Carbon- and sulfur-isotope geochemistry of the Hirnantian (Late Ordovician) Wangjiawan (Riverside) section, South China: Global correlation and environmental event interpretation

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• 作者：Paul Gorjan^a ; ^{pgorjan@levee.wustl.edu} ; Kunio Kaiho^b ; David A. Fike^a ; Chen Xu^c
• 关键词：Hirnantian ; Stratigraphy ; Wangjiawan ; Glaciation ; Carbon isotopes ; Sulfur isotopes
• 刊名：Palaeogeography ; Palaeoclimatology ; Palaeoecology
• 出版年：2012
• 期刊代码：68_00310182
• 类别：ear
• 出版时间：15 June, 2012
• 卷：337-338
• 期：Complete
• 页码：14-22
• 文件大小：1099 K

摘要

Detailed geochemical analyses (未¹³C_carb, 未¹³C_org, 未³⁴S_sulfide, and abundance of sulfide, carbonate and organic carbon) were performed on samples from the Wangjiawan (Riverside) section, close to the GSSP (Global Stratotype Section and Point) for the Hirnantian stage of the Ordovician. New data show two increases in carbonate content coincident with two glacial pulses that reduced detrital input. The new 未³⁴S_sulfide data show distinct changes in this section, with relatively high values in the Kuanyinchiao Formation, a pattern observed throughout the Yangtze Platform. However, there is no consensus on the cause of these changes. The new 未¹³C_carb data show a sharp rise and peak in the extraordinarius zone, below the previously published 未¹³C_org peak in the persculptus zone. A compilation of the new results with other sections indicates the Hirnantian carbon-isotope excursion starts near the pacificus-extraordinarius boundary and elevated values remain until the end of the excursion in the persculptus zone for both 未¹³C_org and 未¹³C_carb. The controversy over correlating Hirnantian graptolite zones with chitinozoan zones can also be addressed. The new 未¹³C_carb data also allow direct comparison with Hirnantian 未¹³C_carb data from Anticosti Island and the Baltic region, which are zoned by chitinozoan fossils. This comparison favors a correlation of the taugourdeaui and scabra chitinozoan zones with the extraordinarius graptolite zone.