铅的配位聚合物的水热合成、结构表征和性质研究
摘要
本论文主要研究在水热合成条件下,铅的配位聚合物的合成、结构和性质。讨论了pH值,配比,温度等条件对合成的影响,并利用多种手段进行了表征。旨在进一步研究铅的配位聚合物的合成规律和结构多样性,开发其潜在应用价值。本论文主要结果有:
1. Pb(II)和Cd(II)与甲基橙反应,得到了3个含有pH指示剂的配位化合物Pb(MO)(phen)Cl(1),Pb(MO)2(phen)2(H2O)(2)和[Cd(en)2(H2O)2](MO)2(3)。化合物1中甲基橙的磺酸根及氯离子作为桥联基团,构筑成了一维的配位聚合物。化合物3是由氢键连接[Cd(en)2(H2O)2]2+和MO构成的二维超分子配合物,在酸碱性溶液与酸碱性气体中都有较好的稳定性,具有作为固体pH指示剂的潜在应用价值。
2.通过水热合成的方法,合成了5个新颖的以芳香多羧酸为配体的Pb(II)的配位聚合物Pb13Na(μ3-O)(μ3-OH)(BDC)12(4),Pb4(μ4-O)(H2O)(1,3-BDC)3(5),Pb(C8H4O4)(6),[Pb2(H2O)2(HBTC)2]·3H2O (7),Pb2(1,4-BDC)(ox)(H2O)3(8)。化合物4中首次出现了以Na离子为中心的Pb12正二十面体簇以及规则的Pb12O20笼结构。化合物5中含有四核铅簇结构单元,以它为节点形成了三维的新颖拓扑结构。化合物6和化合物8中的Pb-Pb弱相互作用形成了相似的蜂巢状二维拓扑结构。初步推测了化合物8中原位反应机理。
3.合成了5个脂肪多羧酸与Pb(II)形成的配位聚合物: [Pb6(H2O)2(cit)4]?3H2O (9),Pb(tar)(H2O)2 (10),Pb(C6H8O4) (11),Pb(C4H4O4) (12),Pb2(C6H6NO6)(NO3) (13)。化合物9,11,12为三维的无限结构,化合物10为一维的链状结构,由氢键连接成三维的超分子配位聚合物。化合物13为nta构筑的三维的配位聚合物,这是首个Pb(II)和nta配体形成的高维的网络结构。
Crystal engineering is involved with the behavior of molecules or chemical groups within the crystal lattice, the control of crystal design and properties, and the prediction of crystal structures. Recently, the new research fields in the crystal engineering contain inorganic-organic hybrid materials, microporous material, molecular magnet and coordination polymers, et al. The design and synthesis of coordination polymers with unusual structures and properties are attracting increasing attention, not only for their interesting molecular topologies, but also for their potential applications as functional materials. With the broad use of the hydrothermal technique and the development of the analytical method, the coordination polymers are developed rapidly. Recently, the research on coordination polymer is mostly concentrated on the transition metals, while the main groups are rarely reported. Lead(II) compounds have unique structure and broad use. The aim of this work is to design and synthesize a series of metal-organic coordination polymers of Pb via the interaction between the metal and the ligands. In this thesis, a series of Pb(II) coordination polymers are synthesized, and their structures and properties are investigated. In the first chapter of five, the concepts, research methods, histories and new developments of coordination polymers are introduced. At the end of this chapter, we pointed out the importance of the search project and summarized the important results obtained in the thesis
In the second chapter, the Pb(II) and Cd(II) coordination polymers containing methyl orange which was used as pH indicator were synthesized for the first time under hydrothermal conditions. The synthetical conditions and the spectra of them were discussed. Methyl orange , Pb(NO3)2 and HCl resulted an one-dimensional coordination polymer Pb(MO)(phen)Cl (1) with chain-like structure connecting by the sulfonic group and Cl- anion. In this compound, the chains are interlaced to each other and give form to a supramolecular structure like slide fasteners. 1 is the first coordination polymer built up by methyl orange and Pb(II). In similar hydrothermal condition, with the reactant HCl changing into HNO3, compound 2 was obtained. Compound 2 has zero-dimensional structure with the neutral Pb(MO)2(phen)2(H2O) molecule as a unit, in which each Pb coordinates to two MO and two phen molecules. It is the Van der Waals interactions that assemble the Pb(MO)2(phen)2(H2O) units in compound 2 into three-dimensional structure. [Cd(en)2(H2O)2](MO)2 (3) was synthesized by Cd(II) salt and MO. In compound 3, there are two en and two H2O molecules coordinated with Cd center to form a [Cd(en)2(H2O)2]2+ unit. [Cd(en)2(H2O)2]2+ units and methyl orange anions are linked by H-bonds to form a 2-D supramolecular compound. The synthetic condition, characteristic of the structure, the response of IR and Raman spectrum to pH were discussed. The stability in acid and basic condition of 3 was primarily validated.
In the third chapter, five Pb(II) coordination polymers constructed by the aromatic polycarboxylic acid Pb13Na(μ3-O)(μ3-OH)(BDC)12 (4), Pb4(μ4-O)(H2O)(1,3-BDC)3 (5), Pb(C8H4O4) (6), [Pb2(H2O)2(HBTC)2]·3H2O (7) Pb2(1,4-BDC)(ox)(H2O)3 (8) were synthesized. Compound 4, 5, 6 were synthesized under similar condition. They are all three-dimensional coordination polymers. Compound 4 was synthesized from Pb(II) and 1,3-BDC. The Pb12 cluster with a Na atom in center and the Pb12O20 cage constructed by the Pb12 cluster and twenty O atoms in compound 4 are reported for the first time. The diameter of inscribed sphere of the Pb12O20 cage is about 7.52?. The Pb12O20 cages are connected to each other via PbO8 units and form an infinite Pb-O chain.
The coordination geometry of Pb1 and Pb2 ions in compound 4 are hemidirected, although the coordination numbers of them are high. It’s the rigidity of the cluster that resists the symmetrical distribution of the bonds of Pb in a whole coordination sphere. In comparison with Pb1 and Pb2, Pb3 has less coordination number but holodirected geometry. In similar condisions with 4, compound 5 was obtained with a novel four-nucleus Pb cluster in it. In this cluster, four Pb ions occupy the vertexes of tetrahedron and aμ4-O atom occupies the center. They are connected by 1,3-BDC lignads to form an infinite three-dimensional framework with complicated topological structure. Compound 6 is a three-dimenstional framework, in which each Pb connects to six BDC molecules. The structure of compound 6 is also considered to be obtained from an infinite two-dimensional layer upheld by BDC. The interactions between Pb ions connect Pb ions into an infinite two-dimensional layer with honeycomb structure. Between each two adjacent Pb ions, there are twoμ2-O atoms. Compound 7 is a three-dimensional structure constructing from one-dimenstional chains by weak Pb-O bonds which are formed from the Pb ions and the O atoms on the protonized carboxyl of BTC on the other chain. Compound 8 is a three-dimensional coordination polymer containing BDC ligand and ox ligand which come from in-situ reaction. In this part, the effect of the weak coordination bonds on the coordination number, dimensionality, stability were also discussed. The mechanism of the in-situ reaction was analyzed.
In hydrothermal condition, several Pb(II) coordination polymers with flexible aliphatic acid ligand [Pb6(H2O)2(cit)4]?3H2O (9),Pb(tar)(H2O)2 (10),Pb(C6H8O4) (11),Pb(C4H4O4) (12),Pb2(C6H6NO6)(NO3) (13) were synthesized. The effect of the temperature, ratio of the reactant on the synthesis were discussed. Compound 9, 11, 12 have three-dimensional structure, while compound 10 is one-dimensional chain-like framework, which is connected to three-dimensional supramolecular structure by H-bonds. Compound 13 is the first Pb(II) three-dimensional coordination polymer containing nta ligand. The similar Pb2(CO2)2 units forming by two Pb ions and two carboxyls in the compound 11, 12, 13 were investigated. In compound 13, the Pb2(CO2)2 unit is separate from each other, while it is connected into one-dimensional parallel chains in compound 11 and three-dimensional framework by sharing Pb ions in compound 12.
1. Pb(II)和Cd(II)与甲基橙反应,得到了3个含有pH指示剂的配位化合物Pb(MO)(phen)Cl(1),Pb(MO)2(phen)2(H2O)(2)和[Cd(en)2(H2O)2](MO)2(3)。化合物1中甲基橙的磺酸根及氯离子作为桥联基团,构筑成了一维的配位聚合物。化合物3是由氢键连接[Cd(en)2(H2O)2]2+和MO构成的二维超分子配合物,在酸碱性溶液与酸碱性气体中都有较好的稳定性,具有作为固体pH指示剂的潜在应用价值。
2.通过水热合成的方法,合成了5个新颖的以芳香多羧酸为配体的Pb(II)的配位聚合物Pb13Na(μ3-O)(μ3-OH)(BDC)12(4),Pb4(μ4-O)(H2O)(1,3-BDC)3(5),Pb(C8H4O4)(6),[Pb2(H2O)2(HBTC)2]·3H2O (7),Pb2(1,4-BDC)(ox)(H2O)3(8)。化合物4中首次出现了以Na离子为中心的Pb12正二十面体簇以及规则的Pb12O20笼结构。化合物5中含有四核铅簇结构单元,以它为节点形成了三维的新颖拓扑结构。化合物6和化合物8中的Pb-Pb弱相互作用形成了相似的蜂巢状二维拓扑结构。初步推测了化合物8中原位反应机理。
3.合成了5个脂肪多羧酸与Pb(II)形成的配位聚合物: [Pb6(H2O)2(cit)4]?3H2O (9),Pb(tar)(H2O)2 (10),Pb(C6H8O4) (11),Pb(C4H4O4) (12),Pb2(C6H6NO6)(NO3) (13)。化合物9,11,12为三维的无限结构,化合物10为一维的链状结构,由氢键连接成三维的超分子配位聚合物。化合物13为nta构筑的三维的配位聚合物,这是首个Pb(II)和nta配体形成的高维的网络结构。
Crystal engineering is involved with the behavior of molecules or chemical groups within the crystal lattice, the control of crystal design and properties, and the prediction of crystal structures. Recently, the new research fields in the crystal engineering contain inorganic-organic hybrid materials, microporous material, molecular magnet and coordination polymers, et al. The design and synthesis of coordination polymers with unusual structures and properties are attracting increasing attention, not only for their interesting molecular topologies, but also for their potential applications as functional materials. With the broad use of the hydrothermal technique and the development of the analytical method, the coordination polymers are developed rapidly. Recently, the research on coordination polymer is mostly concentrated on the transition metals, while the main groups are rarely reported. Lead(II) compounds have unique structure and broad use. The aim of this work is to design and synthesize a series of metal-organic coordination polymers of Pb via the interaction between the metal and the ligands. In this thesis, a series of Pb(II) coordination polymers are synthesized, and their structures and properties are investigated. In the first chapter of five, the concepts, research methods, histories and new developments of coordination polymers are introduced. At the end of this chapter, we pointed out the importance of the search project and summarized the important results obtained in the thesis
In the second chapter, the Pb(II) and Cd(II) coordination polymers containing methyl orange which was used as pH indicator were synthesized for the first time under hydrothermal conditions. The synthetical conditions and the spectra of them were discussed. Methyl orange , Pb(NO3)2 and HCl resulted an one-dimensional coordination polymer Pb(MO)(phen)Cl (1) with chain-like structure connecting by the sulfonic group and Cl- anion. In this compound, the chains are interlaced to each other and give form to a supramolecular structure like slide fasteners. 1 is the first coordination polymer built up by methyl orange and Pb(II). In similar hydrothermal condition, with the reactant HCl changing into HNO3, compound 2 was obtained. Compound 2 has zero-dimensional structure with the neutral Pb(MO)2(phen)2(H2O) molecule as a unit, in which each Pb coordinates to two MO and two phen molecules. It is the Van der Waals interactions that assemble the Pb(MO)2(phen)2(H2O) units in compound 2 into three-dimensional structure. [Cd(en)2(H2O)2](MO)2 (3) was synthesized by Cd(II) salt and MO. In compound 3, there are two en and two H2O molecules coordinated with Cd center to form a [Cd(en)2(H2O)2]2+ unit. [Cd(en)2(H2O)2]2+ units and methyl orange anions are linked by H-bonds to form a 2-D supramolecular compound. The synthetic condition, characteristic of the structure, the response of IR and Raman spectrum to pH were discussed. The stability in acid and basic condition of 3 was primarily validated.
In the third chapter, five Pb(II) coordination polymers constructed by the aromatic polycarboxylic acid Pb13Na(μ3-O)(μ3-OH)(BDC)12 (4), Pb4(μ4-O)(H2O)(1,3-BDC)3 (5), Pb(C8H4O4) (6), [Pb2(H2O)2(HBTC)2]·3H2O (7) Pb2(1,4-BDC)(ox)(H2O)3 (8) were synthesized. Compound 4, 5, 6 were synthesized under similar condition. They are all three-dimensional coordination polymers. Compound 4 was synthesized from Pb(II) and 1,3-BDC. The Pb12 cluster with a Na atom in center and the Pb12O20 cage constructed by the Pb12 cluster and twenty O atoms in compound 4 are reported for the first time. The diameter of inscribed sphere of the Pb12O20 cage is about 7.52?. The Pb12O20 cages are connected to each other via PbO8 units and form an infinite Pb-O chain.
The coordination geometry of Pb1 and Pb2 ions in compound 4 are hemidirected, although the coordination numbers of them are high. It’s the rigidity of the cluster that resists the symmetrical distribution of the bonds of Pb in a whole coordination sphere. In comparison with Pb1 and Pb2, Pb3 has less coordination number but holodirected geometry. In similar condisions with 4, compound 5 was obtained with a novel four-nucleus Pb cluster in it. In this cluster, four Pb ions occupy the vertexes of tetrahedron and aμ4-O atom occupies the center. They are connected by 1,3-BDC lignads to form an infinite three-dimensional framework with complicated topological structure. Compound 6 is a three-dimenstional framework, in which each Pb connects to six BDC molecules. The structure of compound 6 is also considered to be obtained from an infinite two-dimensional layer upheld by BDC. The interactions between Pb ions connect Pb ions into an infinite two-dimensional layer with honeycomb structure. Between each two adjacent Pb ions, there are twoμ2-O atoms. Compound 7 is a three-dimensional structure constructing from one-dimenstional chains by weak Pb-O bonds which are formed from the Pb ions and the O atoms on the protonized carboxyl of BTC on the other chain. Compound 8 is a three-dimensional coordination polymer containing BDC ligand and ox ligand which come from in-situ reaction. In this part, the effect of the weak coordination bonds on the coordination number, dimensionality, stability were also discussed. The mechanism of the in-situ reaction was analyzed.
In hydrothermal condition, several Pb(II) coordination polymers with flexible aliphatic acid ligand [Pb6(H2O)2(cit)4]?3H2O (9),Pb(tar)(H2O)2 (10),Pb(C6H8O4) (11),Pb(C4H4O4) (12),Pb2(C6H6NO6)(NO3) (13) were synthesized. The effect of the temperature, ratio of the reactant on the synthesis were discussed. Compound 9, 11, 12 have three-dimensional structure, while compound 10 is one-dimensional chain-like framework, which is connected to three-dimensional supramolecular structure by H-bonds. Compound 13 is the first Pb(II) three-dimensional coordination polymer containing nta ligand. The similar Pb2(CO2)2 units forming by two Pb ions and two carboxyls in the compound 11, 12, 13 were investigated. In compound 13, the Pb2(CO2)2 unit is separate from each other, while it is connected into one-dimensional parallel chains in compound 11 and three-dimensional framework by sharing Pb ions in compound 12.
引文
[1] A. Werner, Z. Anorg. Chem. 1893, 3, 26
[2] O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim, Nature, 2003, 423, 705
[3] G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, Acc. Chem. Res., 2005, 38, 176
[4] S. L. James, Chem. Soc. Rev., 2003, 32, 276.
[5] S. Kitagawa, R. Kitaura, S. I. Noro, Angew. Chem. Int. Ed., 2004, 43, 2334
[6] C. N. R. Rao, S. Natarajan, R. Vaidhyanathan, Angew. Chem. Int. Ed., 2004, 43, 1466
[7] 王磊,“1,2,4-苯三酸及琉基多氮杂环构筑的配位聚合物水热合成、结构与性质表征”,吉林大学博士论文,2006
[8] Yu-Bin Dong, Peng Wang, Jian-Ping Ma, Xia-Xia Zhao, Hai-Ying Wang, Bo Tang, Ru-Qi Huang, J. Am. Chem. Soc., 2007, 129, 4872
[9] Banerjee, A.; Sarkar, S.; Chopra, D.; Colacio, E.; Rajak, K. K. Inorg. Chem., 2008,10, 4023
[10] Jiang, Y.-S.; Yao, H.-G.; Ji, S.-H.; Ji, M.; An, Y.-L. Inorg. Chem, 2008,10,3922.
[11] Horike, S.; Dinca,? M.; Tamaki, K.; Long, J. R. J. Am. Chem. Soc., 2008, 18, 5854
[12] 何江华,吉林大学博士论文,2005.
[13] Dao-Jun Zhang, Tian-You Song, Ping Zhang, Jing Shi, Ying Wang, Li Wang, Kui-Rong Ma, Wei-Rong Yin, Jie Zhao, Yong Fan, Jia-Ning Xu, Inorganic Chemistry Communications, 2007, 10, 876
[14] X. Xue, X. S. Wang, R. G. Xiong, X. Z. You, B. F. Abrahams, C. M. Che, H. X. Ju, Angew. Chem. Int. Ed. 2002, 41, 2944.
[15] K. Kobayashi, A. Sato, S. Sakamoto, K. Yamaguchi, J. Am. Chem. Soc.,2003, 125, 3035.
[16] Dao-Jun Zhang, Tian-You Song, Jing Shi, Wei-Rong Yin, Ping Zhang, Li Wang, Ying Wang, Kui-Rong Ma, Yong Fan, Jia-Ning Xu, Inorganic Chemistry Communications, 2007, 10, 1067
[17] F. A, A. Paz, J. Klinowski, Chem. Commu., 2003, 1484.
[18] Daiguebonne, C., Kerbellec, N., Guillou, O., Bünzli, J.-C., Gumy, F., Catala, L., Mallah, T., Audebrand, N., Gérault, Y., Bernot, K., Calvez, G., Inorg. Chem., 2008, 9, 3700
[19] N.L. Rosi, J.Kim, O.M. Yaghi,J. Am. Chem. Soc., 2005, 127, 1504-
[20] Li, S.-L., Lan, Y.-Q., Ma, J.-F., Fu, Y.-M, Yang, J.; Ping, G.-J., Liu, J., Su, Z.-M. Cryst. Growth Des., 2008, 5, 1610
[21] Neogi, S.,Navarro, J. A. R., Bharadwaj, P. K.,Cryst. Growth Des., 2008, 5, 1554
[22] Q.R. Fang, G. S. Zhu, S. L. Qiu, Angew. Chem. Int. Ed., 2007, 46, 6638
[23] Z. Ni, A. Yassar, T. Antoun, O. M. Yaghi, J. Am. Chem. Soc., 2005, 127, 12752
[24] D.Kong, A. Clearfield, Cryst. Growth Des., 2005, 5, 1263
[25] C. V. K. Sharma, A. Clearfield,J. Am. Chem. Soc. 2001, 123, 2885-2886
[26] G. G. Briand, Neil Burford, M. D. Eelman, N. Aumeerally, L. Chen, T.S.Cameron, K. N. Robertson, Inorg. Chem., 2004, 43, 6495
[27] X Li, R. Cao, W. Bi, Y. Wang, Y. Wang, X. Li, Z. Guo, Cryst. Growth Des., 2005, 5, 1651
[28] X. Li, X. Wang, S. Gao, R. Cao, Inorg. Chem., 2006, 45, 1508
[29] W. Zheng, X. Liu, J. Guo, L. Wu , D. Liao, Inorg. Chim. Acta ,2004, 357, 1571
[30] N. Hao, F. Liu, E. Wang, R. Huang, Y. Li,C. Hu, Inorg.Chem.Commun. 2003, 6, 728
[315] X. Hu, J. Xu, P. Cheng, Inorg. Chem., 2004, 43, 2261
[32] B.Zhao, L. Yi, P. Cheng, Inorg. Chem.Commun. , 2004, 7, 971
[33] D. Gatteschi, Adv. Master., 1994, 6, 635.
[34] H.Chun, D. Kim, D. N. Dybtsev, K.Kim, Angew. Chem. Int. Ed., 2004, 43, 971.
[35] B.L. Chen, Y. Yang, F. Zapata, G.N. Lin, G.D. Qian, E. B. Lobkovsky, Adv. Mater., 2007, 19, 1693.
[36]B. V. Harbuzaru, A. Corma, F. Rey, P.Atienzar, J. L. Jord, H. García, D. Ananias, Luis D. Carlos, J. Rocha, Angew. Chem. Int. Ed., 2008, 47, 1080
[371] P. J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. Int. Ed., 1999, 38, 2638
[38] L. R. MacGillivray, S. Subramanian, M. J. Zaworotko, Chem.Commun., 1994, 1325
[39] Lloret, G. DeMunno, M. Julve, J. Cano, R. Ruiz, A. Caneschi, Angew. Chem. Int. Ed., 1998, 37, 135
[40] M. Yaghi, H. Li, J. Am. Chem. Soc., 1995, 117, 10401
[41] M. Yaghi, G. M. Li, Angew. Chem. Int. Ed., 1995, 34, 207
[42] P. Losier, M. J. Zaworotko , Angew. Chem. Int. Ed., 1996, 35, 2779
[43] M. Yaghi, H. Li, T. L. Groy, Inorg. Chem., 1997, 36, 4292
[44] Martin, D. P., Supkowski, R. M., LaDuca, R. L.Inorg. Chem., 2007,19, 7917
[45] Liao, J.-H.; Wu, P.-C.; Huang, W.-C., Cryst. Growth Des., 2006, 5, 1062
[46] Yang, G.-D.; Dai, J.-C.; Lian, Y.-X.; Wu, W.-S.; Lin, J.-M.; Hu, S.-M.; Sheng, T.-L.; Fu, Z.-Y.; Wu, X.-T.,Inorg. Chem., 2007, 19, 7910
[47] Zhang, L.-Y.,Zhang, J.-P.; Lin, Y.-Y., Chen, X.-M.,Cryst. Growth Des., 2006, 7, 1684
[48] D. F. Sun, R. Cao, Y. C. Liang, Q. Shi, W. P. Su, M. C. Hong, J. Chem. Soc. Dalton.Trans., 2001, 2335.
[49] R. Cao, D. Sun, U. Liang, M. Hong, K. Tatsumi, Q. Shi, Inorg. Chem., 2002, 41, 2087.
[50] Biemmi, E.; Scherb, C.; Bein, T., J. Am. Chem. Soc., 2007, 26, 8054
[51] L. A. Gerrard, P. T. Wood, Chem. Commnu., 2000, 2107
[52] (a)H. Cui, Z. M. Wang, K. Takahashi, Y. Okano, H. Kobayashi, A. Kobayashi, J. Am. Chem. Soc., 2006, 128, 15074. (b)P. M. Forster, A. K. Cheetha, Angew. Chem. Int. Ed., 2002, 41, 457.
[53] 叶俊伟,“5-硝基间苯二甲酸桥联配体构筑的超分子配位聚合物的合成、结构及性能研究”,吉林大学博士论文,2007
[54] 赵斌, “d-f 混合金属配位聚合物的合成和性质研究”,南开大学博士论文,2004.
[55] B. Zhao, L. Yi, Y. Dai, X. Y. Chen, P. Cheng, D. Z. Liao, S. P. Yan, Z. H. Jiang, Inorg. Chem., 2005, 44, 911.
[56] B. Zhao, P. Cheng, Y. Dai, C. Cheng, D. Z. Liao, S. P. Yan, Z. H. Jiang, G. L. Wang, Angew. Chem. Int. Ed.,2003, 42, 934.
[57] B. Zhao, P. Cheng, X. Y. Chen, W. Shi, D. Z. Liao, S. P. Yan, Z. H. Jiang, J. Am. Chem. Soc., 2004, 126, 3012.
[58] 迈克尔.波普著,王恩波等译,杂多和同多金属氧酸盐,吉林大学出版社,1991.
[59] Wu, P., Volkmer, D.; Bredenkotter..B., Kurth, D. G., Rabe, J. P., Langmuir,2008, 6, 2767
[60] R. S. Rarig, R. Lam, P. Y. Zavalij, J. K. Ngala, R. L. LaDuca, J. E. Greedan, J. Zubieta,Inorg. Chem., 2002, 41, 2124.
[61] H. Y. An, E. B. Wang, Z. M. Su, L. Xu, Angew. Chem. Int. Ed., 2006, 45, 904.
[62] X. L. Wang, C. Qin, E. B. Wang, Z. M. Su, L. Xu, Angew. Chem. Int. Ed., 2004, 43, 5036.
[63] X. L. Wang, E. B. Wang, Y. G. Li, Z. M. Su, L. Xu, L. Carlucci, Angew. Chem. Int. Ed., 2005, 44, 5824.
[64].X. Wang, Y. Guo, Y. Li, E. B. Wang,.Inorg. Chem., 2003, 42, 4135.
[65] X. L. Wang, C. Qin, E. B. Wang, Z. M. Su, Y.G. Li, L. Xu, Angew. Chem. Int. Ed., 2006, 45, 7411.
[66] 孙道峰,“新型含羧基及磺酸基配体超分子化合物的设计合成、结构解析及性能研究”,中国科学院研究生院博士学位论文,2003
[67] (a)A. P. Coté, G. K. H. Shimizu, Coord. Chem. Rev., 2003, 245, 49. (b)J. W. Cai , Coord. Chem. Rev., 2004, 248, 1061.
[68] E. K. H. Shimizu,G. D. Enright, C. I. Ratclife, G. S. Rego, J. L. Reid, J. A. Ripmeester, Chem. Mater., 1998, 10, 3282
[69] E. K. H. Shimizu, G. D. Enright, C. I. Ratclife, K. F. Pr eston, J. L. Reid, J.A. Ripmeester, Chem. Commun.,1999,1485.
[70] S. K. Makinen, N. J. Melcer, M. Parvez, G. K. H. Shimizu, Chem. Eur. J.,2001, 23, 5176
[71] J. Q. Yu, A. P. Cotd, G. D. Enright, and Q. K. H. Shimizu , Inorg. Chem., 2001, 40, 582
[72] B. D. Chandler, D. T. Cramb, and G. K. H. Shimizu, J. Am. Chem. Soc., 2006, 128, 10403
[73] Maheswari, P. U.; van der Ster, M.; Smulders, S.; Barends, S.; van Wezel, G. P.; Massera, C.; Roy, S.; den Dulk, H.; Gamez, P.; Reedijk, J., Inorg. Chem.; 2008, 9, 3719
[74] Jian-Kai Cheng,Yuan-Gen Yao, Jian Zhang, Zhao-Ji Li, Zong-Wei Cai, Xiang-You Zhang,Zhong-Ning Chen,Yu-Biao Chen, Yao Kang,Ye-Yan Qin, Yi-Hang Wen, J. Am. Chem. Soc. 2004, 126, 7796
[75] Forniés, J.; García, A.; Lalinde, E.; Moreno, M. T.,Inorg. Chem., 2008, 9, 3651
[76] M. Ali, A. Ray, W. s. Sheldrick, H. Mayer-figge, S. Gao, A. I. Sahmes, New J. Chem., 2004, 28,412
[77] Li, D.; Shi, W.-J.; Hou, L., Inorg. Chem., 2005, 11, 3907
[78] Bhosekar G.,Jess I., Nather C., Inorg. Chem, 2006, 16, 6508
[79] I. P. Y. Shek, W. T. Wong, S. Gao, T. C. Lau, New J. Chem.,2002, 26, 1099.
[80] Pronold, M.; Scheer, M.; Wachter, J.; Zabel, M.,Inorg. Chem.,2007, 4, 1396
[81] Gu, X.; Xue, D., Inorg. Chem.; 2007; 13; 5349
[82] Ichikawa, S.; Kimura, S.; Takahashi, K.; Mori, H.; Yoshida, G.; Manabe, Y.; Matsuda, M.; Tajima, H.; Yamaura, J.-i., Inorg. Chem., 2008, 10, 4140
[83] 顾金忠, 姜隆, 梁钜红, 鲁统部, 谭民裕,无机化学学报, 2006, 8, 1375
[84] 梁淑惠, 车云霞, 郑吉民, 无机化学学报, 2005, 10, 1520
[85] B. F. Abrahams, B. F. Hoskins, R. Robson, J. Am. Chem. Soc., 1991, 113, 3606; (b) S. R. Baten, R. Robson, Angew. Chem. Int Ed. Engl., 1998, 37, 146 (c)卢静,“含氮、氧及卤素配体的过渡金属配合物的合成、结构与性能”,吉林大学博士论文,2006
[86] D.A. Brown et al., Inorg. Chim. Acta, 2004, 357, 1411
[87] 牛淑云,金晶,范洪涛, 辽宁师范大学学报(自然科学版), 2002,25. 398
[88] K.T. Holman, H.H. Hammud, S. Isber, M. Tabbal, Polyhedron, 2005, 24, 221.
[89] H.J. Choi, M. P. Suh, Inorg. Chem. 1999, 38, 6309.
[90] (a)X. M. Chen, G. F. Liu, Chem. Eur.J. 2002, 4811. (b) L. Yi, X.Yang, T. Lu, P. Cheng. Cryst. Growth Des., 2005, 5, 1215
[91] C. Chen, D. Xu, Y. Xu, C. Cheng, R. Ling, Acta Cryst. 1992, 48, 1231.
[92] H.K. Fun,; S. S. S. Raj, R. G. Xiong, J. L. Zuo, Z. Yu, X. L. Zhu, X. Z. You, J. Chem. Soc. Dalton Trans., 1999, 1711.
[93] S. D. Huang, R. G. Xiong, Polyhedron, 1997, 16, 3929.
[94] L. Carlucci, G. Ciani, D. M. Proserpio, Chem. Commun., 1999, 449.
[95] M. L. Tong, H. J.Chen, X. M. Chen, Inorg. Chem., 2000, 39, 2235.
[96] Yanjuan Qi, Yonghui Wang, Changwen Hu, Inorg. Chem., 2003, 42, 8519
[97]R. Kitaura, F. Iwahori. Inorg. Chem., 2004, 43, 6522
[98] M. Du, X. J. Zhao, Inorg. Chem. Commun., 2004, 1056.
[99] G. B. Gardner, D. Venkataraman, J. S. Moore, S. Lee, Nature, 1995, 374, 792.
[100] K. N. Power, T. L. Hennigar, M. J. Zaworotko, Chem. Commun., 1998, 595.
[101] L. Carlucci, N. Cozzi, G. Ciani, M. Moret, D. M. Proserpio, S. Rizzato, Chem. Commun., 2002, 1354.
[102] B. Rather, B. Moulton, R. D. B. Walsh, M. J. Zaworotko, Chem. Commun. ,2002, 694.
[103] H. Gudbjartson, K. Biradha, K. M. Poirier, M. J. Zaworotko, J. Am. Chem. Soc., 1999, 121, 2599.
[104] B.Chen, N.W. Ockwig, O.M. Yaghi, Inorg. Chem., 2005, 44, 181
[105] M. Eddaoudi, J. Kim, M.l O’Keeffe, O. M. Yaghi, J. Am. Chem. Soc., 2002, 124, 376
[106] Andrea C. Sudik, Adrien P. Cote, Omar M. Yaghi, Inorg. Chem., 2005, 44, 2998
[107] B. G. Lor, E. G. Puebla, M. Iglesias, M. A. Monge, Chem. Mater., 2005, 17, 2568
[108] Seo J. S., Whang D., Lee H. Nature, 2000, 404, 982.
[109] J. Zhang, J. Ensling, V. Ksenofontov, P. Gütlich, A. J. Epstein, J. S. Miller, Angew. Chem. Int. Ed., 1998, 37, 657
[110] K. R. Dunbar, Angew. Chem. Int. Ed., 1996, 35, 1659
[111] H. Zhao, R. A. Heintz, R. d. Rogers, K. R. Dunbar, J. Am. Chem. Soc., 1996, 118, 12844.
[112] H. Wang, H. Li, B.i Xue, Z. Wang, J. Am. Chem. Soc., 2005, 127, 6394
[113] K. Li, Z. Xu, Chem. Mater., 2005, 17, 4426
[114] S. Liu, T. K. Sowa, Inorg. Chem., 2005, 44, 1031
[115] T. Y. Shvareva, T. A. Sullens, Inorg.Chem., 2005, 44, 300
[116] R. Custelcean, M. G. Gorbunova, J. Am. Chem. Soc., 2005, 127, 16362
[117] Y. Liao, Y. Jiang, S. Wang. J. Am. Chem. Soc., 2005, 127, 12794
[118] H. Kim, W. Kim, A. J. Lough, J. Am. Chem. Soc., 2005, 127, 16776
[119] (a)O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim, Nature, 2003, 423, 705.(b) Antek G. Wong-Foy, Adam J. Matzger, Omar M. Yaghi, J. Am. Chem. Soc. , 2006, 128, 3494 (c)Jesse L. C. Rowsell and Omar M. Yaghi, J. Am. Chem. Soc., 2006, 128, 1304 (d) Andrew R. Millward, Omar M. Yaghi, J. Am. Chem. Soc., 2005, 127, 17998
[120] H. Li, M. Eddaoudi, M. O’keeffe, O. M. Yaghi, Nature, 1999,402, 276
[121] E. Gao, S. Bai, Z. Wang, C. Yan, J. Am. Chem. Soc., 2003, 125, 4984.
[122] C. Serre, F. Millange,C. Thouvenot, M. Noguès, G. Marsolier, D. Lou?r, G. Férey, J. Am. Chem. Soc., 2002, 124, 13519.
[123] G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray, J. D. Cashion, Science, 2002, 298, 1762.
[124] S. Feng, R .Xu, Acc. Chem. Res., 2001, 34, 239.
[125] 徐如人,庞文琴, 无机合成与制备化学, 高等教育出版社, 2001.
[126] N. L. Rosi, M. Eddaoudi, J. Kim, M. O' Keeffe, O. M. Yaghi, CrystEngComm 2002, 4, 401.
[127] X. H. Bu, W. Chen, S. L. Lu, R. H. Zhang, D. Z. Liao, W. M. Bu, M. Shionoya, F. Brisse, J. Ribas, Angew. Chem. Int. Ed., 2001, 40, 3201.
[128] S. A. Barnett, A. J. Blake, N. R. Champness, J. E. B. Nicolson, C. Wilson, J. Chem. Soc.Dalton Trans., 2001, 567.
[129] M. L. Tong, S. Hu, J. Wang, S. Kitagawa, S. W. Ng, Cryst. Growth&Des., 2005, 5, 837.
[130] Y. J. Kim, D. Y. Jung, Chem. Commun., 2002, 908.
[131] 杜淼,卜显和, 阴离子在构筑配位聚合物网络结构中的作用, 无机化学学报, 2003, 1.
[132] L. Carlucci, G. Ciani, P. Macchi, D. M. Proserpio, S. Rizzato, Chem. Eur. J., 1999, 237.
[133] C. S. Cundy, P. A. Cox, Chem. Rev., 2003, 103, 663.
[134] A. J. Norquist, P. M. Thomas, M. B. Doran, D. O’Hare, Chem. Mater., 2002, 14, 5179.
[135] A. J. Norquist, M. B. Doran, P. M. Thomas, D. O’Hare, Inorg. Chem., 2003, 42, 5949.
[136] C. L. Cahill; B. Gugliotta; J. B. Parise, Chem. Commun., 1998, 1715.
[137] C. N. R. Rao, S. Natarajan, S. Neeraj, J. Am. Chem. Soc., 2000, 122, 2810.
[138] Z. Shi, G. Li, L. Wang, L. Gao, X. Chen, J. Hua, S. Feng, Cryst. Growth&Des., 2004, 25.
[139] D. T. Lill, N. S. Guning, C. L. Cahill, Inorg. Chem., 2005, 44, 258.
[140] D. T. Lill, D. J. Bozzutoa, C. L. Cahill, J. Chem. Soc.Dalton Trans., 2005, 2111.
[141] Liat Shimoni-Livny, Jenny P. Glusker, Charles W. Bock, Inorg. Chem. 1998, 37, 1853
[142] Qiong Ye, Yong-Hua Li, Qian Wu, Yu-Mei Song, Ju-Xian Wang, Hong Zhao, Ren-Gen Xiong, Ziling Xue, Chem. Eur. J,. 2005, 11, 988
[143] Magyar, J. S.; Weng, T. C.; Stern, C. M.; Dye, D. F.; Rous, B. W.; Payne, J. C.; Bridgewater, B. M.; Mijovilovich, A.; Parkin, G.; Zaleski, J. M.; Penner-Hahn, J. E.; Godwin, H. A. J.Am. Chem. Soc. 2005, 127, 9495.
[144] Dale, S. H.; Elsegood, M. R. J.; Kainth, S. Acta Crystallogr. 2004, C60, m76
[145] Sai-Rong Fan and Long-Guan Zhu, Inorg. Chem., 2007; 46, 6785
[146] Ali Morsali, Ali Ramazanib. Z. Anorg. Allg. Chem., 2005, 631, 1759
[147] Ali Morsali, Veysel T. Yilmaz, Helvetica Chemica Acta., 2005, 88, 2513
[148] Ali Morsali, Mahmod Payheghader, Saeid Salehi Monfared, Z. Anorg. Allg. Chem., 2002, 628, 12
[149] Yu-Jun Shi, Li-Hong Li, Yi-Zhi Li, Xue-Tai Chen, Ziling Xue ,Xiao-Zeng You, Polyhedron, 2003, 22, 917
[150] Ali Morsali, Veysel T. Yilmaz, Helvetica Chemica Acta., 2005, 88, 2513
[151] Barton H., J. Ziegler Inorg. Chem., 43, 2004, 50
[152] Barton H., J. Ziegler, Inorg. Chem., 41, 2002, 4984
[153] Barton H., J. Ziegler, Inorg. Chem., 44, 2005, 4891
[154] N. Singh, Transition Metal Chemistry, 2002, 27, 359
[155] N. Singh, S. Gupta, Inorg. Chem. Comm., 2003, 6 416
[156] N. Singh,S. Gupta, Transition Metal Chemistry, 2005, 30, 383。
[157] Lin Ke Li,Yu Zhu, Eur. J. Inorg. Chem. 2005, 3238
[158] Gang Li, Yu Zhu/ Inorg.Chem., 42, 2003 4995
[159] Hongwei Hou, Yu Zhu, Inorg. Chem., 42, 2003 3501
[160] Lin Ke Li,Yu Zhu, Eur. J. Inorg. Chem. 2005, 3238
[161] Niu Yun Y,Hou Hong Wei, Chinese Journal of Inorganic Chemistry, 2001, 4, 533
[162] Gupta, B. D.; Sonu, S. Opt. Commun., 1998, 154, 282
[163] Jie, L. Trends Anal. Chem., 2000, 19, 541.
[164] Peterson, J. I.; Goldstein, S. R.; Fitzgerald, P. V. Anal.Chem., 1980, 52, 864
[165] Thomas, P. J.; Marc, D. R. Anal. Chem., 1988, 60, 404
[166] Bacci, M.; Baldini, F.; Bracci, S., Appl. Spectrosc., 1991, 45,1508
[167] Rao, B. S.; Puschett, J. B.; Matyjaszewski, K. J., Appl.Polym.Sci., 1991, 43, 925
[168] Zhang, Z. J.; Zhang, Y. K.; Ma, W. B.; Russell, R.; Shakhsher,Z. M.; Grant, C. L.; Seitz, W. R. Anal. Chem., 1989, 61, 202.
[169] F. R. Zaggouta, N. M. El-Ashgarb, S. M. Zouraba, I. M. El-Nahhala, H. Motaweha, Materials Letters, 2005, 59, 2928
[170] F.R. Zaggout, I.M. El-Nahhal, S.M. Zourab, N.M. El-Ashgar, H.J. Motaweh, J. Dispers. Sci. Technol. 2005, 26, 629
[171] I.M. El-Nahhal, S.M. Zourab, N.M. El-Ashgar, J. Dispers. Sci. Technol. 2001, 22, 583.
[172] Luo, F.L.; Liu, Z.H.; Chen, T.L.; Gong, B.L. Chinese Journal of Chemistry, 2006, 24, 341
[173] Nichola J.Burke; Andrew D.Burrows; Mary F.Mahon; Simon J.Teat. CrysEngComm, 2004, 6, 429
[174] Ales ruzicka, Antonin lycka, Roman jambor Appl. Organometal. Chem., 2003, 17, 168
[175] J. B. Benedict, D. E. Cohen, S. Lovell, Andrew L. Rohl, B. Kahr. J. Am. Chem. Soc., 2006, 128, 5548
[176] Zherebov A. Y., Lachinov A. N. Synth Met., 1992,46, 181.
[177] Scaldin O. A., Selezneva O. A., Lebedev Y. A., Chuvyrov A. N., J. Appl. Phys., 1995, 77, 3194.
[178] J. Song, C. Lei, J. Mao. Inorg. Chem., 2004, 43, 5630M
[179] C. Das, A. Saha, C. Hung. Inorg. Chem., 2003, 42, 198
[180] Q. Guo, W. Zhu, S. Dong. J. Mole. Struc., 2003, 650, 159
[181] R. Custelcean, M. D. Ward. Angew. Chem. Int. Ed.,2002, 41, 1724
[182] (a)Akira Onoda, Yusuke Yamada, Mototsugu Doi, Taka-aki Okamura, Norikazu Ueyama,Inorg. Chem., 2001, 40, 516 (b) Tarlok S. Lobana, Isamu Kinoshita, Kentaro Kimura, Takanori Nishioka,Daisuke Shiomi, Kiyoshi Isobe, Eur. J. Inorg. Chem., 2004, 356(c) Armando Marzotto, Dore Augusto Clemente , Thomas Gerola, Giovanni Valle, Polyhedron, 2001, 20, 1079 (d) R. Custelcean, M. D. Ward, Angew. Chem. Int. Ed., 2002, 41, 1724
[183] (a)Kano N., Komatsu F., Kawashima T., J. Am. Chem. Soc., 2001, 43, 10778 (b)Otsuki J., Suwa K., Narutaki K., Sinha C., Yoshikawa I., Araki K., J. Phys. Chem. A.; 2005; 109, 8064 (c)Das C., Saha A., Hung C. H., Lee G.. H., Peng S. M., Goswami S., Inorg. Chem., 2003, 42, 198
[184] L. Zhu, M. Zeng, B. Ye, X. Chen, Z. Anorg. Allg. Chem., 2004, 630, 952
[185] R. Sharma, R. Sharma, R. Bala, U. Rychlewska, B. Warzajtis, J. Mole. Struc., 2005, 738, 291
[186] Rory H. Uibel, Joel M. Harris. Anal. Chem., 2002, 74, 5112
[187] Trotter, P. J., Appl. Spectrosc., 1977, 31, 30
[188] Bajpai, P. K.; Pal, B.; Baul, T. S. B., J. Raman Spectrosc., 1995, 26, 351
[189] (a)H. Li, M. Eddaoudi, M. O’keeffe, O. M. Yaghi, Nature, 1999, 402, 276.(b)S. S. Y. Chui, S. M. F. Lo, J. P. H. Charmant, A. G. Orpen, I. D. Williams, Science, 1999, 283, 1148.(c) M. Eddaoudi, J. Kim, J. B. Wachter, H. K. Chae, M. O’Keeffe, O. M. Yaghi, J. Am. Chem. Soc., 2001, 123, 4368.(d) M. Eddaoudi, H. Li, O. M. Yaghi, J. Am. Chem. Soc., 2000, 122, 1391.
[190] (a) R. Wang, H. D. Selby, H. Liu, M. D. Carducci, T. Jin, Z. Zheng, J. W. Anthis, R. J.Staples, Inorg. Chem., 2002, 41, 278.(b)D. J. Rice, S. R. Batten, B. Moubaraki, K. S. Murray, Chem.Comm., 2002, 762 (c)G. Kickelbick, U. Schubert, Eur. J. Inorg. Chem., 1998, 159.(d)Y. Zhang, B. Ma, S. Gao, J. Li, Q. Liu, G. Wen, X. Zhang, J. Chem. Soc., Dalton Trans., 2000, 2249.(e)W. Schmitt, E. Baissa, A. Mandel, C. Anson, A. K. Powell, Angew. Chem. Int. Ed., 2001, 40, 3578.(f) B. Ma, D. Zhang, S. Gao, T. Jin, C. Yan, G. X. Xu, Angew. Chem. Int. Ed., 2000, 39, 3644. (g) H. Li, M. Eddaoudi, M. O’keeffe, O. M. Yaghi, Nature, 1999, 402, 276.(h) O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H.K. Chae, M. Eddaoudi, J. Kim, Nature, 2003, 423, 705.
[191] (a)M. L. Tong, S. L. Zheng, X. M. Chen, Chem. Eur. J., 2000, 6, 3729.(b)A. Grirrane, A. Pastor, A. Galindo, A. Lenco, C. Mealli, P. Rosa. Chem. Comm., 2003, 512.
[192] (a)Jesse L. C. Rowsell, Juergen Eckert, Omar M. Yaghi, J. Am. Chem. Soc., 2005, 127, 14904. (b) Jesse L. C. Rowsell and Omar M. Yaghi, J. Am. Chem. Soc., 2006, 128, 1304. (c) Hee K. Chae, Jaheon Kim, Olaf Delgado Friedrichs, Michael O_Keeffe, Omar M. Yaghi. Angew. Chem. Int. Ed., 2003, 42, 3907 (d) Banglin Chen, Nathan W. Ockwig, Andrew R. Millward, Damacio S. Contreras, Omar M. Yaghi, Angew. Chem. Int. Ed., 2005, 44, 4745 (e) Z. Wang, V. C. Kravtsov, M. J. Zaworotko, Agnew. Chem. Int. Ed., 2005, 44, 2877 (f) X. Zhang, R. Fang, H. Wu, J. Am. Chem. Soc., 2005, 127, 7670 (g) A. Thirumurugan, Srinivasan Natarajan, Crystal Growth & Design, 2006, 6, 983 (h) Stephane A. Baudron, Mir Wais Hosseini, Nathalie Kyritsakas, New J. Chem., 2006, 30, 1083 (i) John D. Corbett, Inorg. Chem., 2000, 39, 5178 [193] Andreas Decken, Grigori B. Nikiforov, Jack Passmore, Polyhedron, 2005, 24, 2994
[194] (a)Ya Hui Zhao, Hong Bin Xu, Kui Zhan Shao, Yan Xing, Zhong Min Su, Jian Fang Ma, Crystal Growth & Design, 2007, 3, 513 (b) Grimes, S. M.; Jonston, S. R.; Abrahams, I. J. Chem. Soc. Dalton Trans., 1995, 2081. (c) Frostemark F., Bengtsson L. A., Holmberg B. J., Chem. Soc. Faraday Trans., 1994, 90, 2531. (d) Hill R. J., Acta Crystallogr., 1985, C41, 998. (e) Haag Bruhl C., Fuess H., Lightfoot P., Cheetham A. K., Acta Crystallogr., 1988, C44, 8. (f) Yeom Y. H., Kim Y., Seff K., Microporous Mesoporous Mater., 1999, 28, 103. (g) Yeom Y. H., Kim Y., Seff K. J. Phys. Chem., 1997, B101, 5314. (h) Charles S. Weinert, Ilia A. Guzei, Arnold L. Rheingold, Lawrence R. Sita, Organometallics, 17, 1998. 498(i) Krivovichev SV, Burns PC, Zeitschrift Fur Kristallographie, 2003, 218, 357. (j) Yaping Li, Sergey V. Krivovichev, Peter C. Burns, J. Solid. State Chem., 2001, 158, 74, (k) Andreas Eichh?fer, Eur. J. Inorg. Chem., 2005, 1683
[195] a) Virginie Queneau, Slavi C. Sevov, Inorg. Chem., 1998, 37, 1358, b) Emren N. Esenturk, James Fettinger and Bryan Eichhorn, Chem. Commun., 2005, 247 c) Constantin Hoch, Marco Wendorff, Caroline Rohr, J. Alloy Compd. , 2003, 361, 206 d) T. F. Fassler, C. Kronseder, M. Worle, Z. anorg. allg. Chem., 1999, 625 15 e) Xia Zhang, Guoliang Li, Xiaopeng Xing, Xiang Zhao, Zichao Tang,Zhen Gao, Rapid Commun. Mass Spectrom., 2001, 15, 2399 f) P. A. Edwards, J. D. Corbett, Inorg. Chem., 1977, 16, 903 g)Annette Spiekermann, Stephan D. Hoffmann, Thomas F. Fassler, Angew. Chem. Int. Ed., 2006, 45, 3459 , h)Emren N. Esenturk, Bryan Eichhorn, Angew. Chem. Int. Ed., 2004, 43, 2132. i) E. N. Esenturk, J. Fettinger, B. Eichhorn, J. Am. Chem. Soc., 2006, 128, 9178
[196] L. Yong, S. D. Hoffmann, T. F. FSssler, Eur. J. Inorg. Chem., 2005,18, 3363.
[197] J. M. Goicoechea, M. W. Hull, S. C. Sevov, J. Am. Chem. Soc., 2007, 129, 7885
[198] J. Tao,M. L. Tong, J. X. Shi, X. M. Chen, S. W. Ng, Chem. Commun., 2000, 2043
[199] C. Y. Huang, S. L. Wang, K. H. Lii, J. Porous. Mat., 1998, 5, 147
[200] X. J. Li, R. Cao, D. F. Sun, D. Q. Yuan, W. H. Bi, X. Li, Y. Q. Wang, J. Mol. Struct., 2004, 694, 205.
[201] C. Livage, N. Guillou, J. Marrot, G. Ferey, Chem. Mater., 2001, 13, 4387
[202] L. H. Zhu, M. H. Zeng, B. H. Ye, X. M. Chen, Z. Anorg. Allg. Chem., 2004, 630, 952
[203] E. C. M. Grigg, J. R. Hall, Austr. J. Chem., 1962, 15, 864.
[204] (a) K. Krishnan, R. A. Plane, Spectrochim. Acta, 1969, 25A, 831. (b) E. Pretsch, P. Bühlmann, C. Affolter, “Structure Determination of Organic Compounds”, Springer-Verlag, Berlin, 2000.
[205] K. Nakamoto, “Infrared and Raman spectra of Inorganic and Coordination Compounds”, Wiley & Sons, 1986.
[206] L. Castro, J. Faus, M. Julve, A. Gleizes, J. Chem. Soc. Dalton Trans., 1991, 1937.
[207] R. Vaidhyanathan, S. Natarajan, C. N. R. Rao, Inorg.Chem., 2002, 41, 5226
[208] (a)Y. Kim, E. Lee, D. Y. Jung, Chem. Mater., 2001, 13, 2684 (b) E. Lee, Y. Kim, D.Y. Jung, Inorg.Chem., 2002, 41, 501
[209] V. Kiritsis, A. Michaelides, S. Skoulika, S. Golhen, L. Ouahab, Inorg. Chem., 1998, 37, 3407.
[210] Li D. M., Li Y. F., Xu J. Q., et al., Chem. J. Chinese Universities, 2004, 25, 230
[211] Strathmann T. J., Satish C. B., Geochim Cosmochim Ac., 2004, 68, 3441
[212] (a) Zhang G. Q., Yang G. Q., Ma J. S., Cryst.Growth Des., 2006, 6, 375 (b)Xie F. T., Duan L. M, Xu J. Q., et al., Inorg. Chem. Commun., 2005, 8, 274
[213] (a) Alvarado R. J., Rosenberg J. M., Kavallieratos K.,et al., Inorg. Chem., 2005, 44, 7951 (b) Zhua L. H.,Yea B. H., Chen X. M., et al., Z.Anorg.Allg.Chem., 2004, 630, 952 (c)Kavallieratos K., Rosenberg J. M., Bryan J.C., Inorg. Chem., 2005, 44, 2573
[214] (a) Fan J., Shu M. H., Sun W. Y.et al., New J.Chem., 2003, 27, 1307 (b) Shi Y. J.,Chen X. T.,You X. Z.et al..Polyhedron, 2003, 22,917
[215] (a) Zhou Z. H., Hou S.Y., Ma Z. J., Wan H. L., Tsai K. R., Ng S. W., Inorg. Chem. Commun., 2002, 5, 388 (b) Salam M. A., Aoki K.,Inorg. Chim. Acta2000, 311, 15 (c) Starynowicz P., Polyhedron, 2003, 3, 2761 (d) Polyakova I. N., A. Poznyak L., Egorova O. A., Russ. J. Coord. Chem., 2001, 27, 852.
[216] (a) Lu X.,Jiang J., Chen C., Kang B., Su C.,Inorg. Chem., 2005, 44, 4515 (b) Sun B., Wang Z., Gao S., Inorg. Chem. Commun., 2001, 4, 79 (c) Huang L., Zhang L., Jin L., J. Mol. Struct., 2004, 692, 121(d) Zhang Q., Lu C., Yang W., Z. Anorg. Allg. Chem., 2005, 631, 2312 (e) Zhang Q., Lu C., Yang W., Z. Anorg. Allg. Chem., 2004, 630, 1550 (f) Liu Q. , Gao S. , Li J. , Ma B., Zhou Q. , Yu K. , Polyhedron, 2002, 21, 1097 (g) Wang Q., Wu X., Zhang W., Sheng T., Lin P., Li J., Inorg. Chem., 1999, 38, 2223
[2] O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim, Nature, 2003, 423, 705
[3] G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, Acc. Chem. Res., 2005, 38, 176
[4] S. L. James, Chem. Soc. Rev., 2003, 32, 276.
[5] S. Kitagawa, R. Kitaura, S. I. Noro, Angew. Chem. Int. Ed., 2004, 43, 2334
[6] C. N. R. Rao, S. Natarajan, R. Vaidhyanathan, Angew. Chem. Int. Ed., 2004, 43, 1466
[7] 王磊,“1,2,4-苯三酸及琉基多氮杂环构筑的配位聚合物水热合成、结构与性质表征”,吉林大学博士论文,2006
[8] Yu-Bin Dong, Peng Wang, Jian-Ping Ma, Xia-Xia Zhao, Hai-Ying Wang, Bo Tang, Ru-Qi Huang, J. Am. Chem. Soc., 2007, 129, 4872
[9] Banerjee, A.; Sarkar, S.; Chopra, D.; Colacio, E.; Rajak, K. K. Inorg. Chem., 2008,10, 4023
[10] Jiang, Y.-S.; Yao, H.-G.; Ji, S.-H.; Ji, M.; An, Y.-L. Inorg. Chem, 2008,10,3922.
[11] Horike, S.; Dinca,? M.; Tamaki, K.; Long, J. R. J. Am. Chem. Soc., 2008, 18, 5854
[12] 何江华,吉林大学博士论文,2005.
[13] Dao-Jun Zhang, Tian-You Song, Ping Zhang, Jing Shi, Ying Wang, Li Wang, Kui-Rong Ma, Wei-Rong Yin, Jie Zhao, Yong Fan, Jia-Ning Xu, Inorganic Chemistry Communications, 2007, 10, 876
[14] X. Xue, X. S. Wang, R. G. Xiong, X. Z. You, B. F. Abrahams, C. M. Che, H. X. Ju, Angew. Chem. Int. Ed. 2002, 41, 2944.
[15] K. Kobayashi, A. Sato, S. Sakamoto, K. Yamaguchi, J. Am. Chem. Soc.,2003, 125, 3035.
[16] Dao-Jun Zhang, Tian-You Song, Jing Shi, Wei-Rong Yin, Ping Zhang, Li Wang, Ying Wang, Kui-Rong Ma, Yong Fan, Jia-Ning Xu, Inorganic Chemistry Communications, 2007, 10, 1067
[17] F. A, A. Paz, J. Klinowski, Chem. Commu., 2003, 1484.
[18] Daiguebonne, C., Kerbellec, N., Guillou, O., Bünzli, J.-C., Gumy, F., Catala, L., Mallah, T., Audebrand, N., Gérault, Y., Bernot, K., Calvez, G., Inorg. Chem., 2008, 9, 3700
[19] N.L. Rosi, J.Kim, O.M. Yaghi,J. Am. Chem. Soc., 2005, 127, 1504-
[20] Li, S.-L., Lan, Y.-Q., Ma, J.-F., Fu, Y.-M, Yang, J.; Ping, G.-J., Liu, J., Su, Z.-M. Cryst. Growth Des., 2008, 5, 1610
[21] Neogi, S.,Navarro, J. A. R., Bharadwaj, P. K.,Cryst. Growth Des., 2008, 5, 1554
[22] Q.R. Fang, G. S. Zhu, S. L. Qiu, Angew. Chem. Int. Ed., 2007, 46, 6638
[23] Z. Ni, A. Yassar, T. Antoun, O. M. Yaghi, J. Am. Chem. Soc., 2005, 127, 12752
[24] D.Kong, A. Clearfield, Cryst. Growth Des., 2005, 5, 1263
[25] C. V. K. Sharma, A. Clearfield,J. Am. Chem. Soc. 2001, 123, 2885-2886
[26] G. G. Briand, Neil Burford, M. D. Eelman, N. Aumeerally, L. Chen, T.S.Cameron, K. N. Robertson, Inorg. Chem., 2004, 43, 6495
[27] X Li, R. Cao, W. Bi, Y. Wang, Y. Wang, X. Li, Z. Guo, Cryst. Growth Des., 2005, 5, 1651
[28] X. Li, X. Wang, S. Gao, R. Cao, Inorg. Chem., 2006, 45, 1508
[29] W. Zheng, X. Liu, J. Guo, L. Wu , D. Liao, Inorg. Chim. Acta ,2004, 357, 1571
[30] N. Hao, F. Liu, E. Wang, R. Huang, Y. Li,C. Hu, Inorg.Chem.Commun. 2003, 6, 728
[315] X. Hu, J. Xu, P. Cheng, Inorg. Chem., 2004, 43, 2261
[32] B.Zhao, L. Yi, P. Cheng, Inorg. Chem.Commun. , 2004, 7, 971
[33] D. Gatteschi, Adv. Master., 1994, 6, 635.
[34] H.Chun, D. Kim, D. N. Dybtsev, K.Kim, Angew. Chem. Int. Ed., 2004, 43, 971.
[35] B.L. Chen, Y. Yang, F. Zapata, G.N. Lin, G.D. Qian, E. B. Lobkovsky, Adv. Mater., 2007, 19, 1693.
[36]B. V. Harbuzaru, A. Corma, F. Rey, P.Atienzar, J. L. Jord, H. García, D. Ananias, Luis D. Carlos, J. Rocha, Angew. Chem. Int. Ed., 2008, 47, 1080
[371] P. J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. Int. Ed., 1999, 38, 2638
[38] L. R. MacGillivray, S. Subramanian, M. J. Zaworotko, Chem.Commun., 1994, 1325
[39] Lloret, G. DeMunno, M. Julve, J. Cano, R. Ruiz, A. Caneschi, Angew. Chem. Int. Ed., 1998, 37, 135
[40] M. Yaghi, H. Li, J. Am. Chem. Soc., 1995, 117, 10401
[41] M. Yaghi, G. M. Li, Angew. Chem. Int. Ed., 1995, 34, 207
[42] P. Losier, M. J. Zaworotko , Angew. Chem. Int. Ed., 1996, 35, 2779
[43] M. Yaghi, H. Li, T. L. Groy, Inorg. Chem., 1997, 36, 4292
[44] Martin, D. P., Supkowski, R. M., LaDuca, R. L.Inorg. Chem., 2007,19, 7917
[45] Liao, J.-H.; Wu, P.-C.; Huang, W.-C., Cryst. Growth Des., 2006, 5, 1062
[46] Yang, G.-D.; Dai, J.-C.; Lian, Y.-X.; Wu, W.-S.; Lin, J.-M.; Hu, S.-M.; Sheng, T.-L.; Fu, Z.-Y.; Wu, X.-T.,Inorg. Chem., 2007, 19, 7910
[47] Zhang, L.-Y.,Zhang, J.-P.; Lin, Y.-Y., Chen, X.-M.,Cryst. Growth Des., 2006, 7, 1684
[48] D. F. Sun, R. Cao, Y. C. Liang, Q. Shi, W. P. Su, M. C. Hong, J. Chem. Soc. Dalton.Trans., 2001, 2335.
[49] R. Cao, D. Sun, U. Liang, M. Hong, K. Tatsumi, Q. Shi, Inorg. Chem., 2002, 41, 2087.
[50] Biemmi, E.; Scherb, C.; Bein, T., J. Am. Chem. Soc., 2007, 26, 8054
[51] L. A. Gerrard, P. T. Wood, Chem. Commnu., 2000, 2107
[52] (a)H. Cui, Z. M. Wang, K. Takahashi, Y. Okano, H. Kobayashi, A. Kobayashi, J. Am. Chem. Soc., 2006, 128, 15074. (b)P. M. Forster, A. K. Cheetha, Angew. Chem. Int. Ed., 2002, 41, 457.
[53] 叶俊伟,“5-硝基间苯二甲酸桥联配体构筑的超分子配位聚合物的合成、结构及性能研究”,吉林大学博士论文,2007
[54] 赵斌, “d-f 混合金属配位聚合物的合成和性质研究”,南开大学博士论文,2004.
[55] B. Zhao, L. Yi, Y. Dai, X. Y. Chen, P. Cheng, D. Z. Liao, S. P. Yan, Z. H. Jiang, Inorg. Chem., 2005, 44, 911.
[56] B. Zhao, P. Cheng, Y. Dai, C. Cheng, D. Z. Liao, S. P. Yan, Z. H. Jiang, G. L. Wang, Angew. Chem. Int. Ed.,2003, 42, 934.
[57] B. Zhao, P. Cheng, X. Y. Chen, W. Shi, D. Z. Liao, S. P. Yan, Z. H. Jiang, J. Am. Chem. Soc., 2004, 126, 3012.
[58] 迈克尔.波普著,王恩波等译,杂多和同多金属氧酸盐,吉林大学出版社,1991.
[59] Wu, P., Volkmer, D.; Bredenkotter..B., Kurth, D. G., Rabe, J. P., Langmuir,2008, 6, 2767
[60] R. S. Rarig, R. Lam, P. Y. Zavalij, J. K. Ngala, R. L. LaDuca, J. E. Greedan, J. Zubieta,Inorg. Chem., 2002, 41, 2124.
[61] H. Y. An, E. B. Wang, Z. M. Su, L. Xu, Angew. Chem. Int. Ed., 2006, 45, 904.
[62] X. L. Wang, C. Qin, E. B. Wang, Z. M. Su, L. Xu, Angew. Chem. Int. Ed., 2004, 43, 5036.
[63] X. L. Wang, E. B. Wang, Y. G. Li, Z. M. Su, L. Xu, L. Carlucci, Angew. Chem. Int. Ed., 2005, 44, 5824.
[64].X. Wang, Y. Guo, Y. Li, E. B. Wang,.Inorg. Chem., 2003, 42, 4135.
[65] X. L. Wang, C. Qin, E. B. Wang, Z. M. Su, Y.G. Li, L. Xu, Angew. Chem. Int. Ed., 2006, 45, 7411.
[66] 孙道峰,“新型含羧基及磺酸基配体超分子化合物的设计合成、结构解析及性能研究”,中国科学院研究生院博士学位论文,2003
[67] (a)A. P. Coté, G. K. H. Shimizu, Coord. Chem. Rev., 2003, 245, 49. (b)J. W. Cai , Coord. Chem. Rev., 2004, 248, 1061.
[68] E. K. H. Shimizu,G. D. Enright, C. I. Ratclife, G. S. Rego, J. L. Reid, J. A. Ripmeester, Chem. Mater., 1998, 10, 3282
[69] E. K. H. Shimizu, G. D. Enright, C. I. Ratclife, K. F. Pr eston, J. L. Reid, J.A. Ripmeester, Chem. Commun.,1999,1485.
[70] S. K. Makinen, N. J. Melcer, M. Parvez, G. K. H. Shimizu, Chem. Eur. J.,2001, 23, 5176
[71] J. Q. Yu, A. P. Cotd, G. D. Enright, and Q. K. H. Shimizu , Inorg. Chem., 2001, 40, 582
[72] B. D. Chandler, D. T. Cramb, and G. K. H. Shimizu, J. Am. Chem. Soc., 2006, 128, 10403
[73] Maheswari, P. U.; van der Ster, M.; Smulders, S.; Barends, S.; van Wezel, G. P.; Massera, C.; Roy, S.; den Dulk, H.; Gamez, P.; Reedijk, J., Inorg. Chem.; 2008, 9, 3719
[74] Jian-Kai Cheng,Yuan-Gen Yao, Jian Zhang, Zhao-Ji Li, Zong-Wei Cai, Xiang-You Zhang,Zhong-Ning Chen,Yu-Biao Chen, Yao Kang,Ye-Yan Qin, Yi-Hang Wen, J. Am. Chem. Soc. 2004, 126, 7796
[75] Forniés, J.; García, A.; Lalinde, E.; Moreno, M. T.,Inorg. Chem., 2008, 9, 3651
[76] M. Ali, A. Ray, W. s. Sheldrick, H. Mayer-figge, S. Gao, A. I. Sahmes, New J. Chem., 2004, 28,412
[77] Li, D.; Shi, W.-J.; Hou, L., Inorg. Chem., 2005, 11, 3907
[78] Bhosekar G.,Jess I., Nather C., Inorg. Chem, 2006, 16, 6508
[79] I. P. Y. Shek, W. T. Wong, S. Gao, T. C. Lau, New J. Chem.,2002, 26, 1099.
[80] Pronold, M.; Scheer, M.; Wachter, J.; Zabel, M.,Inorg. Chem.,2007, 4, 1396
[81] Gu, X.; Xue, D., Inorg. Chem.; 2007; 13; 5349
[82] Ichikawa, S.; Kimura, S.; Takahashi, K.; Mori, H.; Yoshida, G.; Manabe, Y.; Matsuda, M.; Tajima, H.; Yamaura, J.-i., Inorg. Chem., 2008, 10, 4140
[83] 顾金忠, 姜隆, 梁钜红, 鲁统部, 谭民裕,无机化学学报, 2006, 8, 1375
[84] 梁淑惠, 车云霞, 郑吉民, 无机化学学报, 2005, 10, 1520
[85] B. F. Abrahams, B. F. Hoskins, R. Robson, J. Am. Chem. Soc., 1991, 113, 3606; (b) S. R. Baten, R. Robson, Angew. Chem. Int Ed. Engl., 1998, 37, 146 (c)卢静,“含氮、氧及卤素配体的过渡金属配合物的合成、结构与性能”,吉林大学博士论文,2006
[86] D.A. Brown et al., Inorg. Chim. Acta, 2004, 357, 1411
[87] 牛淑云,金晶,范洪涛, 辽宁师范大学学报(自然科学版), 2002,25. 398
[88] K.T. Holman, H.H. Hammud, S. Isber, M. Tabbal, Polyhedron, 2005, 24, 221.
[89] H.J. Choi, M. P. Suh, Inorg. Chem. 1999, 38, 6309.
[90] (a)X. M. Chen, G. F. Liu, Chem. Eur.J. 2002, 4811. (b) L. Yi, X.Yang, T. Lu, P. Cheng. Cryst. Growth Des., 2005, 5, 1215
[91] C. Chen, D. Xu, Y. Xu, C. Cheng, R. Ling, Acta Cryst. 1992, 48, 1231.
[92] H.K. Fun,; S. S. S. Raj, R. G. Xiong, J. L. Zuo, Z. Yu, X. L. Zhu, X. Z. You, J. Chem. Soc. Dalton Trans., 1999, 1711.
[93] S. D. Huang, R. G. Xiong, Polyhedron, 1997, 16, 3929.
[94] L. Carlucci, G. Ciani, D. M. Proserpio, Chem. Commun., 1999, 449.
[95] M. L. Tong, H. J.Chen, X. M. Chen, Inorg. Chem., 2000, 39, 2235.
[96] Yanjuan Qi, Yonghui Wang, Changwen Hu, Inorg. Chem., 2003, 42, 8519
[97]R. Kitaura, F. Iwahori. Inorg. Chem., 2004, 43, 6522
[98] M. Du, X. J. Zhao, Inorg. Chem. Commun., 2004, 1056.
[99] G. B. Gardner, D. Venkataraman, J. S. Moore, S. Lee, Nature, 1995, 374, 792.
[100] K. N. Power, T. L. Hennigar, M. J. Zaworotko, Chem. Commun., 1998, 595.
[101] L. Carlucci, N. Cozzi, G. Ciani, M. Moret, D. M. Proserpio, S. Rizzato, Chem. Commun., 2002, 1354.
[102] B. Rather, B. Moulton, R. D. B. Walsh, M. J. Zaworotko, Chem. Commun. ,2002, 694.
[103] H. Gudbjartson, K. Biradha, K. M. Poirier, M. J. Zaworotko, J. Am. Chem. Soc., 1999, 121, 2599.
[104] B.Chen, N.W. Ockwig, O.M. Yaghi, Inorg. Chem., 2005, 44, 181
[105] M. Eddaoudi, J. Kim, M.l O’Keeffe, O. M. Yaghi, J. Am. Chem. Soc., 2002, 124, 376
[106] Andrea C. Sudik, Adrien P. Cote, Omar M. Yaghi, Inorg. Chem., 2005, 44, 2998
[107] B. G. Lor, E. G. Puebla, M. Iglesias, M. A. Monge, Chem. Mater., 2005, 17, 2568
[108] Seo J. S., Whang D., Lee H. Nature, 2000, 404, 982.
[109] J. Zhang, J. Ensling, V. Ksenofontov, P. Gütlich, A. J. Epstein, J. S. Miller, Angew. Chem. Int. Ed., 1998, 37, 657
[110] K. R. Dunbar, Angew. Chem. Int. Ed., 1996, 35, 1659
[111] H. Zhao, R. A. Heintz, R. d. Rogers, K. R. Dunbar, J. Am. Chem. Soc., 1996, 118, 12844.
[112] H. Wang, H. Li, B.i Xue, Z. Wang, J. Am. Chem. Soc., 2005, 127, 6394
[113] K. Li, Z. Xu, Chem. Mater., 2005, 17, 4426
[114] S. Liu, T. K. Sowa, Inorg. Chem., 2005, 44, 1031
[115] T. Y. Shvareva, T. A. Sullens, Inorg.Chem., 2005, 44, 300
[116] R. Custelcean, M. G. Gorbunova, J. Am. Chem. Soc., 2005, 127, 16362
[117] Y. Liao, Y. Jiang, S. Wang. J. Am. Chem. Soc., 2005, 127, 12794
[118] H. Kim, W. Kim, A. J. Lough, J. Am. Chem. Soc., 2005, 127, 16776
[119] (a)O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim, Nature, 2003, 423, 705.(b) Antek G. Wong-Foy, Adam J. Matzger, Omar M. Yaghi, J. Am. Chem. Soc. , 2006, 128, 3494 (c)Jesse L. C. Rowsell and Omar M. Yaghi, J. Am. Chem. Soc., 2006, 128, 1304 (d) Andrew R. Millward, Omar M. Yaghi, J. Am. Chem. Soc., 2005, 127, 17998
[120] H. Li, M. Eddaoudi, M. O’keeffe, O. M. Yaghi, Nature, 1999,402, 276
[121] E. Gao, S. Bai, Z. Wang, C. Yan, J. Am. Chem. Soc., 2003, 125, 4984.
[122] C. Serre, F. Millange,C. Thouvenot, M. Noguès, G. Marsolier, D. Lou?r, G. Férey, J. Am. Chem. Soc., 2002, 124, 13519.
[123] G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray, J. D. Cashion, Science, 2002, 298, 1762.
[124] S. Feng, R .Xu, Acc. Chem. Res., 2001, 34, 239.
[125] 徐如人,庞文琴, 无机合成与制备化学, 高等教育出版社, 2001.
[126] N. L. Rosi, M. Eddaoudi, J. Kim, M. O' Keeffe, O. M. Yaghi, CrystEngComm 2002, 4, 401.
[127] X. H. Bu, W. Chen, S. L. Lu, R. H. Zhang, D. Z. Liao, W. M. Bu, M. Shionoya, F. Brisse, J. Ribas, Angew. Chem. Int. Ed., 2001, 40, 3201.
[128] S. A. Barnett, A. J. Blake, N. R. Champness, J. E. B. Nicolson, C. Wilson, J. Chem. Soc.Dalton Trans., 2001, 567.
[129] M. L. Tong, S. Hu, J. Wang, S. Kitagawa, S. W. Ng, Cryst. Growth&Des., 2005, 5, 837.
[130] Y. J. Kim, D. Y. Jung, Chem. Commun., 2002, 908.
[131] 杜淼,卜显和, 阴离子在构筑配位聚合物网络结构中的作用, 无机化学学报, 2003, 1.
[132] L. Carlucci, G. Ciani, P. Macchi, D. M. Proserpio, S. Rizzato, Chem. Eur. J., 1999, 237.
[133] C. S. Cundy, P. A. Cox, Chem. Rev., 2003, 103, 663.
[134] A. J. Norquist, P. M. Thomas, M. B. Doran, D. O’Hare, Chem. Mater., 2002, 14, 5179.
[135] A. J. Norquist, M. B. Doran, P. M. Thomas, D. O’Hare, Inorg. Chem., 2003, 42, 5949.
[136] C. L. Cahill; B. Gugliotta; J. B. Parise, Chem. Commun., 1998, 1715.
[137] C. N. R. Rao, S. Natarajan, S. Neeraj, J. Am. Chem. Soc., 2000, 122, 2810.
[138] Z. Shi, G. Li, L. Wang, L. Gao, X. Chen, J. Hua, S. Feng, Cryst. Growth&Des., 2004, 25.
[139] D. T. Lill, N. S. Guning, C. L. Cahill, Inorg. Chem., 2005, 44, 258.
[140] D. T. Lill, D. J. Bozzutoa, C. L. Cahill, J. Chem. Soc.Dalton Trans., 2005, 2111.
[141] Liat Shimoni-Livny, Jenny P. Glusker, Charles W. Bock, Inorg. Chem. 1998, 37, 1853
[142] Qiong Ye, Yong-Hua Li, Qian Wu, Yu-Mei Song, Ju-Xian Wang, Hong Zhao, Ren-Gen Xiong, Ziling Xue, Chem. Eur. J,. 2005, 11, 988
[143] Magyar, J. S.; Weng, T. C.; Stern, C. M.; Dye, D. F.; Rous, B. W.; Payne, J. C.; Bridgewater, B. M.; Mijovilovich, A.; Parkin, G.; Zaleski, J. M.; Penner-Hahn, J. E.; Godwin, H. A. J.Am. Chem. Soc. 2005, 127, 9495.
[144] Dale, S. H.; Elsegood, M. R. J.; Kainth, S. Acta Crystallogr. 2004, C60, m76
[145] Sai-Rong Fan and Long-Guan Zhu, Inorg. Chem., 2007; 46, 6785
[146] Ali Morsali, Ali Ramazanib. Z. Anorg. Allg. Chem., 2005, 631, 1759
[147] Ali Morsali, Veysel T. Yilmaz, Helvetica Chemica Acta., 2005, 88, 2513
[148] Ali Morsali, Mahmod Payheghader, Saeid Salehi Monfared, Z. Anorg. Allg. Chem., 2002, 628, 12
[149] Yu-Jun Shi, Li-Hong Li, Yi-Zhi Li, Xue-Tai Chen, Ziling Xue ,Xiao-Zeng You, Polyhedron, 2003, 22, 917
[150] Ali Morsali, Veysel T. Yilmaz, Helvetica Chemica Acta., 2005, 88, 2513
[151] Barton H., J. Ziegler Inorg. Chem., 43, 2004, 50
[152] Barton H., J. Ziegler, Inorg. Chem., 41, 2002, 4984
[153] Barton H., J. Ziegler, Inorg. Chem., 44, 2005, 4891
[154] N. Singh, Transition Metal Chemistry, 2002, 27, 359
[155] N. Singh, S. Gupta, Inorg. Chem. Comm., 2003, 6 416
[156] N. Singh,S. Gupta, Transition Metal Chemistry, 2005, 30, 383。
[157] Lin Ke Li,Yu Zhu, Eur. J. Inorg. Chem. 2005, 3238
[158] Gang Li, Yu Zhu/ Inorg.Chem., 42, 2003 4995
[159] Hongwei Hou, Yu Zhu, Inorg. Chem., 42, 2003 3501
[160] Lin Ke Li,Yu Zhu, Eur. J. Inorg. Chem. 2005, 3238
[161] Niu Yun Y,Hou Hong Wei, Chinese Journal of Inorganic Chemistry, 2001, 4, 533
[162] Gupta, B. D.; Sonu, S. Opt. Commun., 1998, 154, 282
[163] Jie, L. Trends Anal. Chem., 2000, 19, 541.
[164] Peterson, J. I.; Goldstein, S. R.; Fitzgerald, P. V. Anal.Chem., 1980, 52, 864
[165] Thomas, P. J.; Marc, D. R. Anal. Chem., 1988, 60, 404
[166] Bacci, M.; Baldini, F.; Bracci, S., Appl. Spectrosc., 1991, 45,1508
[167] Rao, B. S.; Puschett, J. B.; Matyjaszewski, K. J., Appl.Polym.Sci., 1991, 43, 925
[168] Zhang, Z. J.; Zhang, Y. K.; Ma, W. B.; Russell, R.; Shakhsher,Z. M.; Grant, C. L.; Seitz, W. R. Anal. Chem., 1989, 61, 202.
[169] F. R. Zaggouta, N. M. El-Ashgarb, S. M. Zouraba, I. M. El-Nahhala, H. Motaweha, Materials Letters, 2005, 59, 2928
[170] F.R. Zaggout, I.M. El-Nahhal, S.M. Zourab, N.M. El-Ashgar, H.J. Motaweh, J. Dispers. Sci. Technol. 2005, 26, 629
[171] I.M. El-Nahhal, S.M. Zourab, N.M. El-Ashgar, J. Dispers. Sci. Technol. 2001, 22, 583.
[172] Luo, F.L.; Liu, Z.H.; Chen, T.L.; Gong, B.L. Chinese Journal of Chemistry, 2006, 24, 341
[173] Nichola J.Burke; Andrew D.Burrows; Mary F.Mahon; Simon J.Teat. CrysEngComm, 2004, 6, 429
[174] Ales ruzicka, Antonin lycka, Roman jambor Appl. Organometal. Chem., 2003, 17, 168
[175] J. B. Benedict, D. E. Cohen, S. Lovell, Andrew L. Rohl, B. Kahr. J. Am. Chem. Soc., 2006, 128, 5548
[176] Zherebov A. Y., Lachinov A. N. Synth Met., 1992,46, 181.
[177] Scaldin O. A., Selezneva O. A., Lebedev Y. A., Chuvyrov A. N., J. Appl. Phys., 1995, 77, 3194.
[178] J. Song, C. Lei, J. Mao. Inorg. Chem., 2004, 43, 5630M
[179] C. Das, A. Saha, C. Hung. Inorg. Chem., 2003, 42, 198
[180] Q. Guo, W. Zhu, S. Dong. J. Mole. Struc., 2003, 650, 159
[181] R. Custelcean, M. D. Ward. Angew. Chem. Int. Ed.,2002, 41, 1724
[182] (a)Akira Onoda, Yusuke Yamada, Mototsugu Doi, Taka-aki Okamura, Norikazu Ueyama,Inorg. Chem., 2001, 40, 516 (b) Tarlok S. Lobana, Isamu Kinoshita, Kentaro Kimura, Takanori Nishioka,Daisuke Shiomi, Kiyoshi Isobe, Eur. J. Inorg. Chem., 2004, 356(c) Armando Marzotto, Dore Augusto Clemente , Thomas Gerola, Giovanni Valle, Polyhedron, 2001, 20, 1079 (d) R. Custelcean, M. D. Ward, Angew. Chem. Int. Ed., 2002, 41, 1724
[183] (a)Kano N., Komatsu F., Kawashima T., J. Am. Chem. Soc., 2001, 43, 10778 (b)Otsuki J., Suwa K., Narutaki K., Sinha C., Yoshikawa I., Araki K., J. Phys. Chem. A.; 2005; 109, 8064 (c)Das C., Saha A., Hung C. H., Lee G.. H., Peng S. M., Goswami S., Inorg. Chem., 2003, 42, 198
[184] L. Zhu, M. Zeng, B. Ye, X. Chen, Z. Anorg. Allg. Chem., 2004, 630, 952
[185] R. Sharma, R. Sharma, R. Bala, U. Rychlewska, B. Warzajtis, J. Mole. Struc., 2005, 738, 291
[186] Rory H. Uibel, Joel M. Harris. Anal. Chem., 2002, 74, 5112
[187] Trotter, P. J., Appl. Spectrosc., 1977, 31, 30
[188] Bajpai, P. K.; Pal, B.; Baul, T. S. B., J. Raman Spectrosc., 1995, 26, 351
[189] (a)H. Li, M. Eddaoudi, M. O’keeffe, O. M. Yaghi, Nature, 1999, 402, 276.(b)S. S. Y. Chui, S. M. F. Lo, J. P. H. Charmant, A. G. Orpen, I. D. Williams, Science, 1999, 283, 1148.(c) M. Eddaoudi, J. Kim, J. B. Wachter, H. K. Chae, M. O’Keeffe, O. M. Yaghi, J. Am. Chem. Soc., 2001, 123, 4368.(d) M. Eddaoudi, H. Li, O. M. Yaghi, J. Am. Chem. Soc., 2000, 122, 1391.
[190] (a) R. Wang, H. D. Selby, H. Liu, M. D. Carducci, T. Jin, Z. Zheng, J. W. Anthis, R. J.Staples, Inorg. Chem., 2002, 41, 278.(b)D. J. Rice, S. R. Batten, B. Moubaraki, K. S. Murray, Chem.Comm., 2002, 762 (c)G. Kickelbick, U. Schubert, Eur. J. Inorg. Chem., 1998, 159.(d)Y. Zhang, B. Ma, S. Gao, J. Li, Q. Liu, G. Wen, X. Zhang, J. Chem. Soc., Dalton Trans., 2000, 2249.(e)W. Schmitt, E. Baissa, A. Mandel, C. Anson, A. K. Powell, Angew. Chem. Int. Ed., 2001, 40, 3578.(f) B. Ma, D. Zhang, S. Gao, T. Jin, C. Yan, G. X. Xu, Angew. Chem. Int. Ed., 2000, 39, 3644. (g) H. Li, M. Eddaoudi, M. O’keeffe, O. M. Yaghi, Nature, 1999, 402, 276.(h) O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H.K. Chae, M. Eddaoudi, J. Kim, Nature, 2003, 423, 705.
[191] (a)M. L. Tong, S. L. Zheng, X. M. Chen, Chem. Eur. J., 2000, 6, 3729.(b)A. Grirrane, A. Pastor, A. Galindo, A. Lenco, C. Mealli, P. Rosa. Chem. Comm., 2003, 512.
[192] (a)Jesse L. C. Rowsell, Juergen Eckert, Omar M. Yaghi, J. Am. Chem. Soc., 2005, 127, 14904. (b) Jesse L. C. Rowsell and Omar M. Yaghi, J. Am. Chem. Soc., 2006, 128, 1304. (c) Hee K. Chae, Jaheon Kim, Olaf Delgado Friedrichs, Michael O_Keeffe, Omar M. Yaghi. Angew. Chem. Int. Ed., 2003, 42, 3907 (d) Banglin Chen, Nathan W. Ockwig, Andrew R. Millward, Damacio S. Contreras, Omar M. Yaghi, Angew. Chem. Int. Ed., 2005, 44, 4745 (e) Z. Wang, V. C. Kravtsov, M. J. Zaworotko, Agnew. Chem. Int. Ed., 2005, 44, 2877 (f) X. Zhang, R. Fang, H. Wu, J. Am. Chem. Soc., 2005, 127, 7670 (g) A. Thirumurugan, Srinivasan Natarajan, Crystal Growth & Design, 2006, 6, 983 (h) Stephane A. Baudron, Mir Wais Hosseini, Nathalie Kyritsakas, New J. Chem., 2006, 30, 1083 (i) John D. Corbett, Inorg. Chem., 2000, 39, 5178 [193] Andreas Decken, Grigori B. Nikiforov, Jack Passmore, Polyhedron, 2005, 24, 2994
[194] (a)Ya Hui Zhao, Hong Bin Xu, Kui Zhan Shao, Yan Xing, Zhong Min Su, Jian Fang Ma, Crystal Growth & Design, 2007, 3, 513 (b) Grimes, S. M.; Jonston, S. R.; Abrahams, I. J. Chem. Soc. Dalton Trans., 1995, 2081. (c) Frostemark F., Bengtsson L. A., Holmberg B. J., Chem. Soc. Faraday Trans., 1994, 90, 2531. (d) Hill R. J., Acta Crystallogr., 1985, C41, 998. (e) Haag Bruhl C., Fuess H., Lightfoot P., Cheetham A. K., Acta Crystallogr., 1988, C44, 8. (f) Yeom Y. H., Kim Y., Seff K., Microporous Mesoporous Mater., 1999, 28, 103. (g) Yeom Y. H., Kim Y., Seff K. J. Phys. Chem., 1997, B101, 5314. (h) Charles S. Weinert, Ilia A. Guzei, Arnold L. Rheingold, Lawrence R. Sita, Organometallics, 17, 1998. 498(i) Krivovichev SV, Burns PC, Zeitschrift Fur Kristallographie, 2003, 218, 357. (j) Yaping Li, Sergey V. Krivovichev, Peter C. Burns, J. Solid. State Chem., 2001, 158, 74, (k) Andreas Eichh?fer, Eur. J. Inorg. Chem., 2005, 1683
[195] a) Virginie Queneau, Slavi C. Sevov, Inorg. Chem., 1998, 37, 1358, b) Emren N. Esenturk, James Fettinger and Bryan Eichhorn, Chem. Commun., 2005, 247 c) Constantin Hoch, Marco Wendorff, Caroline Rohr, J. Alloy Compd. , 2003, 361, 206 d) T. F. Fassler, C. Kronseder, M. Worle, Z. anorg. allg. Chem., 1999, 625 15 e) Xia Zhang, Guoliang Li, Xiaopeng Xing, Xiang Zhao, Zichao Tang,Zhen Gao, Rapid Commun. Mass Spectrom., 2001, 15, 2399 f) P. A. Edwards, J. D. Corbett, Inorg. Chem., 1977, 16, 903 g)Annette Spiekermann, Stephan D. Hoffmann, Thomas F. Fassler, Angew. Chem. Int. Ed., 2006, 45, 3459 , h)Emren N. Esenturk, Bryan Eichhorn, Angew. Chem. Int. Ed., 2004, 43, 2132. i) E. N. Esenturk, J. Fettinger, B. Eichhorn, J. Am. Chem. Soc., 2006, 128, 9178
[196] L. Yong, S. D. Hoffmann, T. F. FSssler, Eur. J. Inorg. Chem., 2005,18, 3363.
[197] J. M. Goicoechea, M. W. Hull, S. C. Sevov, J. Am. Chem. Soc., 2007, 129, 7885
[198] J. Tao,M. L. Tong, J. X. Shi, X. M. Chen, S. W. Ng, Chem. Commun., 2000, 2043
[199] C. Y. Huang, S. L. Wang, K. H. Lii, J. Porous. Mat., 1998, 5, 147
[200] X. J. Li, R. Cao, D. F. Sun, D. Q. Yuan, W. H. Bi, X. Li, Y. Q. Wang, J. Mol. Struct., 2004, 694, 205.
[201] C. Livage, N. Guillou, J. Marrot, G. Ferey, Chem. Mater., 2001, 13, 4387
[202] L. H. Zhu, M. H. Zeng, B. H. Ye, X. M. Chen, Z. Anorg. Allg. Chem., 2004, 630, 952
[203] E. C. M. Grigg, J. R. Hall, Austr. J. Chem., 1962, 15, 864.
[204] (a) K. Krishnan, R. A. Plane, Spectrochim. Acta, 1969, 25A, 831. (b) E. Pretsch, P. Bühlmann, C. Affolter, “Structure Determination of Organic Compounds”, Springer-Verlag, Berlin, 2000.
[205] K. Nakamoto, “Infrared and Raman spectra of Inorganic and Coordination Compounds”, Wiley & Sons, 1986.
[206] L. Castro, J. Faus, M. Julve, A. Gleizes, J. Chem. Soc. Dalton Trans., 1991, 1937.
[207] R. Vaidhyanathan, S. Natarajan, C. N. R. Rao, Inorg.Chem., 2002, 41, 5226
[208] (a)Y. Kim, E. Lee, D. Y. Jung, Chem. Mater., 2001, 13, 2684 (b) E. Lee, Y. Kim, D.Y. Jung, Inorg.Chem., 2002, 41, 501
[209] V. Kiritsis, A. Michaelides, S. Skoulika, S. Golhen, L. Ouahab, Inorg. Chem., 1998, 37, 3407.
[210] Li D. M., Li Y. F., Xu J. Q., et al., Chem. J. Chinese Universities, 2004, 25, 230
[211] Strathmann T. J., Satish C. B., Geochim Cosmochim Ac., 2004, 68, 3441
[212] (a) Zhang G. Q., Yang G. Q., Ma J. S., Cryst.Growth Des., 2006, 6, 375 (b)Xie F. T., Duan L. M, Xu J. Q., et al., Inorg. Chem. Commun., 2005, 8, 274
[213] (a) Alvarado R. J., Rosenberg J. M., Kavallieratos K.,et al., Inorg. Chem., 2005, 44, 7951 (b) Zhua L. H.,Yea B. H., Chen X. M., et al., Z.Anorg.Allg.Chem., 2004, 630, 952 (c)Kavallieratos K., Rosenberg J. M., Bryan J.C., Inorg. Chem., 2005, 44, 2573
[214] (a) Fan J., Shu M. H., Sun W. Y.et al., New J.Chem., 2003, 27, 1307 (b) Shi Y. J.,Chen X. T.,You X. Z.et al..Polyhedron, 2003, 22,917
[215] (a) Zhou Z. H., Hou S.Y., Ma Z. J., Wan H. L., Tsai K. R., Ng S. W., Inorg. Chem. Commun., 2002, 5, 388 (b) Salam M. A., Aoki K.,Inorg. Chim. Acta2000, 311, 15 (c) Starynowicz P., Polyhedron, 2003, 3, 2761 (d) Polyakova I. N., A. Poznyak L., Egorova O. A., Russ. J. Coord. Chem., 2001, 27, 852.
[216] (a) Lu X.,Jiang J., Chen C., Kang B., Su C.,Inorg. Chem., 2005, 44, 4515 (b) Sun B., Wang Z., Gao S., Inorg. Chem. Commun., 2001, 4, 79 (c) Huang L., Zhang L., Jin L., J. Mol. Struct., 2004, 692, 121(d) Zhang Q., Lu C., Yang W., Z. Anorg. Allg. Chem., 2005, 631, 2312 (e) Zhang Q., Lu C., Yang W., Z. Anorg. Allg. Chem., 2004, 630, 1550 (f) Liu Q. , Gao S. , Li J. , Ma B., Zhou Q. , Yu K. , Polyhedron, 2002, 21, 1097 (g) Wang Q., Wu X., Zhang W., Sheng T., Lin P., Li J., Inorg. Chem., 1999, 38, 2223