Back Cover: A Hydrogen-Bonded Cyanide-Bridged [Co₂Fe₂] Square Complex Exhibiting a Three-Step Spin Transition (Angew. Chem. Int. Ed. 2/2017)

详细信息    查看全文

• 作者：Prof. Dr. Masayuki Nihei ; Yuta Yanai ; Dr. I.-Jui Hsu ; Dr. Yoshihiro Sekine and Prof. Dr. Hiroki Oshio
• 刊名：Angewandte Chemie International Edition
• 出版年：2017
• 出版时间：January 9, 2017
• 年：2017
• 卷：56
• 期：2
• 页码：656
• 全文大小：3584K
• ISSN：1521-3773

文摘

Lord of the Dance Dynamic hydrogen-bonding interactions and spin-transition behavior play a key role in stabilizing intermediate phases in a multi-step spin transition. In their Communication on page 595 ff., M. Nihei, H. Oshio, et al. present a hydrogen-bonding donor–acceptor system, comprising a spin transition-active square complex [Co₂Fe₂] and aromatic hydrogen-bond-donor molecules, which exhibits a three-step spin transition in response to temperature.