柳林泉域岩溶地下水区域演化规律及控制因素
|
摘要
柳林泉是山西省著名的十大岩溶大泉之一,丰富的岩溶地下水资源对吕梁地区经济社会发展具有支撑作用,开展岩溶地下水化学演化规律及控制因素研究对于流域水资源可持续利用意义重大.本研究对补给区、径流区、排泄区、深埋区的29个岩溶地下水主要离子组分进行测试分析.结果表明,水温、Na~+、Ca~(2+)、Mg~(2+)、Cl~-、HCO_3~-、SO_4~(2-)质量浓度从补给区、到径流区、到排泄区、再到深埋区,随着径流途径增加不断升高. K~+、Na~+、Cl~-主要来源于盐岩的溶解;而Ca~(2+)、Mg~(2+)、HCO_3~-、SO_4~(2-)主要来源于方解石、白云石和石膏的溶解.受控于盐岩、石膏的不断溶解,Na~+、C~l-和SO_4~(2-)质量浓度增加幅度大,最大值分别为最小值的50、80和32倍;受去白云化作用的影响,Ca~(2+)、HCO3-质量浓度变化不大,最大值仅为最小值的2～3倍.在补给区、径流区,Na~+、Cl~-质量浓度较低,Ca~(2+)和Mg~(2+)、HCO_3~-为主要阴阳子,但在排泄区和深埋区,Cl~-、Na~+明显超过了HCO_3~-、Ca~(2+)和Mg~(2+),成为最主要的阴阳离子;水化学类型由HCO_3-Ca·Mg型转化为HCO_3·SO_4-Ca·Mg型和HCO_3·SO_4-Ca·Na·Mg型,最终演变为Cl·HCO_3-Na·Ca、Cl·HCO_3-Na型和Cl-Na·Ca型.
The Liulin Spring is one of the ten most famous karst springs in the Shanxi province. The abundant karst groundwater resources support the economic and social development in the Luliang Prefecture. Therefore,the study of evolution and control factors of karst groundwater is of great significance to the sustainable utilization of water resources in the watershed. For revealing the evolution and control factors of karst groundwater in the Liulin Spring area,the main ion components of 29 karst groundwater samples from spring supply area,runoff area,discharge area,and deep buried area were analyzed. The results showed that the temperature and Na~+,Ca~(2+),Mg~(2+),Cl~-,HCO_3~-,and SO_4~(2-)concentrations increased continuously along the runoff route,from the recharge area to the runoff area,to the discharge area,and then to the deep burial area. K~+,Na~+,and Cl~-mainly come from salt rock dissolution,and Ca~(2+),Mg~(2+),HCO_3~-,and SO_4~(2-) mainly come from the dissolution of calcite,dolomite,and gypsum. Because they are controlled by the continuous dissolution of salt rock and gypsum,the concentration of Na+,Cl-,and SO_4~(2-) in groundwater has increased greatly,with the maximum value being 50 times,80 times, and 32 times of the minimum value, respectively. Under the influence of dedolomitization,the concentration of Ca~(2+)and HCO_3~- in groundwater does not change significantly,the maximum is 2-3 times of the minimum. In the recharge area and runoff area,Na+and Cl-amounts are lower,and Ca~(2+)and HCO_3~ -are the main cations and anions in the groundwater. However,in the discharge area and deep buried area,Cl-and Na+exceed HCO_3~-,Ca~(2+),and Mg~(2+)and become the main anions and cations in the groundwater. The hydrochemical type changes from HCO_3~- Ca·Mg in the supply area to HCO_3·SO_4-Ca·Mg in the runoff area,to HCO_3·SO_4-Ca·Na·Mg in the recharge area,and finally to Cl·HCO_3-Na·Ca,Cl·HCO_3-Na,and Cl-Na·Ca in the deep burial area.
The Liulin Spring is one of the ten most famous karst springs in the Shanxi province. The abundant karst groundwater resources support the economic and social development in the Luliang Prefecture. Therefore,the study of evolution and control factors of karst groundwater is of great significance to the sustainable utilization of water resources in the watershed. For revealing the evolution and control factors of karst groundwater in the Liulin Spring area,the main ion components of 29 karst groundwater samples from spring supply area,runoff area,discharge area,and deep buried area were analyzed. The results showed that the temperature and Na~+,Ca~(2+),Mg~(2+),Cl~-,HCO_3~-,and SO_4~(2-)concentrations increased continuously along the runoff route,from the recharge area to the runoff area,to the discharge area,and then to the deep burial area. K~+,Na~+,and Cl~-mainly come from salt rock dissolution,and Ca~(2+),Mg~(2+),HCO_3~-,and SO_4~(2-) mainly come from the dissolution of calcite,dolomite,and gypsum. Because they are controlled by the continuous dissolution of salt rock and gypsum,the concentration of Na+,Cl-,and SO_4~(2-) in groundwater has increased greatly,with the maximum value being 50 times,80 times, and 32 times of the minimum value, respectively. Under the influence of dedolomitization,the concentration of Ca~(2+)and HCO_3~- in groundwater does not change significantly,the maximum is 2-3 times of the minimum. In the recharge area and runoff area,Na+and Cl-amounts are lower,and Ca~(2+)and HCO_3~ -are the main cations and anions in the groundwater. However,in the discharge area and deep buried area,Cl-and Na+exceed HCO_3~-,Ca~(2+),and Mg~(2+)and become the main anions and cations in the groundwater. The hydrochemical type changes from HCO_3~- Ca·Mg in the supply area to HCO_3·SO_4-Ca·Mg in the runoff area,to HCO_3·SO_4-Ca·Na·Mg in the recharge area,and finally to Cl·HCO_3-Na·Ca,Cl·HCO_3-Na,and Cl-Na·Ca in the deep burial area.
引文
[1]梁永平,韩行瑞,时坚,等.鄂尔多斯盆地周边岩溶地下水系统模式及特点[J].地球学报,2005,26(4):365-369.Liang Y P,Han X R,Shi J,et al.The karst groundwater system in the peripheral area of Ordos Basin:Its patterns and characteristics[J].Acta Geoscientica Sinica,2005,26(4):365-369.
[2]高宝玉,梁永平,王维泰.柳林泉域岩溶水特点与地质背景条件分析[J].中国岩溶,2008,27(3):209-214.Gao B Y,Liang Y P,Wang W T.Features of karst water and geologic background in Liulin spring basin[J].Carsologica Sinica,2008,27(3):209-214.
[3]梁永平,王维泰.中国北方岩溶水系统划分与系统特征[J].地球学报,2010,31(6):860-868.Liang Y P,Wang W T.The division and characteristics of karst water systems in Northern China[J].Acta Geoscientica Sinica,2010,31(6):860-868.
[4]臧红飞,贾振兴,郑秀清,等.柳林泉域岩溶水水化学及碳硫同位素特征[J].水电能源科学,2013,31(12):28-32.Zang H F,Jia Z X,Zheng X Q,et al.Characteristics of hydrochemical and carbon-sulfur isotopic for karst water in Liulin spring Area[J].International Journal Hydroelectric Energy,2013,31(12):28-32.
[5]杨敏,卢耀如,张凤娥,等.柳林泉域岩溶水化学演化及地球化学模拟[J].南水北调与水利科技,2018,16(1):127-134.Yang M,Lu Y R,Zhang F E,et al.Hydrochemical evolution and geochemical simulation of karst groundwater in Liulin springs[J].South-to-North Water Transfers and Water Science&Technology,2018,16(1):127-131.
[6]马腾,王国卿,张庆保.山西省柳林泉域地表径流渗漏量的灰色预测[J].地球科学-中国地质大学学报,1997,22(1):90-93.Ma T,Wang G Q,Zhang Q B.A grey system approach to prediction of surface runoff Leakage:with an example from the Liulin karst water system in Shanxi province[J].Earth ScienceJournal of China University of Geosciences,1997,22(1):90-93.
[7]王数,左强.柳林泉区裂隙水流的数值模拟与分析[J].中国农业大学学报,1997,(S2):50-56.Wang S,Zuo Q.The Numerical simulation and analysis of fractured flow in Liulin Spring area[J].Journal of China Agricultural University,1997,(S2):50-56.
[8]王焰新,马腾,罗朝晖,等.山西柳林泉域水岩相互作用地球化学模拟[J].地球科学-中国地质大学学报,1998,23(5):519-522.Wang Y X,Ma T,Luo Z H,et al.Geochemical modeling of water-rock interactions in the Liulin karst system,Shanxi Province[J].Earth Science-Journal of China University of Geosciences,1998,23(5):519-522.
[9]吴吉春,薛禹群,黄海,等.山西柳林泉裂隙发育区溶质运移三维数值模拟[J].南京大学学报(自然科学),2000,36(6):728-734.Wu J C,Xue Y Q,Huang H,et al.Three dimensional numerical simulation for solute transport in Fracture-developed areain Liulin springs,Shanxi Province[J].Journal of Nanjing University(Natural Sciences),2000,36(6):728-734.
[10]吴吉春,薛禹群,黄海,等.山西柳林泉局部区域溶质运移二维数值模拟[J].水利学报,2001,(8):38-43.Wu J C,Xue Y Q,Huang H,et al.Two dimensional numerical simulation of solute transport in Liulin spring local area[J].Journal of Hydraulic Engineering,2001,(8):38-43.
[11]赵娇娟,郝永红,李华敏,等.基于地下水压力波传播过程的泉水流量灰色系统模型[J].水文地质工程地质,2011,38(6):1-7.Zhao J J,Hao Y H,Li H M,et al.Grey model for karst spring discharge based on propagation process of groundwater pressure wave[J].Hydrogeology&Engineering Geology,2011,38(6):1-7.
[12]王雅捷,王国卿,郝永红,等.人类活动对柳林泉域水文过程影响研究[J].水文,2011,31(3):82-87.Wang Y J,Wang G Q,Hao Y H,et al.Effect of human activities on hydrological process of Liulin springs[J].Journal of China Hydrology,2011,31(3):82-87.
[13]梁永平,王维泰,赵春红,等.中国北方岩溶水变化特征及其环境问题[J].中国岩溶,2013,32(1):34-42.Liang Y P,Wang W T,Zhao C H,et al.Variations of karst water and environmental problems in North China[J].Carsologica Sinica,2013,32(1):34-42.
[14]郝永红,王玮,王国卿,等.气候变化及人类活动对中国北方岩溶泉的影响-以山西柳林泉为例[J].地球学报,2009,83(1):138-144.Hao Y H,Wang W,Wang G Q,et al.Effects of climate change and human activities on the karstic springs in Northern China:Acase study of the Liulin springs[J].Acta Geologica Sinica,2009,83(1):138-144.
[15]臧红飞.柳林泉域岩溶地下水水文地球化学特征及演化规律研究[D].太原:太原理工大学,2015.Zang H F.Hydrogeochemical characteristics and evolution rules of karst groundwater in the Liulin spring area[D].Taiyuan:Taiyuan University of Technology,2015.
[16]臧红飞,郑秀清,张永波,等.柳林泉域岩溶水中SO2-4的来源探讨[J].水文地质工程地质,2017,44(1):9-15.Zang H F,Zheng X Q,Zhuang Y B,et al.Source of SO2-4in karst groundwater in the Liulin spring area[J].Hydrogeology&Engineering Geology,2017,44(1):9-15.
[17]贾振兴,臧红飞,郑秀清.柳林泉域滞流区岩溶水的热源及其Na+、Cl-来源探讨[J].中国岩溶,2015,34(6):570-576.Jia Z X,Zang H F,Zheng X Q.The origin of Na+,Cl-and thermal source of karst groundwater in the stagnant area of Liulin spring basin[J].Carsologica Sinica,2015,34(6):570-576.
[18]魏晓鸥,郑秀清,顾江海.柳林泉域岩溶地下水水化学特征及演化分析[J].人民黄河,2012,34(1):72-74,77.Wei X O,Zheng X Q,Gu J H.Analysis of hydrochemical characteristics and evolution of karstic groundwater in Liulin spring catchment[J].Yellow River,2012,34(1):72-74,77.
[19]黄奇波,覃小群,刘朋雨,等.硫酸对乌江中上游段岩溶水化学及δ13CDIC的影响[J].环境科学,2015,36(9):3220-3229.Huang Q B,Qin X Q,Liu P Y,et al.Influence of sulfuric acid to karst hydrochemical andδ13CDIC in the upper and middle reaches of the Wujiang River[J].Environmental Science,2015,36(9):3220-3229.
[20]Pu J B,Yuan D X,Zhao H P,et al.Hydrochemical and PCO2variations of a cave stream in a subtropical karst area,Chongqing,SW China:Piston effects,dilution effects,soil CO2and buffer effects[J].Environmental Earth Sciences,2014,71(9):4039-4049.
[21]Huang Q B,Qin X Q,Liu P Y,et al.Impact of sulfuric and nitric acids on carbonate dissolution,and the associated deficit of CO2uptake in the upper-middle reaches of the Wujiang River,China[J].Journal of Contaminant Hydrology,2017,203:18-27.
[22]蒲俊兵.重庆地区岩溶地下河水溶解无机碳及其稳定同位素特征[J].中国岩溶,2013,32(2):123-132.Pu J B.Dissolved inorganic carbon and stable carbon isotope in karst subterranean streams in Chongqing,China[J].Carsologica Sinica,2013,32(2):123-132.
[23]Li X D,Liu C Q,Harue M,et al.The use of environmental isotopic(C,Sr,S)and hydrochemical tracers to characterize anthropogenic effects on karst groundwater quality:A case study of the Shuicheng Basin,SW China[J].Applied Geochemistry,2010,25(12):1924-1936.
[24]康志强,袁道先,常勇,等.岩溶碳汇的主控因子:水循环[J].吉林大学学报(地球科学版),2011,41(5):1541-1547.Kang Z Q,Yuan D X,Chang Y,et al.The main controlling factor of karst carbon sequestration:about water cycle[J].Journal of Jilin University(Earth Science Edition),2011,41(5):1542-1547.
[25]蒲俊兵,袁道先,蒋勇军,等.重庆岩溶地下河水文地球化学特征及环境意义[J].水科学进展,2010,21(5):628-636.Pu J B,Yuan D X,Jiang Y J,et al.Hydrogeochemistry and environmental meaning of Chongqing subterranean karst streams in China[J].Advances in Water Science,2010,21(5):628-636.
[26]黄奇波,覃小群,刘朋雨,等.人为活动对乌江中上游段岩溶地下水δ13CDIC及碳汇效应的影响[J].第四纪研究,2016,36(6):1358-1369.Huang Q B,Qin X Q,Liu P Y,et al.The impact of human activities toδ13CDIC of karst groundwater and carbon sink in the upper and middle reaches of Wujiang River[J].Quaternary Science,2016,36(6):1358-1369.
[27]黄奇波,覃小群,刘朋雨,等.乌江中上游段河水主要离子化学特征及控制因素[J].环境科学,2016,37(5):1779-1787.Huang Q B,Qin X Q,Liu P Y,et al.Major ionic features and their controlling factors in the upper-middle reaches of Wujiang River[J].Environmental Science,2016,37(5):1779-1787.
[28]黄奇波,覃小群,刘朋雨,等.非岩溶水和硫酸参与溶蚀对湘南地区地下河流域岩溶碳汇通量的影响[J].地球科学进展,2017,32(3):307-318.Huang Q B,Qin X Q,Liu P Y,et al.The influence of allogenic water and sulfuric acid to karst carbon sink in karst subterranean river in southern Hu'nan[J].Advances in Earth Science,2017,32(3):307-318.
[29]顾慰祖,林曾平,费光灿,等.环境同位素硫在大同南寒武-奥陶系地下水资源研究中的应用[J].水科学进展,2000,11(1):14-20.Gu W Z,Lin Z P,Fei G C,et al.The use of environmental sulphur isotopes in the study of the cambrian-ordovician aquifer system in the south of Datong[J].Advances in Water Science,2000,11(1):14-20.
[2]高宝玉,梁永平,王维泰.柳林泉域岩溶水特点与地质背景条件分析[J].中国岩溶,2008,27(3):209-214.Gao B Y,Liang Y P,Wang W T.Features of karst water and geologic background in Liulin spring basin[J].Carsologica Sinica,2008,27(3):209-214.
[3]梁永平,王维泰.中国北方岩溶水系统划分与系统特征[J].地球学报,2010,31(6):860-868.Liang Y P,Wang W T.The division and characteristics of karst water systems in Northern China[J].Acta Geoscientica Sinica,2010,31(6):860-868.
[4]臧红飞,贾振兴,郑秀清,等.柳林泉域岩溶水水化学及碳硫同位素特征[J].水电能源科学,2013,31(12):28-32.Zang H F,Jia Z X,Zheng X Q,et al.Characteristics of hydrochemical and carbon-sulfur isotopic for karst water in Liulin spring Area[J].International Journal Hydroelectric Energy,2013,31(12):28-32.
[5]杨敏,卢耀如,张凤娥,等.柳林泉域岩溶水化学演化及地球化学模拟[J].南水北调与水利科技,2018,16(1):127-134.Yang M,Lu Y R,Zhang F E,et al.Hydrochemical evolution and geochemical simulation of karst groundwater in Liulin springs[J].South-to-North Water Transfers and Water Science&Technology,2018,16(1):127-131.
[6]马腾,王国卿,张庆保.山西省柳林泉域地表径流渗漏量的灰色预测[J].地球科学-中国地质大学学报,1997,22(1):90-93.Ma T,Wang G Q,Zhang Q B.A grey system approach to prediction of surface runoff Leakage:with an example from the Liulin karst water system in Shanxi province[J].Earth ScienceJournal of China University of Geosciences,1997,22(1):90-93.
[7]王数,左强.柳林泉区裂隙水流的数值模拟与分析[J].中国农业大学学报,1997,(S2):50-56.Wang S,Zuo Q.The Numerical simulation and analysis of fractured flow in Liulin Spring area[J].Journal of China Agricultural University,1997,(S2):50-56.
[8]王焰新,马腾,罗朝晖,等.山西柳林泉域水岩相互作用地球化学模拟[J].地球科学-中国地质大学学报,1998,23(5):519-522.Wang Y X,Ma T,Luo Z H,et al.Geochemical modeling of water-rock interactions in the Liulin karst system,Shanxi Province[J].Earth Science-Journal of China University of Geosciences,1998,23(5):519-522.
[9]吴吉春,薛禹群,黄海,等.山西柳林泉裂隙发育区溶质运移三维数值模拟[J].南京大学学报(自然科学),2000,36(6):728-734.Wu J C,Xue Y Q,Huang H,et al.Three dimensional numerical simulation for solute transport in Fracture-developed areain Liulin springs,Shanxi Province[J].Journal of Nanjing University(Natural Sciences),2000,36(6):728-734.
[10]吴吉春,薛禹群,黄海,等.山西柳林泉局部区域溶质运移二维数值模拟[J].水利学报,2001,(8):38-43.Wu J C,Xue Y Q,Huang H,et al.Two dimensional numerical simulation of solute transport in Liulin spring local area[J].Journal of Hydraulic Engineering,2001,(8):38-43.
[11]赵娇娟,郝永红,李华敏,等.基于地下水压力波传播过程的泉水流量灰色系统模型[J].水文地质工程地质,2011,38(6):1-7.Zhao J J,Hao Y H,Li H M,et al.Grey model for karst spring discharge based on propagation process of groundwater pressure wave[J].Hydrogeology&Engineering Geology,2011,38(6):1-7.
[12]王雅捷,王国卿,郝永红,等.人类活动对柳林泉域水文过程影响研究[J].水文,2011,31(3):82-87.Wang Y J,Wang G Q,Hao Y H,et al.Effect of human activities on hydrological process of Liulin springs[J].Journal of China Hydrology,2011,31(3):82-87.
[13]梁永平,王维泰,赵春红,等.中国北方岩溶水变化特征及其环境问题[J].中国岩溶,2013,32(1):34-42.Liang Y P,Wang W T,Zhao C H,et al.Variations of karst water and environmental problems in North China[J].Carsologica Sinica,2013,32(1):34-42.
[14]郝永红,王玮,王国卿,等.气候变化及人类活动对中国北方岩溶泉的影响-以山西柳林泉为例[J].地球学报,2009,83(1):138-144.Hao Y H,Wang W,Wang G Q,et al.Effects of climate change and human activities on the karstic springs in Northern China:Acase study of the Liulin springs[J].Acta Geologica Sinica,2009,83(1):138-144.
[15]臧红飞.柳林泉域岩溶地下水水文地球化学特征及演化规律研究[D].太原:太原理工大学,2015.Zang H F.Hydrogeochemical characteristics and evolution rules of karst groundwater in the Liulin spring area[D].Taiyuan:Taiyuan University of Technology,2015.
[16]臧红飞,郑秀清,张永波,等.柳林泉域岩溶水中SO2-4的来源探讨[J].水文地质工程地质,2017,44(1):9-15.Zang H F,Zheng X Q,Zhuang Y B,et al.Source of SO2-4in karst groundwater in the Liulin spring area[J].Hydrogeology&Engineering Geology,2017,44(1):9-15.
[17]贾振兴,臧红飞,郑秀清.柳林泉域滞流区岩溶水的热源及其Na+、Cl-来源探讨[J].中国岩溶,2015,34(6):570-576.Jia Z X,Zang H F,Zheng X Q.The origin of Na+,Cl-and thermal source of karst groundwater in the stagnant area of Liulin spring basin[J].Carsologica Sinica,2015,34(6):570-576.
[18]魏晓鸥,郑秀清,顾江海.柳林泉域岩溶地下水水化学特征及演化分析[J].人民黄河,2012,34(1):72-74,77.Wei X O,Zheng X Q,Gu J H.Analysis of hydrochemical characteristics and evolution of karstic groundwater in Liulin spring catchment[J].Yellow River,2012,34(1):72-74,77.
[19]黄奇波,覃小群,刘朋雨,等.硫酸对乌江中上游段岩溶水化学及δ13CDIC的影响[J].环境科学,2015,36(9):3220-3229.Huang Q B,Qin X Q,Liu P Y,et al.Influence of sulfuric acid to karst hydrochemical andδ13CDIC in the upper and middle reaches of the Wujiang River[J].Environmental Science,2015,36(9):3220-3229.
[20]Pu J B,Yuan D X,Zhao H P,et al.Hydrochemical and PCO2variations of a cave stream in a subtropical karst area,Chongqing,SW China:Piston effects,dilution effects,soil CO2and buffer effects[J].Environmental Earth Sciences,2014,71(9):4039-4049.
[21]Huang Q B,Qin X Q,Liu P Y,et al.Impact of sulfuric and nitric acids on carbonate dissolution,and the associated deficit of CO2uptake in the upper-middle reaches of the Wujiang River,China[J].Journal of Contaminant Hydrology,2017,203:18-27.
[22]蒲俊兵.重庆地区岩溶地下河水溶解无机碳及其稳定同位素特征[J].中国岩溶,2013,32(2):123-132.Pu J B.Dissolved inorganic carbon and stable carbon isotope in karst subterranean streams in Chongqing,China[J].Carsologica Sinica,2013,32(2):123-132.
[23]Li X D,Liu C Q,Harue M,et al.The use of environmental isotopic(C,Sr,S)and hydrochemical tracers to characterize anthropogenic effects on karst groundwater quality:A case study of the Shuicheng Basin,SW China[J].Applied Geochemistry,2010,25(12):1924-1936.
[24]康志强,袁道先,常勇,等.岩溶碳汇的主控因子:水循环[J].吉林大学学报(地球科学版),2011,41(5):1541-1547.Kang Z Q,Yuan D X,Chang Y,et al.The main controlling factor of karst carbon sequestration:about water cycle[J].Journal of Jilin University(Earth Science Edition),2011,41(5):1542-1547.
[25]蒲俊兵,袁道先,蒋勇军,等.重庆岩溶地下河水文地球化学特征及环境意义[J].水科学进展,2010,21(5):628-636.Pu J B,Yuan D X,Jiang Y J,et al.Hydrogeochemistry and environmental meaning of Chongqing subterranean karst streams in China[J].Advances in Water Science,2010,21(5):628-636.
[26]黄奇波,覃小群,刘朋雨,等.人为活动对乌江中上游段岩溶地下水δ13CDIC及碳汇效应的影响[J].第四纪研究,2016,36(6):1358-1369.Huang Q B,Qin X Q,Liu P Y,et al.The impact of human activities toδ13CDIC of karst groundwater and carbon sink in the upper and middle reaches of Wujiang River[J].Quaternary Science,2016,36(6):1358-1369.
[27]黄奇波,覃小群,刘朋雨,等.乌江中上游段河水主要离子化学特征及控制因素[J].环境科学,2016,37(5):1779-1787.Huang Q B,Qin X Q,Liu P Y,et al.Major ionic features and their controlling factors in the upper-middle reaches of Wujiang River[J].Environmental Science,2016,37(5):1779-1787.
[28]黄奇波,覃小群,刘朋雨,等.非岩溶水和硫酸参与溶蚀对湘南地区地下河流域岩溶碳汇通量的影响[J].地球科学进展,2017,32(3):307-318.Huang Q B,Qin X Q,Liu P Y,et al.The influence of allogenic water and sulfuric acid to karst carbon sink in karst subterranean river in southern Hu'nan[J].Advances in Earth Science,2017,32(3):307-318.
[29]顾慰祖,林曾平,费光灿,等.环境同位素硫在大同南寒武-奥陶系地下水资源研究中的应用[J].水科学进展,2000,11(1):14-20.Gu W Z,Lin Z P,Fei G C,et al.The use of environmental sulphur isotopes in the study of the cambrian-ordovician aquifer system in the south of Datong[J].Advances in Water Science,2000,11(1):14-20.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |