新型量子点的制备及其应用
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摘要
量子点作为一种新型荧光材料具有优异的光谱特性,如激发波长范围宽、发射光谱窄、斯托克斯位移大、光学稳定性好等。近年来,新型的ZnS-CuInS2和ZnS-AgInS2量子点的合成在国内尚未见到过报道,在国外也尚未见到过其应用。本论文对其合成做了改进,提高了量子点的质量,并对其进行了修饰,可将其进一步应用于生物分析中。我们还首次探究了油溶性的量子点的化学发光性质和其在荧光分析的应用。
本论文分为两章。第一章为综述,主要介绍了量子点的基本概念、性质及其在化学发光、荧光分析中的研究进展。第二章为研究报告,分为四部分,具体内容如下：
一、探索改进合成高质量的新型量子点ZnS-CuInS2
本文采用低价的硝酸铟替代文献中昂贵的不易保存的合成原料之一—碘化铟,应用有机金属法制备了粒径分布均一、稳定性好的高质量的ZnS-CuInS2荧光量子点。这种新型量子点不含有毒性大的重金属元素,可通过只控制原料中Zn/Cu的比例而不改变尺寸来调节ZnS-CuInS2量子点的荧光波长。制备的各种ZnS-CuInS2量子点的荧光量子产率最高为24%,与国外文献报道相比,其荧光量子产率较高。我们对其做了修饰,可以将其进一步应用在生命研究中。
二、探索改进合成高质量的新型量子点ZnS-AgInS2
本文改进了文献中的制备过程,通过热分解前驱体,合成了高质量的ZnS-AgInS2量子点。这种新型量子点不含有毒性大的重金属元素。可通过只控制前驱体的组成而不改变量子点的尺寸得到不同荧光波长的ZnS-AgInS2量子点。制备的各种ZnS-AgInS2量子点的荧光量子产率测定结果最高为31%,与国外文献报道相比,其荧光量子产率较高。我们对其做了修饰,可以将其进一步应用在生命研究中。
三、探索新型量子点ZnS-AgInS2的化学发光性质
量子点作为一种新型的化学发光试剂,已成为化学发光领域关注的研究热点。我们探究了油溶性的ZnS-AgInS2量子点在2,4,6-三氯苯基草酸酯(TCPO)-双氧水(H2O2)化学发光体系中的化学发光性质。
四、探索新型量子点ZnS-AgInS2在新领域中的应用
本文将量子产率最高的油溶性的ZnS-AgInS2量子点作为荧光探针,建立了一种简便、快速检测苏丹红Ⅰ的荧光分析新方法。对此体系的试验条件进行了详细的优化。在选定的最优试验条件下,苏丹红Ⅰ在1.0×10-8～1.0×10-6g/mL浓度范围内与量子点的荧光猝灭程度呈良好的线性关系,检出限为6.0×10-9g／mL。本方法的建立将有助于拓展量子点作为荧光探针在食品安全检测中的应用范围。
The novel quantum dots (QDs) exhibited many excellent optical properties, such as:broade excitation spectrum, narrow emission spectrum, broad stokes displacement, good photostability, and so on. Recently, the synthesis of new-type ZnS-CuInS2 QDs and ZnS-AgInS2 QDs have been no reported in China. There also have been no investigation of the application of ZnS-AgInS2 QDs in China and abroad. In this paper, ZnS-CuInS2 QDs and ZnS-AgInS2 QDs with better quality have been made. We prepared water-soluble fluorescent quantum dots by modification. This is very important and significative for life sciences research. We first report the chemiluminescence properties and the application of oil-soluble ZnS-AgInS2 QDs in fluorescence analysis.
This thesis consists of two parts:review and research section. The basic conception and application of QDs are reviwed in the review section. The research section contains the following four parts:
一、Research on the improvement preparation of a novel high-quality ZnS-CuInS2 QDs
We substituted In(NO3)3 which is much cheaper for InI3 as raw material. High-quality ZnS-CuInS2 QDs were synthesized by metalorganic decomposition. The resultant particles were Mono-dispersedand colloidally stable. This new-type ZnS-CuInS2 QDs contain no highly toxic heavy elements. The photoluminescence wavelength of ZnS-CuInS2 QDs were adjusted by altering the ratio of content of Zn and Cu. The highest quantum yield for ZnS-CuInS2 QDs was calculated to be 24%. The yield was better than those reported in former references. Water-soluble ZnS-CuInS2 QDs were prepared by modification. This is very important and significative for life sciences research.
二、Research on the improvement preparation of a novel high-quality ZnS-AgInS2 QDs
High-quality ZnS-AgInS2 QDs were prepared by thermal decomposition of precursor power. This new-type ZnS-AgInS2 QDs contain no highly toxic heavy elements. The resulting particles exhibited broad excitation spectra and the emission color could be tuned from green to red, depending on their chemical composition. The highest quantum yield for ZnS-AgInS2 QDs was calculated to be 31%. The yield was better than those reported in former references. Water-soluble ZnS-AgInS2 QDs were prepared by modification.The modified ZnS-AgInS2 QDs have the great potential for use in life science research.
三、Research on the chemiluminescence properties of ZnS-AgInS2 QDs
QDs as a new type of chemiluminescence reagents is developed in recent years. In particular, it has become a hot topic in luminescence research. We study on the chemiluminescence properties of oil-soluble ZnS-AgInS2 QDs in TCPO-H2O2 chemiluminescence system.
四、Research on the analytical application of ZnS-AgInS2 QDs in food safety testing
With the highest quantum yield oil-soluble ZnS-AgInS2 QDs as fluorescence probe, we propose a very simple and fast method for detecting Sudan I. Under the optimum conditions, the relative fluorescence intensity decreases linearly with the Sudan I concentration in the range from 0.01 to 1.00μg/mL, and the detection limit is 0.006μg/mL. This extend the application of QDs in food safety detection
本论文分为两章。第一章为综述,主要介绍了量子点的基本概念、性质及其在化学发光、荧光分析中的研究进展。第二章为研究报告,分为四部分,具体内容如下：
一、探索改进合成高质量的新型量子点ZnS-CuInS2
本文采用低价的硝酸铟替代文献中昂贵的不易保存的合成原料之一—碘化铟,应用有机金属法制备了粒径分布均一、稳定性好的高质量的ZnS-CuInS2荧光量子点。这种新型量子点不含有毒性大的重金属元素,可通过只控制原料中Zn/Cu的比例而不改变尺寸来调节ZnS-CuInS2量子点的荧光波长。制备的各种ZnS-CuInS2量子点的荧光量子产率最高为24%,与国外文献报道相比,其荧光量子产率较高。我们对其做了修饰,可以将其进一步应用在生命研究中。
二、探索改进合成高质量的新型量子点ZnS-AgInS2
本文改进了文献中的制备过程,通过热分解前驱体,合成了高质量的ZnS-AgInS2量子点。这种新型量子点不含有毒性大的重金属元素。可通过只控制前驱体的组成而不改变量子点的尺寸得到不同荧光波长的ZnS-AgInS2量子点。制备的各种ZnS-AgInS2量子点的荧光量子产率测定结果最高为31%,与国外文献报道相比,其荧光量子产率较高。我们对其做了修饰,可以将其进一步应用在生命研究中。
三、探索新型量子点ZnS-AgInS2的化学发光性质
量子点作为一种新型的化学发光试剂,已成为化学发光领域关注的研究热点。我们探究了油溶性的ZnS-AgInS2量子点在2,4,6-三氯苯基草酸酯(TCPO)-双氧水(H2O2)化学发光体系中的化学发光性质。
四、探索新型量子点ZnS-AgInS2在新领域中的应用
本文将量子产率最高的油溶性的ZnS-AgInS2量子点作为荧光探针,建立了一种简便、快速检测苏丹红Ⅰ的荧光分析新方法。对此体系的试验条件进行了详细的优化。在选定的最优试验条件下,苏丹红Ⅰ在1.0×10-8～1.0×10-6g/mL浓度范围内与量子点的荧光猝灭程度呈良好的线性关系,检出限为6.0×10-9g／mL。本方法的建立将有助于拓展量子点作为荧光探针在食品安全检测中的应用范围。
The novel quantum dots (QDs) exhibited many excellent optical properties, such as:broade excitation spectrum, narrow emission spectrum, broad stokes displacement, good photostability, and so on. Recently, the synthesis of new-type ZnS-CuInS2 QDs and ZnS-AgInS2 QDs have been no reported in China. There also have been no investigation of the application of ZnS-AgInS2 QDs in China and abroad. In this paper, ZnS-CuInS2 QDs and ZnS-AgInS2 QDs with better quality have been made. We prepared water-soluble fluorescent quantum dots by modification. This is very important and significative for life sciences research. We first report the chemiluminescence properties and the application of oil-soluble ZnS-AgInS2 QDs in fluorescence analysis.
This thesis consists of two parts:review and research section. The basic conception and application of QDs are reviwed in the review section. The research section contains the following four parts:
一、Research on the improvement preparation of a novel high-quality ZnS-CuInS2 QDs
We substituted In(NO3)3 which is much cheaper for InI3 as raw material. High-quality ZnS-CuInS2 QDs were synthesized by metalorganic decomposition. The resultant particles were Mono-dispersedand colloidally stable. This new-type ZnS-CuInS2 QDs contain no highly toxic heavy elements. The photoluminescence wavelength of ZnS-CuInS2 QDs were adjusted by altering the ratio of content of Zn and Cu. The highest quantum yield for ZnS-CuInS2 QDs was calculated to be 24%. The yield was better than those reported in former references. Water-soluble ZnS-CuInS2 QDs were prepared by modification. This is very important and significative for life sciences research.
二、Research on the improvement preparation of a novel high-quality ZnS-AgInS2 QDs
High-quality ZnS-AgInS2 QDs were prepared by thermal decomposition of precursor power. This new-type ZnS-AgInS2 QDs contain no highly toxic heavy elements. The resulting particles exhibited broad excitation spectra and the emission color could be tuned from green to red, depending on their chemical composition. The highest quantum yield for ZnS-AgInS2 QDs was calculated to be 31%. The yield was better than those reported in former references. Water-soluble ZnS-AgInS2 QDs were prepared by modification.The modified ZnS-AgInS2 QDs have the great potential for use in life science research.
三、Research on the chemiluminescence properties of ZnS-AgInS2 QDs
QDs as a new type of chemiluminescence reagents is developed in recent years. In particular, it has become a hot topic in luminescence research. We study on the chemiluminescence properties of oil-soluble ZnS-AgInS2 QDs in TCPO-H2O2 chemiluminescence system.
四、Research on the analytical application of ZnS-AgInS2 QDs in food safety testing
With the highest quantum yield oil-soluble ZnS-AgInS2 QDs as fluorescence probe, we propose a very simple and fast method for detecting Sudan I. Under the optimum conditions, the relative fluorescence intensity decreases linearly with the Sudan I concentration in the range from 0.01 to 1.00μg/mL, and the detection limit is 0.006μg/mL. This extend the application of QDs in food safety detection
引文
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