块体非晶合金的非晶形成能力与原子尺寸因素研究
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摘要
块体非晶合金具有许多独特的物理、化学和力学性能,使得其在航空、航天、电子、机械和化工等领域和行业中呈现出广阔的应用前景。因而,对块体非晶的研究无论在理论上还是在应用上都有重要意义。八十年代末国外发现了可以通过铜模冷却制备的块体非晶合金,使得该领域成为新材料研究热点和前沿,但是近几年来,却未见突破性的进展,究其原因,主要是非晶合金的形成机制一直不清楚,对于复杂的多元体系,显然不可能仅仅依靠大量实验及经验规律来获得理想的非晶成分。
本文选择目前已报道的块体非晶合金作为研究目标,利用现有的大量的数据资源,对原子尺寸因素和非晶形成能力的关系进行系统分析,总结了原子尺寸差以及基元素体积有效率与合金非晶形成能力的关系,并对其合理性进行验证。结果表明,不同非晶合金体系的原子尺寸差范围不同,但是与原子的百分含量呈现一种线性关系,而基元素体积有效率同样与原子百分含量呈现明显的线性关系,并且不同非晶合金体系的这两个参数都与基元素原子半径存在一种趋势,可以在一定程度上表征合金的非晶形成能力,用来进行非晶合金的成分优化和设计,为发展能工业化的块体非晶合金材料及其制备技术提供帮助。
Bulk amorphous alloys, due to their special physical, chemical and mechanical properties, have found applications in many fields such as aviation, spaceflight, electronics, mechanics and chemical industry. Thus, investigation into bulk amorphous alloys is of both theoretical and practical significance. Amorphous alloys had attracted increasing attention since the late 1980’s due to the advent of bulk metallic alloys, readily prepared by copper mould casting method, this field has become a focus and frontier in new materials research. However there has been little progress in recent year regarding new bulk amorphous alloys. This is principally due to the fact that their formation mechanism is largely unknown. This discovery of these amorphous alloys has relied on extensive trials based on empirical rules.
In this paper, we surveyed from reported literatures the compositions with high glass forming ability. Based on numerous data, systematic study has been carried out on the relation between the size factor and glass forming ability of different alloys. The atomic size criteria has been suggested and verified by other criteria. Each amorphous alloy system has its own atomic size difference ratio domain. And volume effective ratio of matrix element in amorphous alloys has a liner relation versus its concentration. The aim of this study is to find the effective way and proper composition for designing and optimizing amorphous.
本文选择目前已报道的块体非晶合金作为研究目标,利用现有的大量的数据资源,对原子尺寸因素和非晶形成能力的关系进行系统分析,总结了原子尺寸差以及基元素体积有效率与合金非晶形成能力的关系,并对其合理性进行验证。结果表明,不同非晶合金体系的原子尺寸差范围不同,但是与原子的百分含量呈现一种线性关系,而基元素体积有效率同样与原子百分含量呈现明显的线性关系,并且不同非晶合金体系的这两个参数都与基元素原子半径存在一种趋势,可以在一定程度上表征合金的非晶形成能力,用来进行非晶合金的成分优化和设计,为发展能工业化的块体非晶合金材料及其制备技术提供帮助。
Bulk amorphous alloys, due to their special physical, chemical and mechanical properties, have found applications in many fields such as aviation, spaceflight, electronics, mechanics and chemical industry. Thus, investigation into bulk amorphous alloys is of both theoretical and practical significance. Amorphous alloys had attracted increasing attention since the late 1980’s due to the advent of bulk metallic alloys, readily prepared by copper mould casting method, this field has become a focus and frontier in new materials research. However there has been little progress in recent year regarding new bulk amorphous alloys. This is principally due to the fact that their formation mechanism is largely unknown. This discovery of these amorphous alloys has relied on extensive trials based on empirical rules.
In this paper, we surveyed from reported literatures the compositions with high glass forming ability. Based on numerous data, systematic study has been carried out on the relation between the size factor and glass forming ability of different alloys. The atomic size criteria has been suggested and verified by other criteria. Each amorphous alloy system has its own atomic size difference ratio domain. And volume effective ratio of matrix element in amorphous alloys has a liner relation versus its concentration. The aim of this study is to find the effective way and proper composition for designing and optimizing amorphous.
引文
[1]惠希东,陈国良.块体非晶合金.北京:化学工业出版社,2007.
[2]王晓东.大块非晶合金形成能力及稳定性研究:[硕士学位论文].大连:大连理工大学,2000
[3]郗学奎. Mg基大块非晶的合成、形成能力、塑性流变及断裂行为研究:[博士学位论文].北京:中国科学院研究生院,2005
[4]柳林.锆基大块非晶合金的热稳定性研究:[硕士学位论文].武汉:华中科技大学,2002
[5]蒋美萍.新型大块非晶合金的研究进展.江苏工业学院学报,2003,15(4):57-60
[6]张海峰,丁炳哲,胡壮麒.块体金属玻璃的研究与进展.金属学报,2001,37(11):1131-1141
[7]张博.非晶金属塑料:[博士学位论文].北京:中国科学院研究生院,2006
[8]王丹红.材料新贵步入太空时代.国外科技动态,2001(7):32-33
[9] Weihua Wang. Correlations between elastic moduli and properties in bulk metallic glasses. Journal of applied physics,2006,99:093506
[10]何国,陈国良.金属间化合物与大块玻璃合金的形成.材料研究学报,1999,13(6):569-575
[11]曹晓明,武建军,温鸣.先进结构材料.北京:化学工业出版社,2005.76-77
[12]任招娣. Al基非晶合金的非晶形成能力及热稳定性分析:[硕士学位论文].兰州:兰州理工大学,2005
[13]冯端,金国钧.凝聚态物理.北京:高等教育出版社,2003:93-95
[14]卢柯.非晶态金属的结构与合金的玻璃形成能力.金属学报,1992,28(1):B17-26
[15]王庆,夏雷,肖学山等.大块非晶的研究进展.自然杂志,2001,23(3):145-148
[16]何建军,陈鼎,陈清.大块非晶体材料的研究与进展.湖南冶金,2002,(5):3-7
[17]王翠玲,吴玉萍.非晶态合金的优异性能及应用.煤矿机械,2005,(2):74-77
[18] W.H. Wang, C. Dong, C.H. Shek. Bulk metallic glasses. Materials science and engineering R,2004:45-89
[19]张洛,戴志华,李挹红.非晶态金属与环境保护.上海金属,1998,20(6):23-28
[20]高玉来,沈军,孙剑飞.大块非晶合金的性能、制备及应用.材料科学与工艺,2003,11(2):215-219
[21]田永君,曹茂盛,曹传宝.先进材料导论.哈尔滨:哈尔滨工业大学出版社,2005. 114-118
[22]申玉田,崔春翔,徐艳姬.大块非晶合金制备原理与技术.稀有金属材料与工程,2004,33(5):459-463
[23]A.Peker,W.L.Johnson. A highly processable metallic glass:Zr41.2Ti13.8Cu12.5Ni10.0Be22.5. Appl.Phys. Lett.,1993,63(17):2342-2344
[24]孙琴,王宁,陈刚.块状金属玻璃的研究现状.上海有色金属,2005,26(2):93-96
[25]郝雷,陈学定,袁子洲等.大块非晶合金的研究进展.材料导报,2004,18(8):22-24
[26]黄林军,梁工英.新型多组元大块非晶合金形成能力的研究进展.有色金属,2006,58(2):44-52
[27]陶平均,杨元政.大块非晶材料的研究动向.新技术新工艺,2005,(10):43-57
[28]王焕荣,石志强,滕新营等.合金非晶形成能力的研究进展.功能材料,2002,33(4):357-359
[29]沈军,高玉来,陈德民等.大块非晶合金的玻璃形成能力.材料导报,2004,18(1):85-87
[30]袁子洲,王冰霞,郝雷等.块体非晶合金形成机理及成分设计研究述评.特种铸造及有色合金,2005,25(1):35-38
[31]任英磊,左景辉,邱克强等.一种新型Nd基块体非晶合金.金属学报,2004,40(3):301-304
[32] Z.P. Lu, C.T. Liu. A new approach to understanding and measuring glass formation in bulk amorphous materials. Intermetallics,2004(12):1035-1043
[33]嵇罡,季颖斐,马学鸣等.大块非晶合金的形成能力.材料科学与工程,1999,17(3):55-58
[34]蔡安辉,潘冶,孙国雄.大块金属玻璃非晶形成能力表征参数探讨.特种铸造及有色合金,2004(2):19-20
[35] Mingxu xia, Shuguang Zhang, Chaoli Ma et al. Evaluation of glass-forming ability for metallic glasses based on order-disorder competition. Applied physics letters,2006,89:091917
[36] Akira Takeuchi, Akihisa Inoue. Classification of bulk metallic glassed by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element . Material transactions,2005,46(12):2817-2829
[37] Payman Jalali,Mo li. Atomic size effect on critical cooling rate and glass formation . Physical review,2005,B71:014206
[38]方守狮,肖学山,王庆等. Pd基大块金属玻璃过冷液相区与键参数的关系.稀有金属材料与工程,2004,33(11):1132-1135
[39]陈伟荣. Zr-Al-Ni-Cu大块非晶合金成分设计及性能研究:[博士学位论文].大连:大连理工大学,2002
[40]贺自强,王新林,全白云.非晶态合金的形成及研究进展.金属功能材料,2005,12(6):27-31
[41] D.B. Miracle, O.N. Senkov . Topological criterion for metallic glass formation. Materials science and engineering,2003,A347:50-58
[42] T. Egami. Atomistic mechanism of bulk metallic glass formation. Journal of non-crystalline solids,2003,317:30-33
[43] T.Egami,Y.Waseda. Atomic size effect on the formability of metallic glasses. Journal of non-crystalline solids,1984,64:113-134
[44] O.N. Senkov, D.B. Miracle. Effect of the atomic size distribution on glass forming ability of amorphous metallic alloys. Materials research bulletin,2001,36:2183-2198
[45]陈伟荣,王英敏,羌建兵等. Zr基大块非晶合金成分的等电子浓度和等原子尺寸判据.材料研究学报,2002,16(2):219-224
[46]王清,王英敏,羌建兵等. Cu基Cu-Zr-Al块体非晶合金的成分设计.金属学报,2004,40(11):1183-1188
[47] Hyon-Jee Lee,Tahir Cagin,William L. Johnson et al. Criteria for formation of metallic glasses:the role of atomic size ratio. Journal of chemical physics,2003,119(18):9858-9870
[48]蔡安辉,潘冶,孙国雄.化学键参数和原子半径差与BMG合金的GFA关系.中国工程科学,2004,6(7):81-87
[49]Z.P. Lu,C.T. Liu,Y.D. Dong. Effects of atomic bonding nature and size mismatch on thermal stability and glass-forming ability of bulk metallic glasses. Journal of non-crystalline solids,2004,341:93-100
[50]迟宝全.合金非晶形成能力的研究:[硕士学位论文].长春:吉林大学,2003
[2]王晓东.大块非晶合金形成能力及稳定性研究:[硕士学位论文].大连:大连理工大学,2000
[3]郗学奎. Mg基大块非晶的合成、形成能力、塑性流变及断裂行为研究:[博士学位论文].北京:中国科学院研究生院,2005
[4]柳林.锆基大块非晶合金的热稳定性研究:[硕士学位论文].武汉:华中科技大学,2002
[5]蒋美萍.新型大块非晶合金的研究进展.江苏工业学院学报,2003,15(4):57-60
[6]张海峰,丁炳哲,胡壮麒.块体金属玻璃的研究与进展.金属学报,2001,37(11):1131-1141
[7]张博.非晶金属塑料:[博士学位论文].北京:中国科学院研究生院,2006
[8]王丹红.材料新贵步入太空时代.国外科技动态,2001(7):32-33
[9] Weihua Wang. Correlations between elastic moduli and properties in bulk metallic glasses. Journal of applied physics,2006,99:093506
[10]何国,陈国良.金属间化合物与大块玻璃合金的形成.材料研究学报,1999,13(6):569-575
[11]曹晓明,武建军,温鸣.先进结构材料.北京:化学工业出版社,2005.76-77
[12]任招娣. Al基非晶合金的非晶形成能力及热稳定性分析:[硕士学位论文].兰州:兰州理工大学,2005
[13]冯端,金国钧.凝聚态物理.北京:高等教育出版社,2003:93-95
[14]卢柯.非晶态金属的结构与合金的玻璃形成能力.金属学报,1992,28(1):B17-26
[15]王庆,夏雷,肖学山等.大块非晶的研究进展.自然杂志,2001,23(3):145-148
[16]何建军,陈鼎,陈清.大块非晶体材料的研究与进展.湖南冶金,2002,(5):3-7
[17]王翠玲,吴玉萍.非晶态合金的优异性能及应用.煤矿机械,2005,(2):74-77
[18] W.H. Wang, C. Dong, C.H. Shek. Bulk metallic glasses. Materials science and engineering R,2004:45-89
[19]张洛,戴志华,李挹红.非晶态金属与环境保护.上海金属,1998,20(6):23-28
[20]高玉来,沈军,孙剑飞.大块非晶合金的性能、制备及应用.材料科学与工艺,2003,11(2):215-219
[21]田永君,曹茂盛,曹传宝.先进材料导论.哈尔滨:哈尔滨工业大学出版社,2005. 114-118
[22]申玉田,崔春翔,徐艳姬.大块非晶合金制备原理与技术.稀有金属材料与工程,2004,33(5):459-463
[23]A.Peker,W.L.Johnson. A highly processable metallic glass:Zr41.2Ti13.8Cu12.5Ni10.0Be22.5. Appl.Phys. Lett.,1993,63(17):2342-2344
[24]孙琴,王宁,陈刚.块状金属玻璃的研究现状.上海有色金属,2005,26(2):93-96
[25]郝雷,陈学定,袁子洲等.大块非晶合金的研究进展.材料导报,2004,18(8):22-24
[26]黄林军,梁工英.新型多组元大块非晶合金形成能力的研究进展.有色金属,2006,58(2):44-52
[27]陶平均,杨元政.大块非晶材料的研究动向.新技术新工艺,2005,(10):43-57
[28]王焕荣,石志强,滕新营等.合金非晶形成能力的研究进展.功能材料,2002,33(4):357-359
[29]沈军,高玉来,陈德民等.大块非晶合金的玻璃形成能力.材料导报,2004,18(1):85-87
[30]袁子洲,王冰霞,郝雷等.块体非晶合金形成机理及成分设计研究述评.特种铸造及有色合金,2005,25(1):35-38
[31]任英磊,左景辉,邱克强等.一种新型Nd基块体非晶合金.金属学报,2004,40(3):301-304
[32] Z.P. Lu, C.T. Liu. A new approach to understanding and measuring glass formation in bulk amorphous materials. Intermetallics,2004(12):1035-1043
[33]嵇罡,季颖斐,马学鸣等.大块非晶合金的形成能力.材料科学与工程,1999,17(3):55-58
[34]蔡安辉,潘冶,孙国雄.大块金属玻璃非晶形成能力表征参数探讨.特种铸造及有色合金,2004(2):19-20
[35] Mingxu xia, Shuguang Zhang, Chaoli Ma et al. Evaluation of glass-forming ability for metallic glasses based on order-disorder competition. Applied physics letters,2006,89:091917
[36] Akira Takeuchi, Akihisa Inoue. Classification of bulk metallic glassed by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element . Material transactions,2005,46(12):2817-2829
[37] Payman Jalali,Mo li. Atomic size effect on critical cooling rate and glass formation . Physical review,2005,B71:014206
[38]方守狮,肖学山,王庆等. Pd基大块金属玻璃过冷液相区与键参数的关系.稀有金属材料与工程,2004,33(11):1132-1135
[39]陈伟荣. Zr-Al-Ni-Cu大块非晶合金成分设计及性能研究:[博士学位论文].大连:大连理工大学,2002
[40]贺自强,王新林,全白云.非晶态合金的形成及研究进展.金属功能材料,2005,12(6):27-31
[41] D.B. Miracle, O.N. Senkov . Topological criterion for metallic glass formation. Materials science and engineering,2003,A347:50-58
[42] T. Egami. Atomistic mechanism of bulk metallic glass formation. Journal of non-crystalline solids,2003,317:30-33
[43] T.Egami,Y.Waseda. Atomic size effect on the formability of metallic glasses. Journal of non-crystalline solids,1984,64:113-134
[44] O.N. Senkov, D.B. Miracle. Effect of the atomic size distribution on glass forming ability of amorphous metallic alloys. Materials research bulletin,2001,36:2183-2198
[45]陈伟荣,王英敏,羌建兵等. Zr基大块非晶合金成分的等电子浓度和等原子尺寸判据.材料研究学报,2002,16(2):219-224
[46]王清,王英敏,羌建兵等. Cu基Cu-Zr-Al块体非晶合金的成分设计.金属学报,2004,40(11):1183-1188
[47] Hyon-Jee Lee,Tahir Cagin,William L. Johnson et al. Criteria for formation of metallic glasses:the role of atomic size ratio. Journal of chemical physics,2003,119(18):9858-9870
[48]蔡安辉,潘冶,孙国雄.化学键参数和原子半径差与BMG合金的GFA关系.中国工程科学,2004,6(7):81-87
[49]Z.P. Lu,C.T. Liu,Y.D. Dong. Effects of atomic bonding nature and size mismatch on thermal stability and glass-forming ability of bulk metallic glasses. Journal of non-crystalline solids,2004,341:93-100
[50]迟宝全.合金非晶形成能力的研究:[硕士学位论文].长春:吉林大学,2003