纳米结构金属氧化物气敏材料的研究进展
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摘要
具有纳米结构的金属氧化物由于纳米效应表现出了非常优异的气敏性能;以维度为线索,简要综述了零维、一维、二维和三维纳米结构金属氧化物气敏材料的制备方法和不同结构对其气敏性能的影响,最后指出了未来该领域的研究和发展方向。
Nanostructured metal oxides exhibits outstanding gas sensing properties due to nanometer effect.From the perspective of dimension,the preparation for zero,one,two,and three dimensional structured metal oxides and the effect of different structure on gas sensing properties are briefly reviewed.At last,it is pointed that the research and development direction for the field in future.
Nanostructured metal oxides exhibits outstanding gas sensing properties due to nanometer effect.From the perspective of dimension,the preparation for zero,one,two,and three dimensional structured metal oxides and the effect of different structure on gas sensing properties are briefly reviewed.At last,it is pointed that the research and development direction for the field in future.
引文
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[32]ZHANG X L,QIAO R,KIM J C,et al.Inorganic clustersynthesis and characterization of transition-metal-doped ZnOhollow spheres[J].Crystal Growth&Design,2008,8(8):2609-2613.
[33]ZHANG J,WANG S,WANG Y,et al.NO2sensing per-formance of SnO2hollow-sphere sensor[J].Sensors and Ac-tuators B:Chemical,2009,135(2):610-617.
[34]MO M,YU J C,ZHANG L Z,et al.Self-assembly of ZnOnanorods and nanosheets into hollow microhemispheres andmicrospheres[J].Advanced Materials,2005,17(6):756-760.
[35]LIU J,LUO T,MENG F,et al.Porous hierarchical In2O3micro-nanostructures:Preparation,formation mechanism,and their application in gas sensors for noxious volatile organ-ic compound detection[J].Journal of Physical Chemistry C,2010,114(11):4887-4894.
[36]DONG Q,SU H,XU J,et al.Influence of hierarchicalnanostructures on the gas sensing properties of SnO2biomor-phic films[J].Sensors and Actuators B-Chemical,2007,123(1):420-428.
[37]SONG F,SU H,HAN J,et al.Controllable synthesis andgas response of biomorphic SnO2with architecture hierarchyof butterfly wings[J].Sensors and Actuators B-Chemical,2010,145(1):39-45.
[2]杨华明,张科,史蓉蓉,等.介孔组装纳米TiO2催化材料的研究进展[J].机械工程材料,2005,29(4):7-10.
[3]宋也黎,李国伟,晋跃,等.水热法合成花状MoS2纳米粉及其摩擦学性能[J].机械工程材料,2011,35(6):49-52.
[4]KENNEDY M K,KRUIS F E,FISSAN H,et al.Tailorednanoparticle films from monosized tin oxide nanocrystals:Par-ticle synthesis,film formation,and size-dependent gas-sensingproperties[J].Journal of Applied Physics,2003,93(1):551-560.
[5]SAHM T,MADLER L,GURLO A,et al.Flame spray syn-thesis of tin dioxide nanoparticles for gas sensing[J].Sensorsand Actuators B-Chemical,2004,98(2/3):148-153.
[6]ZHU B L,XIE C S,ZENG D W,et al.New method of syn-thesizing In2O3nanoparticles for application in volatile organiccompounds(VOCs)gas sensors[J].Journal of Materials Sci-ence,2005,40(21):5783-5785.
[7]PINNA N,NERI G,ANTONIETTI M,et al.Nonaqueoussynthesis of nanocrystalline semiconducting metal oxides forgas sensing[J].Angewandte Chemie-International Edition,2004,43(33):4345-4349.
[8]NAYRAL C,VIALA E,FAU P,et al.Synthesis of tin andtin oxide nanoparticles of low size dispersity for application ingas sensing[J].Chemistry-a European Journal,2000,6(22):4082-4090.
[9]HEIDARI E K,MARZBANRAD E,ZAMANI C,et al.Nanocasting synthesis of ultrafine WO3nanoparticles for gassensing applications[J].Nanoscale Research Letters,2010,5(2):370-373.
[10]KERSEN U,SUNDBERG M R.The reactive surface sitesand the H2S sensing potential for the SnO2 produced by amechanochemical milling[J].Journal of the ElectrochemicalSociety,2003,150(6):H129-H134.
[11]LIM S K,HWANG S H,CHANG D,et al.Preparation ofmesoporous In2O3nanofibers by electrospinning and their ap-plication as a CO gas sensor[J].Sensors and Actuators B-Chemical,2010,149(1):28-33.
[12]ZHENG W,LU X,WANG W,et al.A highly sensitive andfast-responding sensor based on electrospun In2O3nanofibers[J].Sensors and Actuators B-Chemical,2009,142(1):61-65.
[13]XU L,DONG B,WANG Y,et al.Electrospinning prepara-tion and room temperature gas sensing properties of porousIn2O3nanotubes and nanowires[J].Sensors and Actuators B-Chemical,2010,147(2):531-538.
[14]PASHCHANKA M,HOFFMANN R C,GURLO A,et al.Molecular based,chimie douce approach to 0Dand 1Dindiumoxide nanostructures:Evaluation of their sensing propertiestowards CO and H2[J].Journal of Materials Chemistry,2010,20(38):8311-8319.
[15]YIN Y X,JIANG L Y,WAN L J,et al.Polyethylene gly-col-directed SnO2nanowires for enhanced gas-sensing proper-ties[J].Nanoscale,2011,3(4):1802-1806.
[16]XI G,YE J.Ultrathin SnO2nanorods:Template-and surfac-tant-free solution phase synthesis,growth mechanism,opti-cal,gas-sensing,and surface adsorption properties[J].Inor-ganic Chemistry,2010,49(5):2302-2309.
[17]LIAO L,ZHENG Z,YAN B,et al.Morphology controlla-ble synthesis of alpha-Fe2O31D nanostructures:Growthmechanism and nanodevice based on single nanowire[J].Jour-nal of Physical Chemistry C,2008,112(29):10784-10788.
[18]JING Z,ZHAN J.Fabrication and gas-sensing properties ofporous ZnO nanoplates[J].Advanced Materials,2008,20(23):4547-4551.
[19]GURLO A,BARSAN N,IVANOVSKAYA M,et al.In2O3and MoO3-In2O3thin film semiconductor sensors:Interactionwith NO2and O3[J].Sensors and Actuators B-Chemical,1998,47(1/3):92-99.
[20]CHAISITSAK S.Nanocrystalline SnO2:F thin films for liq-uid petroleum gas sensors[J].Sensors,2011,11(7):7127-7140.
[21]DANDENEAU C S,JEON Y-H,SHELTON C T,et al.Thin film chemical sensors based on p-CuO/n-ZnO heterocon-tacts[J].Thin Solid Films,2009,517(15):4448-4454.
[22]KANNAN S,STEINEBACH H,RIETH L,et al.Selectivi-ty,stability and repeatability of In2O3thin films towards NOxat high temperatures(≥500℃)[J].Sensors and Actuators B-Chemical,2010,148(1):126-134.
[23]VAEZI M R.SnO2/ZnO double-layer thin films:A noveleconomical preparation and investigation of sensitivity andstability of double-layer gas sensors[J].Materials Chemistryand Physics,2008,110(1):89-94.
[24]ABADI M H S,HAMIDON M N,SHAARI A H,et al.SnO2/Pt thin film laser ablated gas sensor array[J].Sensors,2011,11(8):7724-7735.
[25]JIA L,CAI W.Micro/nanostructured ordered porous filmsand their structurally induced control of the gas sensingperformances[J].Advanced Functional Materials,2010,20(21):3765-3773.
[26]SHAO S,QIU X,HE D,et al.Low temperature crystalliza-tion of transparent,highly ordered nanoporous SnO2 thinfilms:Application to room-temperature hydrogen sensing[J].Nanoscale,2011,3(10):4283-4289.
[27]YANG P D,ZHAO D Y,MARGOLESE D I,et al.Gener-alized syntheses of large-pore mesoporous metal oxides withsemicrystalline frameworks[J].Nature,1998,396:152-155.
[28]WANG Y D,MA C L,SUN X D,et al.Synthesis and char-acterization of ordered hexagonal and cubic mesoporous tinoxides via mixed-surfactant templates route[J].Journal ofColloid and Interface Science,2005,286(2):627-631.
[29]HAYASHI M,HYODO T,SHIMIZU Y,et al.Effects ofmicrostructure of mesoporous SnO2powders on their H2sen-sing properties[J].Sensors and Actuators B-Chemical,2009,141(2):465-470.
[30]TIAN B,LIU X,SOLOVYOV L A,et al.Facile synthesisand characterization of novel mesoporous and mesorelief ox-ides with gyroidal structures[J].Journal of the AmericanChemical Society,2003,126(3):865-875.
[31]WALTZ T,BECKER B,WAGNER T,et al.Ordered nano-porous SnO2gas sensors with high thermal stability[J].Sen-sors and Actuators B-Chemical,2010,150(2):788-793.
[32]ZHANG X L,QIAO R,KIM J C,et al.Inorganic clustersynthesis and characterization of transition-metal-doped ZnOhollow spheres[J].Crystal Growth&Design,2008,8(8):2609-2613.
[33]ZHANG J,WANG S,WANG Y,et al.NO2sensing per-formance of SnO2hollow-sphere sensor[J].Sensors and Ac-tuators B:Chemical,2009,135(2):610-617.
[34]MO M,YU J C,ZHANG L Z,et al.Self-assembly of ZnOnanorods and nanosheets into hollow microhemispheres andmicrospheres[J].Advanced Materials,2005,17(6):756-760.
[35]LIU J,LUO T,MENG F,et al.Porous hierarchical In2O3micro-nanostructures:Preparation,formation mechanism,and their application in gas sensors for noxious volatile organ-ic compound detection[J].Journal of Physical Chemistry C,2010,114(11):4887-4894.
[36]DONG Q,SU H,XU J,et al.Influence of hierarchicalnanostructures on the gas sensing properties of SnO2biomor-phic films[J].Sensors and Actuators B-Chemical,2007,123(1):420-428.
[37]SONG F,SU H,HAN J,et al.Controllable synthesis andgas response of biomorphic SnO2with architecture hierarchyof butterfly wings[J].Sensors and Actuators B-Chemical,2010,145(1):39-45.
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