钒钨酸盐-CdS纳米粒子复合膜的制备与电致变色性能
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摘要
通过层-层自组装方法制备了由Dawson结构三钒取代型钨酸盐1-K_9P_2W_(15)V_3O_(62)·18H_2O(P_2W_(15)V_3)与CdS纳米粒子构筑的复合膜材料,研究了CdS纳米粒子添加和复合膜层数对P_2W_(15)V_3多酸复合膜材料电致变色性能的影响.采用UV,XRD,SEM和循环伏安等测试手段对复合材料的结构和性能进行了表征;将电化学工作站和紫外-可见吸收光谱联用,在-1. 0～+1. 0 V的电压范围内,对不同层数、有无CdS纳米粒子复合的的膜材料的电致变色性能进行研究.研究结果表明,20层的复合膜材料性能最佳,光反差为38. 05%,着色时间为3. 57 s,褪色时间为6. 94 s,最大着色效率达到94. 04 cm~2/C,实现了从无色、蓝色到蓝紫色,再到无色的可逆颜色变化,相对于单独P_2W_(15)V_3膜,光反差提高46. 07%,着色效率提高96. 53%,电致变色性能显著提高.
In order to study the effects of the addition of CdS nanoparticles and the number of composite film layers on the electrochromic properties of tri-vanadium substituted Dawson-type tungstate 1-K_9P_2W_(15)V_3O_(62)·18H_2O( P_2W_(15)V_3) polyoxometalate composite films,composite films constructed by P_2W_(15)V_3 and CdS nanoparticles were prepared by layer-by-layer self-assembly method. The structure and properties of the composite films were characterized by UV-Vis spectroscopy, XRD, SEM and cyclic voltammetry, and electrochemical workstation and UV-visible absorption spectroscopy were used to investigate the electrochromic properties of composite films with different layers and with or without CdS nanoparticles in the voltage range of-1. 0—+1. 0 V. The results show that the perfomanc of 20-layer composite film is the best,for which the optical contrast is 38. 05%,response time for recolorstion and bleaching are 3. 57 and 6. 94 s,respectively,the maximum coloring efficiency is 94. 04 cm2/C,compared with the P_2W_(15)V_3 film,the optical contrast increases by 46. 07% and the color efficiency increases by 96. 53%,the electrochromic performance is improved remarkably.
In order to study the effects of the addition of CdS nanoparticles and the number of composite film layers on the electrochromic properties of tri-vanadium substituted Dawson-type tungstate 1-K_9P_2W_(15)V_3O_(62)·18H_2O( P_2W_(15)V_3) polyoxometalate composite films,composite films constructed by P_2W_(15)V_3 and CdS nanoparticles were prepared by layer-by-layer self-assembly method. The structure and properties of the composite films were characterized by UV-Vis spectroscopy, XRD, SEM and cyclic voltammetry, and electrochemical workstation and UV-visible absorption spectroscopy were used to investigate the electrochromic properties of composite films with different layers and with or without CdS nanoparticles in the voltage range of-1. 0—+1. 0 V. The results show that the perfomanc of 20-layer composite film is the best,for which the optical contrast is 38. 05%,response time for recolorstion and bleaching are 3. 57 and 6. 94 s,respectively,the maximum coloring efficiency is 94. 04 cm2/C,compared with the P_2W_(15)V_3 film,the optical contrast increases by 46. 07% and the color efficiency increases by 96. 53%,the electrochromic performance is improved remarkably.
引文
[1]Runnerstrom E.L.,Llordes A.,Lounis S.D.,Milliron D.J.,Chemical Communications,2014,50(73),10555-10572
[2]Dyer A.L.,Bulloch R.H.,Zhou Y.H.,Kippelen B.,Rwynolds J.R.,Zhang F.L.,Advanced Materials,2014,26(28),4895-4900
[3]Palilis L.C.,Vasilopoulou M.,Douvas A.M.,Georgiadou D.G.,Kennou S.,Stathopoulos N.A.,Constantoudis V.,Argitis P.,Solar Energy Materials&Solar Cells,2013,114(7),205-213
[4]Ma D.Y.,Shi G.Y.,Wang H.Z.,Zhang Q.H.,Li Y.G.,Journal of Materials Chemistry A,2012,1(3),684-691
[5]Zhang D.,Tu J.P.,Xiang J.Y.,Qiao Y.Q.,Xia X.H.,Wang X.L.,Gu C.D.,Electrochimica Acta,2011,56(27),9980-9985
[6]Li K.R.,Zhang Q.H.,Wang H.Z.,Li Y.G.,Journal of Materials Chemistry C,2016,4(24),5849-5857
[7]Yamase T.,Chemical Reviews,1998,98(1),307-326
[8]Yang Y.Y.,Xu L.,Li F.Y.,Gan G.G.,Qu X.S.,Journal of Coordination Chemistry,2014,67(13),2249-2256
[9]Nomiya K.,Nemoto Y.,Hasegawa T.,Matsuoka S.,Journal of Molecular Catalysis A:Chemical,2000,152(1),55-68
[10]Keita B.,Mbomekalle I.M.,Nadjo L.,Oliveira P.D.,Ranjbari A.,Contant R.,Comptes Rendus-Chimie,2005,8(6),1057-1066
[11]Zhou C.,Li S.,Zhu W.,Pang H.,Ma H.Y.,Electrochimica Acta,2013,113(4),454-463
[12]Zhu W.,Zhang W.J.,Li S.,Ma H.Y.,Chen W.,Pang H.J.,Sensors&Actuators B Chemical,2013,181(5),773-781
[13]Li S.,Ma H.Y.,O’Halloran K.P.,Pang H.J.,Ji H.R.,Zhou C.L.,Electrochimica Acta,2013,108(10),717-726
[14]Dong X.B.,Wang D.J.,Li K.B.,Zhen Y.Z.,Hu H.M.,Xue G.L.,Materials Research Bulletin,2014,57(23),210-220
[15]Liu L.,Wang S.M.,Li C.,Liu C.G.,Ma C.L.,Han Z.B.,Journal of Materials Chemistry C,2015,3(20),5175-5182
[16]Hodos M.,Horváth E.,Haspel H.,Kukovecz A.,Kónya Z.,Kiricsi I.,Chemical Physics Letters,2004,399(4),512-515
[17]Shalom M.,Dor S.,Rühle S.,Grinis L.,Zaban A.,Journal of Physical Chemistry C,2015,113(9),3895-3898
[18]Chen S.G.,Paulose M.,Ruan C.M.,Mor G.K.,Varghese O.K.,Kouzoudis D.,Grimes C.A.,Journal of Photochemistry&Photobiology A:Chemistry,2006,177(2),177-184
[19]Peter L.M.,Riley D.J.,Tull E.J.,Wijayantha.K.G.U.,Chemical Communications,2002,(10),1030-1031
[20]Gu H.X.,Bi L.H.,Fu Y.,Wang N.,Liu S.Q.,Tang Z.Y.,Chemical Science,2013,4(12),4371-4377
[21]Qin B.,Chen H.Y.,Liang H.,Fu L.,Liu X.F.,Qu X.H.,Liu S.Q.,Song R.,Tang Z.Y.,Journal of the American Chemical Society,2010,132(9),2886-2888
[22]Li N.,Xu L.,Sun Z.X.,Progress in Chemistry,2015,27(8),1065-1073(李娜,许林,孙志霞.化学进展,2015,27(8),1065-1073)
[23]Zhang D.,Chen Y.Y.,Pang H.J.,Yan Y.,Ma H.Y.,Electrochimica Acta,2013,105(26),560-568
[24]Tan J.N.,Yang N.,Han R.F.,Feng S.Y.,Yang Y.Y.,Qu X.S.,Feng H.,Topics in Chemical&Material Engineering,2018,1(1),297-299
[25]Chen W.L.,Wang E.B.,Polyoxometalate Chemistry,Science Press,Beijing,2016,178-179(陈维林,王恩波.多酸化学,北京:科学出版社,2016,178-179)
[26]Rayevska O.E.,Grodzyuk G.Y.,Dzhagan V.M.,Stroyuk O.L.,Kuchmiy S.Y.,Plyusnin V.F.,Crivin V.P.,Valakh M.Y.,Journal of Physical Chemistry C,2010,114(51),22478-22486
[27]Abbessi M.,Contant R.,Thouvenot R.,Herve G.,Inorganic Chemistry,1991,30,1695-1702
[28]Fu Y.,Zhong J.Q.,Yang Y.Y.,Qu X.S.,Han Q.Q.,Chemical Reagents,2018,40(2),119-122(付勇,钟坚强,杨艳艳,曲小姝,韩晴晴.化学试剂,2018,40(2),119-122)
[29]Liu S.P.,Journal of Materials Science:Materials in Electronics,2016,27(10),11118-11125
[30]Wang B.,Wang X.H.,Li J.M.,Wang X.H.,Xie L.J.,Duan L.M.,Liu Z.R.,Chinese Journal of Applied Chemistry,2017,34(2),233-241(王斌,王晓红,李久明,王晓辉,谢丽娟,段莉梅,刘宗瑞.应用化学,2017,34(2),233-241)
[31]Feng S.Y.,Zhong J.Q.,Tan J.N.,Qu X.S.,Yang Y.Y,Journal of Jilin Institute of Chemical Technology,2018,35(07),75-78(冯素洋,钟坚强,谭佳宁,曲小姝,杨艳艳.吉林化工学院学报,2018,35(7),75-78)
[32]Gao G.G.,Xu L.,Wang W.J.,An W.J.,Qiu Y.F.,Wang Z.Q.,Wang E.B.,Journal of Physical Chemistry B,2005,109(18),8948-8953
[33]Wang S.M.,Liu L.,Huang Z.Y.,Han Z.B.,RSC Advances,2016,6,38782-38789
[34]Xie Z.,Gao L.,Liang B.,Wang X.F.,Chen G.,Liu Z.,Chao J.F.,Chen D.,Shen G.Z.,Journal of Materials Chemistry,2012,22(37),19904-19910
[35]Liu S.P.,Qu X.S.,Applied Surface Science,2017,412,189-195
[36]Liu S.P.,Yang Y.Y.,Qu X.S.,Journal of Northeast Normal University(Natural Science Edition),2015,47(3),100-104(刘树萍,杨艳艳,曲小姝.东北师范大学学报(自然科学版),2015,47(3),100-104)
[37]Gao G.G.,Xu L.,Wang W.J.,An W.J.,Qiu Y.F.,Wang Z.Q.,Wang E.B.,Journal of Physical Chemistry B,2005,109(18),8948-8953
[2]Dyer A.L.,Bulloch R.H.,Zhou Y.H.,Kippelen B.,Rwynolds J.R.,Zhang F.L.,Advanced Materials,2014,26(28),4895-4900
[3]Palilis L.C.,Vasilopoulou M.,Douvas A.M.,Georgiadou D.G.,Kennou S.,Stathopoulos N.A.,Constantoudis V.,Argitis P.,Solar Energy Materials&Solar Cells,2013,114(7),205-213
[4]Ma D.Y.,Shi G.Y.,Wang H.Z.,Zhang Q.H.,Li Y.G.,Journal of Materials Chemistry A,2012,1(3),684-691
[5]Zhang D.,Tu J.P.,Xiang J.Y.,Qiao Y.Q.,Xia X.H.,Wang X.L.,Gu C.D.,Electrochimica Acta,2011,56(27),9980-9985
[6]Li K.R.,Zhang Q.H.,Wang H.Z.,Li Y.G.,Journal of Materials Chemistry C,2016,4(24),5849-5857
[7]Yamase T.,Chemical Reviews,1998,98(1),307-326
[8]Yang Y.Y.,Xu L.,Li F.Y.,Gan G.G.,Qu X.S.,Journal of Coordination Chemistry,2014,67(13),2249-2256
[9]Nomiya K.,Nemoto Y.,Hasegawa T.,Matsuoka S.,Journal of Molecular Catalysis A:Chemical,2000,152(1),55-68
[10]Keita B.,Mbomekalle I.M.,Nadjo L.,Oliveira P.D.,Ranjbari A.,Contant R.,Comptes Rendus-Chimie,2005,8(6),1057-1066
[11]Zhou C.,Li S.,Zhu W.,Pang H.,Ma H.Y.,Electrochimica Acta,2013,113(4),454-463
[12]Zhu W.,Zhang W.J.,Li S.,Ma H.Y.,Chen W.,Pang H.J.,Sensors&Actuators B Chemical,2013,181(5),773-781
[13]Li S.,Ma H.Y.,O’Halloran K.P.,Pang H.J.,Ji H.R.,Zhou C.L.,Electrochimica Acta,2013,108(10),717-726
[14]Dong X.B.,Wang D.J.,Li K.B.,Zhen Y.Z.,Hu H.M.,Xue G.L.,Materials Research Bulletin,2014,57(23),210-220
[15]Liu L.,Wang S.M.,Li C.,Liu C.G.,Ma C.L.,Han Z.B.,Journal of Materials Chemistry C,2015,3(20),5175-5182
[16]Hodos M.,Horváth E.,Haspel H.,Kukovecz A.,Kónya Z.,Kiricsi I.,Chemical Physics Letters,2004,399(4),512-515
[17]Shalom M.,Dor S.,Rühle S.,Grinis L.,Zaban A.,Journal of Physical Chemistry C,2015,113(9),3895-3898
[18]Chen S.G.,Paulose M.,Ruan C.M.,Mor G.K.,Varghese O.K.,Kouzoudis D.,Grimes C.A.,Journal of Photochemistry&Photobiology A:Chemistry,2006,177(2),177-184
[19]Peter L.M.,Riley D.J.,Tull E.J.,Wijayantha.K.G.U.,Chemical Communications,2002,(10),1030-1031
[20]Gu H.X.,Bi L.H.,Fu Y.,Wang N.,Liu S.Q.,Tang Z.Y.,Chemical Science,2013,4(12),4371-4377
[21]Qin B.,Chen H.Y.,Liang H.,Fu L.,Liu X.F.,Qu X.H.,Liu S.Q.,Song R.,Tang Z.Y.,Journal of the American Chemical Society,2010,132(9),2886-2888
[22]Li N.,Xu L.,Sun Z.X.,Progress in Chemistry,2015,27(8),1065-1073(李娜,许林,孙志霞.化学进展,2015,27(8),1065-1073)
[23]Zhang D.,Chen Y.Y.,Pang H.J.,Yan Y.,Ma H.Y.,Electrochimica Acta,2013,105(26),560-568
[24]Tan J.N.,Yang N.,Han R.F.,Feng S.Y.,Yang Y.Y.,Qu X.S.,Feng H.,Topics in Chemical&Material Engineering,2018,1(1),297-299
[25]Chen W.L.,Wang E.B.,Polyoxometalate Chemistry,Science Press,Beijing,2016,178-179(陈维林,王恩波.多酸化学,北京:科学出版社,2016,178-179)
[26]Rayevska O.E.,Grodzyuk G.Y.,Dzhagan V.M.,Stroyuk O.L.,Kuchmiy S.Y.,Plyusnin V.F.,Crivin V.P.,Valakh M.Y.,Journal of Physical Chemistry C,2010,114(51),22478-22486
[27]Abbessi M.,Contant R.,Thouvenot R.,Herve G.,Inorganic Chemistry,1991,30,1695-1702
[28]Fu Y.,Zhong J.Q.,Yang Y.Y.,Qu X.S.,Han Q.Q.,Chemical Reagents,2018,40(2),119-122(付勇,钟坚强,杨艳艳,曲小姝,韩晴晴.化学试剂,2018,40(2),119-122)
[29]Liu S.P.,Journal of Materials Science:Materials in Electronics,2016,27(10),11118-11125
[30]Wang B.,Wang X.H.,Li J.M.,Wang X.H.,Xie L.J.,Duan L.M.,Liu Z.R.,Chinese Journal of Applied Chemistry,2017,34(2),233-241(王斌,王晓红,李久明,王晓辉,谢丽娟,段莉梅,刘宗瑞.应用化学,2017,34(2),233-241)
[31]Feng S.Y.,Zhong J.Q.,Tan J.N.,Qu X.S.,Yang Y.Y,Journal of Jilin Institute of Chemical Technology,2018,35(07),75-78(冯素洋,钟坚强,谭佳宁,曲小姝,杨艳艳.吉林化工学院学报,2018,35(7),75-78)
[32]Gao G.G.,Xu L.,Wang W.J.,An W.J.,Qiu Y.F.,Wang Z.Q.,Wang E.B.,Journal of Physical Chemistry B,2005,109(18),8948-8953
[33]Wang S.M.,Liu L.,Huang Z.Y.,Han Z.B.,RSC Advances,2016,6,38782-38789
[34]Xie Z.,Gao L.,Liang B.,Wang X.F.,Chen G.,Liu Z.,Chao J.F.,Chen D.,Shen G.Z.,Journal of Materials Chemistry,2012,22(37),19904-19910
[35]Liu S.P.,Qu X.S.,Applied Surface Science,2017,412,189-195
[36]Liu S.P.,Yang Y.Y.,Qu X.S.,Journal of Northeast Normal University(Natural Science Edition),2015,47(3),100-104(刘树萍,杨艳艳,曲小姝.东北师范大学学报(自然科学版),2015,47(3),100-104)
[37]Gao G.G.,Xu L.,Wang W.J.,An W.J.,Qiu Y.F.,Wang Z.Q.,Wang E.B.,Journal of Physical Chemistry B,2005,109(18),8948-8953
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