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异质结构软磁材料的高频磁特性研究
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摘要
本博十论文针对目前高频软磁材料领域如何提高磁导率和使用截止频率这一重大科学问题,以异质结构软磁材料为主要研究对象,从高频软磁材料理论基础出发,开展了颗粒尺寸分布对磁导率影响、高频磁性测试方法、多层膜异质结构、纳米球壳和纳米环异质结构、FeCo-NiZn铁氧体异质结构复合颗粒膜等方面的研究,得到的主要创新性结果如下:
     1.改进了Herzer的随机各向异性模型。考虑了颗粒尺寸分布对材料磁导率、矫顽力等的影响,对Herzer模型的理论表达式进行了修正。使得Herzer模型可以在全尺寸范围更好的符合实验结果;提出了颗粒尺寸分布在研究颗粒磁性材料特性时的重要性。
     2.发展了一种利用高频测试手段测量材料磁性参数的方法。该方法避免了在确定薄膜材料饱和磁化强度时薄膜厚度测量带来的误差,在确定材料饱和磁化强度方面具有更高的精度。该方法同样在研究难轴的磁化反磁化过程时具有更高的精度。
     3.提出了一种利用多层膜中层调控材料高频磁特性的方法。利用层间相互作用和层间距的关系,通过改变多层膜材料的中间层厚度,实现了多层膜材料的高频磁导率(21-894)、共振频率(1.4-6.5GHz)和面内单轴各向异性场(12-520Oe)在大范围内可随意调控。
     4.提出了一种利用界面各向异性提高多层膜材料的Snoek的方法。通过引入界面各向异性,改善了多层膜内的双各向异性系统能量分布,从而在不影响材料磁导率的情况下大幅度的提高了材料的使用截止频率
     5.给出了另外一些具有高Snoek极限的系统—纳米管和纳米球壳。通过微磁学模拟证明,在纳米管和纳米球壳中通过改变材料的几何参数可以实现双各向异性系统,从而提高材料的Snoek极限数值。
     6.得到了一种同时具有高电阻率和优异高频磁性的CoFe-NiZn铁氧体双磁性复合颗粒膜。通过掺杂NiZn铁氧体磁性电介质相提高了材料的电阻率(>1000μΩ cm),并且可以同时保证材料具有高饱和磁化强度(>10kGs)和高的共振频率(2.88GHz)。
In this PhD thesis, we mainly study the topics on increasing the high frequency permeability and the using band by using the heterostructure magnetic materials. We mainly study the effects of grain size distribution on permeability of magnetic materials; study the magnetization reversal process of the magnetization of soft magnetic materials with dynamic method; study the high frequency properties in multilayers; study the high frequency properties in nanoshell and nanotube; study the high frequency properties of FeCo-NiZn ferrite bi-magnetic phase granular thin films.
     The major finding and innovations are shown as follow:
     1. Improvement of random anisotropy model. By introducing the distribution, the revised RAM model with grain size distribution can be well fitting with the real magnetic system. It indicate that the grain size distribution play an important role in the study of the magnetic material characteristics of the particle system.
     2. Development of a method to measure the parameters of magnetic materials with high frequency measurement. When measuring the saturation magnetization of thin film, this method can avoids the error during the film thickness measurement. This method is also useful to study the magnetization reversal process of hard-axis with greater accuracy.
     3. Adjust the high frequency properties by changing the interlayer interaction in multilayers. We change the interlayer interaction by controlling the thickness of the nonmagnetic interlayer thickness. The high-frequency magnetic permeability (21-894), the resonance frequency (1.4-6.5GHz) and in-plane uniaxial anisotropic field (12-520Oe) can be adjusted in wide range.
     4. Improve the Snoek's limit in multilayers. With the interface anisotropy changing in multilayers, the energy distribution should be changed in such bi-anisotropic system. Then, the resonance frequency can be increased but do not reduce the permeability.
     5. Nanotube and nanoshell with high Snoek's limit. With micromagnetic simulation, the Snoek's limit can be enlarged because of the bi-anisotropy. The permeability and resonance frequency can be adjusted by changing the geometrical parameters.
     6. Obtained such CoFe-NiZn ferrite bi magnetic granular thin films with both high resistivity and excellent high frequency magnetic properties. With NiZn ferrite doping, the resistivity (>1000μΩ cm) can be enlarged, simultaneously, we can also obtain high saturation magnetization (>10kGs), and high resonant frequency (2.88GHz).
引文
1全国磁性材料行业协会.中国磁性材料行业发展研究报告.2008
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