土壤氟形态与氟污染土壤修复
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摘要
我国土壤氟污染问题严峻,给部分地区人体健康和生态安全造成严重威胁,但土壤氟污染与防治问题仍没有受到人们的广泛关注.本文概述了土壤中氟的存在形态以及发生的主要化学反应,综述了近年来国内外有关氟污染土壤修复的研究进展,提出了今后氟污染土壤修复的研究方向,以期为氟污染土壤的修复提供借鉴和参考.土壤中氟主要分为5种形态,其中90%以上以残渣态存在,土壤溶液中的氟主要发生沉淀-溶解、络合-解离和吸附-解吸等反应来维持水-土系统中的氟平衡.目前,氟污染土壤修复技术研究主要集中在化学固定修复技术、化学淋洗技术、电动修复技术以及植物修复技术.今后需要重点研究氟在土壤中的赋存形态及其影响因子,筛选功能微生物和植物,开发联合修复技术以修复氟污染土壤.
In China,fluoride pollution in soil is severe and poses a serious threat to human health and ecological security. However,how to control fluorine-contaminated soil has not received widespread attention. Here,we summarized fluorine speciation in soil and its main chemical reactions in water-soil system and reviewed the research progress on the remediation of fluorine-contaminated soils. Then,we proposed the focus of future research on fluorine-contaminated soil remediation. The aim of this review was providing the reference for the remediation of fluoride-contaminated soil.There are five forms of fluorine in soils,with the proportion of residual fluorine being over 90%. The reactions of fluorine in the soil solution mainly include precipitation-dissolution,complexation-dissociation,and adsorption-desorption. At present,the remediation technology of fluorine contaminated soil mainly focused on chemo-immobilization,chemical leaching,electrokinetic remediation,and phytoremediation. Clarifying the combined forms of fluorine in soil,screening functional microorganisms and plants,developing the combined remediation technology will be the focus of future research. Ultimately,on site fluorine-contaminated soil remediation could be implemented.
In China,fluoride pollution in soil is severe and poses a serious threat to human health and ecological security. However,how to control fluorine-contaminated soil has not received widespread attention. Here,we summarized fluorine speciation in soil and its main chemical reactions in water-soil system and reviewed the research progress on the remediation of fluorine-contaminated soils. Then,we proposed the focus of future research on fluorine-contaminated soil remediation. The aim of this review was providing the reference for the remediation of fluoride-contaminated soil.There are five forms of fluorine in soils,with the proportion of residual fluorine being over 90%. The reactions of fluorine in the soil solution mainly include precipitation-dissolution,complexation-dissociation,and adsorption-desorption. At present,the remediation technology of fluorine contaminated soil mainly focused on chemo-immobilization,chemical leaching,electrokinetic remediation,and phytoremediation. Clarifying the combined forms of fluorine in soil,screening functional microorganisms and plants,developing the combined remediation technology will be the focus of future research. Ultimately,on site fluorine-contaminated soil remediation could be implemented.
引文
[1]Xue S-Y(薛粟尹),Li P(李萍),Wang S-L(王胜利),et al.Chemical forms of fluorine and influential factors in the mining areas of oases,Gansu Province,China.Journal of Agro-Environment Science(农业环境科学学报),2012,31(12):2407-2414(in Chinese)
[2]Mohapatra M,Anand S,Mishra BK,et al.Review of fluoride removal from drinking water.Journal of Environmental Management,2009,91:67-77
[3]Chen J-J(陈剑杰),Cao J-L(曹谨玲),Luo Y-J(罗永巨),et al.Effects of nano-selenium on antioxidant capacity and histopathology of Cyprinus carpio liver under fluoride stress.Chinese Journal of Applied Ecology(应用生态学报),2013,24(10):2970-2976(in Chinese)
[4]Chen Y-Y(陈玉银),Lu S-G(卢升高).Fluoride accumulation and distribution in mulberry insects near fluoride pollution sources.Chinese Journal of Applied Ecology(应用生态学报),2002,13(1):106-108(in Chinese)
[5]Li Y-H(李永华),Wang W-Y(王五一),Hou S-F(侯少范).Safety threshold of fluorine in endemic fluorosis regions in China.Environmental Science(环境科学),2002,23(4):118-122(in Chinese)
[6]Zhu SF,Han D,Zhou M,et al.Ammonia enhanced electrokinetics coupled with bamboo charcoal adsorption for remediation of fluorine-contaminated kaolin clay.Electrochimica Acta,2016,198:241-248
[7]Chen H,Yan M,Yang X,et al.Spatial distribution and temporal variation of high fluoride contents in groundwater and prevalence of fluorosis in humans in Yuanmou County,Southwest China.Journal of Hazardous Materials,2012,235-236:201-209
[8]Wang X-F(王兴峰).Actuality investigation and prevention measures on fluorine pollution of soil in some aluminium factory area.Gansu Metallurgy(甘肃冶金),2008,30(5):62-65(in Chinese)
[9]Li Q(李青),Zhou L-B(周连碧),Zhu Y-B(祝怡斌).Review of heavy metal pollution remediation technology in mine soil.Non-Ferrous Metal Engineering(有色金属工程),2013,3(2):56-59(in Chinese)
[10]Chen H-M(陈怀满),Zhu Y-G(朱永官),Dong Y-H(董元华),et al.Environmental Soil Science.2nd Ed.Beijing:Science Press,2018(in Chinese)
[11]Yang J-Y(杨金燕),Gou M(苟敏).The research status of fluorine contamination in soils of China.Ecology and Environmnet(生态环境学报),2017,26(3):506-513(in Chinese)
[12]Yi C-Y(易春瑶),Wang B-G(汪丙国),Jin M-G(靳孟贵).Research progress of migration and transformation laws of fluoride in ground water-soil-plant system.Safety and Environmental Engineering(安全与环境工程),2013,20(6):59-64(in Chinese)
[13]Xie Z-M(谢正苗),Wu W-H(吴卫红),Xu J-M(徐建民).Translocation and transformation of fluorides in the environment and their biological effects.Progress in Environmental Science(环境科学进展),1999,7(2):41-54(in Chinese)
[14]Pan H(潘宏),Chen B-B(陈邦本),Fang M(方明).Discussion on mechanism of variations in content of water-soluble fluorine during desalinization of coastal saline soils of Jiangsu Province.Acta Pedologica Sinica(土壤学报),1993,30(4):416-422(in Chinese)
[15]Li C-H(黎成厚),Wan H-Y(万红友),Shi H-Q(师会勤),et al.Preliminary study on the water-soluble fluorine content in soil and the factors affecting it.Journal of Mountain Agriculture and Biology(山地农业生物学报),2003,22(2):99-104(in Chinese)
[16]Loganathan P,Gray CW,Hedley MJ,et al.Total and soluble fluorine concentrations in relation to properties of soils in New Zealand.European Journal of Soil Science,2006,57:411-421
[17]Yu D-F(余大富).Fluorine pollution in soil and its harm.Environmental Science(环境科学),1982,3(6):70-74(in Chinese)
[18]Yu Q-Y(于群英),Ci E(慈恩),Yang L-Z(杨林章).Contents of different soil fluorine forms in North Anhui and their affecting factors.Chinese Journal of Applied Ecology(应用生态学报),2007,18(6):1333-1340(in Chinese)
[19]Wenzel W,Blum WEH.Fluorine speciation and mobility in F-contaminated soils.Soil Science,1992,153:357-364
[20]Wang L-X(王凌霞),Fu Q-L(付庆灵),Hu H-Q(胡红青),et al.Fluorine content in tea leaf and fluorine fractionation in soils of tea gardens in Hubei Province.Environmental Chemistry(环境化学),2011,30(3):662-667(in Chinese)
[21]Elrashidi MA,Adriano DC,Workman SM,et al.Chemical equilibria of fluorine in soils:A theoretical development.Soil Science,1986,141:274-280
[22]Liu Z-Y(刘征原),Hao R-B(郝瑞彬).Environmental geochemistry characteristics of fluorine and its biological effects.Journal of Tangshan Teachers College(唐山师范学院学报),2007,29(2):34-36(in Chinese)
[23]Zhang H-Y(张海燕),Liu Y(刘阳),Li J(李娟),et al.Review of heavy metal contaminated soil remediation technology.Sichuan Environment(四川环境),2010,29(6):138-141(in Chinese)
[24]Wang L-Q(王立群),Luo L(罗磊),Ma Y-B(马义兵),et al.In situ immobilization remediation of heavy metals-contaminated soils:A review.Chinese Journal of Applied Ecology(应用生态学报),2009,20(5):1214-1222(in Chinese)
[25]Liang C-H(梁成华),Chen X-Z(陈新之),Li H-Z(李焕珍),et al.Effect of application phosphogysum on contents and adsorption characteristic of fluorine in alkline soils.Acta Scientiae Circumstantiae(环境科学学报),1999,19(1):111-114(in Chinese)
[26]Cui J-X(崔俊学),Chen W(陈文),Ouyang J(欧阳津).The effect of calcium on different species of fluorine in soil.Guangzhou Chemistry(广州化学),2009,34(9):13-18(in Chinese)
[27]Wang L-X(王凌霞),Hu H-Q(胡红青),Min Y-L(闵艳林),et al.Simulated control of water-soluble fluoride content in tea garden soils.Acta Scientiae Circumstantiae(环境科学学报),2011,31(7):1517-1525(in Chinese)
[28]Huang L(黄雷),Zhang S-W(张时伟),Shen Y(沈彦),et al.Effect of the combination of calcium oxide and calcium magnesium phosphate fertilizer on water soluble fluorine content in soil.Environmental Science&Technology(环境科学与技术),2016,39(suppl.2):109-112(in Chinese)
[29]Wang K-Y(王开勇),Yang L(杨乐),Zhao T-Y(赵天一),et al.The environmental effect of organic materials on soil soluble fluorine.Ecology and Environment(生态环境),2007,16(3):879-882(in Chinese)
[30]Gao H,Zhang Z,Wan X.Influences of charcoal and bamboo charcoal amendment on soil-fluoride fractions and bioaccumulation of fluoride in tea plants.Environmental Geochemistry and Health,2012,34:551-562
[31]Zhang Y-L(张永利),Wang Y-J(王烨军),Song L(宋莉),et al.Effects of N,P and K fertilizer on the concentration of fluoride in tea garden soil solution.Soil and Fertilizer Sciences in China(中国土壤与肥料),2017,46(3):28-35(in Chinese)
[32]An CJ,Huang GH,Wei J,et al.Effect of short-chain organic acids on the enhanced desorption of phenanthrene by rhamnolipid biosurfactant in soil-water environment.Water Research,2011,45:5501-5510
[33]Zou Z,Qiu R,Zhang W,et al.The study of operating variables in soil washing with EDTA.Environmental Pollution,2009,157:229-236
[34]Xu R,Wang Y,Zhao A,et al.Effect of low molecular weight organic acids on adsorption and desorption of fluoride on variable charge soils.Environmental Geochemistry and Health,2006,28:141-146
[35]Li Q(李琼),Zeng Q-R(曾清如).A technique for simultaneous removal of heavy metals,arsenic and fluoride from contaminated soil by chelating agents.Journal of Hunan City University(Natural Science)(湖南城市学院学报:自然科学版),2014,23(2):63-66(in Chinese)
[36]Kim DH,Jeon CS,Baek K,et al.Electrokinetic remediation of fluorine-contaminated soil:Conditioning of anolyte.Journal of Hazardous Materials,2009,161:565-569
[37]Moon DH,Jo R,Koutsospyros A,et al.Soil washing of fluorine contaminated soil using various washing solutions.Bulletin of Environmental Contamination and Toxicology,2015,94:334-339
[38]Yuan LZ,Xu XJ,Li HY,et al.Development of novel assisting agents for the electrokinetic remediation of heavy metal-contaminated kaolin.Electrochimica Acta,2016,218:140-148
[39]Guo SH,Fan RJ,Li TT,et al.Synergistic effects of bioremediation and electrokinetics in the remediation of petroleum-contaminated soil.Chemosphere,2014,109:226-233
[40]Yeung AT,Gu YY.A review on techniques to enhance electrochemical remediation of contaminated soils.Journal of Hazardous Materials,2011,195:11-29
[41]Zhu SF,Zhang J,Dong T.Removal of fluorine from contaminated field soil by anolyte enhanced electrokinetic remediation.Environmental Earth Sciences,2009,59:379-384
[42]Zhu S-F(朱书法),Du J-P(杜锦屏),Suo M-Y(索美玉),et al.Alkaline electrolyte circulation enhanced electrokinetic remediation of fluorine-contaminated soils.Ecology and Environmental Sciences(生态环境学报),2009,18(5):1767-1771(in Chinese)
[43]Zhu S-F(朱书法),Yan C-L(闫春丽),Dong T-Y(董铁有),et al.Anolyte enhanced electrokinetic remediation of fluorine-contaminated soils.Environmental Science(环境科学),2009,30(7):2082-2086(in Chinese)
[44]Zhou M,Zhu SF,Liu Y,et al.Removal of fluorine from contaminated soil by electrokinetic treatment driven by solar energy.Environmental Science and Pollution Research,2013,20:5806-5812
[45]Zhou M,Zhu SF,Liu F,et al.Pulse-enhanced electrokinetic remediation of fluorine-contaminated soil.Korean Journal of Chemical Engineering,2014,31:2008-2013
[46]Zhou M,Zhu SF,Liu Y,et al.Electrokinetic remediation of fluorine-contaminated soil using approaching cathodes.Clean:Soil,Air,Water,2014,42:1771-1775
[47]Zhou M,Wang H,Zhu SF,et al.Electrokinetic remediation of fluorine-contaminated soil and its impact on soil fertility.Environmental Science and Pollution Research,2015,22:16907-16913
[48]Zhu SF,Zhu D,Wang X.Removal of fluorine from red mud(bauxite residue)by electrokinetics.Electrochimica Acta,2017,242:300-306
[49]Cui D-J(崔德杰),Zhang Y-L(张玉龙).Current situation of soil contamination by heavy metals and research advances on the remediation techniques.Chinese Journal of Soil Science(土壤通报),2004,35(3):366-370(in Chinese)
[50]Dickinson NM,Baker AJM,Doronila A,et al.Phytoremediation of inorganics:Realism and synergies.International Journal of Phytoremediation,2009,11:97-114
[51]Ma L-F(马立锋),Ruan J-Y(阮建云),Shi Y-Z(石元值),et al.Study on accumulation characteristics of fluorine in tea plants.Acta Agriculturae Zhejiangensis(浙江农业学报),2004,16(2):46-48(in Chinese)
[52]Hu Z-L(胡志林).Trace elements in soil and plant of Tianshan grassland.Xinjiang Agricultural Sciences(新疆农业科学),1990,62(6):257-260(in Chinese)
[53]Wen Y-L(文勇立),Li H(李辉),Li X-W(李学伟),et al.Research on caparison of the content of trace element in soft and forage in Northwest Sichuan grassland.Acta Ecologica Sinica(生态学报),2007,27(7):2837-2846(in Chinese)
[54]Wu D-S(吴代赦),Wu T(吴铁),Dong R-B(董瑞斌),et al.Advances in absorption and enrichment of soil fluoride by plants.Journal of Nanchang University(Engineering&Technology)(南昌大学学报:工科版),2008,30(2):103-111(in Chinese)
[55]Li F(利锋).Soil fluorine and plants.Guangdong Trace Elements Science(广东微量元素科学),2004,11(5):6-11(in Chinese)
[56]Meng X-X(孟宪玺),Zhang L-P(张丽萍),Wang Z-Y(王宗义),et al.Fluorine in the eco-environment in the southwestern of Songnen Plain.Acta Ecologica Sinica(生态学报),1988,8(4):324-329(in Chinese)
[57]Cao J(曹进),Zhao Y(赵燕),Liu J-W(刘箭卫),et al.Environmental fluorine level in Tibet.Chinese Journal of Applied Ecology(应用生态学报),2000,11(5):777-779(in Chinese)
[58]He F(何锋),Duan C-Q(段昌群),Hou Y-P(侯永平).Investigation of fluorine accumulation in some vegetables in Yunnan,China.Ecology and Environmnet(生态环境),2004,13(3):327-329(in Chinese)
[59]Wang TH,Lin CS,Wu C,et al.Fluorine content of Fukien teas.Journal of Food Science,1949,14:98-103
[60]Fung KF,Zhang ZQ,Wong JWC,et al.Fluoride contents in tea and soil from tea plantations and the release of fluoride into tea liquor during infusion.Environmental Pollution,1999,104:197-205
[61]Sha J-Q(沙济琴),Zheng D-X(郑达贤).Bioaccumulation characteristics of fluoride in tea tree Astragalus.Fujian Tea(福建茶叶),1993,20(3):25-28(in Chinese)
[62]Loganathan P,Hedley MJ,Wallace GC,et al.Fluoride accumulation in pasture forages and soils following longterm applications of phosphorus fertilisers.Environmental Pollution,2001,115:275-282
[63]Zhu F-H(朱法华),Zhang J-R(张景荣),Yao S-P(姚素平).Fluorine distribution in plants of Xuzhou epidemic fluorosis area and its environmental significance.Geological Journal of China Universities(高校地质学报),2001,7(2):158-163(in Chinese)
[64]Hu Y-D(胡永定),Li J(李炬).Fluoride pollution and its characteristics in soil and vegetables in Jingmahe area.Agro-Environmental Protection(农业环境保护),1993,12(5):204-207(in Chinese)
[65]Duan M(段敏),Ma W-X(马往校),Sun X-T(孙新涛),et al.Analyses and assessment of fluorine pollution situation in 10 kinds of vegetables in Xian.Journal of Anhui Agricultural Sciences(安徽农业科学),2008,36(15):6267-6269(in Chinese)
[66]Lan D,Wu D,Li P,et al.Influence of high-fluorine environmental background on crops and human health in hot spring-type fluorosis-diseased areas.Chinese Journal of Geochemistry,2008,27:335-341
[67]Liang C-P(梁翠萍),Liu L(刘蕾),Yu S-P(于书萍),et al.Technical analysis of groundwater and soil ecological management in high fluoride areas.Water Sciences and Engineering Technology(水科学与工程技术),2015,25(2):59-61(in Chinese)
[68]Li R-B(李日邦),Zheng D-X(郑达贤),Wang L-Z(王丽珍),et al.A study of fluoride absorption of by plants in soil-plant ecological system.Acta Geographica Sinica(地理学报),1986,41(2):123-131(in Chinese)
[69]Chen G-J(陈国阶).Discussion on the experiment of fluoride-containing sewage irrigation.Environmental Science(环境科学),1979,4(2):13-17(in Chinese)
[70]Xie ZM,Ye ZH,Wong MH.Distribution characteristics of fluoride and aluminum in soil profiles of an abandoned tea plantation and their uptake by six woody species.Environment International,2001,26:341-346
[71]Fung KF,Zhang ZQ,Wong JWC,et al.Aluminium and fluoride concentrations of three tea varieties growing at Lantau Island,Hong Kong.Environmental Geochemistry and Health,2003,25:219-232
[72]Arnesen AKM.Availability of fluoride to plants grown in contaminated soils.Plant and Soil,1997,191:13-25
[73]lvarez-Ayuso E,Giménez A,Ballesteros JC.Fluoride accumulation by plants grown in acid soils amended with flue gas desulphurisation gypsum.Journal of Hazardous Materials,2011,192:1659-1666
[74]Ruan J,Ma L,Shi Y.et al.The impact of p H and calcium on the uptake of fluoride by tea plants(Camellia sinensis L.).Annals of Botany,2004,93:97-105
[75]Ma L-F(马立锋),Ruan J-Y(阮建云),Shi Y-Z(石元值),et al.Uptake of fluorine by tea plant(Camellia sinensis)and the impact of calcium(calcium oxide and calcium nitrate)on F uptake.Chinese Journal of Soil Science(土壤通报),2005,36(1):85-87(in Chinese)
[2]Mohapatra M,Anand S,Mishra BK,et al.Review of fluoride removal from drinking water.Journal of Environmental Management,2009,91:67-77
[3]Chen J-J(陈剑杰),Cao J-L(曹谨玲),Luo Y-J(罗永巨),et al.Effects of nano-selenium on antioxidant capacity and histopathology of Cyprinus carpio liver under fluoride stress.Chinese Journal of Applied Ecology(应用生态学报),2013,24(10):2970-2976(in Chinese)
[4]Chen Y-Y(陈玉银),Lu S-G(卢升高).Fluoride accumulation and distribution in mulberry insects near fluoride pollution sources.Chinese Journal of Applied Ecology(应用生态学报),2002,13(1):106-108(in Chinese)
[5]Li Y-H(李永华),Wang W-Y(王五一),Hou S-F(侯少范).Safety threshold of fluorine in endemic fluorosis regions in China.Environmental Science(环境科学),2002,23(4):118-122(in Chinese)
[6]Zhu SF,Han D,Zhou M,et al.Ammonia enhanced electrokinetics coupled with bamboo charcoal adsorption for remediation of fluorine-contaminated kaolin clay.Electrochimica Acta,2016,198:241-248
[7]Chen H,Yan M,Yang X,et al.Spatial distribution and temporal variation of high fluoride contents in groundwater and prevalence of fluorosis in humans in Yuanmou County,Southwest China.Journal of Hazardous Materials,2012,235-236:201-209
[8]Wang X-F(王兴峰).Actuality investigation and prevention measures on fluorine pollution of soil in some aluminium factory area.Gansu Metallurgy(甘肃冶金),2008,30(5):62-65(in Chinese)
[9]Li Q(李青),Zhou L-B(周连碧),Zhu Y-B(祝怡斌).Review of heavy metal pollution remediation technology in mine soil.Non-Ferrous Metal Engineering(有色金属工程),2013,3(2):56-59(in Chinese)
[10]Chen H-M(陈怀满),Zhu Y-G(朱永官),Dong Y-H(董元华),et al.Environmental Soil Science.2nd Ed.Beijing:Science Press,2018(in Chinese)
[11]Yang J-Y(杨金燕),Gou M(苟敏).The research status of fluorine contamination in soils of China.Ecology and Environmnet(生态环境学报),2017,26(3):506-513(in Chinese)
[12]Yi C-Y(易春瑶),Wang B-G(汪丙国),Jin M-G(靳孟贵).Research progress of migration and transformation laws of fluoride in ground water-soil-plant system.Safety and Environmental Engineering(安全与环境工程),2013,20(6):59-64(in Chinese)
[13]Xie Z-M(谢正苗),Wu W-H(吴卫红),Xu J-M(徐建民).Translocation and transformation of fluorides in the environment and their biological effects.Progress in Environmental Science(环境科学进展),1999,7(2):41-54(in Chinese)
[14]Pan H(潘宏),Chen B-B(陈邦本),Fang M(方明).Discussion on mechanism of variations in content of water-soluble fluorine during desalinization of coastal saline soils of Jiangsu Province.Acta Pedologica Sinica(土壤学报),1993,30(4):416-422(in Chinese)
[15]Li C-H(黎成厚),Wan H-Y(万红友),Shi H-Q(师会勤),et al.Preliminary study on the water-soluble fluorine content in soil and the factors affecting it.Journal of Mountain Agriculture and Biology(山地农业生物学报),2003,22(2):99-104(in Chinese)
[16]Loganathan P,Gray CW,Hedley MJ,et al.Total and soluble fluorine concentrations in relation to properties of soils in New Zealand.European Journal of Soil Science,2006,57:411-421
[17]Yu D-F(余大富).Fluorine pollution in soil and its harm.Environmental Science(环境科学),1982,3(6):70-74(in Chinese)
[18]Yu Q-Y(于群英),Ci E(慈恩),Yang L-Z(杨林章).Contents of different soil fluorine forms in North Anhui and their affecting factors.Chinese Journal of Applied Ecology(应用生态学报),2007,18(6):1333-1340(in Chinese)
[19]Wenzel W,Blum WEH.Fluorine speciation and mobility in F-contaminated soils.Soil Science,1992,153:357-364
[20]Wang L-X(王凌霞),Fu Q-L(付庆灵),Hu H-Q(胡红青),et al.Fluorine content in tea leaf and fluorine fractionation in soils of tea gardens in Hubei Province.Environmental Chemistry(环境化学),2011,30(3):662-667(in Chinese)
[21]Elrashidi MA,Adriano DC,Workman SM,et al.Chemical equilibria of fluorine in soils:A theoretical development.Soil Science,1986,141:274-280
[22]Liu Z-Y(刘征原),Hao R-B(郝瑞彬).Environmental geochemistry characteristics of fluorine and its biological effects.Journal of Tangshan Teachers College(唐山师范学院学报),2007,29(2):34-36(in Chinese)
[23]Zhang H-Y(张海燕),Liu Y(刘阳),Li J(李娟),et al.Review of heavy metal contaminated soil remediation technology.Sichuan Environment(四川环境),2010,29(6):138-141(in Chinese)
[24]Wang L-Q(王立群),Luo L(罗磊),Ma Y-B(马义兵),et al.In situ immobilization remediation of heavy metals-contaminated soils:A review.Chinese Journal of Applied Ecology(应用生态学报),2009,20(5):1214-1222(in Chinese)
[25]Liang C-H(梁成华),Chen X-Z(陈新之),Li H-Z(李焕珍),et al.Effect of application phosphogysum on contents and adsorption characteristic of fluorine in alkline soils.Acta Scientiae Circumstantiae(环境科学学报),1999,19(1):111-114(in Chinese)
[26]Cui J-X(崔俊学),Chen W(陈文),Ouyang J(欧阳津).The effect of calcium on different species of fluorine in soil.Guangzhou Chemistry(广州化学),2009,34(9):13-18(in Chinese)
[27]Wang L-X(王凌霞),Hu H-Q(胡红青),Min Y-L(闵艳林),et al.Simulated control of water-soluble fluoride content in tea garden soils.Acta Scientiae Circumstantiae(环境科学学报),2011,31(7):1517-1525(in Chinese)
[28]Huang L(黄雷),Zhang S-W(张时伟),Shen Y(沈彦),et al.Effect of the combination of calcium oxide and calcium magnesium phosphate fertilizer on water soluble fluorine content in soil.Environmental Science&Technology(环境科学与技术),2016,39(suppl.2):109-112(in Chinese)
[29]Wang K-Y(王开勇),Yang L(杨乐),Zhao T-Y(赵天一),et al.The environmental effect of organic materials on soil soluble fluorine.Ecology and Environment(生态环境),2007,16(3):879-882(in Chinese)
[30]Gao H,Zhang Z,Wan X.Influences of charcoal and bamboo charcoal amendment on soil-fluoride fractions and bioaccumulation of fluoride in tea plants.Environmental Geochemistry and Health,2012,34:551-562
[31]Zhang Y-L(张永利),Wang Y-J(王烨军),Song L(宋莉),et al.Effects of N,P and K fertilizer on the concentration of fluoride in tea garden soil solution.Soil and Fertilizer Sciences in China(中国土壤与肥料),2017,46(3):28-35(in Chinese)
[32]An CJ,Huang GH,Wei J,et al.Effect of short-chain organic acids on the enhanced desorption of phenanthrene by rhamnolipid biosurfactant in soil-water environment.Water Research,2011,45:5501-5510
[33]Zou Z,Qiu R,Zhang W,et al.The study of operating variables in soil washing with EDTA.Environmental Pollution,2009,157:229-236
[34]Xu R,Wang Y,Zhao A,et al.Effect of low molecular weight organic acids on adsorption and desorption of fluoride on variable charge soils.Environmental Geochemistry and Health,2006,28:141-146
[35]Li Q(李琼),Zeng Q-R(曾清如).A technique for simultaneous removal of heavy metals,arsenic and fluoride from contaminated soil by chelating agents.Journal of Hunan City University(Natural Science)(湖南城市学院学报:自然科学版),2014,23(2):63-66(in Chinese)
[36]Kim DH,Jeon CS,Baek K,et al.Electrokinetic remediation of fluorine-contaminated soil:Conditioning of anolyte.Journal of Hazardous Materials,2009,161:565-569
[37]Moon DH,Jo R,Koutsospyros A,et al.Soil washing of fluorine contaminated soil using various washing solutions.Bulletin of Environmental Contamination and Toxicology,2015,94:334-339
[38]Yuan LZ,Xu XJ,Li HY,et al.Development of novel assisting agents for the electrokinetic remediation of heavy metal-contaminated kaolin.Electrochimica Acta,2016,218:140-148
[39]Guo SH,Fan RJ,Li TT,et al.Synergistic effects of bioremediation and electrokinetics in the remediation of petroleum-contaminated soil.Chemosphere,2014,109:226-233
[40]Yeung AT,Gu YY.A review on techniques to enhance electrochemical remediation of contaminated soils.Journal of Hazardous Materials,2011,195:11-29
[41]Zhu SF,Zhang J,Dong T.Removal of fluorine from contaminated field soil by anolyte enhanced electrokinetic remediation.Environmental Earth Sciences,2009,59:379-384
[42]Zhu S-F(朱书法),Du J-P(杜锦屏),Suo M-Y(索美玉),et al.Alkaline electrolyte circulation enhanced electrokinetic remediation of fluorine-contaminated soils.Ecology and Environmental Sciences(生态环境学报),2009,18(5):1767-1771(in Chinese)
[43]Zhu S-F(朱书法),Yan C-L(闫春丽),Dong T-Y(董铁有),et al.Anolyte enhanced electrokinetic remediation of fluorine-contaminated soils.Environmental Science(环境科学),2009,30(7):2082-2086(in Chinese)
[44]Zhou M,Zhu SF,Liu Y,et al.Removal of fluorine from contaminated soil by electrokinetic treatment driven by solar energy.Environmental Science and Pollution Research,2013,20:5806-5812
[45]Zhou M,Zhu SF,Liu F,et al.Pulse-enhanced electrokinetic remediation of fluorine-contaminated soil.Korean Journal of Chemical Engineering,2014,31:2008-2013
[46]Zhou M,Zhu SF,Liu Y,et al.Electrokinetic remediation of fluorine-contaminated soil using approaching cathodes.Clean:Soil,Air,Water,2014,42:1771-1775
[47]Zhou M,Wang H,Zhu SF,et al.Electrokinetic remediation of fluorine-contaminated soil and its impact on soil fertility.Environmental Science and Pollution Research,2015,22:16907-16913
[48]Zhu SF,Zhu D,Wang X.Removal of fluorine from red mud(bauxite residue)by electrokinetics.Electrochimica Acta,2017,242:300-306
[49]Cui D-J(崔德杰),Zhang Y-L(张玉龙).Current situation of soil contamination by heavy metals and research advances on the remediation techniques.Chinese Journal of Soil Science(土壤通报),2004,35(3):366-370(in Chinese)
[50]Dickinson NM,Baker AJM,Doronila A,et al.Phytoremediation of inorganics:Realism and synergies.International Journal of Phytoremediation,2009,11:97-114
[51]Ma L-F(马立锋),Ruan J-Y(阮建云),Shi Y-Z(石元值),et al.Study on accumulation characteristics of fluorine in tea plants.Acta Agriculturae Zhejiangensis(浙江农业学报),2004,16(2):46-48(in Chinese)
[52]Hu Z-L(胡志林).Trace elements in soil and plant of Tianshan grassland.Xinjiang Agricultural Sciences(新疆农业科学),1990,62(6):257-260(in Chinese)
[53]Wen Y-L(文勇立),Li H(李辉),Li X-W(李学伟),et al.Research on caparison of the content of trace element in soft and forage in Northwest Sichuan grassland.Acta Ecologica Sinica(生态学报),2007,27(7):2837-2846(in Chinese)
[54]Wu D-S(吴代赦),Wu T(吴铁),Dong R-B(董瑞斌),et al.Advances in absorption and enrichment of soil fluoride by plants.Journal of Nanchang University(Engineering&Technology)(南昌大学学报:工科版),2008,30(2):103-111(in Chinese)
[55]Li F(利锋).Soil fluorine and plants.Guangdong Trace Elements Science(广东微量元素科学),2004,11(5):6-11(in Chinese)
[56]Meng X-X(孟宪玺),Zhang L-P(张丽萍),Wang Z-Y(王宗义),et al.Fluorine in the eco-environment in the southwestern of Songnen Plain.Acta Ecologica Sinica(生态学报),1988,8(4):324-329(in Chinese)
[57]Cao J(曹进),Zhao Y(赵燕),Liu J-W(刘箭卫),et al.Environmental fluorine level in Tibet.Chinese Journal of Applied Ecology(应用生态学报),2000,11(5):777-779(in Chinese)
[58]He F(何锋),Duan C-Q(段昌群),Hou Y-P(侯永平).Investigation of fluorine accumulation in some vegetables in Yunnan,China.Ecology and Environmnet(生态环境),2004,13(3):327-329(in Chinese)
[59]Wang TH,Lin CS,Wu C,et al.Fluorine content of Fukien teas.Journal of Food Science,1949,14:98-103
[60]Fung KF,Zhang ZQ,Wong JWC,et al.Fluoride contents in tea and soil from tea plantations and the release of fluoride into tea liquor during infusion.Environmental Pollution,1999,104:197-205
[61]Sha J-Q(沙济琴),Zheng D-X(郑达贤).Bioaccumulation characteristics of fluoride in tea tree Astragalus.Fujian Tea(福建茶叶),1993,20(3):25-28(in Chinese)
[62]Loganathan P,Hedley MJ,Wallace GC,et al.Fluoride accumulation in pasture forages and soils following longterm applications of phosphorus fertilisers.Environmental Pollution,2001,115:275-282
[63]Zhu F-H(朱法华),Zhang J-R(张景荣),Yao S-P(姚素平).Fluorine distribution in plants of Xuzhou epidemic fluorosis area and its environmental significance.Geological Journal of China Universities(高校地质学报),2001,7(2):158-163(in Chinese)
[64]Hu Y-D(胡永定),Li J(李炬).Fluoride pollution and its characteristics in soil and vegetables in Jingmahe area.Agro-Environmental Protection(农业环境保护),1993,12(5):204-207(in Chinese)
[65]Duan M(段敏),Ma W-X(马往校),Sun X-T(孙新涛),et al.Analyses and assessment of fluorine pollution situation in 10 kinds of vegetables in Xian.Journal of Anhui Agricultural Sciences(安徽农业科学),2008,36(15):6267-6269(in Chinese)
[66]Lan D,Wu D,Li P,et al.Influence of high-fluorine environmental background on crops and human health in hot spring-type fluorosis-diseased areas.Chinese Journal of Geochemistry,2008,27:335-341
[67]Liang C-P(梁翠萍),Liu L(刘蕾),Yu S-P(于书萍),et al.Technical analysis of groundwater and soil ecological management in high fluoride areas.Water Sciences and Engineering Technology(水科学与工程技术),2015,25(2):59-61(in Chinese)
[68]Li R-B(李日邦),Zheng D-X(郑达贤),Wang L-Z(王丽珍),et al.A study of fluoride absorption of by plants in soil-plant ecological system.Acta Geographica Sinica(地理学报),1986,41(2):123-131(in Chinese)
[69]Chen G-J(陈国阶).Discussion on the experiment of fluoride-containing sewage irrigation.Environmental Science(环境科学),1979,4(2):13-17(in Chinese)
[70]Xie ZM,Ye ZH,Wong MH.Distribution characteristics of fluoride and aluminum in soil profiles of an abandoned tea plantation and their uptake by six woody species.Environment International,2001,26:341-346
[71]Fung KF,Zhang ZQ,Wong JWC,et al.Aluminium and fluoride concentrations of three tea varieties growing at Lantau Island,Hong Kong.Environmental Geochemistry and Health,2003,25:219-232
[72]Arnesen AKM.Availability of fluoride to plants grown in contaminated soils.Plant and Soil,1997,191:13-25
[73]lvarez-Ayuso E,Giménez A,Ballesteros JC.Fluoride accumulation by plants grown in acid soils amended with flue gas desulphurisation gypsum.Journal of Hazardous Materials,2011,192:1659-1666
[74]Ruan J,Ma L,Shi Y.et al.The impact of p H and calcium on the uptake of fluoride by tea plants(Camellia sinensis L.).Annals of Botany,2004,93:97-105
[75]Ma L-F(马立锋),Ruan J-Y(阮建云),Shi Y-Z(石元值),et al.Uptake of fluorine by tea plant(Camellia sinensis)and the impact of calcium(calcium oxide and calcium nitrate)on F uptake.Chinese Journal of Soil Science(土壤通报),2005,36(1):85-87(in Chinese)