南黄海盆地碳酸盐岩生烃动力学参数特征
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摘要
南黄海盆地碳酸盐岩生烃动力学参数的研究对于估算该盆地油气资源潜力极为重要.利用黄金管-高压釜封闭体系的实验设备,对南黄海盆地栖霞组和青龙组2个碳酸盐岩样品进行了热模拟实验及生烃动力学分析.结果表明,栖霞组灰岩热解气体最高产率为102mL/g TOC,青龙组灰岩为78mL/g TOC;栖霞组灰岩生烃活化能主峰为52kcal/mol,青龙组灰岩生烃活化能主峰为60kcal/mol.栖霞组灰岩活化能主峰偏低可能是受样品中残留烃类影响,热成熟度参数Ro与气体产率的关系不受地质升温速率的影响,可以利用实验结果进行碳酸盐岩生烃量模拟.
The kinetics data of hydrocarbon generation in South Yellow Sea Basin is very important for its hydrocarbon potential evaluation.Pyrolysis experiments of Qixia Formation and Qinglong Formation carbonate samples in South Yellow Sea basin were carried out by using gold tube-autoclave instruments in finite space and then the kinetics data of hydrocarbon generation was analyzed.The results show that gas generation rate of Qixia carbonate is 102 mL/g TOC,and that of Qinglong Formation is 78 mL/g TOC.The mean value of activation energy of Qixia carbonate is 52 kcal/mol,and that of Qinglong carbonate is 60 kcal/mol.The low value of activation energy of Qixia carbonate is possibly caused by the residual hydrocarbon in the sample.The relationship between the maturity parameter Roand the gas generation rate is not affected by the rate of geo-heating rate,so the parameters can be used to simulate the carbonate hydrocarbon generation in South Yellow Sea Basin.
The kinetics data of hydrocarbon generation in South Yellow Sea Basin is very important for its hydrocarbon potential evaluation.Pyrolysis experiments of Qixia Formation and Qinglong Formation carbonate samples in South Yellow Sea basin were carried out by using gold tube-autoclave instruments in finite space and then the kinetics data of hydrocarbon generation was analyzed.The results show that gas generation rate of Qixia carbonate is 102 mL/g TOC,and that of Qinglong Formation is 78 mL/g TOC.The mean value of activation energy of Qixia carbonate is 52 kcal/mol,and that of Qinglong carbonate is 60 kcal/mol.The low value of activation energy of Qixia carbonate is possibly caused by the residual hydrocarbon in the sample.The relationship between the maturity parameter Roand the gas generation rate is not affected by the rate of geo-heating rate,so the parameters can be used to simulate the carbonate hydrocarbon generation in South Yellow Sea Basin.
引文
Feng,Z.Q.,Chen,C.F.,Yao,Y.J.,et al.,2008.Tectonic Evolution and Exploration Target of the Northern Foreland Basin of the South Yellow Sea.Earth Science Frontiers,15(6):219-231(in Chinese with English abstract).
Geng,X.H.,Geng,A.S.,Xiong,Y.Q.,et al.,2005.Kinetic Simulating Experiment on Marine Carbonate Source Rocks:Comparison of Source Rocks with Isolated Kerogens.Geochimica,34(6):612-618(in Chinese with English abstract).
Guo,X.W.,He,S.,Liu,K.Y.,et al.,2013.A Quantitative Estimation Model for the Overpressure Caused by Natural Gas Generation and Its Influential Factors.Earth Science,38(6):1263-1270(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2013.123
Han,W.X.,Ma,W.J.,Tao,S.Z.,et al.,2018.Hydrocarbon Generation Potential Evaluation of Upper Paleozoic Limestone in Ordos Basin.Earth Science,43(2):599-609(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2017.529
Jiang,Q.G.,Ma,Y.Y.,Li,X.,2011.Application of Single Cold Trap Pyrolysis Chromatography in Source Rock Evaluation.Petroleum Geology&Experiment,33(5):546-551,558(in Chinese with English abstract).
Jiang,Q.G.,Wang,Y.B.,Qin,J.Z.,et al.,2010.Kinetics of the Hydrocarbon Generation Process of Marine Source Rocks in South China.Petroleum Exploration and Development,37(2):174-180(in Chinese with English abstract).
Li,Q.,Zhang,Z.H.,Ou,G.X.,et al.,2014.Chemical Kinetics Study on Organic Matter in Source Rocks in Huangqiao Area.China Mining Magazine,23(6):92-95(in Chinese with English abstract).
Li,Z.M.,Zheng,L.J.,Jiang,Q.G.,et al.,2018.Simulation of Hydrocarbon Generation and Expulsion for Lacustrine Organic-Rich Argillaceous Dolomite and Its Implications for Shale Oil Exploration.Earth Science,43(2):566-576(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2018.024
Liang,D.G.,Guo,T.L.,Chen,J.P.,et al.,2008.Some Progresses on Studies of Hydrocarbon Generation and Accumulation in Marine Sedimentary Regions,Southern China(Part 1):Distribution of Four Suits of Regional Marine Source Rocks.Marine Origin Petroleum Geology,13(2):1-16(in Chinese with English abstract).
Liu,L.F.,Jiang,Z.X.,Zhong,N.N.,et al.,2009.HydrocarbonGenerating Dynamic Characteristics of Paleocene Source Rocks in Western Depression,Liaohe Basin.Earth Science,34(5):799-805(in Chinese with English abstract).
Lu,S.F.,Zhong,N.N.,Xue,H.T.,et al.,2007.Kinetics of the Hydrocarbon Secondary Generation of Carbonate Source Rocks and Its Meaning.Scientia Sinica Terrae,37(2):178-184(in Chinese).
Ma,Y.S.,Cai,X.Y.,Zhao,P.R.,et al.,2010.Distribution and Further Exploration of the Large-Medium Sized Gas Fields in Sichuan Basin.Acta Petrolei Sinica,31(3):347-354(in Chinese with English abstract).
Rao,S.,Hu,S.B.,Wang,J.Y.,2010.Hydrocarbon Generation Kinetic Parameters of Organic Matter:Review and Outlook.Progress in Geophysics,25(4):1424-1432(in Chinese with English abstract).
Tang,Q.Y.,Zhang,M.J.,Zhang,T.W.,et al.,2013.A Review on Pyrolysis Experimentation on Hydrocarbon Generation.Journal of Southwest Petroleum University(Science&Technology Edition),35(1):52-62(in Chinese with English abstract).
Tissot,B.P.,Welte,D.H.,1984.Petroleum Formation and Occurrence.Springer-Verlag,Berlin.
Wang,M.,Lu,S.F.,Xue,H.T.,et al.,2011.The Influence and Appraisement of Source Rock Heterogeneity on Kinetic Parameters of Hydrocarbon Generation from Organic Matter.Earth Science,36(3):530-540(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2011.054
Xu,L.H.,Chen,J.F.,Xue,H.T.,et al.,2008.Quantitative E-valuation of Secondary Hydrocarbon Generation of Carbonate Source Rocks Using Chemical Kinetics Method of Hydrocarbon Generation:A Case Study of the Zhujiadun Reservoir.Geochimica,37(3):251-257(in Chinese with English abstract).
Yao,Y.J.,Xia,B.,Feng,Z.Q.,et al.,2005.Tectonic Evolution of the South Yellow Sea since the Paleozoic.Petroleum Geology&Experiment,27(2):124-128(in Chinese with English abstract).
Zhang,L.,Xiong,Y.Q.,Chen,Y.,et al.,2017.Mechanisms of Shale Gas Generation from Typically Organic-Rich Marine Shales.Earth Science,42(7):1092-1106(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2017.088
Zhao,W.F.,Yang,F.L.,Zhuang,J.J.,2011.Analysis of the Tectonic Characteristics of Mesozoic-Palaeozoic in the Middle Uplift of the South Yellow Sea.Reservoir Evaluation and Development.1(5):6-13(in Chinese with English abstract).
Zhao,W.Z.,Wang,Z.C.,Hu,S.Y.,et al.,2012.Large-Scale Hydrocarbon Accumulation Factors and Characteristics of Marine Carbonate Reservoirs in Three Large Onshore Cratonic Basins in China.ActaPetroleiSinica,33(S2):1-10(in Chinese with English abstract).
Zheng,L.J.,Guan,D.F.,Guo,X.W.,et al.,2015.Key Geological Conditions Affecting Pyrolysis Experiments of Marine Source Rocks for Hydrocarbon Generation.Earth Science,40(5):909-917(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2015.075
Zheng,L.J.,He,S.,Qin,J.Z.,et al.,2011a.Formation Water of Near-Critical Properties and Its Effects on the Processes of Hydrocarbon Generation and Expulsion.Earth Science,36(1):83-92(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2011.009
Zheng,L.J.,Ma,Z.L.,Wang,Q.,et al.,2011b.Quantitative Evaluation of Hydrocarbon Yielding Potential of Source Rock:Application of Pyrolysis in Finite Space.Petroleum Geology&Experiment,33(5):452-459(in Chinese with English abstract).
Zou,C.N.,Du,J.H.,Xu,C.C.,et al.,2014.Formation,Distribution,Resource Potential and Discovery of the SinianCambrian Giant Gas Field,Sichuan Basin,SW China.Petroleum Exploration and Development,41(3):278-293(in Chinese with English abstract).
冯志强,陈春峰,姚永坚,等,2008.南黄海北部前陆盆地的构造演化与油气突破.地学前缘,15(6):219-231.
耿新华,耿安松,熊永强,等,2005.海相碳酸盐岩烃源岩热解动力学研究:全岩和干酪根的对比.地球化学,34(6):612-618.
郭小文,何生,刘可禹,等,2013.烃源岩生气增压定量评价模型及影响因素.地球科学,38(6):1263-1270.https://doi.org/10.3799/dqkx.2013.123
韩文学,麻伟娇,陶士振,等,2018.鄂尔多斯盆地上古生界灰岩烃源岩生烃潜力评价.地球科学,43(2):599-609.https://doi.org/10.3799/dqkx.2017.529
蒋启贵,马媛媛,李欣,等,2011.单冷阱热解色谱仪在烃源岩评价中的应用.石油实验地质,33(5):546-551,558.
蒋启贵,王延斌,秦建中,等,2010.中国南方海相烃源岩生烃过程动力学研究.石油勘探与开发,37(2):174-180.
黎琼,张枝焕,欧光习,等,2014.黄桥地区烃源岩有机质的化学动力学研究.中国矿业,23(6):92-95.
李志明,郑伦举,蒋启贵,等,2018.湖相富有机质泥质白云岩生排烃模拟及其对页岩油勘探的启示.地球科学,43(2):566-576.https://doi.org/10.3799/dqkx.2018.024
梁狄刚,郭彤楼,陈建平,等,2008.中国南方海相生烃成藏研究的若干新进展(一)南方四套区域性海相烃源岩的分布.海相油气地质,13(2):1-16.
刘立峰,姜振学,钟宁宁,等,2009.辽河西部凹陷古近系烃源岩生烃动力学特征.地球科学,34(5):799-805.
卢双舫,钟宁宁,薛海涛,等,2007.碳酸盐岩有机质二次生烃的化学动力学研究及其意义.中国科学(D辑),37(2):178-184.
马永生,蔡勋育,赵培荣,等,2010.四川盆地大中型天然气田分布特征与勘探方向.石油学报,31(3):347-354.
饶松,胡圣标,汪集旸,2010.有机质生烃动力学参数研究进展:回顾和展望.地球物理学进展,25(4):1424-1432.
汤庆艳,张铭杰,张同伟,等,2013.生烃热模拟实验方法述评.西南石油大学学报(自然科学版),35(1):52-62.
王民,卢双舫,薛海涛,等,2011.烃源岩非均质性对有机质生烃动力学参数影响及评价.地球科学,36(3):530-540.https://doi.org/10.3799/dqkx.2011.054
徐立恒,陈践发,薛海涛,等,2008.应用生烃动力学法定量评价碳酸盐岩的二次生烃:以朱家墩气藏为例.地球化学,37(3):251-257.
姚永坚,夏斌,冯志强,等,2005.南黄海古生代以来构造演化.石油实验地质,27(2):124-128.
张莉,熊永强,陈媛等,2017.中国典型海相富有机质页岩的生气机理.地球科学,42(7):1092-1106.https://doi.org/10.3799/dqkx.2017.088
赵文芳,杨风丽,庄建建,2011.南黄海中部隆起中-古生界构造特征分析.油气藏评价与开发,1(5):6-13.
赵文智,汪泽成,胡素云,等,2012.中国陆上三大克拉通盆地海相碳酸盐岩油气藏大型化成藏条件与特征.石油学报,33(增刊2):1-10.
郑伦举,关德范,郭小文,等,2015.影响海相烃源岩热解生烃过程的地质条件.地球科学,40(5):909-917.https://doi.org/10.3799/dqkx.2015.075
郑伦举,何生,秦建中,等,2011a.近临界特性的地层水及其对烃源岩生排烃过程的影响.地球科学,36(1):83-92.https://doi.org/10.3799/dqkx.2011.009
郑伦举,马中良,王强,等,2011b.烃源岩有限空间热解生油气潜力定量评价研究.石油实验地质,33(5):452-459.
邹才能,杜金虎,徐春春,等,2014.四川盆地震旦系-寒武系特大型气田形成分布、资源潜力及勘探发现.石油勘探与开发,41(3):278-293.
Geng,X.H.,Geng,A.S.,Xiong,Y.Q.,et al.,2005.Kinetic Simulating Experiment on Marine Carbonate Source Rocks:Comparison of Source Rocks with Isolated Kerogens.Geochimica,34(6):612-618(in Chinese with English abstract).
Guo,X.W.,He,S.,Liu,K.Y.,et al.,2013.A Quantitative Estimation Model for the Overpressure Caused by Natural Gas Generation and Its Influential Factors.Earth Science,38(6):1263-1270(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2013.123
Han,W.X.,Ma,W.J.,Tao,S.Z.,et al.,2018.Hydrocarbon Generation Potential Evaluation of Upper Paleozoic Limestone in Ordos Basin.Earth Science,43(2):599-609(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2017.529
Jiang,Q.G.,Ma,Y.Y.,Li,X.,2011.Application of Single Cold Trap Pyrolysis Chromatography in Source Rock Evaluation.Petroleum Geology&Experiment,33(5):546-551,558(in Chinese with English abstract).
Jiang,Q.G.,Wang,Y.B.,Qin,J.Z.,et al.,2010.Kinetics of the Hydrocarbon Generation Process of Marine Source Rocks in South China.Petroleum Exploration and Development,37(2):174-180(in Chinese with English abstract).
Li,Q.,Zhang,Z.H.,Ou,G.X.,et al.,2014.Chemical Kinetics Study on Organic Matter in Source Rocks in Huangqiao Area.China Mining Magazine,23(6):92-95(in Chinese with English abstract).
Li,Z.M.,Zheng,L.J.,Jiang,Q.G.,et al.,2018.Simulation of Hydrocarbon Generation and Expulsion for Lacustrine Organic-Rich Argillaceous Dolomite and Its Implications for Shale Oil Exploration.Earth Science,43(2):566-576(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2018.024
Liang,D.G.,Guo,T.L.,Chen,J.P.,et al.,2008.Some Progresses on Studies of Hydrocarbon Generation and Accumulation in Marine Sedimentary Regions,Southern China(Part 1):Distribution of Four Suits of Regional Marine Source Rocks.Marine Origin Petroleum Geology,13(2):1-16(in Chinese with English abstract).
Liu,L.F.,Jiang,Z.X.,Zhong,N.N.,et al.,2009.HydrocarbonGenerating Dynamic Characteristics of Paleocene Source Rocks in Western Depression,Liaohe Basin.Earth Science,34(5):799-805(in Chinese with English abstract).
Lu,S.F.,Zhong,N.N.,Xue,H.T.,et al.,2007.Kinetics of the Hydrocarbon Secondary Generation of Carbonate Source Rocks and Its Meaning.Scientia Sinica Terrae,37(2):178-184(in Chinese).
Ma,Y.S.,Cai,X.Y.,Zhao,P.R.,et al.,2010.Distribution and Further Exploration of the Large-Medium Sized Gas Fields in Sichuan Basin.Acta Petrolei Sinica,31(3):347-354(in Chinese with English abstract).
Rao,S.,Hu,S.B.,Wang,J.Y.,2010.Hydrocarbon Generation Kinetic Parameters of Organic Matter:Review and Outlook.Progress in Geophysics,25(4):1424-1432(in Chinese with English abstract).
Tang,Q.Y.,Zhang,M.J.,Zhang,T.W.,et al.,2013.A Review on Pyrolysis Experimentation on Hydrocarbon Generation.Journal of Southwest Petroleum University(Science&Technology Edition),35(1):52-62(in Chinese with English abstract).
Tissot,B.P.,Welte,D.H.,1984.Petroleum Formation and Occurrence.Springer-Verlag,Berlin.
Wang,M.,Lu,S.F.,Xue,H.T.,et al.,2011.The Influence and Appraisement of Source Rock Heterogeneity on Kinetic Parameters of Hydrocarbon Generation from Organic Matter.Earth Science,36(3):530-540(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2011.054
Xu,L.H.,Chen,J.F.,Xue,H.T.,et al.,2008.Quantitative E-valuation of Secondary Hydrocarbon Generation of Carbonate Source Rocks Using Chemical Kinetics Method of Hydrocarbon Generation:A Case Study of the Zhujiadun Reservoir.Geochimica,37(3):251-257(in Chinese with English abstract).
Yao,Y.J.,Xia,B.,Feng,Z.Q.,et al.,2005.Tectonic Evolution of the South Yellow Sea since the Paleozoic.Petroleum Geology&Experiment,27(2):124-128(in Chinese with English abstract).
Zhang,L.,Xiong,Y.Q.,Chen,Y.,et al.,2017.Mechanisms of Shale Gas Generation from Typically Organic-Rich Marine Shales.Earth Science,42(7):1092-1106(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2017.088
Zhao,W.F.,Yang,F.L.,Zhuang,J.J.,2011.Analysis of the Tectonic Characteristics of Mesozoic-Palaeozoic in the Middle Uplift of the South Yellow Sea.Reservoir Evaluation and Development.1(5):6-13(in Chinese with English abstract).
Zhao,W.Z.,Wang,Z.C.,Hu,S.Y.,et al.,2012.Large-Scale Hydrocarbon Accumulation Factors and Characteristics of Marine Carbonate Reservoirs in Three Large Onshore Cratonic Basins in China.ActaPetroleiSinica,33(S2):1-10(in Chinese with English abstract).
Zheng,L.J.,Guan,D.F.,Guo,X.W.,et al.,2015.Key Geological Conditions Affecting Pyrolysis Experiments of Marine Source Rocks for Hydrocarbon Generation.Earth Science,40(5):909-917(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2015.075
Zheng,L.J.,He,S.,Qin,J.Z.,et al.,2011a.Formation Water of Near-Critical Properties and Its Effects on the Processes of Hydrocarbon Generation and Expulsion.Earth Science,36(1):83-92(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2011.009
Zheng,L.J.,Ma,Z.L.,Wang,Q.,et al.,2011b.Quantitative Evaluation of Hydrocarbon Yielding Potential of Source Rock:Application of Pyrolysis in Finite Space.Petroleum Geology&Experiment,33(5):452-459(in Chinese with English abstract).
Zou,C.N.,Du,J.H.,Xu,C.C.,et al.,2014.Formation,Distribution,Resource Potential and Discovery of the SinianCambrian Giant Gas Field,Sichuan Basin,SW China.Petroleum Exploration and Development,41(3):278-293(in Chinese with English abstract).
冯志强,陈春峰,姚永坚,等,2008.南黄海北部前陆盆地的构造演化与油气突破.地学前缘,15(6):219-231.
耿新华,耿安松,熊永强,等,2005.海相碳酸盐岩烃源岩热解动力学研究:全岩和干酪根的对比.地球化学,34(6):612-618.
郭小文,何生,刘可禹,等,2013.烃源岩生气增压定量评价模型及影响因素.地球科学,38(6):1263-1270.https://doi.org/10.3799/dqkx.2013.123
韩文学,麻伟娇,陶士振,等,2018.鄂尔多斯盆地上古生界灰岩烃源岩生烃潜力评价.地球科学,43(2):599-609.https://doi.org/10.3799/dqkx.2017.529
蒋启贵,马媛媛,李欣,等,2011.单冷阱热解色谱仪在烃源岩评价中的应用.石油实验地质,33(5):546-551,558.
蒋启贵,王延斌,秦建中,等,2010.中国南方海相烃源岩生烃过程动力学研究.石油勘探与开发,37(2):174-180.
黎琼,张枝焕,欧光习,等,2014.黄桥地区烃源岩有机质的化学动力学研究.中国矿业,23(6):92-95.
李志明,郑伦举,蒋启贵,等,2018.湖相富有机质泥质白云岩生排烃模拟及其对页岩油勘探的启示.地球科学,43(2):566-576.https://doi.org/10.3799/dqkx.2018.024
梁狄刚,郭彤楼,陈建平,等,2008.中国南方海相生烃成藏研究的若干新进展(一)南方四套区域性海相烃源岩的分布.海相油气地质,13(2):1-16.
刘立峰,姜振学,钟宁宁,等,2009.辽河西部凹陷古近系烃源岩生烃动力学特征.地球科学,34(5):799-805.
卢双舫,钟宁宁,薛海涛,等,2007.碳酸盐岩有机质二次生烃的化学动力学研究及其意义.中国科学(D辑),37(2):178-184.
马永生,蔡勋育,赵培荣,等,2010.四川盆地大中型天然气田分布特征与勘探方向.石油学报,31(3):347-354.
饶松,胡圣标,汪集旸,2010.有机质生烃动力学参数研究进展:回顾和展望.地球物理学进展,25(4):1424-1432.
汤庆艳,张铭杰,张同伟,等,2013.生烃热模拟实验方法述评.西南石油大学学报(自然科学版),35(1):52-62.
王民,卢双舫,薛海涛,等,2011.烃源岩非均质性对有机质生烃动力学参数影响及评价.地球科学,36(3):530-540.https://doi.org/10.3799/dqkx.2011.054
徐立恒,陈践发,薛海涛,等,2008.应用生烃动力学法定量评价碳酸盐岩的二次生烃:以朱家墩气藏为例.地球化学,37(3):251-257.
姚永坚,夏斌,冯志强,等,2005.南黄海古生代以来构造演化.石油实验地质,27(2):124-128.
张莉,熊永强,陈媛等,2017.中国典型海相富有机质页岩的生气机理.地球科学,42(7):1092-1106.https://doi.org/10.3799/dqkx.2017.088
赵文芳,杨风丽,庄建建,2011.南黄海中部隆起中-古生界构造特征分析.油气藏评价与开发,1(5):6-13.
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