氧化褐煤制备及其对有机废水处理的工艺装备及试验研究
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摘要
本文以开发用于印染废水处理的褐煤吸附材料及水处理工艺为目的,采用低温空气氧化法制备了褐煤粉吸附材料,以亚甲基蓝为对象,研究了氧化褐煤对偶氮阳离子染料的吸附性能,采用滤网过滤和阳离子聚丙烯酰胺絮凝的方法对吸附液进行固液分离,并自行设计建设了褐煤吸附水处理的中试平台,对工艺装置的实际运行效果进行了研究。结果表明,低温氧化处理后褐煤粉表面含氧官能团数量增加是褐煤表面性质和孔隙结构变化及吸附性能增加的根本原因,褐煤对亚甲基蓝的吸附属于自发进行的放热化学吸附过程,阳离子聚丙烯酰胺对褐煤微粒的絮凝作用是电中和和架桥吸附的双重作用,最终的静态试验及中试动态试验结果表明,褐煤粉处理偶氮阳离子染料废水处理工艺是有效可行的。
This paper is intended to develop a new lignite-based adsorption material and water treatment process for printing and dyeing wastewater treatment. The lignite adsorption material was prepared using low-temperature air oxidation. With the methylene blue as study object, the adsorption properties of oxidized lignite on azo cationic dye were studied. The net filter and cationic polyacrylamide flocculation method were used to separate lignite from adsorption solution. Based on the designing and construction of water treatment test platform using lignite adsorption technology, the actual operation effect of the process units was studied. The results show that the oxygen containing functional groups increases during the low-temperature oxidation process, which is the fundamental cause of the changed lignite surface properties and pore structure and the increased adsorption performance of lignite on methylene blue. The adsorption process belongs to the spontaneous exothermic chemical adsorption process. The flocculation mechanism of cationic polyacrylamide on lignite particle includes charge neutralization and adsorption bridging. The experimental results of the static and pilot dynamic tests show that the azo cationic dye wastewater treatment process with lignite adsorption and separation is feasible and effective.
This paper is intended to develop a new lignite-based adsorption material and water treatment process for printing and dyeing wastewater treatment. The lignite adsorption material was prepared using low-temperature air oxidation. With the methylene blue as study object, the adsorption properties of oxidized lignite on azo cationic dye were studied. The net filter and cationic polyacrylamide flocculation method were used to separate lignite from adsorption solution. Based on the designing and construction of water treatment test platform using lignite adsorption technology, the actual operation effect of the process units was studied. The results show that the oxygen containing functional groups increases during the low-temperature oxidation process, which is the fundamental cause of the changed lignite surface properties and pore structure and the increased adsorption performance of lignite on methylene blue. The adsorption process belongs to the spontaneous exothermic chemical adsorption process. The flocculation mechanism of cationic polyacrylamide on lignite particle includes charge neutralization and adsorption bridging. The experimental results of the static and pilot dynamic tests show that the azo cationic dye wastewater treatment process with lignite adsorption and separation is feasible and effective.
引文
1. 戴和武,谢可玉.褐煤利用技术.北京：煤炭工业出版社,1998：5-25
2. 毛节华,许惠龙.中国煤炭资源预测与评价.北京：科学出版社,1999：3-22
3. 陈文敏.煤质分级结果的定性与定量审查.北京：煤炭工业出版社,1994
4. Allardice DJ, Young BC. Proceeding of the eighteenth annual international Pittsburgh conference. Newcastle, Australia,3-7 December,2001
5. 李好管.煤化工技术进展及产业现状分析.煤化工,2009(3)：1-6
6. 李春柱,余江龙,常丽萍,等.维多利亚褐煤科学进展.北京：化学工业出版社,2009：76-92
7. 黄建湘,李明,袁翠翠,刘少芳.褐煤煤化工利用现状及前景[J].广州化工,2011,39：35-36
8. 周夏.褐煤气化技术评述.煤化工,2009,(6)：1-4
9. Moreea-Taha R. In:modelling and simulation for coal gasfication.CCC/42, London:IEA Coal Research,2000
10. Miura K. Fuel Processing Technology,2009,62:119
11.王路宁.褐煤低温热解特性实验研究及理论分析.北京：中国矿业大学(北京)：2009：5-15
12.赵振新,朱书全,马名杰等.中国褐煤的综合优化利用.洁净煤技术,2008,14(1)：28-31
13. 马艳梅,纪龙,赵宏宇,等.褐煤制浆和配煤制浆技术.清洁煤技术,2012,18(4)：49-51
14.赵振新,朱书全,马名杰,等.中国褐煤的综合优化利用.洁净煤技术,2008,14(1)：28-31
15.张意颖,张文辉.煤基活性炭对原料煤的适应性.煤,2000,2,27-28
16.徐革联,刘伟.褐煤改质制备炭分子筛的研究.洁净煤技术,2006,12(2):89-91
17. 董洪峰,云增杰,曹勇飞.我国褐煤的综合利用途径及前景展望.煤炭技术,2008,27(9)：122-124
18.陈慧,陶秀祥,石开义,等.褐煤生物转化及其研究进展.清洁煤技术,2008,14(5)：39-42
19. 朱学栋,朱子彬,韩崇家等.煤中含氧官能团的红外光谱定量分析[J].燃料化学学报,1999,(27),(4)：335-339.
20. Yao Z S, Wei X Y, Lv J, Liu F J, et al. Oxidation of Shenfu coal with RuO4 and NaOCl. Energy and Fuels, 2010,24(3):1801-1808
21.刘转年.煤基超细复合剂的制备及吸附性能研究.西安：西安建筑科技大学,2004:16-30
22.晋云玲,杨阿三,孙勤,等.褐煤氧化氨解过程中腐植酸挂能团含量的研究.高校化学工程学报,2010,24(3)：446--450
23.罗道成,刘俊峰,李忠远.用磺化褐煤处理含铬废水的研究.煤化工,2010,(2)：36-39
24.朱红,王淀佐,李虎林,欧泽深.电化学法对细粒煤表面改性机理的研究.煤炭学报,200,25(3)：307-311
25. 刘加龙.褐煤电化学氧化的新方法.腐植酸,2001,(11)：9-11
26. GothatyML, Prominenifroniiersofeoalscience:Past. Preseniandfuture, Fuel.1994,3(12):1819-1828
27.侯爽.煤分子活性基团低温氧化过程研究.西安科技大学,2007
28. Fanor Mondragon, Wilson Ruiz, Alexander Santamaria. Effect of early stages of coal oxidation on its reaction with elemental sulphur.Fuel,2002, (81):381-388.
29.朱学栋,朱子彬,韩崇家等.煤中含氧官能团的红外光谱定量分析.燃料化学学报,1999,(27),(4)：335-339.
30.石必明.易自燃煤低温氧化和阻化的微观结构分析.煤炭学报,2000,(25),(3)：294-298.
31.刘伟军,陈拴柱,张书华,曾红.煤粉电晕荷电特性的多因素实验研究.煤炭转化,2010,33(4)：5-8
32.陈丕亚,黄瀛华,高杰,等.这赉诺尔褐煤在液相中吸附特性的研究—扎赉诺尔褐煤及其炭化物对酚的研究.燃烧化学学报,1987,15(4)：343-348
33.陈丕亚,杨凤莲,胡慕中,等.扎赉诺尔褐煤在液相中吸附特性的研究—吸附阳离子染料的特性.燃烧化学学报,1986,14(2)：171-176
34.赵勤荣.褐煤吸附法治理二硝基废水.化工环保,1988,8(4)：201-209
35.丁德润,顾健民.褐煤对碱性染料吸附的研究.化学世界,1994,(6)：322-325
36. S.J.Allen, G.Mckay, K.Y.H. Khader. Environmental Pollution,1989,(56):39-44
37.郭喜亮.褐煤对含染料废水的吸附与絮凝作用研究.辽宁,辽宁工程技术大学,2009：10-45
38.许端平,储海燕,徐雪松.褐煤对废水中酸性红B的吸附去除.环境工程学报,2012,6(6)：1961-1965
39.邓昌亮,徐海宁.褐煤处理含酚废水的研究.山东师大学报(自然科学版),1997,12(3)：350-353
40. Tarasevich Y I. Porous structure and adsorption properties of natural porous coal. Colloids Surfance.2001,176(2-3):267-272
41. Jiang X, Zheng C,Yan C, et al. Phusical structure and combustion properties of super fine pulverized coal paitical. Fuel,2002,81(5):691-698
42.刘转年,周安宁,金奇庭.超细煤粉吸附苯胺机理研究.燃烧化学学报,2006,24(1)：20-24
43.杨健,章非娟,余志荣.有机工业废水处理理论与技术.北京：化学工业出版社,2005：1-36
44.2011年中国环境状况公报.
45. Few son, C. A. Biodegradation of xenobiotic and other persistent compound:the causes of recalcitrance. Trends Biotech.1998,6,148-153
46.丁真真.难降解有机物废水的处理方法研究现状.2006,22(2)：113-115
47.于建伟.有毒难降解有机物—硝墓盼的厌氧生物降解性和毒性研究.青岛：中国海洋大学,2004：34
48. 国家环境保护局科技处纺织工业部生产司.我国集中工业废水治理技术研究—第二分册—纺织印染废水.北京：化学工业出版社,1988：2
49.王侃,陈英旭,叶芬霞.SiO2负载的TiO2光催化剂可见光催化降解染料污染物.催化学报,2004,25(12)：931-936
50. Judd S, Jefferson B.膜技术也工业废水回用.蔡邦肖译.北京：化学工业出版社,2006：108-113
51.奚旦立,陈季华,马春燕.印染废水处理现状及存在问题.全国纺织印染废水深度处理及回用和污水达标排放学术研讨会,2005
52.国家环境保护总局,国家统计局.2004中国绿色国民经济核算研究报告.环境保护,2006,(18)：22-29
53.王世和,吴惠芳,晏再生.印染废水的多格室水解—膜生物法处理技术.北京：科学出版社,2011：1-5
54.梁佳,曹明明.印染废水特点及其处理技术.地下水,2011,33(2)：67-69
55.张林生.印染废水处理技术及典型工程.北京：化学工程出版社,2005：20-22
56. Ghoreishi S.M., Haghighi R. Chemical catalytic reaction and biological oxidation for treatment of non-biodegradable textile effluent. Chemistry Engineering of Journal,2003,95:163-169
57.李家珍.染料、染色工业废水处理.北京：化学工业出版社,1997
58. Rozzi A, Ficara E, Cellamare C.M. et al. Characterization of textile wastewater and other industrial wastewater by respirometric and titration biosensors. Water Science Technology,1999,40(1):161-168
59. Gulays H. Process for the removal of recalcitrant organics from industrial wastewater. Water Science Technology,1997,36(2-3):9-16
60. Stolz A. Basic and applied aspects in the microbial degradation of azo dyes. Applied Microbielogical Biotechnology,2001,56:69-80
61. Pereira M.F.R., Soares S.F., Orfao J.J.M., et al. Adsorption of dyes on activated carbons:influence of surface chemical groups. Carbon,41:811-821
62. Esther F., Tibor C., Gyula O. et al. Removal of synthetic dyes from wastewater:a review. Environment International,2004,30:953-971
63. Kunz A., Mansilla H., Duran N. A degradation and toxicity study of three textile tractive dyes by ozone. Environmental Technology,2002,23:911-918
64. Chang J S, Chou C, Lin Y C, et al. Kinetic characteristics of bacterial azo-dye decolorization by pseudomonas luteola. Water Research,1002,35(21):2841-2850
65.刘颖.染料废水的可生化性及其处理工艺研究.山东：中国海洋大学,2005：6
66. Buitron G., Quezada M., Moreno G. Aevobic degradation of zhe azo dye acid red 151 in a sequencing batch biofilter. Bioresource Technology,2004,92:143-149
67. Anjaneyulu Y, Chary N S, Raj D S S. Decolourization of industrial effluents-available meth-ods and emerging technologies-a review. Reviews in Environmental Science and Biotechnoogy,2005,4:25-273
68. Simone P, Giorgio R, Fabio F, et al. Comparision of different pilot scale bioreactors for the treatment of a real wastewater from the textile industry. International Biodeterioration and Biodegradation,2011,65(3):396-403
69. Cenek N, Bhavin R, Manish B, et al. Capacity of Irpex lacteus and pleurotus ostreatus for decolorization of chemically different dyes. Journal of Biotechnology,2001,89:113-122
70. Gottlieb A, Shaw C, Smith A, et al. The toxicity of textile reactive azo dyes after hydrolysis and decolourization. Journal of Biotechnology,2003,101:49-56
71. Nachiyar C V, Rajakumar G S. Purification and characterization of an oxtgen insensitive azoreductase from pseufomonas aeruginosa. Enzyme and Micobial Technology,2005,36(4):503-509
72.李慧荣.白腐真菌对染料的脱色降解及应用前景.染料与染色,2002,6：
73. A Conneely, W F Smyth, G M Mullan. Study of the white-rot fungal degradation of selected phthalocyanine dyes by capillary electrophoresis and liquid chaomatography. Analitica Chimica Acta,2002,431(2):359-270
74.丁华,金若菲,周集体.基因工程菌在厌氧膜生物反应器中对偶氮染料废水的脱色.环境工程学报,2007,1(3)：25-29
75. Zheng Z., Sheth U., Nadig M., et al. A model for the role of the proline-linked petose phosphate pathway in polymeric dye-tolrance in oregano. Process Biochemistry,2001,36:941-946
76. Georgiou D, Aivasidis A. Decolorization of textile wastewater by means of a fluidized-bed loop reactor and immobilized anaerobic bacteria.Journal of Hazardous Materials,2006,135:372-373
77.刘海成,常张红,王现丽,等.水解酸化/生物接触氧化工艺处理印染废水应用实例.工业水处理,2010,30(10)：84-85
78. Wang X J, Gu X Y, Lin D X, et al. Treatment of acid rose dye containing wastewater by ozoning-biological aerated filter.Dye and Pigments,2007,74:736-740
79.顾晓扬,汪晓军,林德贤Fenton试剂—曝气生物滤池处理酸性玫瑰红印染废水.工业水处理,2006,26(11)：28-31
80.吴志敏,韦朝海,吴超飞.H2O2湿式氧化法处理含酸性红B染料模拟废水的研究.环境科学学报,2004,24 (5)：809-814
81. Neyens E, Baeyens J. A review of classic fenton's peroxidation as an advanced oxidation technique. Journal of Hazardous Materials,2003,98:33-50
82.李宏.Fenton高级氧化技术氧化降解多环芳烃类染料废水的研究.重庆：重庆大学,2007：17-18
83. Erdal K., Osman G., Sibel I., et al. Comparision of several advanced oxidation peocesses for the decolorization of Rezctive Red 120 azo dye in aqueous solution. Journal of Hazardous Materials, 2004,109:85-93
84. Kacar Y, Alpay E, Ceylan V K. Pretreatment of afyon alcaloide factory's wastewater by wet air oxidation. Water Research,2003,37(5):1170-1176
85.刘春明,董秀琴,张敏华.超临界水氧化技术处理工业废水的研究进展.化工进展,2011,30(8)：1841-1848
86. Prikopsky K, wellig B, Rudolf V R P. SC WO of salt containing artificial wastewater using a transpiring wall reactor. Journal of Supercritical Fluids,2007,40(2):246-257
87.常青.水处理絮凝学(第二版).北京：化学工业出版社,2011：1-5
88.何珍宝.印染废水特点及处理技术.印染,2007,17：41-44
89.杨爱丽.负载型光催化降解有机废水的研究进展.工业水处理,2003,23(3)：1-4
90. Bhattachhryya A., Kawi S., Ray M. B. Photocatalytic degradation of orange Ⅱ by TiO2 catalysis supported on adsorbents. Catalysis Today,2004,98:431-439
91. Lin Sheng H, Peng Chi F. Treatment of textile wastewater by electrochemical method. Water Research, 1994,28(2):277-282
92.王禹.吸附与电化学氧化联合处理染料废水的实验研究.吉林：吉林大学,2011
93. Naomi L. Stock,Julie Peller, K Vinodgopal., et al. Environmental Science and Technology, 2000,34(9):1747-1750
94.祁梦兰,杜静,郭晓红.声化学氧化—SBR法处理染料废水.河北科技大学学报(自然科学版),1997,18(1)：76-80
95.苑宝玲,王洪杰.水处理新技术原理与应用.北京：化学工业出版社,2006：73-83
96. Dajka K., Tskacs E., Solpan D., et al. High-energy irradiation treatment of aqueous solutions of C I Reactive Black 5 azo dye:pluse radiolysis experiments. Radiation Physics and Chemistry,2003,37:535-538
97.林琪,秦炜,黄少凯,等.溶剂萃取法处理苯酚稀溶液及其废水的研究.高校化学工程学报,2003,17(3)：261-265
98.冯旭东.萃取技术在难降解有机废水处理中的应用.北京工商大学学报(自然科学版),2003,21(4)：7-9
99.蒋晓芸,陈松,李国兵.萃取法处理高含量含苯胺废水.化学工业与工程,2008,25(3)：248-250
100.罗学辉,秦炜,符钰,等.络合萃取法处理磺酸类染料中间体工业废水的研究.化学工程,2003,31(2)：51-54
101.李长平,辛宝平,徐文国,等.疏水性离子液体萃取脱色水溶性染料实验研究.北京理工大学学报,2006,26(7)：647-650
102. Ying T. Y, Yiacoumi S, Tsouris C. High-gradient magnetically seeded filtration. Chemical Engineering Science,2000,55(6):110-1113
103.韩虹,陈文松,韦朝海.印染废水处理的磁混凝-高梯度磁分离协同作用.环境工程学报,2007,1(1)：64-68
104.邹卫华,白红娟,李苛,等.天然沸石对阳离子染料中性红的吸附及机理研究.郑州大学学报(理学版), 2011,43(4)：71-76
105.栗印环,张秀兰,邵东圆,等.阴-阳离子改性沸石处理染料废水.信仰师范学院学报(自然科学版),2011,24(1)：127-130
106. Juang L.C., Wang C. C., Lee C.K.Adsorption of basic dyes onto MCM41. Chemosphere,2006,64:1962-1928
107.罗友元,陈杰瑢,蒲思川等.碱性阴离子交换纤维处理印染废水的研究.环境科学与技术,2010,33(6)：138-141
108. Yang Z. Experimental investigation of waste water treatment using a hollow fiber membrane bioreactor. China-Japan international symposium on membrane hybrid system applied to water treating process, Tianjing, China,1999
109. Mahewsja-Niwak K, Wisniewski J, Winnicki T. New rod-type membranes made of various polymeis for organic dye separation. Environmental Science Design,1991,42:653-663
110.彭党聪.水污染控制工程(第三版).北京：冶金工业出版社,2010：227
111. Valderrama C, Gamisans X, HerasX, Farran A Cortina J L. Sorption kinetics of polycyelie aromatic hydrocarbons removal using granular activated carbon. Jounal of Harzardous Materials.2008, 157(2-3):386-39
112. Moreno-Castilla C. Adsorption of organic molecules from aqueous solutions on carbon materials[J]. Carbon, 2009,42 (1):83-94
113.张双全.国内外活性炭市场及新产品开发.中国煤炭,1997,23(2)：26-29.
114.袁晓红,姚源.活性炭吸附剂的孔结构表征.中国粉体技术,2000,6：190-191
115. K. S. Kim and H. C. Choi. Characteristics of adsorption of rice-hull activated car-bon. Wai. Res.,1998,38 (4-5):95-101.
116. Nagarethinam Kannan, Mariappan Meenakshi Sundaram. Kinetics and mechanism ofremoval of methylene blue adsorption on various carbons a comparative study. Dyes and2001,51:25-40.
117. Santhy K, Selvapathy P. Removal of reactive dyes from wastewater by adsorption on coirpith activated carbon. Bioresource Technology,2006,96:1329-1336
118.崔永君,颜振明,不同变质程度无烟煤制活性炭的研究.山西矿业学院学报.1997,15(2)：194-197.
119. Jose J. Pis, Manuel Mahamud, Jose B. Parra, Jesus A. Pajares, Roop C. Bansal.reparation of activated carbons from coal Part Ⅱ Carbonisation of oxidized coal. Fu-Proc. Technol,1997,50:249-260.
120. J. J. Pis, M. Mahamud, J. A. Pajares, J. B. Parra, R. C. Bansal. Prepara-of activated carbons from coal Part rn Activation of char. Fuel. Proc. Technol.1998,57:149-161.
121. Yahya S, Musa I, Amiad H, et al. Effect of solution pH ionic strength and temperature on adsorption behaviour of reactive dyes on avtiveted carbon. Dyes and Pigments,2008,77(1):16
122.张建英,梁缘东.染色废水吸附混凝效应研究.环境污染与防治,1998,20(3)：9
123. Doulia D, Leodopou los C, G im ouhopou los K, et a.1 Adsorption of hum ic acid on acid activated G reek bentonite[J]. Journal of Co Ho id and Interface Science,2009,340(2):131-141.
124. Zohra B, A icha K, Fa tim a S, et a.l Adsorption of Direct Red on bentonite modified by cetyltrimethy lammonium bromide[J]. Chem ical Eng ineering Journal,2008,136(2-3):295-305.
125. Eren E, A fsin B. Investigation of a basic dye adsorption from aqueous solution onto raw and pretreated bentonite surfaces[J]. Dyes and Pigments 2010,76 (1) 220-225.
126.高廷耀,范瑾初,向阳.蒙脱土和海泡石对水中苯、甲苯和乙苯的吸附研究.同济大学学报(自然科学版),1993,21(2)：139-144.
127. Gurses A, Dogar C, Yalcin M, et al.The adsorption kinetics of the cationicdye, methylene blue on clay. Journal of Hazardous Materials B,2006(131):217-228
128.任建敏,张永民,吴四维,等.纳基膨润土吸附亚甲基蓝的热力学与动力学研究.离子交换与吸附,2010,26(2)：179-186
129. O.R. Pal, A.K.Vanjara. Removal of malathion and butachlor rom aqueous solution by clays and organoclays. Separation and Purification Thchnology,2001,24:167-172
130. Saeid Gitipour, Mark T.130wers, Warren Huff and Andrew Bodocsi. The efficiency modified bentonite clays for removal of aromatic organics from oily liquid wastes.Spill Science and Terechnology Bulletin, 1997,7,4 (3):155-164.
131.于漧,包亚芳.硅藻土在污水处理中的应用.中国矿业,2002,,11(2)：33-36
132.裘祖楠,翁行尚,李勇,等.活化凹凸棒石对阳离子染料的脱色作用以及应用研究.中国环境科学,1999,17(4)：373-376
133.陈天虎,凌丽华.凹凸棒黏土处理印染废水研究.环境污染与防治,1995,17(1)：24-26
134.彭书传,王诗生,陈天虎,等.坡缕石对水中亚甲基蓝的吸附动力学.硅酸盐学报,2006,34(6)：733-738
135. P. H. Chen. Adsorption of Organic Compounds in Water Using a Synthetic Adsorbent. Environment International.1997,23(1):63-73
136.田文华,李培元.有机物在大孔吸附树脂上的竞争吸附.水处理技术,1994,20(5)：254-258
137.邹敏.大孔树脂吸附法处理甲苯硝化废水的研究.江苏环境科技,1999,12(3)：7-8
138.张全兴,王勇.树脂吸附法处理硝基苯和小几率本生产废水的研究.化工环保,1997,(6)：323-326
139. Ruey-Shin Juang, Jia-Yun Shian. Adsorption isotherms of phenols from water onto maceoreticular resins. Journal of Hazardous Materials,1999,B70:171-178
140. Gulay B, Begum A, Arica M Y. Adsorptionkinetics and therm-odynamic parameters of cationic dyes from aqueous solutions by using a new strong cation-exchange resin [J]. Chemical Engi-neering Journal, 2009,152(2-3):339-346.
141. Alyu2 B, Veli S. Kinetics and equilibrium studies for the rem-oval of nickel and zinc from aqueous solutions by ion exchange resins [J]. Journal of Hazard Materials,2009,167(1-3):482-488
142. Dogan M, Abak H, Alkan M. Adsorption of methylene blue onto hazelnut shell:Kinetics, mechanism and activation parameters [J]. Journal of Hazardous Materialsls,2009,164(1):172-181.
143.李志平,欧阳玉祝,麻成金,等.打孔树脂吸附法处理印染废水的研究.广西民族学院学报,2005,11(2)：95-97
144.袁勋,柳玉英,蕉淑萍,等.有序介孔炭的合成及液相有机大分子吸附性能研究.化学学报,2007,65(17)：1848-1820
145.陈永.多孔材料制备与表征.合肥：中国科技大学出版社,2010：20-50
146. Park D.-H., Nishiyama N., Egashira Y., et al. Separation of organic/water mixtures with silylated MCM-48 silica membranes[J]. icroporous and Mesoporous Materials,2003,66 (1):69-70
147. Zhao X.S., Lu G.Q. Modification of MCM-41 by surface ilylation with trimethylchlorosilane and adsorption study[J]. Journal of Physical Chemistry B,1998,102 (9):1556-1561
148.付新.有序介孔材料的合成及应用研究进展.化学与生物工程,2012,29(8)：7-10
149.魏诗辉,何艳,李风亭,等.功能化介孔材料SBA-16对水中碱性橙染料的去除.环境科学,2010,31(6)：1537-1541
150.施胜华.介孔材料的超支化改性及其对偶氮染料的吸附性能研究.上海：东华大学,2011
151. G. Balasubramanian, D. D Dionysiou, M. T Suidan, I. Baudin, J. La ne,Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation oforganic contaminants in water, Appl. Catal. B:Environ.47 (2004) 73-84.
152. L. Huang, C. Sun, Y. Liu, Pt/N-codoped TiO2 nanotubes and its photocatalytic activity under visible light, Appl. Surf. Sci.253(2007) 7029-7035.
153.何春东,朱雪强,刘汉湖,等.活性氧化铝吸附水中四氯化碳的实验研究.环境科技,2012,25(4)：14-18
154. C. Namasivayam, D.J.S.E.Arasi, Removal of congo red from wastewater by adsorption onto waste red mud, Chemosphere,34(2),1997,401-417.
155.李方文.赤泥质多孔陶瓷滤料表面改性及其在水处理中的应用研究.武汉：武汉理工大学,2008：20-77
156. Akgerman A., Zardkoohi M. Adsorption of Phenolic Compounds on Fly Ash[J]. Journal of Chemical & Engineering Data,1996,41 (2):185-187
157. Wang S, Wu H. Environmental-benign utilisation of fly ash as low-cost adsorbents. Journal of Hazardous Materials,2006,136(3):482-501
158. Shaobin Wang, Lin Li, Z. H. Zhu. Solid-state conversion of fly ash to effective ad-Jrbents for Cu removal from wastewater. Journal of Hazardous Materials,2007139):254-259.
159. Srivastava V C, Mall I D, Mishra I M, et al. Equilibrium modelling of ternary adsorption of metal tons onto rice hush ash. Journal of Chemical Engineering Data,2009,54(3):705-711
160. Han R P, Han P, Cai Z H, et al. Kinetics and isotherms of neutral red adsorption on peanuthusk. Journal of Environment Science,2008,20(9):1035-1041
161. Nasuha N., Hameed B.H., Din A.T.M. Rejected tea as a potential low-cost adsorbent for the removal of methylene blue[J]. Journal of Hazardous Materials,2010,175 (1-3):126-132
162. Memon G.Z., Bhanger M.I., Akhtar M., et al. Adsorption of methyl parathion pesticide from water using watermelon peels as a low cost adsorbent[J]. Chemical Engineering Journal,2008,138 (1-3):616-621
163. Mane V S, Mall D I, Srivastava C V. Kinetic and equilibrium isotherm studies for the adsorptive removal of Brilliant Green dye from aqueous solution by rich hush ash. Journal of Environment Management, 2007,84(4):390-396
164. Rajeshwarisivaraj, Namasibayam C. Kadirvelu K. Orange peel as an adsorbent in the removal of acid violet 17(acid dye) from aqueous solutions. Waste Mange,2001,21:105-110
165. Purkait M K, Gusain D S, Das Gupta S. Adsorption behaviour of chrysoidine dye on avtivated charcoal and its regeneration characteristics by using different surfactants. Seperation Science Technology, 2004,39(5):2419-2440
166. Jiang Xiumin, Zheng Chugang, Yan Che, et al. Physical structure and combustion properties of super fine pulverized coal particle. Fuel,2002,81:793-797.
167.廖传华,史勇春,鲍金刚,燃烧过程与设备.北京：中国石化出版社,2008：270-278
168.王亚超.锅炉分册.北京：中国电力出版社,2010：123-135
169. Mamleev V, Bourbigot S, Bras M Le, et al. Modelling of nonisothermal kinetics in the mogravimetry. Chemistry Physical,2002,2:47084716
170.戴和武,谢可玉.北京：煤炭工业出版社,1998：299-350
171.胡荣祖,史居祯.热分析动力学.北京：科学出版社,2001
172.叶振兴.煤的低温氧化实验及对模拟试验数值模拟研究.合肥：安徽理工大学,2005
173. Ortega,A. The kinetics of solid-state reactions toward consensus-part 2:fitting kinetics data in dynamic convention on althermal analysis. International Journal of Chemitry kinetics.2002,34:193-208
174. Opfermann J. Kinetic analysis using multivariable non-linenar regression. Thermal Analysis Coal. 2000,60:641-658
175.何启林,王德明.煤的氧化和热解反应的动力学研究.北京科技大学学报,2006,28(1)：1-5
176.舒新前,王祖纳.神府煤煤岩组分的结构特性及其差异.燃烧化学学报,1996,24(5)：426-429
177.陶建红.褐煤中含氧官能团的测定与研究.河南化工,2010,27(4)：8-10
178.叶振兴.煤的低温氧化实验及对模拟实验数值模拟研究.合肥：安徽理工大学,2005,15-25
179.李少章,朱书全.煤的表面疏水性与其组成之间的关系,洁净煤技术,2004,10(3)：15-18
180.张恒.褐煤提质改性工艺中含氧官能团的研究.北京：中国矿业大学(北京),2006：47-55
181.村田逞诠著,朱春笙,龚祯祥译.煤的润湿研究及应用.北京：煤炭工业出版社,1992
182. Woskoboenko F, Stacy W O, Raisbeck D. Chapter 4 in The Science of Victorian Brown coal(Ed:R.A.Durie), Butterworth-Heinemanm.Oxford,1991
183.何余生,李忠,奚红霞,等.气固吸附等温线的研究进展.离子交换与吸附,2004,20(4)：376-384
184.姚超,刘敏,李为民,等.凹凸棒石/氧化锌纳米复合材料对亚甲基蓝的吸附性能.环境科学学报,2010,30(6)：1211-1219
18S. Khattri S D. Colour removal from dye wastewater using sugar calc as an adsorbent. Adsorption Science Technology,1999,(4):269-282
186.潘竟军,陈光明,韩布兴,等.亚甲基蓝在纳、铝和铁蒙脱土上的吸附研究.油田化学,1999,16(3)：195-197
187. T.Mathialagan, T Viraraghavan. Adsorption of cadmium from aqueous solution by perlite. Journal of Hazardous Materials,2002,B94:291-303
188. M.Otero, F. Rozada, L F Calvo, et al. Kinetic and equilibrium modelling of the mithylene blue removal from solution by adsorbent materials produced from sewage sludges. Biochemical Engineering Journal,2003,15(1): 59-68
189. Jili Zhang, Liping Liang, Lijun Pu, et al. Adsorption Characteristics of Cr(VI) by Wheat Straw Including Kinetic and Thermodynamics Analysis[J]. Research of Environmental Sciences,2010,23(12):1546-1552.
190.马伟.固水界面化学与吸附技术.北京：冶金工业出版社,2011,160-165
191. Weber W J, Morris J C. Proceeding of internationsl conference on water pollution symposium. Oford: Perganmo Press,1962:231
192.任建敏,张永民,吴四维,等.纳基膨润土吸附亚甲基蓝的热力学与动力学研究.离子交换与吸附,2010,26(2)：179-186
193. Tingchu Hsu, Chuangchin Yu,吃奶名Yeh.Adsorption of Cu from water using raw and modified coal fly ashes. Fuel,2008,87(7):1355-1359
194.刘福强,陈金龙,费正皓,等.复合功能超高交联吸附树脂对氨基萘酚磺酸的静态吸附热力学及动力学. 应用化学,2003,20(12)：1123-1128.
195.解建坤,岳钦艳,于慧,等.污泥活性炭对活性艳红K-2BP染料的吸附特性研究.山东大学学报(理学版),2007,42(3)：64-70.
196.孙体昌.固液分离.湖南：中南大学出版社,2011：1-5
197.钟润生.颗粒表面有机物吸附对混凝和沉淀影响的研究.北京：清华大学,2009,40-60
198.常青.水处理絮凝学.北京：化学工业出版社,2011：221-227
199.宿凯.高浊度矿井水的混凝处理研究.北京：中国矿业大学(北京),2008：25-30
200.马青山,贾瑟.絮凝化学和絮凝剂.北京：中国环境科学出版社,1988：10-89
201.任俊,沈健,卢寿慈.颗粒分散科学与技术.北京：化学工业出版社,2005：66-107
202.郭玲香,欧泽深,胡明星.煤泥水悬浮液体系中EDLVO理论及应用.中国矿业,1999,8(6)：69-72
203.卢寿慈.粉体技术手册.北京：化学工业出版社,2004
204.王凯,虞军.搅拌设备.北京：化学工业出版社,2006：12-45
205.永田进治著,马继舜译.混合原理与应用.北京：化学工业出版社,1984
206.崔玉川,员建,陈宏平.给水厂处理设施设计计算.北京：化学工业出版社,2003：68
2. 毛节华,许惠龙.中国煤炭资源预测与评价.北京：科学出版社,1999：3-22
3. 陈文敏.煤质分级结果的定性与定量审查.北京：煤炭工业出版社,1994
4. Allardice DJ, Young BC. Proceeding of the eighteenth annual international Pittsburgh conference. Newcastle, Australia,3-7 December,2001
5. 李好管.煤化工技术进展及产业现状分析.煤化工,2009(3)：1-6
6. 李春柱,余江龙,常丽萍,等.维多利亚褐煤科学进展.北京：化学工业出版社,2009：76-92
7. 黄建湘,李明,袁翠翠,刘少芳.褐煤煤化工利用现状及前景[J].广州化工,2011,39：35-36
8. 周夏.褐煤气化技术评述.煤化工,2009,(6)：1-4
9. Moreea-Taha R. In:modelling and simulation for coal gasfication.CCC/42, London:IEA Coal Research,2000
10. Miura K. Fuel Processing Technology,2009,62:119
11.王路宁.褐煤低温热解特性实验研究及理论分析.北京：中国矿业大学(北京)：2009：5-15
12.赵振新,朱书全,马名杰等.中国褐煤的综合优化利用.洁净煤技术,2008,14(1)：28-31
13. 马艳梅,纪龙,赵宏宇,等.褐煤制浆和配煤制浆技术.清洁煤技术,2012,18(4)：49-51
14.赵振新,朱书全,马名杰,等.中国褐煤的综合优化利用.洁净煤技术,2008,14(1)：28-31
15.张意颖,张文辉.煤基活性炭对原料煤的适应性.煤,2000,2,27-28
16.徐革联,刘伟.褐煤改质制备炭分子筛的研究.洁净煤技术,2006,12(2):89-91
17. 董洪峰,云增杰,曹勇飞.我国褐煤的综合利用途径及前景展望.煤炭技术,2008,27(9)：122-124
18.陈慧,陶秀祥,石开义,等.褐煤生物转化及其研究进展.清洁煤技术,2008,14(5)：39-42
19. 朱学栋,朱子彬,韩崇家等.煤中含氧官能团的红外光谱定量分析[J].燃料化学学报,1999,(27),(4)：335-339.
20. Yao Z S, Wei X Y, Lv J, Liu F J, et al. Oxidation of Shenfu coal with RuO4 and NaOCl. Energy and Fuels, 2010,24(3):1801-1808
21.刘转年.煤基超细复合剂的制备及吸附性能研究.西安：西安建筑科技大学,2004:16-30
22.晋云玲,杨阿三,孙勤,等.褐煤氧化氨解过程中腐植酸挂能团含量的研究.高校化学工程学报,2010,24(3)：446--450
23.罗道成,刘俊峰,李忠远.用磺化褐煤处理含铬废水的研究.煤化工,2010,(2)：36-39
24.朱红,王淀佐,李虎林,欧泽深.电化学法对细粒煤表面改性机理的研究.煤炭学报,200,25(3)：307-311
25. 刘加龙.褐煤电化学氧化的新方法.腐植酸,2001,(11)：9-11
26. GothatyML, Prominenifroniiersofeoalscience:Past. Preseniandfuture, Fuel.1994,3(12):1819-1828
27.侯爽.煤分子活性基团低温氧化过程研究.西安科技大学,2007
28. Fanor Mondragon, Wilson Ruiz, Alexander Santamaria. Effect of early stages of coal oxidation on its reaction with elemental sulphur.Fuel,2002, (81):381-388.
29.朱学栋,朱子彬,韩崇家等.煤中含氧官能团的红外光谱定量分析.燃料化学学报,1999,(27),(4)：335-339.
30.石必明.易自燃煤低温氧化和阻化的微观结构分析.煤炭学报,2000,(25),(3)：294-298.
31.刘伟军,陈拴柱,张书华,曾红.煤粉电晕荷电特性的多因素实验研究.煤炭转化,2010,33(4)：5-8
32.陈丕亚,黄瀛华,高杰,等.这赉诺尔褐煤在液相中吸附特性的研究—扎赉诺尔褐煤及其炭化物对酚的研究.燃烧化学学报,1987,15(4)：343-348
33.陈丕亚,杨凤莲,胡慕中,等.扎赉诺尔褐煤在液相中吸附特性的研究—吸附阳离子染料的特性.燃烧化学学报,1986,14(2)：171-176
34.赵勤荣.褐煤吸附法治理二硝基废水.化工环保,1988,8(4)：201-209
35.丁德润,顾健民.褐煤对碱性染料吸附的研究.化学世界,1994,(6)：322-325
36. S.J.Allen, G.Mckay, K.Y.H. Khader. Environmental Pollution,1989,(56):39-44
37.郭喜亮.褐煤对含染料废水的吸附与絮凝作用研究.辽宁,辽宁工程技术大学,2009：10-45
38.许端平,储海燕,徐雪松.褐煤对废水中酸性红B的吸附去除.环境工程学报,2012,6(6)：1961-1965
39.邓昌亮,徐海宁.褐煤处理含酚废水的研究.山东师大学报(自然科学版),1997,12(3)：350-353
40. Tarasevich Y I. Porous structure and adsorption properties of natural porous coal. Colloids Surfance.2001,176(2-3):267-272
41. Jiang X, Zheng C,Yan C, et al. Phusical structure and combustion properties of super fine pulverized coal paitical. Fuel,2002,81(5):691-698
42.刘转年,周安宁,金奇庭.超细煤粉吸附苯胺机理研究.燃烧化学学报,2006,24(1)：20-24
43.杨健,章非娟,余志荣.有机工业废水处理理论与技术.北京：化学工业出版社,2005：1-36
44.2011年中国环境状况公报.
45. Few son, C. A. Biodegradation of xenobiotic and other persistent compound:the causes of recalcitrance. Trends Biotech.1998,6,148-153
46.丁真真.难降解有机物废水的处理方法研究现状.2006,22(2)：113-115
47.于建伟.有毒难降解有机物—硝墓盼的厌氧生物降解性和毒性研究.青岛：中国海洋大学,2004：34
48. 国家环境保护局科技处纺织工业部生产司.我国集中工业废水治理技术研究—第二分册—纺织印染废水.北京：化学工业出版社,1988：2
49.王侃,陈英旭,叶芬霞.SiO2负载的TiO2光催化剂可见光催化降解染料污染物.催化学报,2004,25(12)：931-936
50. Judd S, Jefferson B.膜技术也工业废水回用.蔡邦肖译.北京：化学工业出版社,2006：108-113
51.奚旦立,陈季华,马春燕.印染废水处理现状及存在问题.全国纺织印染废水深度处理及回用和污水达标排放学术研讨会,2005
52.国家环境保护总局,国家统计局.2004中国绿色国民经济核算研究报告.环境保护,2006,(18)：22-29
53.王世和,吴惠芳,晏再生.印染废水的多格室水解—膜生物法处理技术.北京：科学出版社,2011：1-5
54.梁佳,曹明明.印染废水特点及其处理技术.地下水,2011,33(2)：67-69
55.张林生.印染废水处理技术及典型工程.北京：化学工程出版社,2005：20-22
56. Ghoreishi S.M., Haghighi R. Chemical catalytic reaction and biological oxidation for treatment of non-biodegradable textile effluent. Chemistry Engineering of Journal,2003,95:163-169
57.李家珍.染料、染色工业废水处理.北京：化学工业出版社,1997
58. Rozzi A, Ficara E, Cellamare C.M. et al. Characterization of textile wastewater and other industrial wastewater by respirometric and titration biosensors. Water Science Technology,1999,40(1):161-168
59. Gulays H. Process for the removal of recalcitrant organics from industrial wastewater. Water Science Technology,1997,36(2-3):9-16
60. Stolz A. Basic and applied aspects in the microbial degradation of azo dyes. Applied Microbielogical Biotechnology,2001,56:69-80
61. Pereira M.F.R., Soares S.F., Orfao J.J.M., et al. Adsorption of dyes on activated carbons:influence of surface chemical groups. Carbon,41:811-821
62. Esther F., Tibor C., Gyula O. et al. Removal of synthetic dyes from wastewater:a review. Environment International,2004,30:953-971
63. Kunz A., Mansilla H., Duran N. A degradation and toxicity study of three textile tractive dyes by ozone. Environmental Technology,2002,23:911-918
64. Chang J S, Chou C, Lin Y C, et al. Kinetic characteristics of bacterial azo-dye decolorization by pseudomonas luteola. Water Research,1002,35(21):2841-2850
65.刘颖.染料废水的可生化性及其处理工艺研究.山东：中国海洋大学,2005：6
66. Buitron G., Quezada M., Moreno G. Aevobic degradation of zhe azo dye acid red 151 in a sequencing batch biofilter. Bioresource Technology,2004,92:143-149
67. Anjaneyulu Y, Chary N S, Raj D S S. Decolourization of industrial effluents-available meth-ods and emerging technologies-a review. Reviews in Environmental Science and Biotechnoogy,2005,4:25-273
68. Simone P, Giorgio R, Fabio F, et al. Comparision of different pilot scale bioreactors for the treatment of a real wastewater from the textile industry. International Biodeterioration and Biodegradation,2011,65(3):396-403
69. Cenek N, Bhavin R, Manish B, et al. Capacity of Irpex lacteus and pleurotus ostreatus for decolorization of chemically different dyes. Journal of Biotechnology,2001,89:113-122
70. Gottlieb A, Shaw C, Smith A, et al. The toxicity of textile reactive azo dyes after hydrolysis and decolourization. Journal of Biotechnology,2003,101:49-56
71. Nachiyar C V, Rajakumar G S. Purification and characterization of an oxtgen insensitive azoreductase from pseufomonas aeruginosa. Enzyme and Micobial Technology,2005,36(4):503-509
72.李慧荣.白腐真菌对染料的脱色降解及应用前景.染料与染色,2002,6：
73. A Conneely, W F Smyth, G M Mullan. Study of the white-rot fungal degradation of selected phthalocyanine dyes by capillary electrophoresis and liquid chaomatography. Analitica Chimica Acta,2002,431(2):359-270
74.丁华,金若菲,周集体.基因工程菌在厌氧膜生物反应器中对偶氮染料废水的脱色.环境工程学报,2007,1(3)：25-29
75. Zheng Z., Sheth U., Nadig M., et al. A model for the role of the proline-linked petose phosphate pathway in polymeric dye-tolrance in oregano. Process Biochemistry,2001,36:941-946
76. Georgiou D, Aivasidis A. Decolorization of textile wastewater by means of a fluidized-bed loop reactor and immobilized anaerobic bacteria.Journal of Hazardous Materials,2006,135:372-373
77.刘海成,常张红,王现丽,等.水解酸化/生物接触氧化工艺处理印染废水应用实例.工业水处理,2010,30(10)：84-85
78. Wang X J, Gu X Y, Lin D X, et al. Treatment of acid rose dye containing wastewater by ozoning-biological aerated filter.Dye and Pigments,2007,74:736-740
79.顾晓扬,汪晓军,林德贤Fenton试剂—曝气生物滤池处理酸性玫瑰红印染废水.工业水处理,2006,26(11)：28-31
80.吴志敏,韦朝海,吴超飞.H2O2湿式氧化法处理含酸性红B染料模拟废水的研究.环境科学学报,2004,24 (5)：809-814
81. Neyens E, Baeyens J. A review of classic fenton's peroxidation as an advanced oxidation technique. Journal of Hazardous Materials,2003,98:33-50
82.李宏.Fenton高级氧化技术氧化降解多环芳烃类染料废水的研究.重庆：重庆大学,2007：17-18
83. Erdal K., Osman G., Sibel I., et al. Comparision of several advanced oxidation peocesses for the decolorization of Rezctive Red 120 azo dye in aqueous solution. Journal of Hazardous Materials, 2004,109:85-93
84. Kacar Y, Alpay E, Ceylan V K. Pretreatment of afyon alcaloide factory's wastewater by wet air oxidation. Water Research,2003,37(5):1170-1176
85.刘春明,董秀琴,张敏华.超临界水氧化技术处理工业废水的研究进展.化工进展,2011,30(8)：1841-1848
86. Prikopsky K, wellig B, Rudolf V R P. SC WO of salt containing artificial wastewater using a transpiring wall reactor. Journal of Supercritical Fluids,2007,40(2):246-257
87.常青.水处理絮凝学(第二版).北京：化学工业出版社,2011：1-5
88.何珍宝.印染废水特点及处理技术.印染,2007,17：41-44
89.杨爱丽.负载型光催化降解有机废水的研究进展.工业水处理,2003,23(3)：1-4
90. Bhattachhryya A., Kawi S., Ray M. B. Photocatalytic degradation of orange Ⅱ by TiO2 catalysis supported on adsorbents. Catalysis Today,2004,98:431-439
91. Lin Sheng H, Peng Chi F. Treatment of textile wastewater by electrochemical method. Water Research, 1994,28(2):277-282
92.王禹.吸附与电化学氧化联合处理染料废水的实验研究.吉林：吉林大学,2011
93. Naomi L. Stock,Julie Peller, K Vinodgopal., et al. Environmental Science and Technology, 2000,34(9):1747-1750
94.祁梦兰,杜静,郭晓红.声化学氧化—SBR法处理染料废水.河北科技大学学报(自然科学版),1997,18(1)：76-80
95.苑宝玲,王洪杰.水处理新技术原理与应用.北京：化学工业出版社,2006：73-83
96. Dajka K., Tskacs E., Solpan D., et al. High-energy irradiation treatment of aqueous solutions of C I Reactive Black 5 azo dye:pluse radiolysis experiments. Radiation Physics and Chemistry,2003,37:535-538
97.林琪,秦炜,黄少凯,等.溶剂萃取法处理苯酚稀溶液及其废水的研究.高校化学工程学报,2003,17(3)：261-265
98.冯旭东.萃取技术在难降解有机废水处理中的应用.北京工商大学学报(自然科学版),2003,21(4)：7-9
99.蒋晓芸,陈松,李国兵.萃取法处理高含量含苯胺废水.化学工业与工程,2008,25(3)：248-250
100.罗学辉,秦炜,符钰,等.络合萃取法处理磺酸类染料中间体工业废水的研究.化学工程,2003,31(2)：51-54
101.李长平,辛宝平,徐文国,等.疏水性离子液体萃取脱色水溶性染料实验研究.北京理工大学学报,2006,26(7)：647-650
102. Ying T. Y, Yiacoumi S, Tsouris C. High-gradient magnetically seeded filtration. Chemical Engineering Science,2000,55(6):110-1113
103.韩虹,陈文松,韦朝海.印染废水处理的磁混凝-高梯度磁分离协同作用.环境工程学报,2007,1(1)：64-68
104.邹卫华,白红娟,李苛,等.天然沸石对阳离子染料中性红的吸附及机理研究.郑州大学学报(理学版), 2011,43(4)：71-76
105.栗印环,张秀兰,邵东圆,等.阴-阳离子改性沸石处理染料废水.信仰师范学院学报(自然科学版),2011,24(1)：127-130
106. Juang L.C., Wang C. C., Lee C.K.Adsorption of basic dyes onto MCM41. Chemosphere,2006,64:1962-1928
107.罗友元,陈杰瑢,蒲思川等.碱性阴离子交换纤维处理印染废水的研究.环境科学与技术,2010,33(6)：138-141
108. Yang Z. Experimental investigation of waste water treatment using a hollow fiber membrane bioreactor. China-Japan international symposium on membrane hybrid system applied to water treating process, Tianjing, China,1999
109. Mahewsja-Niwak K, Wisniewski J, Winnicki T. New rod-type membranes made of various polymeis for organic dye separation. Environmental Science Design,1991,42:653-663
110.彭党聪.水污染控制工程(第三版).北京：冶金工业出版社,2010：227
111. Valderrama C, Gamisans X, HerasX, Farran A Cortina J L. Sorption kinetics of polycyelie aromatic hydrocarbons removal using granular activated carbon. Jounal of Harzardous Materials.2008, 157(2-3):386-39
112. Moreno-Castilla C. Adsorption of organic molecules from aqueous solutions on carbon materials[J]. Carbon, 2009,42 (1):83-94
113.张双全.国内外活性炭市场及新产品开发.中国煤炭,1997,23(2)：26-29.
114.袁晓红,姚源.活性炭吸附剂的孔结构表征.中国粉体技术,2000,6：190-191
115. K. S. Kim and H. C. Choi. Characteristics of adsorption of rice-hull activated car-bon. Wai. Res.,1998,38 (4-5):95-101.
116. Nagarethinam Kannan, Mariappan Meenakshi Sundaram. Kinetics and mechanism ofremoval of methylene blue adsorption on various carbons a comparative study. Dyes and2001,51:25-40.
117. Santhy K, Selvapathy P. Removal of reactive dyes from wastewater by adsorption on coirpith activated carbon. Bioresource Technology,2006,96:1329-1336
118.崔永君,颜振明,不同变质程度无烟煤制活性炭的研究.山西矿业学院学报.1997,15(2)：194-197.
119. Jose J. Pis, Manuel Mahamud, Jose B. Parra, Jesus A. Pajares, Roop C. Bansal.reparation of activated carbons from coal Part Ⅱ Carbonisation of oxidized coal. Fu-Proc. Technol,1997,50:249-260.
120. J. J. Pis, M. Mahamud, J. A. Pajares, J. B. Parra, R. C. Bansal. Prepara-of activated carbons from coal Part rn Activation of char. Fuel. Proc. Technol.1998,57:149-161.
121. Yahya S, Musa I, Amiad H, et al. Effect of solution pH ionic strength and temperature on adsorption behaviour of reactive dyes on avtiveted carbon. Dyes and Pigments,2008,77(1):16
122.张建英,梁缘东.染色废水吸附混凝效应研究.环境污染与防治,1998,20(3)：9
123. Doulia D, Leodopou los C, G im ouhopou los K, et a.1 Adsorption of hum ic acid on acid activated G reek bentonite[J]. Journal of Co Ho id and Interface Science,2009,340(2):131-141.
124. Zohra B, A icha K, Fa tim a S, et a.l Adsorption of Direct Red on bentonite modified by cetyltrimethy lammonium bromide[J]. Chem ical Eng ineering Journal,2008,136(2-3):295-305.
125. Eren E, A fsin B. Investigation of a basic dye adsorption from aqueous solution onto raw and pretreated bentonite surfaces[J]. Dyes and Pigments 2010,76 (1) 220-225.
126.高廷耀,范瑾初,向阳.蒙脱土和海泡石对水中苯、甲苯和乙苯的吸附研究.同济大学学报(自然科学版),1993,21(2)：139-144.
127. Gurses A, Dogar C, Yalcin M, et al.The adsorption kinetics of the cationicdye, methylene blue on clay. Journal of Hazardous Materials B,2006(131):217-228
128.任建敏,张永民,吴四维,等.纳基膨润土吸附亚甲基蓝的热力学与动力学研究.离子交换与吸附,2010,26(2)：179-186
129. O.R. Pal, A.K.Vanjara. Removal of malathion and butachlor rom aqueous solution by clays and organoclays. Separation and Purification Thchnology,2001,24:167-172
130. Saeid Gitipour, Mark T.130wers, Warren Huff and Andrew Bodocsi. The efficiency modified bentonite clays for removal of aromatic organics from oily liquid wastes.Spill Science and Terechnology Bulletin, 1997,7,4 (3):155-164.
131.于漧,包亚芳.硅藻土在污水处理中的应用.中国矿业,2002,,11(2)：33-36
132.裘祖楠,翁行尚,李勇,等.活化凹凸棒石对阳离子染料的脱色作用以及应用研究.中国环境科学,1999,17(4)：373-376
133.陈天虎,凌丽华.凹凸棒黏土处理印染废水研究.环境污染与防治,1995,17(1)：24-26
134.彭书传,王诗生,陈天虎,等.坡缕石对水中亚甲基蓝的吸附动力学.硅酸盐学报,2006,34(6)：733-738
135. P. H. Chen. Adsorption of Organic Compounds in Water Using a Synthetic Adsorbent. Environment International.1997,23(1):63-73
136.田文华,李培元.有机物在大孔吸附树脂上的竞争吸附.水处理技术,1994,20(5)：254-258
137.邹敏.大孔树脂吸附法处理甲苯硝化废水的研究.江苏环境科技,1999,12(3)：7-8
138.张全兴,王勇.树脂吸附法处理硝基苯和小几率本生产废水的研究.化工环保,1997,(6)：323-326
139. Ruey-Shin Juang, Jia-Yun Shian. Adsorption isotherms of phenols from water onto maceoreticular resins. Journal of Hazardous Materials,1999,B70:171-178
140. Gulay B, Begum A, Arica M Y. Adsorptionkinetics and therm-odynamic parameters of cationic dyes from aqueous solutions by using a new strong cation-exchange resin [J]. Chemical Engi-neering Journal, 2009,152(2-3):339-346.
141. Alyu2 B, Veli S. Kinetics and equilibrium studies for the rem-oval of nickel and zinc from aqueous solutions by ion exchange resins [J]. Journal of Hazard Materials,2009,167(1-3):482-488
142. Dogan M, Abak H, Alkan M. Adsorption of methylene blue onto hazelnut shell:Kinetics, mechanism and activation parameters [J]. Journal of Hazardous Materialsls,2009,164(1):172-181.
143.李志平,欧阳玉祝,麻成金,等.打孔树脂吸附法处理印染废水的研究.广西民族学院学报,2005,11(2)：95-97
144.袁勋,柳玉英,蕉淑萍,等.有序介孔炭的合成及液相有机大分子吸附性能研究.化学学报,2007,65(17)：1848-1820
145.陈永.多孔材料制备与表征.合肥：中国科技大学出版社,2010：20-50
146. Park D.-H., Nishiyama N., Egashira Y., et al. Separation of organic/water mixtures with silylated MCM-48 silica membranes[J]. icroporous and Mesoporous Materials,2003,66 (1):69-70
147. Zhao X.S., Lu G.Q. Modification of MCM-41 by surface ilylation with trimethylchlorosilane and adsorption study[J]. Journal of Physical Chemistry B,1998,102 (9):1556-1561
148.付新.有序介孔材料的合成及应用研究进展.化学与生物工程,2012,29(8)：7-10
149.魏诗辉,何艳,李风亭,等.功能化介孔材料SBA-16对水中碱性橙染料的去除.环境科学,2010,31(6)：1537-1541
150.施胜华.介孔材料的超支化改性及其对偶氮染料的吸附性能研究.上海：东华大学,2011
151. G. Balasubramanian, D. D Dionysiou, M. T Suidan, I. Baudin, J. La ne,Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation oforganic contaminants in water, Appl. Catal. B:Environ.47 (2004) 73-84.
152. L. Huang, C. Sun, Y. Liu, Pt/N-codoped TiO2 nanotubes and its photocatalytic activity under visible light, Appl. Surf. Sci.253(2007) 7029-7035.
153.何春东,朱雪强,刘汉湖,等.活性氧化铝吸附水中四氯化碳的实验研究.环境科技,2012,25(4)：14-18
154. C. Namasivayam, D.J.S.E.Arasi, Removal of congo red from wastewater by adsorption onto waste red mud, Chemosphere,34(2),1997,401-417.
155.李方文.赤泥质多孔陶瓷滤料表面改性及其在水处理中的应用研究.武汉：武汉理工大学,2008：20-77
156. Akgerman A., Zardkoohi M. Adsorption of Phenolic Compounds on Fly Ash[J]. Journal of Chemical & Engineering Data,1996,41 (2):185-187
157. Wang S, Wu H. Environmental-benign utilisation of fly ash as low-cost adsorbents. Journal of Hazardous Materials,2006,136(3):482-501
158. Shaobin Wang, Lin Li, Z. H. Zhu. Solid-state conversion of fly ash to effective ad-Jrbents for Cu removal from wastewater. Journal of Hazardous Materials,2007139):254-259.
159. Srivastava V C, Mall I D, Mishra I M, et al. Equilibrium modelling of ternary adsorption of metal tons onto rice hush ash. Journal of Chemical Engineering Data,2009,54(3):705-711
160. Han R P, Han P, Cai Z H, et al. Kinetics and isotherms of neutral red adsorption on peanuthusk. Journal of Environment Science,2008,20(9):1035-1041
161. Nasuha N., Hameed B.H., Din A.T.M. Rejected tea as a potential low-cost adsorbent for the removal of methylene blue[J]. Journal of Hazardous Materials,2010,175 (1-3):126-132
162. Memon G.Z., Bhanger M.I., Akhtar M., et al. Adsorption of methyl parathion pesticide from water using watermelon peels as a low cost adsorbent[J]. Chemical Engineering Journal,2008,138 (1-3):616-621
163. Mane V S, Mall D I, Srivastava C V. Kinetic and equilibrium isotherm studies for the adsorptive removal of Brilliant Green dye from aqueous solution by rich hush ash. Journal of Environment Management, 2007,84(4):390-396
164. Rajeshwarisivaraj, Namasibayam C. Kadirvelu K. Orange peel as an adsorbent in the removal of acid violet 17(acid dye) from aqueous solutions. Waste Mange,2001,21:105-110
165. Purkait M K, Gusain D S, Das Gupta S. Adsorption behaviour of chrysoidine dye on avtivated charcoal and its regeneration characteristics by using different surfactants. Seperation Science Technology, 2004,39(5):2419-2440
166. Jiang Xiumin, Zheng Chugang, Yan Che, et al. Physical structure and combustion properties of super fine pulverized coal particle. Fuel,2002,81:793-797.
167.廖传华,史勇春,鲍金刚,燃烧过程与设备.北京：中国石化出版社,2008：270-278
168.王亚超.锅炉分册.北京：中国电力出版社,2010：123-135
169. Mamleev V, Bourbigot S, Bras M Le, et al. Modelling of nonisothermal kinetics in the mogravimetry. Chemistry Physical,2002,2:47084716
170.戴和武,谢可玉.北京：煤炭工业出版社,1998：299-350
171.胡荣祖,史居祯.热分析动力学.北京：科学出版社,2001
172.叶振兴.煤的低温氧化实验及对模拟试验数值模拟研究.合肥：安徽理工大学,2005
173. Ortega,A. The kinetics of solid-state reactions toward consensus-part 2:fitting kinetics data in dynamic convention on althermal analysis. International Journal of Chemitry kinetics.2002,34:193-208
174. Opfermann J. Kinetic analysis using multivariable non-linenar regression. Thermal Analysis Coal. 2000,60:641-658
175.何启林,王德明.煤的氧化和热解反应的动力学研究.北京科技大学学报,2006,28(1)：1-5
176.舒新前,王祖纳.神府煤煤岩组分的结构特性及其差异.燃烧化学学报,1996,24(5)：426-429
177.陶建红.褐煤中含氧官能团的测定与研究.河南化工,2010,27(4)：8-10
178.叶振兴.煤的低温氧化实验及对模拟实验数值模拟研究.合肥：安徽理工大学,2005,15-25
179.李少章,朱书全.煤的表面疏水性与其组成之间的关系,洁净煤技术,2004,10(3)：15-18
180.张恒.褐煤提质改性工艺中含氧官能团的研究.北京：中国矿业大学(北京),2006：47-55
181.村田逞诠著,朱春笙,龚祯祥译.煤的润湿研究及应用.北京：煤炭工业出版社,1992
182. Woskoboenko F, Stacy W O, Raisbeck D. Chapter 4 in The Science of Victorian Brown coal(Ed:R.A.Durie), Butterworth-Heinemanm.Oxford,1991
183.何余生,李忠,奚红霞,等.气固吸附等温线的研究进展.离子交换与吸附,2004,20(4)：376-384
184.姚超,刘敏,李为民,等.凹凸棒石/氧化锌纳米复合材料对亚甲基蓝的吸附性能.环境科学学报,2010,30(6)：1211-1219
18S. Khattri S D. Colour removal from dye wastewater using sugar calc as an adsorbent. Adsorption Science Technology,1999,(4):269-282
186.潘竟军,陈光明,韩布兴,等.亚甲基蓝在纳、铝和铁蒙脱土上的吸附研究.油田化学,1999,16(3)：195-197
187. T.Mathialagan, T Viraraghavan. Adsorption of cadmium from aqueous solution by perlite. Journal of Hazardous Materials,2002,B94:291-303
188. M.Otero, F. Rozada, L F Calvo, et al. Kinetic and equilibrium modelling of the mithylene blue removal from solution by adsorbent materials produced from sewage sludges. Biochemical Engineering Journal,2003,15(1): 59-68
189. Jili Zhang, Liping Liang, Lijun Pu, et al. Adsorption Characteristics of Cr(VI) by Wheat Straw Including Kinetic and Thermodynamics Analysis[J]. Research of Environmental Sciences,2010,23(12):1546-1552.
190.马伟.固水界面化学与吸附技术.北京：冶金工业出版社,2011,160-165
191. Weber W J, Morris J C. Proceeding of internationsl conference on water pollution symposium. Oford: Perganmo Press,1962:231
192.任建敏,张永民,吴四维,等.纳基膨润土吸附亚甲基蓝的热力学与动力学研究.离子交换与吸附,2010,26(2)：179-186
193. Tingchu Hsu, Chuangchin Yu,吃奶名Yeh.Adsorption of Cu from water using raw and modified coal fly ashes. Fuel,2008,87(7):1355-1359
194.刘福强,陈金龙,费正皓,等.复合功能超高交联吸附树脂对氨基萘酚磺酸的静态吸附热力学及动力学. 应用化学,2003,20(12)：1123-1128.
195.解建坤,岳钦艳,于慧,等.污泥活性炭对活性艳红K-2BP染料的吸附特性研究.山东大学学报(理学版),2007,42(3)：64-70.
196.孙体昌.固液分离.湖南：中南大学出版社,2011：1-5
197.钟润生.颗粒表面有机物吸附对混凝和沉淀影响的研究.北京：清华大学,2009,40-60
198.常青.水处理絮凝学.北京：化学工业出版社,2011：221-227
199.宿凯.高浊度矿井水的混凝处理研究.北京：中国矿业大学(北京),2008：25-30
200.马青山,贾瑟.絮凝化学和絮凝剂.北京：中国环境科学出版社,1988：10-89
201.任俊,沈健,卢寿慈.颗粒分散科学与技术.北京：化学工业出版社,2005：66-107
202.郭玲香,欧泽深,胡明星.煤泥水悬浮液体系中EDLVO理论及应用.中国矿业,1999,8(6)：69-72
203.卢寿慈.粉体技术手册.北京：化学工业出版社,2004
204.王凯,虞军.搅拌设备.北京：化学工业出版社,2006：12-45
205.永田进治著,马继舜译.混合原理与应用.北京：化学工业出版社,1984
206.崔玉川,员建,陈宏平.给水厂处理设施设计计算.北京：化学工业出版社,2003：68