生物冶金技术的发展及其在黄金行业中的应用现状
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摘要
生物冶金技术因具有环境友好、成本低、不产生有害气体、产生的液体易于处理及控制、适用面广等优点,不断被现代矿业企业所采用。介绍了生物冶金的原理,综述了生物冶金技术工艺类型及特点,总结了生物冶金技术在黄金行业中的应用,展望了生物冶金技术未来的发展方向,为生物冶金技术的推广应用提供依据。
Biometallurgical technology has the advantages of environmental friendliness,low cost,zero harmful gas generation,easy control of liquid production and wide range of applicability,so it is constantly adopted by modern mining enterprises.This paper introduced the principle of biometallurgy,overviewed the process type and features of biometallurgical technology,summarized the application of biometallurgical technology in the gold industry,and looked at the prospect of biometallurgical technology development,providing basis for the promotion and application of biometallurgical technology.
Biometallurgical technology has the advantages of environmental friendliness,low cost,zero harmful gas generation,easy control of liquid production and wide range of applicability,so it is constantly adopted by modern mining enterprises.This paper introduced the principle of biometallurgy,overviewed the process type and features of biometallurgical technology,summarized the application of biometallurgical technology in the gold industry,and looked at the prospect of biometallurgical technology development,providing basis for the promotion and application of biometallurgical technology.
引文
[1] 杨显万.微生物湿法冶金[M].北京:冶金工业出版社,2003.
[2] 张析,王军,王进龙.生物浸出技术及其应用研究进展[J].世界有色金属,2016(14):110-112.
[3] KONYSBAYEVA A A,KANAYEV A T,KURMANBEYEVA M S,et al.Percolation bioleaching the gold from ores of Kazakhstan[J].Journal of Biotechnology,2016,231:S39.
[4] MAHMOUD A,CéZAC P,HOADLEY A F A,et al.A review of sulfide minerals microbially assisted leaching in stirred tank reactors[J].International Biodeterioration & Biodegradation,2017,119:118-146.
[5] CHAERUN S K,SULISTYO R S,MINWAL W P,et al.Indirect bio-leaching of low-grade nickel limonite and saprolite ores using fungal metabolic organic acids generated by Aspergillus niger[J].Hydrometallurgy,2017,174:29-37.
[6] CHEN G B,YANG H Y,LI H J,et al.Recovery of cobalt as cobalt oxalate from cobalt tailings using moderately thermophilic bioleaching technology and selective sequential extraction[J].Minerals,2016,6(3):67-77.
[7] DODSON J R,HUNT A J,PARKER H L,et al.Elemental sustaina-bility:Towards the total recovery of scarce metals[J].Chemical Engineering and Processing:Process Intensification,2012,51:69-78.
[8] ETEMADZADEH S S,EMTIAZI G,ETEMADIFAR Z.Heterotrophic bioleaching of sulfur,iron,and silicon impurities from coal by Fusarium Oxysporum FE and Exophiala Spinifera FM with growing and resting cells[J].Current Microbiology,2016,72(6):707-715.
[9] ELLAHI S S,TAGHIPOUR B,NEJADHADAD M.The role of orga-nic matter in the formation of high-grade Al deposits of the Dopolan Karst Type Bauxite,Iran:Mineralogy,geochemistry,and sulfur isotope data[J].Minerals,2017,7(6):1-16.
[10] BABA A A,ADEKOLA F A,ATATA R F,et al.Bioleaching of Zn(Ⅱ) and Pb(Ⅱ) from Nigerian sphalerite and galena ores by mixed culture of acidophilic bacteria[J].Transactions of Nonferrous Metals Society of China,2011,21(11):2 535-2 541.
[11] KUYUCAK N.Acid mine drainage prevention and control options[J].CIM Bulletin,2002,95(4):96-102.
[12] 刘顺亮.微生物浸矿技术的现状及展望[J].江西化工,2017(5):46-48.
[13] 陈薇.微生物浸出技术研究及其应用现状[J].盐业与化工,2014,43(12):8-11.
[14] TRIBUTSCH H.Direct versus indirect bioleaching[J].Hydrometal-lurgy,2001,59(2/3):177-185.
[15] PETERSEN J.Unravelling the complexity of heap bioleaching[J].Solid State Phenomena,2017,262:246-249.
[16] 张夏弟,刘世坚,褚晓华.金矿氰化堆浸技术简介[J].黑龙江冶金,2001(4):30-32.
[17] GHORBANI Y,FRANZIDIS J P,PETERSEN J.Heap leaching technology—current state,innovations,and future directions:A review[J].Mineral Processing and Extractive Metallurgy Review,2016,37(2):73-119.
[18] BATTY J D,RORKE G V.Development and commercial demonstration of the BioCOPTM thermophile process[J].Hydrometallurgy,2006,83(1/2/3/4):83-89.
[19] 吉兆宁,余斌.中条山地下溶浸布液集液系统研究[C]//中国有色金属学会.中国有色金属学术铜镍湿法冶金技术交流及应用推广会论文集.北京:中国有色金属学会,2001:184-186.
[20] 李宏煦,王淀佐.生物冶金中的微生物及其作用[J].有色金属,2003,55(2):58-63.
[21] VAN ASWEGEN P C,VAN NIEKERK J,OLIVIER W.The BIOXTM process for the treatment of refractory gold concentrates[M]//RAWLINGS D E,JOHNSON D B.Biomining.Berlin:Heidelberg,2007:1-33.
[22] ENFORS S O,JAHIC M,ROZKOV A,et al.Physiological responses to mixing in large scale bioreactors[J].Journal of Biotechnology,2001,85(2):175-185.
[23] CLARK M E,BATTY J D,VAN BUUREN C B,et al.Biotechnology in minerals processing:Technological breakthroughs creating value[J].Hydrometallurgy,2006,83(1/2/3/4):3-9.
[24] SPENCER P A.Influence of bacterial culture selection on the ope-ration of a plant treating refractory gold ore[J].International Journal of Mineral Processing,2001,62(1):217-229.
[25] HANSFORD G S,VARGAS T.Chemical and electrochemical basis of bioleaching processes[J].Hydrometallurgy,2001,59(2):135-145.
[26] BRIERLEY J A.Response of microbial systems to thermal stress in biooxidation-heap pretreatment of refractory gold ores[J].Hydrometallurgy,2003,71(1):13-19.
[27] 徐家振,金哲男.重贵金属冶金中的微生物技术[J].有色矿冶,2002,18(1):31-34.
[28] VIJAYARAGHAVAN K,YUN Y S.Bacterial biosorbents and biosorption[J].Biotechnology Advances,2008,26(3):266-291.
[29] 谭玲,谭志斌,何佳,等.生物吸附法回收溶液中铂族金属的研究进展[J].贵金属,2017,38(增刊1):163-168.
[30] 熊英,柏全金,杨红霞,等.强化生物浸金剂的浸金性能研究[J].黄金,2002,23(1):38-41.
[31] 杨松荣,邱冠周,谢纪元,等.国外生物氧化提取技术的进展[J].有色金属,2001,53(3):84-88.
[32] YANG H,GONG E,YANG L,et al.XPS characteristics of sulfur of bio-oxidized arsenic-bearing gold concentrate and changes of surface nature of bio-oxidation residue[J].Transactions of the Nonferrous Metals Society of China,2004,14(6):1 187-1 191.
[33] 周乐光.工艺矿物学[M].北京:冶金工业出版社,2002:1-5.
[34] 何勇军.发展生物冶金技术实现中国黄金行业可持续发展[C]∥中国黄金协会.2002中国-南非黄金技术、设备引进暨项目融资经贸洽谈会论文集.北京:中国黄金协会,2002.
[35] 王治科,叶存玲,范顺利,等.浸金体系的Eh-pH 图及其热力学分析[J].有色金属(冶炼部分),2008(3):37-40.
[2] 张析,王军,王进龙.生物浸出技术及其应用研究进展[J].世界有色金属,2016(14):110-112.
[3] KONYSBAYEVA A A,KANAYEV A T,KURMANBEYEVA M S,et al.Percolation bioleaching the gold from ores of Kazakhstan[J].Journal of Biotechnology,2016,231:S39.
[4] MAHMOUD A,CéZAC P,HOADLEY A F A,et al.A review of sulfide minerals microbially assisted leaching in stirred tank reactors[J].International Biodeterioration & Biodegradation,2017,119:118-146.
[5] CHAERUN S K,SULISTYO R S,MINWAL W P,et al.Indirect bio-leaching of low-grade nickel limonite and saprolite ores using fungal metabolic organic acids generated by Aspergillus niger[J].Hydrometallurgy,2017,174:29-37.
[6] CHEN G B,YANG H Y,LI H J,et al.Recovery of cobalt as cobalt oxalate from cobalt tailings using moderately thermophilic bioleaching technology and selective sequential extraction[J].Minerals,2016,6(3):67-77.
[7] DODSON J R,HUNT A J,PARKER H L,et al.Elemental sustaina-bility:Towards the total recovery of scarce metals[J].Chemical Engineering and Processing:Process Intensification,2012,51:69-78.
[8] ETEMADZADEH S S,EMTIAZI G,ETEMADIFAR Z.Heterotrophic bioleaching of sulfur,iron,and silicon impurities from coal by Fusarium Oxysporum FE and Exophiala Spinifera FM with growing and resting cells[J].Current Microbiology,2016,72(6):707-715.
[9] ELLAHI S S,TAGHIPOUR B,NEJADHADAD M.The role of orga-nic matter in the formation of high-grade Al deposits of the Dopolan Karst Type Bauxite,Iran:Mineralogy,geochemistry,and sulfur isotope data[J].Minerals,2017,7(6):1-16.
[10] BABA A A,ADEKOLA F A,ATATA R F,et al.Bioleaching of Zn(Ⅱ) and Pb(Ⅱ) from Nigerian sphalerite and galena ores by mixed culture of acidophilic bacteria[J].Transactions of Nonferrous Metals Society of China,2011,21(11):2 535-2 541.
[11] KUYUCAK N.Acid mine drainage prevention and control options[J].CIM Bulletin,2002,95(4):96-102.
[12] 刘顺亮.微生物浸矿技术的现状及展望[J].江西化工,2017(5):46-48.
[13] 陈薇.微生物浸出技术研究及其应用现状[J].盐业与化工,2014,43(12):8-11.
[14] TRIBUTSCH H.Direct versus indirect bioleaching[J].Hydrometal-lurgy,2001,59(2/3):177-185.
[15] PETERSEN J.Unravelling the complexity of heap bioleaching[J].Solid State Phenomena,2017,262:246-249.
[16] 张夏弟,刘世坚,褚晓华.金矿氰化堆浸技术简介[J].黑龙江冶金,2001(4):30-32.
[17] GHORBANI Y,FRANZIDIS J P,PETERSEN J.Heap leaching technology—current state,innovations,and future directions:A review[J].Mineral Processing and Extractive Metallurgy Review,2016,37(2):73-119.
[18] BATTY J D,RORKE G V.Development and commercial demonstration of the BioCOPTM thermophile process[J].Hydrometallurgy,2006,83(1/2/3/4):83-89.
[19] 吉兆宁,余斌.中条山地下溶浸布液集液系统研究[C]//中国有色金属学会.中国有色金属学术铜镍湿法冶金技术交流及应用推广会论文集.北京:中国有色金属学会,2001:184-186.
[20] 李宏煦,王淀佐.生物冶金中的微生物及其作用[J].有色金属,2003,55(2):58-63.
[21] VAN ASWEGEN P C,VAN NIEKERK J,OLIVIER W.The BIOXTM process for the treatment of refractory gold concentrates[M]//RAWLINGS D E,JOHNSON D B.Biomining.Berlin:Heidelberg,2007:1-33.
[22] ENFORS S O,JAHIC M,ROZKOV A,et al.Physiological responses to mixing in large scale bioreactors[J].Journal of Biotechnology,2001,85(2):175-185.
[23] CLARK M E,BATTY J D,VAN BUUREN C B,et al.Biotechnology in minerals processing:Technological breakthroughs creating value[J].Hydrometallurgy,2006,83(1/2/3/4):3-9.
[24] SPENCER P A.Influence of bacterial culture selection on the ope-ration of a plant treating refractory gold ore[J].International Journal of Mineral Processing,2001,62(1):217-229.
[25] HANSFORD G S,VARGAS T.Chemical and electrochemical basis of bioleaching processes[J].Hydrometallurgy,2001,59(2):135-145.
[26] BRIERLEY J A.Response of microbial systems to thermal stress in biooxidation-heap pretreatment of refractory gold ores[J].Hydrometallurgy,2003,71(1):13-19.
[27] 徐家振,金哲男.重贵金属冶金中的微生物技术[J].有色矿冶,2002,18(1):31-34.
[28] VIJAYARAGHAVAN K,YUN Y S.Bacterial biosorbents and biosorption[J].Biotechnology Advances,2008,26(3):266-291.
[29] 谭玲,谭志斌,何佳,等.生物吸附法回收溶液中铂族金属的研究进展[J].贵金属,2017,38(增刊1):163-168.
[30] 熊英,柏全金,杨红霞,等.强化生物浸金剂的浸金性能研究[J].黄金,2002,23(1):38-41.
[31] 杨松荣,邱冠周,谢纪元,等.国外生物氧化提取技术的进展[J].有色金属,2001,53(3):84-88.
[32] YANG H,GONG E,YANG L,et al.XPS characteristics of sulfur of bio-oxidized arsenic-bearing gold concentrate and changes of surface nature of bio-oxidation residue[J].Transactions of the Nonferrous Metals Society of China,2004,14(6):1 187-1 191.
[33] 周乐光.工艺矿物学[M].北京:冶金工业出版社,2002:1-5.
[34] 何勇军.发展生物冶金技术实现中国黄金行业可持续发展[C]∥中国黄金协会.2002中国-南非黄金技术、设备引进暨项目融资经贸洽谈会论文集.北京:中国黄金协会,2002.
[35] 王治科,叶存玲,范顺利,等.浸金体系的Eh-pH 图及其热力学分析[J].有色金属(冶炼部分),2008(3):37-40.
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