聚合物改性沥青流变特性研究
|
摘要
本文考察了工艺条件对聚合物改性沥青流变性质的影响并通过流变性评价确定了最佳的制备工艺条件。用几种流变性评价方法和热分析法测试了最佳工艺条件下制备的不同LSBS含量的改性沥青的流变性,并确定简便有效的流变性评价方法和评价指标。
通过研究发现,剪切时间、剪切速率、发育时间等加工条件对改性沥青的流变性均有不同程度的影响,以流变性指标作为参考,确定了制备改性沥青的最佳工艺参数。用不同温度和不同拉伸速率条件下的测力延度实验研究上述的LSBS改性沥青的流变性质,在众多的测力延度实验指标中确定出评价改性沥青感时、感温性的有效指标。
通过对不同L-SBS加入量改性沥青流变性质的研究发现,改性剂的加入量、温度、荷载、时间、拉伸速率等因素对改性沥青的流变性质有重要影响。针入度法、弹性恢复法和测力延度法可以作为评价改性沥青的感时、感温性以及对荷载的敏感性的有效评价方法,其中,测力延度法可以综合拉伸柔度、粘弹比、SBS的当量劲度作为评价沥青改性效果和改性沥青低温性能的指标。DSC试验结果可以预测改性沥青相容性和改性沥青高、低温性和感温性等流变性质,表现为吸热量的变化。
The research examined the influence of process conditions on the rheological characteristic of polymer modified asphalt and explored the optimal process conditions, tested the rheological characteristic of modified asphalt with different LSBS content by means of rheological characteristic assessment methods and thermal analysis method, and ascertained effective rheological characteristic assessment methods and evaluating indicators.
It was indicated that many process factors, such as shearing time, shearing velocity and development time would affect the rheological characteristic of modified asphalt to some different extent, and the optimal technological parameter was ascertained with reference to rheological characteristic indicators. Force and ductility test was used to evaluate the rheological characteristic of the above LSBS modified asphalt sample, and effective indicators of evaluating temperature sensitivity, time sensitivity of the sample were determined among the numerous experiment indicators.
It was found that modifier content, temperature, load time and rate of extension have considerable influence on rheological characteristic of modified asphalt. The method of penetration, elastic recovery, force and ductility test could be used as effective methods of evaluating time sensitivity, temperature sensitivity and load sensitivity. And among them, force and ductility test could integrate with extension compliance, viscoelastic proportion and equivalent stiffness to evaluate the asphalt modified effect and cryogenic property. DSC experimental result could predict compatibility of LSBS and base asphalt, high temperature performance, cryogenic property and temperature sensitivity performance and so on, with a change of heat absorption capacity.
通过研究发现,剪切时间、剪切速率、发育时间等加工条件对改性沥青的流变性均有不同程度的影响,以流变性指标作为参考,确定了制备改性沥青的最佳工艺参数。用不同温度和不同拉伸速率条件下的测力延度实验研究上述的LSBS改性沥青的流变性质,在众多的测力延度实验指标中确定出评价改性沥青感时、感温性的有效指标。
通过对不同L-SBS加入量改性沥青流变性质的研究发现,改性剂的加入量、温度、荷载、时间、拉伸速率等因素对改性沥青的流变性质有重要影响。针入度法、弹性恢复法和测力延度法可以作为评价改性沥青的感时、感温性以及对荷载的敏感性的有效评价方法,其中,测力延度法可以综合拉伸柔度、粘弹比、SBS的当量劲度作为评价沥青改性效果和改性沥青低温性能的指标。DSC试验结果可以预测改性沥青相容性和改性沥青高、低温性和感温性等流变性质,表现为吸热量的变化。
The research examined the influence of process conditions on the rheological characteristic of polymer modified asphalt and explored the optimal process conditions, tested the rheological characteristic of modified asphalt with different LSBS content by means of rheological characteristic assessment methods and thermal analysis method, and ascertained effective rheological characteristic assessment methods and evaluating indicators.
It was indicated that many process factors, such as shearing time, shearing velocity and development time would affect the rheological characteristic of modified asphalt to some different extent, and the optimal technological parameter was ascertained with reference to rheological characteristic indicators. Force and ductility test was used to evaluate the rheological characteristic of the above LSBS modified asphalt sample, and effective indicators of evaluating temperature sensitivity, time sensitivity of the sample were determined among the numerous experiment indicators.
It was found that modifier content, temperature, load time and rate of extension have considerable influence on rheological characteristic of modified asphalt. The method of penetration, elastic recovery, force and ductility test could be used as effective methods of evaluating time sensitivity, temperature sensitivity and load sensitivity. And among them, force and ductility test could integrate with extension compliance, viscoelastic proportion and equivalent stiffness to evaluate the asphalt modified effect and cryogenic property. DSC experimental result could predict compatibility of LSBS and base asphalt, high temperature performance, cryogenic property and temperature sensitivity performance and so on, with a change of heat absorption capacity.
引文
[1] 景彦平,李秀君,原健安,戴经梁.沥青延度与流变特性关系研究分析(一). 石油沥青. 2002,16(3).
[2] 沈金安 . 沥青及沥青混合料路用性能 . 人民交通出版社.2001.5.
[3] Development of Standard CAN/CGSB-16.3-M.Asphalt Cement for Road Purposes.I.Deme 1990 Canadian Technical Asphalt Association Conference,Nov.1990.
[4] 柳永行,张昌祥.石油沥青.
[5] 李葵英.界面与胶体的物理化学.1998,4.
[6]李兆敏,蔡国琰.非牛顿流体力学.石油大学出版社.1998.4.
[7]David Whiteoak. The HELL Bitumen handbook. SHELL BITUMEN. London. 1990.
[8]W.Heukelom.A Bitumen test date chart for showing the effort of temperature on the mechanical behavior of asphaltic bitumens.Journal of the Institute of Petroleum.Vol 55.No.546.1996.11.
[9] 杨挺青.粘弹性力学.武汉:华中理工大学出版社,1989.
[10] 郝培文,刘红瑛.运用蠕变速率评价沥青混合料低温抗裂性能的研究. 石油沥青.1994.
[11] 张孝宁.粘弹性实脸原理.哈尔滨:哈尔滨船铂工程学院出版社.1991.
[12] Monismith,C.L.,Viscoelastic Behavier of Asphalt Congrete Pavements,1st international Conference on the Structural Design ofAsphalt Pavements,1962,1.
[13] 徐佩弦.高聚流变学及其应用.化学工业出版社.2003.9
[14] 潘道成.高聚物及其共混物的力学性能.上海:上海科学技术出版社,1988.
[15] 刘福明,邓英才,桂增俭.用流变学原理评价改性沥青的高温稳定性. 天津建设科技.2002,1.
[16]丛玉凤,廖克俭,翟玉春.辽曙道路沥青感温性的评价.辽宁石油化工大学学报. 2004. 24(4).
[17] 余剑英. SBS 改性沥青流变特性的研究. 武汉工业大学学报,1992,14 (4):21-24.
[18]沈金安.李福普.评价沥青质量的核心指标—沥青感温性.1997, 11(2).
[19] 王子军,张书红,李锐.AH-90 重交通道路沥青的感温性研究[J].石油沥青,2002,16(3):6-9 .
[20]沥青和聚合物改性沥青特性与沥青混凝土混合料性能的关系.改性沥青译文集.1991
[21]King,etal,Influence of asphalt grade and polymer concentration on the low temperature performance of polymer modified asphalt,AAPT1993.
[22]Woodhams, Polyethylene-modified titumens for paving applications, AAPT 1986.
[23]黄卫东,孙立军.聚合物改性沥青的试验方法和评价指标.中国市政工程.1999, 4.
[24]张南鹭.60℃高粘度沥青路用性能评价.石油沥青. 1998,12(1).
[25]黄卫东,孙立军.SBS 改性沥青软化点与混合料动稳定度关系的研究[J].中国公路学报,2001,14(增刊):1-3.
[26]黄卫东,孙立军.SBS 改性沥青软化点的衰变[J].中国公路学报,2002,15(增刊):1-3.
[27]张争奇.对 SBS 改性沥青试验中异常现象的研究[J].西安公路交通大学学报,2001,21(4):13-16.
[28]薛小刚,李宁利,陈华鑫,张争奇.改性沥青高温指标可靠性评价.内蒙古公路与运输.2004, 1.
[29]刘忠信.道路沥青标准若干指标的讨论. 石油炼制与化工.1994,25.
[30]GayleN.King,Helen W.Kingetc.Influence of Aphalt Grade and Polymer Concentration on the High Temperature Performance of Polymer-Modified Asphalt AAPT,1992,73:196-210.
[31]陈佩茹,李立寒,刘宇.沥青高温性能指标评价.石油沥青.2002,16(3).
[32]曾赘,郭淑华.零剪切粘度与沥青高温性能的关系.石油沥青. 2003,17(增刊).
[33] 李秀君,景彦平,原健安,戴经梁.沥青延度与流变特性关系研究分析(二).石油沥青.2002,16.
[34]沈金安.道路沥青及沥青混合料的气候分区及关键性技术指标—“八五”国家科技攻关专题成果介绍.石油沥青. 1996.12 (l.4).
[35]郭峰伟,马全胜沥青测力延度仪的应用分析.华东公路.2003. 5.
[36] 束德林.工程材料力学性能.北京:机械工业出版社,2003.
[37]李志栋,侯曙光,黄晓明.SBR 改性沥青的低温性能评价.石油沥青. 2004,18(2).
[38]陈平,黄晓明,李丹,测力延度在沥青低温性能指标研究中的应用.公路交通科技,2005,22(7):7-9.
[39]李志栋,黄晓明,侯曙光,岳学军,纪宁华. 应用测力延度试验评价改性沥青的低温性能.公路交通科技.Vol.22.No.5. May.2005.
[40]黄哲,孙明哲,陈跃,林晓莉.沥青路面温度稳定性评价指标的探讨.黑龙江交通科技.1999,2.
[41] 邹桂莲,张肖宁,韩传代.应用 DSR 评价沥青胶浆路用性能的研究.哈尔滨建筑大学学报,200l,34(3).
[43]徐世法,周朝晖,钱培中,高建立.Superpave 规范对于改性沥青的有效性分析.公路交通科技.2003, l(1).
[42]原健安,刘地成,纪东.动态剪切流变仪在评价 SBS 改性沥青中存在的一个问题.公路. 2003,8
[44]徐世法,周朝晖,钱培中,高建立. SuPerPave 规范对于改性沥青的有效性分析. 公路交通科技,2003,20 (1):41-44.
[45]H.U.Bahia,D.I.Hanson,M.Zeng,H.Zhai,M.A.Khatri,R.M.Anderson. NCHRP REPORT 459. Transportation Research Board - National Research Council,2001.
[46]沈金安,姬菊枝.道路沥青及沥青混合料使用性能.公路交通科技.1994,3: 1-10.
[47]Naomi Kassabian.美国 TRB 国家研究委员会现代技术发展水平报告至 7.TRB NRC. State of the Art Report7.Low Temperature Properties of Paving Asphalt Cements.李福普译.1998.
[48]日加寒冷地区沥青路面研究组.Paving in cold arenas report on common test on asphalt properties.1989.5.
[49]Petersen JC. Asphaltoxidation Anoverview including a new model for oxidatio nproposing that physicochemical factors dominate the oxidation kinetics. FuelSci TechnolInt'l,1993,11(1):57-58
[50] 张德勤.石油沥青的生产与应用.中国石化出版社 2001.7
[51] 付海英,窦大营,李林繁,谢雷东,姚思德.,SBS改性沥青的储存稳定性研究. 石油沥青,2005,19(1):27-28.
[52] 王立志,制备储存稳定的LDPE/SBS共混物改性沥青.石油沥青2002,16(4):41-45.
[53] 王立志,LDPE/SBS 共混物改性沥青体系的反应共混行为合成橡胶工业.合成橡胶工业.2003,26(2):98-100.
[54] 吕伟民,反应性SBS改性沥青的研制.石油沥青.2002,16(1):30-32
[55] 黄卫东,孙立军.SBS改性沥青的混合原理与过程[J].同济大学学报,2002,30(2):189-192.
[2] 沈金安 . 沥青及沥青混合料路用性能 . 人民交通出版社.2001.5.
[3] Development of Standard CAN/CGSB-16.3-M.Asphalt Cement for Road Purposes.I.Deme 1990 Canadian Technical Asphalt Association Conference,Nov.1990.
[4] 柳永行,张昌祥.石油沥青.
[5] 李葵英.界面与胶体的物理化学.1998,4.
[6]李兆敏,蔡国琰.非牛顿流体力学.石油大学出版社.1998.4.
[7]David Whiteoak. The HELL Bitumen handbook. SHELL BITUMEN. London. 1990.
[8]W.Heukelom.A Bitumen test date chart for showing the effort of temperature on the mechanical behavior of asphaltic bitumens.Journal of the Institute of Petroleum.Vol 55.No.546.1996.11.
[9] 杨挺青.粘弹性力学.武汉:华中理工大学出版社,1989.
[10] 郝培文,刘红瑛.运用蠕变速率评价沥青混合料低温抗裂性能的研究. 石油沥青.1994.
[11] 张孝宁.粘弹性实脸原理.哈尔滨:哈尔滨船铂工程学院出版社.1991.
[12] Monismith,C.L.,Viscoelastic Behavier of Asphalt Congrete Pavements,1st international Conference on the Structural Design ofAsphalt Pavements,1962,1.
[13] 徐佩弦.高聚流变学及其应用.化学工业出版社.2003.9
[14] 潘道成.高聚物及其共混物的力学性能.上海:上海科学技术出版社,1988.
[15] 刘福明,邓英才,桂增俭.用流变学原理评价改性沥青的高温稳定性. 天津建设科技.2002,1.
[16]丛玉凤,廖克俭,翟玉春.辽曙道路沥青感温性的评价.辽宁石油化工大学学报. 2004. 24(4).
[17] 余剑英. SBS 改性沥青流变特性的研究. 武汉工业大学学报,1992,14 (4):21-24.
[18]沈金安.李福普.评价沥青质量的核心指标—沥青感温性.1997, 11(2).
[19] 王子军,张书红,李锐.AH-90 重交通道路沥青的感温性研究[J].石油沥青,2002,16(3):6-9 .
[20]沥青和聚合物改性沥青特性与沥青混凝土混合料性能的关系.改性沥青译文集.1991
[21]King,etal,Influence of asphalt grade and polymer concentration on the low temperature performance of polymer modified asphalt,AAPT1993.
[22]Woodhams, Polyethylene-modified titumens for paving applications, AAPT 1986.
[23]黄卫东,孙立军.聚合物改性沥青的试验方法和评价指标.中国市政工程.1999, 4.
[24]张南鹭.60℃高粘度沥青路用性能评价.石油沥青. 1998,12(1).
[25]黄卫东,孙立军.SBS 改性沥青软化点与混合料动稳定度关系的研究[J].中国公路学报,2001,14(增刊):1-3.
[26]黄卫东,孙立军.SBS 改性沥青软化点的衰变[J].中国公路学报,2002,15(增刊):1-3.
[27]张争奇.对 SBS 改性沥青试验中异常现象的研究[J].西安公路交通大学学报,2001,21(4):13-16.
[28]薛小刚,李宁利,陈华鑫,张争奇.改性沥青高温指标可靠性评价.内蒙古公路与运输.2004, 1.
[29]刘忠信.道路沥青标准若干指标的讨论. 石油炼制与化工.1994,25.
[30]GayleN.King,Helen W.Kingetc.Influence of Aphalt Grade and Polymer Concentration on the High Temperature Performance of Polymer-Modified Asphalt AAPT,1992,73:196-210.
[31]陈佩茹,李立寒,刘宇.沥青高温性能指标评价.石油沥青.2002,16(3).
[32]曾赘,郭淑华.零剪切粘度与沥青高温性能的关系.石油沥青. 2003,17(增刊).
[33] 李秀君,景彦平,原健安,戴经梁.沥青延度与流变特性关系研究分析(二).石油沥青.2002,16.
[34]沈金安.道路沥青及沥青混合料的气候分区及关键性技术指标—“八五”国家科技攻关专题成果介绍.石油沥青. 1996.12 (l.4).
[35]郭峰伟,马全胜沥青测力延度仪的应用分析.华东公路.2003. 5.
[36] 束德林.工程材料力学性能.北京:机械工业出版社,2003.
[37]李志栋,侯曙光,黄晓明.SBR 改性沥青的低温性能评价.石油沥青. 2004,18(2).
[38]陈平,黄晓明,李丹,测力延度在沥青低温性能指标研究中的应用.公路交通科技,2005,22(7):7-9.
[39]李志栋,黄晓明,侯曙光,岳学军,纪宁华. 应用测力延度试验评价改性沥青的低温性能.公路交通科技.Vol.22.No.5. May.2005.
[40]黄哲,孙明哲,陈跃,林晓莉.沥青路面温度稳定性评价指标的探讨.黑龙江交通科技.1999,2.
[41] 邹桂莲,张肖宁,韩传代.应用 DSR 评价沥青胶浆路用性能的研究.哈尔滨建筑大学学报,200l,34(3).
[43]徐世法,周朝晖,钱培中,高建立.Superpave 规范对于改性沥青的有效性分析.公路交通科技.2003, l(1).
[42]原健安,刘地成,纪东.动态剪切流变仪在评价 SBS 改性沥青中存在的一个问题.公路. 2003,8
[44]徐世法,周朝晖,钱培中,高建立. SuPerPave 规范对于改性沥青的有效性分析. 公路交通科技,2003,20 (1):41-44.
[45]H.U.Bahia,D.I.Hanson,M.Zeng,H.Zhai,M.A.Khatri,R.M.Anderson. NCHRP REPORT 459. Transportation Research Board - National Research Council,2001.
[46]沈金安,姬菊枝.道路沥青及沥青混合料使用性能.公路交通科技.1994,3: 1-10.
[47]Naomi Kassabian.美国 TRB 国家研究委员会现代技术发展水平报告至 7.TRB NRC. State of the Art Report7.Low Temperature Properties of Paving Asphalt Cements.李福普译.1998.
[48]日加寒冷地区沥青路面研究组.Paving in cold arenas report on common test on asphalt properties.1989.5.
[49]Petersen JC. Asphaltoxidation Anoverview including a new model for oxidatio nproposing that physicochemical factors dominate the oxidation kinetics. FuelSci TechnolInt'l,1993,11(1):57-58
[50] 张德勤.石油沥青的生产与应用.中国石化出版社 2001.7
[51] 付海英,窦大营,李林繁,谢雷东,姚思德.,SBS改性沥青的储存稳定性研究. 石油沥青,2005,19(1):27-28.
[52] 王立志,制备储存稳定的LDPE/SBS共混物改性沥青.石油沥青2002,16(4):41-45.
[53] 王立志,LDPE/SBS 共混物改性沥青体系的反应共混行为合成橡胶工业.合成橡胶工业.2003,26(2):98-100.
[54] 吕伟民,反应性SBS改性沥青的研制.石油沥青.2002,16(1):30-32
[55] 黄卫东,孙立军.SBS改性沥青的混合原理与过程[J].同济大学学报,2002,30(2):189-192.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |