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Variations of Ca2+, Mg2+, Sr2+ in Groundwater and Surface Water from the Xueyu Cave
详细信息   
摘要

A one-year study of water geochemistry was performed in the Xueyu cave in 2011, the concentra- tions of Ca2 , Mg2 ,St2 and elemental ratios of Mg/Ca,Sr/Ca in drip water, groundwater and epikarst spring water from the overlaying bedrock as well as the surface water from the Long River were measured. The results indicate the variation of Ca2 ,Mg ,Sr2 along with the precipitation was notable. The Caz in epikarst spring water can response with the change of precipitation sensitively. The drop water responses to the change of precipitation may last for a month. The rainy season and the dry season can be reflected by the underground water. The content of Caf in the surface water was stable all year round but had pronounced reflection to extreme dry weather. The variations of Mg2 and Sr2 in different types of water were consist- ent with each other yearly in 2011, and the concentrations of Mg2 and Sr were lower in March, May and October with much rainfall, but higher in other months with little rainfall. The above changes in cation con- centrations were related to the dilution effect, COz effect and lithology. The ratios of Mg/Ca and Sr/Ca in different kinds of waters from the Xueyu cave system ranged from high to low as follows drip water, surface water, ground water and spring water, reflecting different detention time in the aquifer media and reacting time with bedrock. The ratios of Mg/Ca and St/Ca were low during wet period and high during dry period. For the impact of the former calcium carbonate precipitation and the variance in transport routes, there are slight differences in the ratios of Mg/Ca,Sr/Ca. Therefore, the change of ions concentration and their ratios in different types of water is different in the responding time and features to external precipitation, which de- ciding that it should make difference when determining external environmental changes with the elements and their ratios.

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