(34):4021-4030.
[44]Gier T E,Bu X,Feng P,et al. Synthesis and organization of zeolite-like materials with three-dimensional helical pores [J]. Nature,1998,395(6698):154-157.
[45]Tang L,Shi L,Bonneau C,et al. A zeolite family with chiral and achiral structures built from the same building layer [J]. Nature Mater,2008,7(5):381-385.
[1]Cheetham A K,Férey G,Loiseau T. Open-framework inorganic materials [J]. Angew Chem Int Ed,1999,38(22):3268-3292.
[2]Davis M E. Ordered porous materials for emerging applications [J]. Nature,2002,417(6891):813-821.
[3]Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[4]Parnham E R,Morris R E. Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[5]Morris R E. Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[6]Morris R E. Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21):2990-2998.
[7]Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesis using ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[8]Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[9]Parnham E R,Wheatley P S,Morris R E. The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[10]Parnham E R,Morris R E. 1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[11]Parnham E R,Morris R E. Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[12]Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[13]Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[14]Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[15]Parnham E R,Morris R E. The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[16]Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[17]Wang L,Xu Y P,Wang B C,et al. Ionothermal synthesis of magnesium-containing aluminophosphatemolecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[18]Harrison W T A. C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[19]Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Micropor Mesopor Mater,2008,115(3):624-628.
[20]Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[21]Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[22]Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Micropor Mesopor Mater,2009,120(3):278-284.
[23]Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[24]Lin Z,Wragg D S,Morris R E.Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[25]Parnham E R,Slawin A M Z,Morris R E. Ionothermal synthesis of b-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[26]Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[27]Lin Z,Slawin A M Z,Morris R E.Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[28]Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[29]Zhang J,Chen S,Bu X. Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[30]Chen S,Zhang J,Bu X. Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[31]Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[32]Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[33]Sheldrick G M. Program for crystal structure solution and refinement[CP]. SHELXL-97,University of G?ttingen,1997.
[34]Brese N E,O’Keeffe M. Bond-valence parameters for solids [J]. Acta Cryst,1991,B47(2):192-197.
[35]Wang Y,Yu J,Guo M,et al. [{Zn2(HPO4)4}{Co(dien)2}]·H3O: a zinc phosphate with multidirectional intersecting helical channels [J]. Angew Chem Int Ed,2003,42(34):4089-4092.
[36]Lin Z E,Yao Y W,Zhang J,et al. Synthesis and structure of a novel open-framework zincophosphate with intersecting three-dimensional helical channels [J]. J Chem Soc,Dalton Trans,2002(24):4527-4528.
[37]Harrison W T A,Phillips M L F. Hydrothermal syntheses and single-crystal structures of some novel guanidinium-zinc-phosphates [J]. Chem Mater,1997,9(8):1837-1846.
[38]Harrison W T A,Gier T E,Stucky G D,et al. NaZnPO4·H2O,an open-framework sodium zincophosphate with a new chiral tetrahedral framework topology [J]. Chem Mater,1996,8(1):145-151.
[39]Neeraj S,Forster P M,Rao C N R,et al. A new route for the synthesis of open-framework metal phosphates using organophosphates [J]. Chem Commun,2001(24):2716-2717.
[40]Khan M I,Meyer L M,Haushalter R C,et al. Giant voids in the hydrothermally synthesized microporous square pyramidal-tetrahedral framework vanadium phosphates [HN(CH2CH2)3NH]K1.35[V5O9(PO4)2]·xH2O and Cs3[V5O9(PO4)2]·xH2O [J]. Chem Mater,1996,8(1):43-53.
[41]Spek A L. Single-crystal structure validation with the program PLATON [J]. J Appl Cryst,2003,36(1):7-13.
[42]Zou X,Conradsson T,Klingstedt M,et al. A mesoporous germanium oxide with crystalline pore walls and its chiral derivative [J]. Nature,2005,437(7059):716-719.
[43]Plévert J,Gentz T M,Laine A,et al. A flexible germanate structure containing 24-ring channels and with very low framework density [J]. J Am Chem Soc,2001,123(50):12706-12707.
[44]Yu J,Xu R. Chiral zeolitic materials:structural insights and synthetic challenges [J]. J Mater Chem,2008,18(34):4021-4030.
[45]Del Pópolo M G,Voth G A. On the structure and dynamics of ionic liquids [J]. J Phys Chem B,2004,108(5):1744-1752.
[46]Yu J,Xu R. Rich structure chemistry in the aluminophosphate family [J]. Acc Chem Res,2003,36(7):481-490.
[47]Yu J,Xu R. Insight into the construction of open-framework aluminophosphates [J]. Chem Soc Rev,2006,35(7):593-604.
[1]Cheetham A K,Férey G,Loiseau T. Open-framework inorganic materials [J]. Angew Chem Int Ed,1999,38(22):3268-3292.
[2]Davis M E. Ordered porous materials for emerging applications [J]. Nature,2002,417(6891):813-821.
[3]Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[4]Parnham E R,Morris R E. Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[5]Morris R E. Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[6]Morris R E. Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21):2990-2998.
[7]Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesis using ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[8]Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[9]Parnham E R,Wheatley P S,Morris R E. The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[10]Parnham E R,Morris R E. 1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[11]Parnham E R,Morris R E. Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[12]Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[13]Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[14]Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[15]Parnham E R,Morris R E. The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[16]Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[17]Wang L,Xu Y P,Wang B C,et al. Ionothermal synthesis of magnesium-containing aluminophosphatemolecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[18]Harrison W T A. C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[19]Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Micropor Mesopor Mater,2008,115(3):624-628.
[20]Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[21]Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[22]Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Micropor Mesopor Mater,2009,120(3):278-284.
[23]Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[24]Lin Z,Wragg D S,Morris R E.Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[25]Parnham E R,Slawin A M Z,Morris R E. Ionothermal synthesis of b-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[26]Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[27]Lin Z,Slawin A M Z,Morris R E.Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[28]Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[29]Zhang J,Chen S,Bu X. Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[30]Chen S,Zhang J,Bu X. Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[31]Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[32]Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[33]Sheldrick G M. Program for crystal structure solution and refinement[CP]. SHELXL-97,University of G?ttingen,1997.
[34]Brese N E,O’Keeffe M. Bond-valence parameters for solids [J]. Acta Cryst,1991,B47(2):192-197.
[35]Spek A L. Single-crystal structure validation with the program PLATON [J]. J Appl Crystallogr,2003,36(1):7-13.
[1]Cheetham A K,Férey G,Loiseau T. Open-framework inorganic materials [J]. Angew Chem Int Ed,1999,38(22):3268-3292.
[2]Davis M E. Ordered porous materials for emerging applications [J]. Nature,2002,417(6891):813-821.
[3]Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[4]Parnham E R,Morris R E. Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[5]Morris R E. Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[6]Morris R E.Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21):2990-2998.
[7]Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesis using ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[8]Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[9]Parnham E R,Wheatley P S,Morris R E. The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[10]Parnham E R,Morris R E. 1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[11]Parnham E R,Morris R E. Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[12]Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[13]Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[14]Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[15]Parnham E R,Morris R E. The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[16]Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[17]Wang L,Xu Y P,Wang B C,et al. Ionothermal synthesis of magnesium-containing aluminophosphate molecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[18]Harrison W T A. C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[19]Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Micropor MesoporMater,2008,115(3):624-628.
[20]Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[21]Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[22]Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Micropor Mesopor Mater,2009,120(3):278-284.
[23]Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[24]Lin Z,Wragg D S,Morris R E. Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[25]Parnham E R,Slawin A M Z,Morris R E. Ionothermal synthesis of b-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[26]Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[27]Lin Z,Slawin A M Z,Morris R E. Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[28]Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[29]Zhang J,Chen S,Bu X. Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[30]Chen S,Zhang J,Bu X. Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[31]Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[32]Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[33]Chen L,Bu X. (3,4)-Connected zincophosphites as structural analogues of zinc hydrogen phosphate [J]. Inorg Chem,2006,45(12):4654-4660.
[34]Liang J,Li J,Yu J,et al. [(C4H12N)2][Zn3(HPO3)4]:an open-framework zinc phosphite containing extra-large 24-ring channels [J]. Angew Chem Int Ed,2005,45(16):2546-2548.
[35]Li J,Li L,Chen P,et al. Template-designed syntheses of open-framework zinc phosphites with extra-large 24-ring channels [J]. Cryst Growth Des,2008,8(7):2318-2323.
[36]Liang J,Wang Y,Yu J,et al. Synthesis and structure of a new layered zinc phosphite (C5H6N2)Zn(HPO3) containing helical chains [J]. Chem Commun,2003(7):882-883.
[37]Zhao L,Li J,Chen P,et al. 2H3O·[Co8(HPO3)9(CH3OH)3]·2H2O: an open-framework cobalt phosphite containing extra-Large 18-ring channels [J]. Chem Mater,2008,20(1):17-19.
[38]Mandal S,Natarajan S. Synthesis,structure,and polymorphism studies in amine-templated open-framework zinc phosphites [J]. Inorg Chem,2008,47(12):5304-5313.
[39]Liu X,Xing Y,Liu X. Solvothermal synthesis and magnetic properties of cobalt(II) phosphite structures of varying dimensionality [J]. CrystEngComm,2010,12(2):383-386.
[40]Liu X,Xing Y,Wang X et al. Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials [J]. Chem Commun,2010,ASAP.
[41]Sheldrick G M. Program for crystal structure solution and refinement[CP]. SHELXL-97,University of G?ttingen,1997.
[42]Wiebcke M. [Zn3(HPO4)4](NMe4)2 : a zincophosphate containing interruptions of isolated hydrogen-bonding [H-O(P)]4 groupings within a novel three-dimensional four-connected framework [J]. J Mater Chem,2002,12(3):421-425.
[43]Murugavel R,Walawalkar M G,Dan M,et al. Transformations of molecules and secondary building units to materials: a bottom-up approach [J]. Acc Chem Res,2004,37(10):763-774.
[44]Fan J,Slebodnick C,Troya D,et al. Five new zinc phosphite structures:tertiary building blocks in the construction of hybrid materials [J]. Inorg Chem,2005,44(8):2719-2727.
[45]Hu L,Fan J,Slebodnick C,et al. Structural diversity in 4,4’-trimethylenedipyridine-zinc phosphite hybrids:incorporation of neutral guest molecules in hybrid materials [J]. Inorg Chem,2006,45(19):7681-7688.
[46]Lin C H,Wang S L,Lii K H. [Ga2(DETA)(PO4)2]·2H2O (DETA = diethylenetriamine):a novel porous gallium phosphate containing 24-ring channels [J]. J Am Chem Soc,2001,123(19):4649-4650.
[47]Zhou Y,Zhu H,Chen Z,et al. A large 24-membered-ring germanate zeolite-type open-framework structure with three-dimensional intersecting channels [J]. Angew Chem Int Ed,2001,40(11):2166-2168.
[48]Yang Y , Zhao Y , Yu J , et al. Doping-induced structure variation of 1 ,3-cyclohexane-bis(methylamine)-templated zinc-phosphorus open structures [J]. Inorg Chem,2008,47(3):769-771.
[49]Lai Y L,Lii K H,Wang S L. 26-Ring-channel structure constructed from bimetal phosphite helical chains [J]. J Am Chem Soc,2007,129(17):5350-5351.
[50]Yang G Y,Sevov S C. Zinc phosphate with gigantic pores of 24 tetrahedra [J]. J Am Chem Soc,1999,121(36):8389-8390.
[51]Spek A L. Single-crystal structure validation with the program PLATON [J]. J Appl Cryst,2003,36(1):7-13.
[2]Everett D H.IUPAC manual of symbols and terminology [J]. Pure Appl Chem,1972,31(4):577-638.
[3]Francis R J,O’Hare D.The kinetics and mechanisms of the crystallisation of microporous materials [J]. J Chem Soc,Dalton Trans,1998(19):3133-3148.
[4]Di Renzo F,Cambon H,Dutartre R.A 28-year-old synthesis of micelle-templated mesoporous silica [J]. Micropor Mater,1997,10(4-6):283-286.
[5]Yanagisawa T,Shimizu T,Kuroda K,et al. Synthesis,characterization of mesoporous Al-Mg composite oxide and catalytic performance for oxyethylation of fatty alcohol [J]. Bull Chem Soc Jpn,1990,63(5):988-992.
[6]徐如人.科学,1998,50 (1):12-15.
[7]Sayari A,Karra V R,Reddy J S,et al. Synthesis of mesostructured lamellar aluminophosphates [J]. Chem Commun,1996(3):411-412.
[8]Bagshaw S A,Pinnavain T J. Mesoporous alumina molecular sieves [J]. Angew Chem Int Ed Engl,1996,35(10):1102-1105.
[9]Braun P V,Osenar P,Stupp S I.Semiconducting superlattices templated by molecular assemblies [J]. Nature,1996,380(6572):325-327.
[10]Attard G S,Corker J M,G?ltner C G,et al. Liquid-crystal templates for nanostructured metals [J]. Angew Chem Int Ed Engl,1997,36(12):1315-1317.
[11]Ryoo R,Joo S H,Kruk M,et al. [J]. Ordered mesoporous carbons [J]. Adv Mater,2001,13(9):677-681.
[12]Huo Q S,Margolese D I,Stucky G D. Surfactant control of phases in the synthesis of mesoporous silica-Based materials [J]. Chem Mater,1996,8(5):1147-1160.
[13]Velev O D,Jede T A,Lobo R F,et al. Microstructured porous silica obained via colloidal crystal template [J]. Chem Mater,1998 10(11):3597-3602.
[14]Davis M E,Saldarriaga C,Montes C,et al.A molecular sieve with eighteen-membered rings [J]. Nature,1988,331(6158):698-699.
[15]Davis S A,Burkett S L,Mendelson N H,et al. Bacterial templating of ordered macrostructures in silica and silica-surfactant mesophases [J]. Nature,1997,385(6615):420-423.
[16]Imhof A,Pine D J.Ordered macroporous materials by emulsion templating [J]. Nature,1997,389(6654):948-951.
[17]Choi K , Gardner D , Hilbrandt N , et al. Combinatorial Methods for the Synthesis of Aluminophosphate Molecular Sieves [J]. Angew Chem Int Ed,1999,38(19):2891-2894.
[18]Flanigen E M,Lok B M,Patton R L,et al. Aluminophosphate Molecular Sievesand the periodic Table.Proc.Of the 7th Intl.Zeolite Conf.Kodansha-Elsevier,Murakam Y,Lijima A,Ward J W(Eds),1986,103-112.
[19]Yu J,Xu R.Rich structure chemistry in the aluminophosphate family [J]. Acc Chem Res,2003,36(7):481-490.
[20]Yu J,Li J,Xu R. Structural diversity of a family of aluminophosphates with Al/P ratio of non-unity [J].Solid State Sci,2000,2(2):181-192.
[21]Chen J,Pang W,Xu R. Mixed-bonded open-framework aluminophosphates and related layered materials [J]. Top Catal,1999,9(1-2):93-103.
[22]Wang K,Yu J,Miao P,et al. A new layered aluminophosphate [C4H12N2][Al2P2O8(OH)2] templated by piperazine [J]. J Mater Chem,2001,11(7):1898-1902.
[23]Kongshaug K O,Fjellvag H,Lillerud K P. Layered aluminophosphates I.crystal structure of two novel layered aluminophosphates solved ab initio from powder diffraction data [J]. Micropor Mesopor Mater,1999,32(1-2):17-28.
[24]Kongshaug K O,Fjellvag H,Lillerud K P. Layered aluminophosphates II.crystal structure and thermal behaviour of the layered aluminophosphate UiO-15 and its high temperature variants [J]. J Mater Chem,1999,9(7):1591-1598.
[25]Maeda K,Tuel A,Baerlocher C. Synthesis and characterization of a new layered aluminophosphate templated with 1,3-diaminopropane:[H3N(CH2)3NH3]0.5[AlPO4(OH)(OH2)]·H2O [J]. J Chem Soc,Dalton Trans,2000(14):2457-2462.
[26]Riou D , Loiseau T , Férey G. Structure determination of(N2C2H10)4(NH4)AlP4O16 : a new aluminophosphate templated by ethylenediamine [J]. J Solid State Chem,1992,99(2):414-418.
[27]Yan W,Yu J,Shi Z,et al. A novel open-framework aluminophosphate [AlP2O6(OH)2][H3O] containing propeller-like chiral motifs [J]. Chem Commun,2000(15):1431-1432.
[28]Yu J,Williams I D.Two unusual layer aluminophosphates templated by imidazolium ions:[N2C3H5][AlP2O8H2·2H2O] and 2[N2C3H5][Al3P4O16H] [J]. J Solid State Chem,1998,136(1):141-144.
[29]Yu J,Terasaki O,Williams I D,et al. Solvothermal synthesis and characterization of new aluminophosphate layers templated by imidazolium ions [J]. Supramol Sci,1998,5(3-4):297-302.
[30]Morgan K R , Gainsford G J , Milestone N B. A new type of layered aluminiumphosphate[NH4]3[Co(NH3)6]3[Al2(PO4)4]2 assembled about a cobalt(III) hexammine complex [J]. Chem Commun,1997(1):61-62.
[31]Leech M A,Cowley A R,Prout K,et al. Ambient-temperature synthesis of new layered AlPOs and GaPOs in silica gels [J]. Chem Mater,1998,10(1):451-456.
[32]Jones R H,Thomas J M,Xu R,et al. Synthesis and structure of a one-dimensionally extended aluminium phosphate Et3NH+(H2AlP2O8)- [J]. J Chem Soc,Chem Commun,1990(17):1170-1172.
[33]Williams I D,Yu J,Gao Q,et al. New chain architecture for a one-dimensional aluminophosphate,[H3NCH2CH2NH3][AlP2O8H] [J]. Chem Commun,1997(14):1273-1274.
[34]Gao Q,Chen J,Li S,et al. Synthesis and structure of a chain aluminophosphate filled with [NH4]+and[H3NCH2CH2NH3]2+cations [J]. J Solid State Chem,1996,127(2):145-150.
[35]Ayi A A,Choudhury A,Natarajan S. Linear-chain AlPOs obtained by the reaction of amine phosphates with Al3+ions [J]. J Solid State Chem,2001,156(1):185-193.
[36]Wei B,Yu J,Shi Z,et al. A new layered aluminophosphate [Al2P4O16][C6H22N4][C2H10N2] with 4.12-net porous sheets [J]. J Chem Soc,Dalton Trans,2000(13):1979-1980.
[37]Bircsak Z,Harrison W T A.Template cooperation effect leading to the new layered aluminophosphate CN3H6·Al(HPO4)2·2H2O [J]. Chem Mater,1998,10(10):3016-3019.
[38]Sugiyama K,Hiraga K,Yu J,et al. A one-dimensionally extended chain aluminophosphate [J]. Acta Cryst,1999,C55(10):1615-1617.
[39]Wei B,Zhu G,Yu J,et al. Solvothermal synthesis and characterization of a new 3-D open-frameworkaluminophosphate [Al2P3O12][C4N3H16] [J]. Chem Mater,1999,11(12):3417-3419.
[40]Yu J,Sugiyama K,Togashi N,et al. Synthesis and characterization of a new two-dimensional aluminophosphate layer and structural diversity in anionic aluminophosphates with Al2P3O123- stoichiometry [J]. Chem Mater,1998,10(11):3636-3642.
[41]Chippindale A M,Powell A V,Bull L M,et al. Synthesis and characterization of 2 layered aluminophosphates,(T)2HAl2P3O12(T=2-BuNH3+) and (T)H2Al2P3O12(T=PyH+) [J]. J Solid State Chem,1992,96(1):199-210.
[42]Oliver S,Kuperman A,Lough A,et al. Aluminophosphate chain-to-layer transformation [J].Chem Mater,1996,8(9):2391-2398.
[43]Oliver S,Kuperman A,Lough A,et al.The synthesis and structure oftwo novel layered aluminophosphates containing interlamellar cyclohexylammonium[J].Chem Commun,1996(15):1761-1762.
[44]Chippindale A M,Walton R I.[C9H20N][Al2(HPO4)2(PO4)]:An aluminium phosphate with a new layer topology[J].J Solid State Chem,1999,145(2):731-738.
[45]Xu Y,Zhang B,Chen X,et al.An open frameworkaluminophosphate with unique 12-membered ring channels:Al9(PO4)12(C24H91N16)17·H2O [J].J Solid State Chem,1999,145(1):220-226.
[46]Jones R H,Thomas J M,Xu R,et al.Synthesis and structure of a novel aluminum phosphate anion-(Al3P4O16)3-[J].J Chem Soc,Chem Commun,1991(18):1266-1268.
[47]Gao Q,Li B,Chen J,et al. Nonaqueous synthesis and charaterization of a new 2-dimensional layered aluminophosphate [Al3P4O16]·3[CH3CH2NH3] [J].J Solid State Chem,1997,129(1):37-44.
[48]Thomas J M , Jones R H , Xu R , et al. A novel porous sheet aluminophosphate (Al3P4O16)3-·1.5[NH3(CH2)4NH3]2+ [J].J Chem Soc,Chem Commun,1992(13):929-931.
[49]Chippindale A M,Cowley A R,Huo Q,et al.Synthesis and structure of a new layered aluminium phosphate: [BuNH3]3[Al3P4O16][J].J Chem Soc,Dalton Trans,1997,15:2639-2643.
[50]Williams I D,Gao Q,Chen J,et al.Organic-template controlof inorganic structure: a low-symmetry two-dimensional sheet aluminophosphate 3[NH3CHMeCH2NH3][Al6P8O32]·H2O [J].Chem Commun,1996(15):1781-1782.
[51]Yu J , Li J , Sugiyama K , et al. Formation of a new layered aluminophosphate [Al3P4O16][C5N2H9]2[NH4] [J].Chem Mater,1999,11(7):1727-1732.
[52]Jones R H,Chippindale A M,Natarajan S,et al. A reactive template in the synthesis of a novel layered aluminum phosphate(Al3P4O16)3-[NH3(CH2)5NH3]2+(C5H10NH2)+ [J].J Chem Soc,Chem Commun,1994(5):565-566.
[53]Barrett P A,Jones R H.The pore-size modification of a layered aluminophosphate [Al3P4O16C9H24N3] by rational selection of the intercalated template cation [J].J Chem Soc,Chem Commun,1995(19):1979-1980.
[54] Oliver S,Kuperman A,Lough A,et al. Synthesis and crystal structures of two novel anionic aluminophosphates: a one-dimensional chain,UT-7([Al3P5O20H]5-[C7H13NH3+]5),and a layer containing two cycli amines,UT-8([Al3P4O16]3-[C4H7NH3+]2[C5H10NH2+]) [J].Inorg Chem,1996,35(22):6373-6380.
[55] Togashi N,Yu J,Zheng S,et al. Synthesis and structure of a 2-D layer Al3P4O16 center dot 3CH3CH2CH2NH3 [J].J Mater Chem,1998,8(12):2827-2830.
[56] Yao Y,Natarajan S,Chen J,et al.Synthesis and structural characterization of a new layered aluminophosphate intercalated with triply-protonated triethylenetetramine [C6H21N4][Al3P4O16] [J].JSolid State Chem,1999,146(2):458-463.
[57] Vidal L,Gramlich V,Patarin J,et al. Synthesis,characterization and structure of Mu-7,a new layered aluminophosphate with a 4×8 network [J]. Chem Lett,1999,3:201-202.
[58] Yu J,Williams I D.Two unusual layer aluminophosphates templated by imidazolium ions: [N2C3H5][AlP2O8H2·2H2O] and 2[N2C3H5][Al3P4O16H] [J]. J Solid State Chem,1998,136(1):141-144.
[59] Oliver S,Kuperman A,Lough A,et al. Aluminophosphate chain-to-layer transformation [J].Chem Mater,1996,8(9):2391-2398.
[60] Zhang M , Zhou D , Li J Y , et al. Synthesis and characterization of a new layered fluoroaluminophosphate (C4H11NOH)3.5[Al4(PO4)5F]·0.5H3O with extra-large 16-rings [J]. Inorg Chem 2007,46(1):136-140.
[61] Yu J,Sugiyama K,Zheng S,et al. Al16P20O80H44C6H18N2: A new microporous aluminophosphate containing intersecting 12- and 8-membered ring channels [J]. Chem.Mater,1998,10(5):1208-1211.
[62] Vidal L,Gramlich V,Patarin J,et al. Synthesis and structure of Mu-4,the new layered aluminophosphate [(C2H5)2NH2]4[Al8P10O40H2][H2O]2.5 [J]. Eur J Solid State Chem,1998,35(8-9):545-563.
[63] Jones R H , Thomas J M , Chen J , et al.Structure of anunusual aluminium phosphate ([Al5P6O24H]2-2[N(C2H5)3H]+·2H2O) JDF-20 with large elliptical apertures [J]. J Solid State Chem,1993,102(1):204-208.
[64] Wang K , Yu J , Shi Z , et al.Synthesis and characterization ofa new three-dimensional aluminophosphate [Al11P12O48][C4H12N2][C4H11N2] with an Al/P ratio of 11/12 [J]. J Chem Soc,Dalton Trans,2001(12):1809-1812.
[65] Yan W,Yu J,Shi Z,et al.An anionic framework aluminophosphate vertical bar (CH2)6N4H3·H2O center dot H2O vertical bar [Al11P12O48] and computer simulation of the template positions [J]. Microporous and Mesoporous Mater,2001,50(2-3):151-158.
[66] Yan W,Yu J,Xu R,et al. [Al12P13O52]3-[(CH2)6N4H3]3+: An anionic aluminophosphate molecular sieve with bronsted acidity [J]. Chem Mater,2000,12(9):2517-2519.
[67] Feng P,Bu X,Stucky G D. Control of structural ordering in crystalline lamellar aluminophosphates with periodicity from 51 to 62 angstrom [J]. Inorg Chem,2000,39(1):2-3.
[68] Huo Q,Xu R,Li S,et al. Syntehesis and characterization of a novel extra large ring of aluminophasphate JDF-20 [J]. J Chem Soc,Chem Commun,1992(12):875-876.
[69] Parise J B. Preparation and structural characterization of 2 metallophosphate frameworks clathrating diprotonated ethylenediamine:AlPO4-12(en) and GaPO4-12(en) [J]. Inorg Chem,1985,24(25):4312-4316.
[70] Feng S,Xu R,Yang G,et al.Chem J Chin Univ,1988(4):1.
[71]冯守华. [D]:[博士学位论文].长春:吉林大学化学学院,1986.
[72] Estermann M E,McCusker L B,Boelocher C,et al.A synthetic gallophosphate molecular-sieve with a 20-tetrahedral-atom pore opening [J]. Nature,1991,352: 320-323.
[73] Kan Q,Glasser F P,Xu R. Synthesis and characterization of 2 galliophosphates with occluded methylamine [J]. J Mater Chem,1993,3(9):983.
[74] Chippindale A M,Walton R I,Turner C. Synthesis and structure of a novel open-framework gallium phosphate [Me2NH(CH2)2NHMe2]2+[Ga4P5O20H]2-·H2O [J]. J Chem Soc,Chem Commun,1995(12):1261-1262
[75] Lin C,Wang S. [(1S,2S)-H2DACH][Ga2(1S,2S-DACH)(HPO4)(PO4)2]: A layered chiral gallophosphate containing chiral ligand and chiral template [J]. Inorg Chem,2001,40(12):2918-2921.
[76] Loiseau T,Ferey G. Oxyfluorinated microporous compounds,VII. synthesis and crystal structure of ULM-5,a new fluorinated gallophosphate Ga16(PO4)14(HPO4)2(OH)2F7,[H3N(CH2)6NH3]4,6H2O with 16-membered rings and both bonding and encapsulated F- [J]. J Solid State Chem ,1994,111(2):403-415.
[77] Loiseau T,Ferey G. Synthesis and crystal structure of ULM-16,a new open-framework fluorinated gallium phosphate with 16-ring channels: Ga4(PO4)4F2-·1.5NC6H14·0.5H2O·0.5H3O [J]. J Mater Chem,1996,6(6):1073-1074.
[78] Sassoye C,Loiseau T,Taulelle F,et al. A new open-framework fluorinated gallium phosphate with large 18-ring channels(MIL-31)[J] .Chem Commun,2000,11: 943-944.
[79] Sassoye C,Marrot J,Loiseau T,et al. Utilization of cyclopentylamine as structure-directing agent for the formation of fluorinated gallium phosphates exhibiting extra-large-pore open frameworks with 16-ring (ULM-16) and 18-ring channels (MIL-46) [J]. Chem Mater,2002,14(3):1340-1347.
[80] Beitone L,Marrot J,Loiseau T,et al. MIL-50,an open-framework GaPO with a periodic pattern of small water ponds and dry rubidium atoms:a combined XRD,NMR,and computational study[J]. J Am Chem Soc,2003,125(7):1912-1922.
[81] Walton R I,Millange F,Loiseau T,et al. Crystallization of a large-pore three-dimensional gallium fluorophosphate under mild conditions [J].Angew Chem Int Ed,2000,39(24):4552-4555.
[82] Chippindale A M,Peacock K J,Cowley A R.Synthesis and characterization of a large-pore,open-framework gallium phosphate,[NH3(CH2)4NH3]2[Ga4(HPO4)2(PO4)3(OH)3]·yH2O,and its vanadium-gallium phosphate analogue , [NH3(CH2)4NH3]2[Ga4-xVx(HPO4)2(PO4)3(OH)3]·yH2O (x≈0.4,y≈0.6) [J]. J Solid State Chem,1999,145(2):379-386.
[83] Lin C-H,Wang S-N,Lii K-H.[Ga2(DETA)(PO4)2]·2H2O (DETA=diethylenetriamine): A novel porous gallium phosphate containing 24-ring channels [J]. J Am Chem Soc,2001,123(19): 4649-4650.
[84] Schuth F,Schmidt W. Advanced materials progess repot on microporous and mesoporous material [J]. Adv Mater. 2002,14(9): 629-638.
[85] Yang Y L,Liu Y,Chen C. Hydrothermal synthesis and characterization of an organically templated gallophosphate JGP-5 [J]. Polyhedron,2004,23(9): 1535-1539
[86]杨玉林.稀反应体系下开放骨架结构的磷酸镓(亚磷酸镓)微孔晶体的水热合成研究[D]:[博士学位论文].长春:吉林大学化学学院,2004.
[87]杨磊.具有开放骨架结构磷酸镓(亚磷酸镓)微孔晶体的水热合成与研究[D]:[博士学位论文].长春:吉林大学化学学院,2005.
[88]高源.新型骨架结构的磷酸镓类微孔晶体材料的水热合成[D]: [硕士学位论文].哈尔滨:哈尔滨工业大学应用化学系,2006.
[89]马晶.开放骨架结构磷酸镓微孔晶体的水热合成与表征[D]: [硕士学位论文].哈尔滨:哈尔滨工业大学应用化学系,2007.
[90] Dhingra S S , Haushalter R C. Hydrothermal Synthesis and Crystal Structure of H3NCH2CH2NH3[In2(HPO4)4]-A Novel Octahedral-Trahedral Framework Indium Phosphate with Occluded Organic Cations [J]. J Chem Soc,Chem Comm,1993,21: 1665-1667.
[91]伊卓.新型磷酸铟(亚磷酸铟)微孔晶体的水热合成研究[D]:[硕士学位论文].长春:吉林大学化学学院,2005.
[92]陈超.具有开放骨架结构的磷酸铟,磷酸钛微孔晶体的水热合成研究[D]:[博士学位论文].长春:吉林大学化学学院,2006.
[93]刘成站.微孔亚磷酸铟和磷酸铟晶体的水热合成研究[D]:[博士学位论文].长春:吉林大学化学学院,2007.
[94] Harrison W T A,Gier T E,Stucky G D,et al. Structure and Properties of New Zeolite X-Type Zincophosphate and Beryllophosphate Molecular-Sieves [J]. Chem.Mater,1991,3(1): 27-29.
[95] Nenoff T M,Harrison W T A,Gier T E,et al. Room-temperature synthesis and characterization of new ZnPO and ZnAsO sodalite open frameworks [J]. J Am Chem Soc,1991,113(1) 378-379.
[96] Yang G Y,Sevov S C. Zinc Phosphate with Gigantic Pores of 24 Tetrahedra [J]. J Am Chem Soc,1999,121(36): 8389-8390.
[97] Zhu J,Bu X H,Feng P Y,et al. An Open-Framework Material with Dangling Organic Functional Groups in 24-Ring Channels [J]. J Am Chem Soc,2000,122(46): 11563-11564.
[98] Rao C N R,Natarajan S,Choudhury A,et al. Aufbau Princople of Complex Open-Framework Strutures of Metal Phosphates with Different Dimensionalities [J]. Acc Chem Res,2001,34(1): 80-87.
[99] Harrison W T A,Gier T E,Stucky G D,et al. NaZnPO4·H2O,an Open-Framework Sodium Zincophosphate with a New Chiral Tetrahedral Framework Topology [J]. Chem Mater,1996,8(1): 145-151.
[100] Neeraj S,Natarajan S,Rao C N R. A Novel Open-Framework Zinc Phosphate with Intersecting Helical Channels [J]. Chem Commun,1999(2):165-166.
[101] Lin Z E,Yao Y W,Zhang J,et al. Synthesis and Structure of a Novel Open-Framework Zincophosphate with Intersecting Three-Dimensional Helical Channels [J]. J Chem Soc,Dalton Trans,2002,24:4527-4528.
[102]Fan J,Slebodnick C,Angel R,et al. New Zinc Phosphates decorated by imidazole-containing Ligands [J]. Inorg.Chem,2005,44(3):552-558.
[103] Soghomonian V,Chen Q,Haushalter R C,et al. An inorganic double helix: hydrothermal synthesis,structure,and magnetism of chiral [(CH3)2NH2]K4[V10O10(H2O)2(OH)4(PO4)7]·4H2O [J]. Science,1993,259(5101):1596-1599.
[104]Shi Z , Feng S H , Gao S , et al. Inorganic-organic hybrid materials constructed from [(VO2)(HPO4)](infinity) helical chains and [M(4,4`-bpy)2]2+ (M = Co,Ni) fragments [J]. Angew Chem,Int Ed,2000,39(13):2325-2327.
[105] Khan M I,Meyer L M,Haushalter R C,et al. Giant voids in the hydrothermally synthesized microporous square pyramidal tetrahedral framework vanadium phosphates [HN(CH2CH2)3NH]K1.35[V5O9(PO4)2]·xH2O and Cs3[V5O9(PO4)2]·xH2O [J]. Chem Mater,1996,8(1):43-53.
[106]Escobal J,Pizarro J L,Mesa J L,et al. A New Manganese(II) Phosphate Templated by Ethylenediamine: (C2H10N2)[Mn2(HPO4)3(H2O)]. Hydrothermal Synthesis,Crystal Structure,and Spectroscopic and Magnetic Properties [J]. Chem Mater,2000,12(2),376-382.
[107] Kongshaug K O,Fjellvag H,Lillerud K F. The Synthesis and Characterization of a New Manganese Phosphate Templated by Piperazine [J]. J Solid State Chem,2001,156(1):32-36.
[108] Chippindale A M,Gaslain F O M,Cowley A R,et al. Synthesis and Characterisation of a Layered Organically-Templated Manganese Phosphate,[Mn2(HPO4)3]·(NH3(CH2)2NH3)3/2·H2PO4,and Its Reaction with Water [J]. J Mater Chem,2001,11(12):3172-3179.
[109]石磊. Mn(II)取代磷酸铝和磷酸锰微孔化合物的水热合成与表征[D]:[博士学位论文].长春:吉林大学化学学院,2005.
[110] Wloka M,Trojanov S I,Kemnitz E. New zirconium phosphate fluorides: Hydrothermal synthesis and crystal structures [J]. J Solid State Chem,1998,135(2):293-301.
[111] Natarajan S,Attfield M P,Cheetham A K. [H3N(CH2)2NH3]0.52+[Sn4P3O12]-: An open-framework Tin(II) phosphate [J]. Angew Chem Int Ed Engl,1997,36(9):978-980.
[112] Natarajan S,Ayyappan S,Cheetham A K,et al. Novel open-framework tin(II) phosphate materials containing Sn-O-Sn linkages and three-coordinated oxygens [J]. Chem Mater,1998,10(6): 1627-1631.
[113] Serre C,Guillou N,Férey G. Hydrothermal synthesis and ab initio structure determination from powder data of a new three-dimensional mixed valence oxyfluorinated titanium phosphate with an open structure: (TiTiF)-Ti-III-F-IV(PO4)2·2H2O or MIL-15 [J]. J Mater Chem,1999,9(5): 1185-1189.
[114]刘云凌.新型钛硅酸盐及磷酸盐分子筛的合成研究[D]:[博士学位论文].长春:吉林大学化学学院,2005.
[115] Fan J,Yee G T,Wang G B,et al. Syntheses,structures,and magnetic properties of inorganic-organic hybrid cobalt(II) phosphites containing bifunctional ligands [J]. Inorg Chem,2006,45(2):599-608.
[116] Liu X,Xing Y,Liu X. Solvothermal synthesis and magnetic properties of cobalt(II) phosphite structures of varying dimensionality [J]. CrystEngComm,2010,12(2):383-386.
[117] Fernandez S,Mesa J L,Pizarro J L,et al. (C2H10N2)[Cr(HPO3)F3]: The first organically templated fluorochromium(III) phosphite [J]. Angew Chem Int Ed,2002,41(19):3683-3685.
[118] Fernández S, Mesa J L,Pizarro J L,et al. A new organically templated gallium (III)-doped chromium(III) fluorophosphite,(C2H10N2)[Ga0.98Cr0.02(HPO3)F3] hydrothermal synthesis, crystal structure and spectroscopic properties [J]. J Solid State Chem,2004,177(3):765-771.
[119] Fernandez S,Mesa J L,Pizarro J L,et al. A new layered inorganic-organic hybrid manganese(II) phosphite:(C2H10N2)[Mn3(HPO3)4]. Hydrothermal synthesis,crystal structure,and spectroscopic and magnetic properties [J]. Chem Mater,2000,12(8):2092-2098.
[120] Fernandez S,Pizarro J L,Mesa J L,et al. Hydrothermal synthesis and structural characterization of the (CnH2n+6N2)[Mn3(HPO3)4)] (n=3-8) new layered inorganic-organic hybrid manganese(II) phosphites. Crystal structure and spectroscopic and magnetic properties of (C3H12N2)[Mn3(HPO3)4] [J]. Inorg Chem,2001,40(14):3476-3483.
[121] Chung U C,Mesa J L,Pizarro J L,et al. Mn(HPO3): A new manganese (II) phosphite with a condensed structure [J]. J Solid State Chem,2005,178(9):2913-2921.
[122] Fernandez S,Mesa J L,Pizarro J L,et al. Two new three-dimensional vanadium(III) and iron(III) phosphites templated by ethylenediamine : (C2H10N2)0.5[M(HPO3)2].Ab initio structure determination,spectroscopic,and magnetic properties [J]. Chem Mater,2002,14(5):2300-2307.
[123]刘成站,朱广山,方千荣,等. [In2(HPO3)4]·(NH3CH2CH2NH3)的水热合成与晶体结构[J].高等学校化学学报,2007,28(9):1637-1639.
[124] Mandal S,Pati S K,Green M A,et al. Inorganic-organic hybrid compounds: Synthesis,structure,and magnetic properties of the first organically templated iron oxalate-phosphite ,[C4N2H12[Fe4(II)(HPO3)2(C2O4)3],possessing infinite Fe-O-Fe chains [J]. Chem Mater,2005,17(11):2912-2917.
[125] Shi Z,Li G H,Zhang D,et al. A vanadium(IV) phosphite with a pillared layered structure: Hydrothermal synthesis and characterization of (VO)4(4,4’-bpy)2(HPO3)4 [J]. Inorg Chem,2003,42(7):2357-2361.
[126] Harrison W T A. (CN3H6)2·(VO)3(H2O)3(HPO3)4·3H2O,a guanidinium vanadium phosphite hydrate based on a (3,4) connected net: an "Orthogonal Templating" effect [J]. Solid State Sci,2003,5(2):297-302.
[127] Chiang R K,Chuang N T. Hydrothermal synthesis and structure characterization of a new 3D vanadium hydrogen phosphite with 14-ring channels: (C5N2H14)[VO(H2O)]3(HPO3)4·H2O [J]. J Solid State Chem,2005,178(10):3040-3045.
[128] Shi S H,Wang L,Yuan H M,et al. Hydrothermal synthesis and characterization of a new 3D vanadium (III) phosphite (C4H8N2H4)0.5(C4H8N2H3)[V4(HPO3)7(H2O)3]·1.5H2O [J]. J Solid State Chem,2004,177(11):4183-4187.
[129] Chen L,Bu X. (3,4)-Connected zincophosphites as structural analogues of zinc hydrogen phosphate [J]. Inorg Chem,2006,45(12):4654-4660.
[130] Liang J,Li J,Yu J,et al. [(C4H12N)2][Zn3(HPO3)4]: an open-framework zinc phosphite containing extra-large 24-ring channels [J]. Angew Chem Int Ed,2005,45(16):2546-2548.
[131] Li J,Li L,Chen P,et al. Template-designed syntheses of open-framework zinc phosphites with extra-large 24-ring channels [J]. Cryst Growth Des,2008,8(7):2318-2323.
[132] Liang J,Wang Y,Yu J,et al. Synthesis and structure of a new layered zinc phosphite (C5H6N2)Zn(HPO3) containing helical chains [J]. Chem Commun,2003(7):882-883.
[133] Yu J,Xu R. Insight into the construction of open-framework aluminophosphates [J]. Chem Soc Rev,2006,35(7):593-604.
[134] Fu W S , Wang L , Shi Z , et al. The first organically templated beryllium phosphite [NH3(CH2)3NH3]·Be3(HPO3)4: Hydrothermal synthesis and X-ray crystal structure [J]. Crystal Growth&Design,2004,4(2):297-300.
[135] Feng P Y,Bu X H,Stucky G D. Hydrothermal syntheses and structural characterization of zeolite analogue compounds based on cobalt phosphate [J]. Nature,1997,388(6644):735-741.
[136] Balkus K J J,Gabrielov A G,Zones S I,et al. Synthesis of porous materials[M],Occelli M,Kessler H(Eds). Marcel Dekker,NY 1996,77.
[137] Based on a 14 Membered Rings System.Stu Balkus K J,Jr.Biscotto M,Gabrielov A G. The Synthesis and Characterization of UTD-1: The First Large Pore Zeolite. Surf Sci Catal,1997 105A,415-421.
[138] Seddon K R.Ionic liquids for clean technology [J]. Chem Biotechnol,1997,68(4):351-356.
[139] Wasserscheid P,Keim W. Ionic liquids-new“solution”for transition metal catalysis [J]. Angew Chem Int Ed,2000,39(21):3773-3789.
[140] Tait S,Osteryoung R A.Infrared study of ambient–temperature chloroaluminates as a function of melt acidity [J]. Inorg Chem,1984,23(25):4352-4360.
[141] Wilkes J S. A short history of ionic liquid–from molten salts to neoteric solvents [J]. Green Chem,2002,4(2):73-80.
[142] Chum H L,Koch V R,Miller L L,et al. Electrochemical scrutiny of organometallic iron complexes and hexamethylbenzene in a room temperature molten salt [J]. J Am Chem Soc,1975,97(11):3264-3265.
[143] Wilkes J S,Levisky J A,Wilson R A,et al. Dialkylimidazolium chloroaluminate metals: a new class of room–temperature ionic liquids for electrochemistry,spectroscopy,and synthesis [J]. Inorg Chem,1982,21(3):1263-1264.
[144] Hussey C L. Room temperature haloaluminate ionic liquids–novel solvents for transition metal solution chemistry [J]. Pure Appl Chem,1988,60(12):1763-1772.
[145] Wilkes J S,Zaworotko M J. Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids [J]. J Chem Soc,Chem Commun,1992,(13):965-966.
[146]杨雅立,王晓化,寇元等.不断壮大的离子液体家族[J].化学进展,2003,15(6):471-476.
[147] Cola A C,Jensen J L,Ntai I,et al. Novel bronsted acidic ionic liquids and their use as dual solvent–catalysts [J]. J Am Chem Soc,2002,124(21):5962-5963.
[148] Bao W L,Wang Z M,Li Y X. Synthesis of chiral ionic liquids from natural amino acids [J]. J Org Chem,2003,68(2):591-593.
[149] Zhao D B,Fei Z F,Geldbach T J,et al. Nitrile–functionalized pyridinium ionic liquids: synthesis,characterization,and their application in carbon-carbon coupling reactions [J]. J Am Chem Soc,2004,126(48):876-882.
[150] Paul A,Mandal P K,Samanta A. On the optical properties of the imidazolium ionic liquids [J]. J Phys Chem B,2005,109(18):9148-9153.
[151] Paul A,Samanta A. Photoinduced electron transfer reaction in room temperature ionic liquids: a combined laser flash photolysis and fluorescence study [J]. J Phys Chem B,2007,111(8): 1957-1962.
[152] Leone A M,Weatherly S C,Williams M E,et al. An ionic liquid form of DNA: redox–active molten salts of nucleic acids [J]. J Am Chem Soc,2001,123(2):218-222.
[153] Huang J,Jiang T,Gao H X,et al. Pd nanoparticles immobilized on molecular sieves by ionic liquids: Heterogeneous catalysts for solvent-free hydrogenation [J]. Angew Chem Int Ed,2004,43(11):1397-1399.
[154] Dai L Y,Yu S Y,Shan Y K,et al. Novel room temperature inorganic ionic liquids [J]. Eur J Inorg Chem,2004,(2): 237-241.
[155]顾彦龙,石峰,邓有全.室温离子液体:一类新型的软介质和功能材料[J].科学通报,2004,49(6):515-521.
[156]王均凤,张锁江,陈慧萍等.离子液体的性质及其在催化反应中的应用[J].过程工程学报,2003,3(2):177-185.
[157] Zhang S,Sun N,Zhang X,et al. Periodicity and map for discovery of new ionic liquids [J].Sci China Ser B,2006,49(2): 103-115.
[158] Zhang J,Zhang S,Dong K,et al. Supported absorption of CO2 by tetrabutylphosphonium amino acids ionic liquids [J]. Chem Eur J,2006,12(15):4021-4026.
[159]刘鹰,刘植昌,徐春明等.室温离子液体催化异丁烷-丁烯烷基化的中试研究[J].化工进展,2005,24(6):656-660.
[160] Holbery J D,Seddon K R.The phase behavior of 1-alkyl-3-methylimidazolium tetrafluoroborates: ionic liquids and ionic liquid crystals [J]. J Chem Soc,Dalton Trans,1999(13):2133-2139.
[161]李汝雄.绿色溶剂—离子液体的合成与应用[M].北京:化学工业出版社,2004,10-31
[162]张锁江,吕兴梅.离子液体—从基础研究到工业应用[M].北京:科学出版社,2006,1-2
[163] Decastro C,Sauvage E,Valkenberg M H,et al. Immobilised ionic liquids as lewis acid catalysts forthe alkylation of aromatic compounds with dodecene [J]. J Catal,2000,196(1):86-94.
[164] Valkenberg M H,deCastro C,Holderich W F. Friedel-Crafts acylation of aromatics catalysed by supported ionic liquids [J]. Appl Catal A-General,2001,215(1-2):185-190.
[165] Fadeev A G,Meagher M M. Opportunities for ionic liquids in recovery of biofuels [J]. Chem Commun,2001(3):295-296.
[166] Visser A E,Swatloski R P,Reichert W M,et al. Task-specific ionic liquids for the extraction of metal ions from aqueous solutions [J]. Chem Commun,2001,(1):135-136.
[167] Dai S,Ju Y H,Barnes C E. Solvent extraction of strontium nitrate by a crown ether using room-temperature ionic liquids [J]. J Chem Soc,Dalton Trans,1999,8:1201-1202.
[168] Blanchard L A,Hancu D,Beckman E J,et al. Green processing using ionic liquids and CO2 [J]. Nature,1999,399(6731):28-29.
[169] Armstrong D W,He L F,Liu Y S. Examination of ionic liquids and their interaction with molecules,when used as stationary phases in gas chromatography [J]. Ana Chem,1999,71(17):3873-3876.
[170] He L J,Zhang W Z,Zhao L,et al. Effect of 1-alkyl-3-methylimidazolium-based ionic liquids as the eluent on the separation of ephedrines by liquid chromatography [J]. J Chromatogr A,2003,1007(1-2):39-45.
[171] Mikoshiba S,Murai S,Sumino H,et al. Ionic liquid type dye-sensitized solar cells: Increase in photovoltaic performances by adding a small amount of water [J]. Cur Appl Phys,2005,5(2):152-158.
[172] Antonietti M,Kuang D B,Smarsly B,et al. Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures [J]. Angew Chem Int Ed,2004,43(38):4988-4992.
[173] Zhou Y,Antonietti M. Synthesis of very small TiO2 nanocrystals in a room-temperature ionic liquid and their self-assembly toward mesoporous spherical aggregates [J]. J Am Chem Soc,2003,125(49):14960-14961.
[174] Zhou Y,Schattka J H,Antonietti M. Room-temperature ionic liquids as template to monolithic mesoporous silica with wormlike pores via a sol-gel nanocasting technique [J]. Nano Lett,2004,4(3):477-481.
[175] Scheeren C W,Machado G,Dupont J,et al. Nanoscale Pt(0) particles prepared in imidazolium room temperature ionic liquids: Synthesis from an organometallic precursor,characterization,and catalytic properties in hydrogenation reactions [J]. Inorg Chem,2003,42(15):4738-4742.
[176] Zones S I. Synthesis of pentasil zeolites from sodium-silicate solutions in the presence of quaternary imidazole compounds [J]. Zeolites,1989,9(6):458-467.
[177] Adams C J,Bradley A E,Seddon K R. The synthesis of mesoporous materials using novel ionic liquid templates in water [J]. Aust J Chem,2001,54(11):679-681.
[178] Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[179] Parnham E R,Morris R E.Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[180] Morris R E.Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[181] Morris R E.Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21):2990-2998.
[182] Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesisusing ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[183] Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[184] Parnham E R,Wheatley P S,Morris R E.The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[185] Parnham E R,Morris R E.1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[186] Parnham E R,Morris R E.Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[187] Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[188] Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[189] Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[190] Parnham E R,Morris R E.The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[191] Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[192] Wang L , Xu Y P , Wang B C , et al. Ionothermal synthesis of magnesium-containing aluminophosphate molecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[193] Harrison W T A.C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[194] Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Micropor Mesopor Mater,2008,115(3):624-628.
[195] Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[196] Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[197] Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Micropor Mesopor Mater,2009,120(3):278-284.
[198] Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[199] Lin Z,Wragg D S,Morris R E. Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[200] Parnham E R,Slawin A M Z,Morris R E.Ionothermal synthesis of b-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[201] Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[202] Lin Z,Slawin A M Z,Morris R E.Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[203] Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[204] Zhang J,Chen S,Bu X.Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[205] Chen S,Zhang J,Bu X.Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[206] Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[207] Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[208] Liao J H,Wu P C,Bai Y H. Eutectic mixture of choline chloride/urea as a green solvent in synthesis of a coordination polymer:[Zn(O3PCH2CO2)]·NH4 [J]. Inorg Chem Commun,2005,8(4):390-392.
[1]Cheetham A K,Férey G,Loiseau T. Open-framework inorganic materials [J]. Angew Chem Int Ed,1999,38(22):3268-3292.
[2]Davis M E. Ordered porous materials for emerging applications [J]. Nature,2002,417(6891):813-821.
[3]Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[4]Parnham E R,Morris R E. Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[5]Morris R E. Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[6]Morris R E. Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21),2990-2998.
[7]Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesis using ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[8]Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[9]Parnham E R,Wheatley P S,Morris R E. The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[10]Parnham E R,Morris R E. 1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[11]Parnham E R,Morris R E. Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[12]Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[13]Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[14]Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[15]Parnham E R,Morris R E. The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[16]Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[17]Wang L,Xu Y P,Wang B C,et al. Ionothermal synthesis of magnesium-containing aluminophosphatemolecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[18]Harrison W T A. C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[19]Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Microporous Mesoporous Mater,2008,115(3):624-628.
[20]Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[21]Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[22]Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Microporous Mesoporous Mater,2009,120(3):278-284.
[23]Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[24]Lin Z,Wragg D S,Morris R E.Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[25]Parnham E R,Slawin A M Z,Morris R E. Ionothermal synthesis ofβ-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[26]Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[27]Lin Z,Slawin A M Z,Morris R E.Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[28]Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[29]Zhang J,Chen S,Bu X. Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[30]Chen S,Zhang J,Bu X. Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[31]Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[32]Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[33]Wang Y,Yu J,Guo M,et al. [{Zn2(HPO4)4}{Co(dien)2}]·H3O: a zinc phosphate with multidirectional intersecting helical channels [J]. Angew Chem Int Ed,2003,42(34):4089-4092.
[34]Lin Z E,Yao Y W,Zhang J,et al. Synthesis and structure of a novel open-framework zincophosphate with intersecting three-dimensional helical channels [J]. J Chem Soc,Dalton Trans,2002(24):4527-4528.
[35]Harrison W T A,Phillips M L F.Hydrothermal syntheses and single-crystal structures of some novel guanidinium-zinc-phosphates [J]. Chem Mater,1997,9(8):1837-1846.
[36]Harrison W T A,Gier T E,Stucky G D,et al. NaZnPO4·H2O,an open-framework sodium zincophosphate with a new chiral tetrahedral framework topology [J]. Chem Mater,1996,8(1):145-151.
[37]Neeraj S,Forster P M,Rao C N R,et al. A new route for the synthesis of open-framework metal phosphates using organophosphates [J]. Chem Commun,2001(24):2716-2717.
[38]Zhang J,Chen S,Bu X. Nucleotide-catalyzed conversion of racemic zeolite-type zincophosphate into enantioenriched crystals [J]. Angew Chem Int Ed,2009,48(33):6049-6051.
[39]Sheldrick G M.Program for crystal structure solution and refinement[CP]. SHELXL-97,University of G?ttingen,1997.
[40]Brese N E,O’Keeffe M. Bond-valence parameters for solids [J]. Acta Cryst,1991,B47(2):192-197.
[41]Khan M I,Meyer L M,Haushalter R C,et al. Giant voids in the hydrothermally synthesized microporous square pyramidal-tetrahedral framework vanadium phosphates [HN(CH2CH2)3NH]K1.35[V5O9(PO4)2]·xH2O and Cs3[V5O9(PO4)2]·xH2O [J]. Chem Mater,1996,8(1):43-53.
[42]Spek A L. Single-crystal structure validation with the program PLATON [J]. J Appl Crystallogr,2003,36(1):7-13.
[43]Yu J,Xu R. Chiral zeolitic materials:structural insights and synthetic challenges [J]. J Mater Chem,2008,18(34):4021-4030.
[44]Gier T E,Bu X,Feng P,et al. Synthesis and organization of zeolite-like materials with three-dimensional helical pores [J]. Nature,1998,395(6698):154-157.
[45]Tang L,Shi L,Bonneau C,et al. A zeolite family with chiral and achiral structures built from the same building layer [J]. Nature Mater,2008,7(5):381-385.
[1]Cheetham A K,Férey G,Loiseau T. Open-framework inorganic materials [J]. Angew Chem Int Ed,1999,38(22):3268-3292.
[2]Davis M E. Ordered porous materials for emerging applications [J]. Nature,2002,417(6891):813-821.
[3]Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[4]Parnham E R,Morris R E. Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[5]Morris R E. Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[6]Morris R E. Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21):2990-2998.
[7]Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesis using ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[8]Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[9]Parnham E R,Wheatley P S,Morris R E. The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[10]Parnham E R,Morris R E. 1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[11]Parnham E R,Morris R E. Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[12]Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[13]Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[14]Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[15]Parnham E R,Morris R E. The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[16]Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[17]Wang L,Xu Y P,Wang B C,et al. Ionothermal synthesis of magnesium-containing aluminophosphatemolecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[18]Harrison W T A. C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[19]Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Micropor Mesopor Mater,2008,115(3):624-628.
[20]Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[21]Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[22]Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Micropor Mesopor Mater,2009,120(3):278-284.
[23]Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[24]Lin Z,Wragg D S,Morris R E.Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[25]Parnham E R,Slawin A M Z,Morris R E. Ionothermal synthesis of b-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[26]Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[27]Lin Z,Slawin A M Z,Morris R E.Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[28]Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[29]Zhang J,Chen S,Bu X. Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[30]Chen S,Zhang J,Bu X. Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[31]Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[32]Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[33]Sheldrick G M. Program for crystal structure solution and refinement[CP]. SHELXL-97,University of G?ttingen,1997.
[34]Brese N E,O’Keeffe M. Bond-valence parameters for solids [J]. Acta Cryst,1991,B47(2):192-197.
[35]Wang Y,Yu J,Guo M,et al. [{Zn2(HPO4)4}{Co(dien)2}]·H3O: a zinc phosphate with multidirectional intersecting helical channels [J]. Angew Chem Int Ed,2003,42(34):4089-4092.
[36]Lin Z E,Yao Y W,Zhang J,et al. Synthesis and structure of a novel open-framework zincophosphate with intersecting three-dimensional helical channels [J]. J Chem Soc,Dalton Trans,2002(24):4527-4528.
[37]Harrison W T A,Phillips M L F. Hydrothermal syntheses and single-crystal structures of some novel guanidinium-zinc-phosphates [J]. Chem Mater,1997,9(8):1837-1846.
[38]Harrison W T A,Gier T E,Stucky G D,et al. NaZnPO4·H2O,an open-framework sodium zincophosphate with a new chiral tetrahedral framework topology [J]. Chem Mater,1996,8(1):145-151.
[39]Neeraj S,Forster P M,Rao C N R,et al. A new route for the synthesis of open-framework metal phosphates using organophosphates [J]. Chem Commun,2001(24):2716-2717.
[40]Khan M I,Meyer L M,Haushalter R C,et al. Giant voids in the hydrothermally synthesized microporous square pyramidal-tetrahedral framework vanadium phosphates [HN(CH2CH2)3NH]K1.35[V5O9(PO4)2]·xH2O and Cs3[V5O9(PO4)2]·xH2O [J]. Chem Mater,1996,8(1):43-53.
[41]Spek A L. Single-crystal structure validation with the program PLATON [J]. J Appl Cryst,2003,36(1):7-13.
[42]Zou X,Conradsson T,Klingstedt M,et al. A mesoporous germanium oxide with crystalline pore walls and its chiral derivative [J]. Nature,2005,437(7059):716-719.
[43]Plévert J,Gentz T M,Laine A,et al. A flexible germanate structure containing 24-ring channels and with very low framework density [J]. J Am Chem Soc,2001,123(50):12706-12707.
[44]Yu J,Xu R. Chiral zeolitic materials:structural insights and synthetic challenges [J]. J Mater Chem,2008,18(34):4021-4030.
[45]Del Pópolo M G,Voth G A. On the structure and dynamics of ionic liquids [J]. J Phys Chem B,2004,108(5):1744-1752.
[46]Yu J,Xu R. Rich structure chemistry in the aluminophosphate family [J]. Acc Chem Res,2003,36(7):481-490.
[47]Yu J,Xu R. Insight into the construction of open-framework aluminophosphates [J]. Chem Soc Rev,2006,35(7):593-604.
[1]Cheetham A K,Férey G,Loiseau T. Open-framework inorganic materials [J]. Angew Chem Int Ed,1999,38(22):3268-3292.
[2]Davis M E. Ordered porous materials for emerging applications [J]. Nature,2002,417(6891):813-821.
[3]Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[4]Parnham E R,Morris R E. Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[5]Morris R E. Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[6]Morris R E. Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21):2990-2998.
[7]Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesis using ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[8]Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[9]Parnham E R,Wheatley P S,Morris R E. The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[10]Parnham E R,Morris R E. 1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[11]Parnham E R,Morris R E. Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[12]Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[13]Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[14]Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[15]Parnham E R,Morris R E. The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[16]Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[17]Wang L,Xu Y P,Wang B C,et al. Ionothermal synthesis of magnesium-containing aluminophosphatemolecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[18]Harrison W T A. C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[19]Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Micropor Mesopor Mater,2008,115(3):624-628.
[20]Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[21]Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[22]Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Micropor Mesopor Mater,2009,120(3):278-284.
[23]Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[24]Lin Z,Wragg D S,Morris R E.Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[25]Parnham E R,Slawin A M Z,Morris R E. Ionothermal synthesis of b-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[26]Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[27]Lin Z,Slawin A M Z,Morris R E.Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[28]Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[29]Zhang J,Chen S,Bu X. Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[30]Chen S,Zhang J,Bu X. Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[31]Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[32]Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[33]Sheldrick G M. Program for crystal structure solution and refinement[CP]. SHELXL-97,University of G?ttingen,1997.
[34]Brese N E,O’Keeffe M. Bond-valence parameters for solids [J]. Acta Cryst,1991,B47(2):192-197.
[35]Spek A L. Single-crystal structure validation with the program PLATON [J]. J Appl Crystallogr,2003,36(1):7-13.
[1]Cheetham A K,Férey G,Loiseau T. Open-framework inorganic materials [J]. Angew Chem Int Ed,1999,38(22):3268-3292.
[2]Davis M E. Ordered porous materials for emerging applications [J]. Nature,2002,417(6891):813-821.
[3]Cooper E R,Andrews C D,Wheatley P S,et al. Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J]. Nature,2004,430(7003):1012-1016.
[4]Parnham E R,Morris R E. Ionothermal synthesis of zeolites,metal-organic frameworks,and inorganic-organic hybrids [J]. Acc Chem Res,2007,40(10):1005-1013.
[5]Morris R E. Ionic liquids and microwaves-making zeolites for emerging applications [J]. Angew Chem Int Ed,2008,47(3):442-444.
[6]Morris R E.Ionothermal synthesis—ionic liquids as functional solvents in the preparation of crystalline materials [J]. Chem Commun,2009(21):2990-2998.
[7]Cooper E R,Andrews C D,Wheatley P S,et al. A new methodology for zeolite analogue synthesis using ionic liquids as solvent and template [J]. Stud Surf Sci Catal,2005,158(1):247-254.
[8]Parnham E R,Drylie E A,Wheatley P S,et al. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents [J]. Angew Chem Int Ed,2006,45(30):4962-4966.
[9]Parnham E R,Wheatley P S,Morris R E. The ionothermal synthesis of SIZ-6—a layered aluminophosphate [J]. Chem Commun,2006(4):380-382.
[10]Parnham E R,Morris R E. 1-Alkyl-3-methyl Imidazolium Bromide Ionic Liquids in the Ionothermal Synthesis of Aluminium Phosphate Molecular Sieves [J]. Chem Mater,2006,18(20):4882-4887.
[11]Parnham E R,Morris R E. Ionothermal synthesis using a hydrophobic ionic liquid as solvent in the preparation of a novel aluminophosphate chain structure [J]. J Mater Chem,2006,16(37):3682-3684.
[12]Xu Y P,Tian Z J,Wang S J,et al. Microwave-enhanced ionothermal synthesis of aluminophosphate molecular sieves [J]. Angew Chem Int Ed,2006,45(24):3965-3970.
[13]Xing H,Li J,Yan W,et al. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7 [J]. Chem Mater,2008,20(13):4179-4181.
[14]Xu Y,Tian Z,Xu Z,et al. Ionothermal synthesis of silicoaluminophosphate molecular sieve in N-alkyl imidazolium bromide [J]. Chin J Catal,2005,26(6):446-448.
[15]Parnham E R,Morris R E. The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks [J]. J Am Chem Soc,2006,128(7):2204-2205.
[16]Drylie E A,Wragg D S,Parnham E R,et al. Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates [J]. Angew Chem Int Ed,2007,46(41):7839-7843.
[17]Wang L,Xu Y P,Wang B C,et al. Ionothermal synthesis of magnesium-containing aluminophosphate molecular sieves and their catalytic performance [J]. Chem-Eur J,2008,14(34):10551-10555.
[18]Harrison W T A. C5H14NO ZnCl(HPO3),an unexpected product from an ionic-liquid synthesis [J]. Inorg Chem Commun,2007,10(7):833-835.
[19]Liu L,Kong Y,Xu H,et al. Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent [J]. Micropor MesoporMater,2008,115(3):624-628.
[20]Liu L,Ferdov S,Coelho C,et al. New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers [J]. Inorg Chem,2009,48(11):4598-4600.
[21]Liu L,Wragg D S,Zhang H,et al. Ionothermal synthesis,structure and characterization of three-dimensional zinc phosphates [J]. Dalton Trans,2009(34):6715-6718.
[22]Ma H,Xu R,You W,et al. Ionothermal synthesis of gallophosphate molecular sieves in 1-alkyl-3-methyl imidazolium bromide ionic liquids [J]. Micropor Mesopor Mater,2009,120(3):278-284.
[23]Liu L,Li Y,Wei H,et al. Ionothermal synthesis of zirconium phosphates and their catalytic behavior in the selective oxidation of cyclohexane [J]. Angew Chem Int Ed,2009,48(12):2206-2209.
[24]Lin Z,Wragg D S,Morris R E. Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions [J]. Chem Commun,2006(19):2021-2023.
[25]Parnham E R,Slawin A M Z,Morris R E. Ionothermal synthesis of b-NH4AlF4 and the determination by single crystal X-ray diffraction of its room temperature and low temperature phases [J]. J Solid State Chem,2007,180(1):49-53.
[26]Lin Z,Wragg D S,Warren J E,et al. Anion control in the ionothermal synthesis of coordination polymers [J]. J Am Chem Soc,2007,129(34):10334-10335.
[27]Lin Z,Slawin A M Z,Morris R E. Chiral induction in the ionothermal synthesis of a 3-D coordination polymer [J]. J Am Chem Soc,2007,129(16):4880-4881.
[28]Lin Z,Li Y,Slawin A M Z,et al. Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers [J]. Dalton Trans,2008(30):3989-3994.
[29]Zhang J,Chen S,Bu X. Multiple functions of ionic liquids in the synthesis of three-dimensional low-connectivity homochiral and achiral frameworks [J]. Angew Chem Int Ed,2008,47(29):5434-5437.
[30]Chen S,Zhang J,Bu X. Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture [J]. Inorg Chem,2008,47(13):5567-5569.
[31]Lin Z,Wragg D S,Lightfoot P,et al. A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis [J]. Dalton Trans,2009(27):5287-5289.
[32]Hulvey Z,Wragg D S,Lin Z,et al. Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands [J]. Dalton Trans,2009(7):1131-1135.
[33]Chen L,Bu X. (3,4)-Connected zincophosphites as structural analogues of zinc hydrogen phosphate [J]. Inorg Chem,2006,45(12):4654-4660.
[34]Liang J,Li J,Yu J,et al. [(C4H12N)2][Zn3(HPO3)4]:an open-framework zinc phosphite containing extra-large 24-ring channels [J]. Angew Chem Int Ed,2005,45(16):2546-2548.
[35]Li J,Li L,Chen P,et al. Template-designed syntheses of open-framework zinc phosphites with extra-large 24-ring channels [J]. Cryst Growth Des,2008,8(7):2318-2323.
[36]Liang J,Wang Y,Yu J,et al. Synthesis and structure of a new layered zinc phosphite (C5H6N2)Zn(HPO3) containing helical chains [J]. Chem Commun,2003(7):882-883.
[37]Zhao L,Li J,Chen P,et al. 2H3O·[Co8(HPO3)9(CH3OH)3]·2H2O: an open-framework cobalt phosphite containing extra-Large 18-ring channels [J]. Chem Mater,2008,20(1):17-19.
[38]Mandal S,Natarajan S. Synthesis,structure,and polymorphism studies in amine-templated open-framework zinc phosphites [J]. Inorg Chem,2008,47(12):5304-5313.
[39]Liu X,Xing Y,Liu X. Solvothermal synthesis and magnetic properties of cobalt(II) phosphite structures of varying dimensionality [J]. CrystEngComm,2010,12(2):383-386.
[40]Liu X,Xing Y,Wang X et al. Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials [J]. Chem Commun,2010,ASAP.
[41]Sheldrick G M. Program for crystal structure solution and refinement[CP]. SHELXL-97,University of G?ttingen,1997.
[42]Wiebcke M. [Zn3(HPO4)4](NMe4)2 : a zincophosphate containing interruptions of isolated hydrogen-bonding [H-O(P)]4 groupings within a novel three-dimensional four-connected framework [J]. J Mater Chem,2002,12(3):421-425.
[43]Murugavel R,Walawalkar M G,Dan M,et al. Transformations of molecules and secondary building units to materials: a bottom-up approach [J]. Acc Chem Res,2004,37(10):763-774.
[44]Fan J,Slebodnick C,Troya D,et al. Five new zinc phosphite structures:tertiary building blocks in the construction of hybrid materials [J]. Inorg Chem,2005,44(8):2719-2727.
[45]Hu L,Fan J,Slebodnick C,et al. Structural diversity in 4,4’-trimethylenedipyridine-zinc phosphite hybrids:incorporation of neutral guest molecules in hybrid materials [J]. Inorg Chem,2006,45(19):7681-7688.
[46]Lin C H,Wang S L,Lii K H. [Ga2(DETA)(PO4)2]·2H2O (DETA = diethylenetriamine):a novel porous gallium phosphate containing 24-ring channels [J]. J Am Chem Soc,2001,123(19):4649-4650.
[47]Zhou Y,Zhu H,Chen Z,et al. A large 24-membered-ring germanate zeolite-type open-framework structure with three-dimensional intersecting channels [J]. Angew Chem Int Ed,2001,40(11):2166-2168.
[48]Yang Y , Zhao Y , Yu J , et al. Doping-induced structure variation of 1 ,3-cyclohexane-bis(methylamine)-templated zinc-phosphorus open structures [J]. Inorg Chem,2008,47(3):769-771.
[49]Lai Y L,Lii K H,Wang S L. 26-Ring-channel structure constructed from bimetal phosphite helical chains [J]. J Am Chem Soc,2007,129(17):5350-5351.
[50]Yang G Y,Sevov S C. Zinc phosphate with gigantic pores of 24 tetrahedra [J]. J Am Chem Soc,1999,121(36):8389-8390.
[51]Spek A L. Single-crystal structure validation with the program PLATON [J]. J Appl Cryst,2003,36(1):7-13.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |