氧化物热电材料研究进展
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摘要
由于能源危机正在到来,废热回收已经成为解决能源短缺问题的有效途径之一,热电材料在废热收集环节中占有举足轻重的地位。其中,氧化物热电材料拥有抗氧化能力强、热稳定性好、原料相对低廉、制备工艺相对简单、无毒、无污染、使用寿命长等传统合金材料不具备的优点,但由于低的电导率因而限制了其在热电性能方面的表现。已经有大量研究发现,可以通过元素掺杂,改善氧化物热电材料的热电性能,氧化物热电材料再次受到广大研究者的关注。综述了氧化物热电材料的研究进展与今后的发展方向,着重阐述了以BiCuSeO为代表的氧化物热电材料的基本结构、性能特征与研究进展;评述了BiCuSeO材料Bi位、Cu位和O位掺杂研究以及BiCuSeO的结构优化;并简单介绍了NaCo_2O_4、Ca_3Co_4O_9、SrTiO_3、ZnO、In_2O_3热电材料的研究情况。
As the energy crisis is coming, waste heat recovery has become one of the effective ways to solve the energy shortage problem, and thermoelectric materials occupy a pivotal position in the waste heat collection. Among them, compared with traditional alloy thermoelectric materials, the oxide thermoelectric materials have strong anti-oxidation ability, good thermal stability, relatively low raw materials, relatively simple preparation process, non-toxic, non-polluting and long service life, but low electrical conductivity limits its performance in terms of thermoelectric performance. A large number of studies have found that the thermoelectric properties of oxide thermoelectric materials can be improved by element doping, and oxide thermoelectric materials have received the attention of researchers once again. In this paper, the research progress and future development direction of oxide thermoelectric materials were reviewed. The basic structure, performance characteristics and research progress of oxide thermoelectric materials represented by BiCuSeO were reviewed. The Bi, Cu and O sites of BiCuSeO materials and doping research and structural optimization of BiCuSeO were reviewed. The research of NaCo_2O_4, Ca_3Co_4O_9, SrTiO_3, ZnO, In_2O_3 thermoelectric materials was briefly introduced.
As the energy crisis is coming, waste heat recovery has become one of the effective ways to solve the energy shortage problem, and thermoelectric materials occupy a pivotal position in the waste heat collection. Among them, compared with traditional alloy thermoelectric materials, the oxide thermoelectric materials have strong anti-oxidation ability, good thermal stability, relatively low raw materials, relatively simple preparation process, non-toxic, non-polluting and long service life, but low electrical conductivity limits its performance in terms of thermoelectric performance. A large number of studies have found that the thermoelectric properties of oxide thermoelectric materials can be improved by element doping, and oxide thermoelectric materials have received the attention of researchers once again. In this paper, the research progress and future development direction of oxide thermoelectric materials were reviewed. The basic structure, performance characteristics and research progress of oxide thermoelectric materials represented by BiCuSeO were reviewed. The Bi, Cu and O sites of BiCuSeO materials and doping research and structural optimization of BiCuSeO were reviewed. The research of NaCo_2O_4, Ca_3Co_4O_9, SrTiO_3, ZnO, In_2O_3 thermoelectric materials was briefly introduced.
引文
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