阴离子型清洁压裂液耐温性研究进展
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摘要
阴离子型清洁压裂液是一种基于阴离子黏弹性表面活性剂的非聚合物水基压裂液,具有配制简单、易返排、无残渣、冻胶黏度低且弹性好、压裂性能稳定等特性。随着低压低渗油田开采困难和油井开采深度的不断增加,阴离子型清洁压裂液(Anionic Viscoelastic Surfactant Fluid,简称AVES)的耐温性成为重要研究课题。对典型非聚AVES压裂液和新型含聚AVES压裂液两大体系的应用性能和特征进行综述,列表阐明各类AVES压裂液在油田应用中的优势与不足。针对国内外AVES压裂液高温下压裂效果不明显、胶束稳定性差及主剂合成复杂等状况,提出改进阴离子侧链、研制不对称结构双子阴离子及开发新型纳米粒子等方法,从而达到简化体系配制、增加其耐温性与稳定性的目的。
Anionic clean fracturing fluid is a non-polymer water-based fracturing fluid based on anionic viscoelastic surfactant. It has such characteristics as simple configuration, easy flowback, no residue, low viscosity and good elasticity of gel, stable fracturing performance and so on. With the increasing of the difficulties of low pressure and low permeability oil field and the depth of oil well exploitation, the temperature resistance of anionic viscoelastic surfactant fluid(AVES) has become an important aspect of the research topic. The application performance and characteristics of typical non-polymer AVES fracturing fluids and new polymer AVES fracturing fluids are reviewed, and the advantages and disadvantages of various types of AVES fracturing fluids in oilfield applications are illustrated. In view of the domestic and foreign situation of AVES fracturing fluid with low fracturing effect at high temperature, poor micellar stability and complex synthesis of main agent, the methods of improving the anion side chain, developing asymmetric twin anions and developing new nanoparticles are proposed, so as to simplify the system preparation and increase its temperature resistance and stability.
Anionic clean fracturing fluid is a non-polymer water-based fracturing fluid based on anionic viscoelastic surfactant. It has such characteristics as simple configuration, easy flowback, no residue, low viscosity and good elasticity of gel, stable fracturing performance and so on. With the increasing of the difficulties of low pressure and low permeability oil field and the depth of oil well exploitation, the temperature resistance of anionic viscoelastic surfactant fluid(AVES) has become an important aspect of the research topic. The application performance and characteristics of typical non-polymer AVES fracturing fluids and new polymer AVES fracturing fluids are reviewed, and the advantages and disadvantages of various types of AVES fracturing fluids in oilfield applications are illustrated. In view of the domestic and foreign situation of AVES fracturing fluid with low fracturing effect at high temperature, poor micellar stability and complex synthesis of main agent, the methods of improving the anion side chain, developing asymmetric twin anions and developing new nanoparticles are proposed, so as to simplify the system preparation and increase its temperature resistance and stability.
引文
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[12]Li L,Nasrelgin H A,Cawiezel K E.Rheological properties of a new class of viscoelastic surfanctant[J].SPE Production Operations,2010,25(3):355-366.
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[20]Hu Xiaodong(胡小冬),Hou Mingming(侯明明),Hu Wenting(胡文庭),et al.Synthesis and application of anionic gemini surfactant in oil field[J].Chemical Engineering of Oil and Gas(石油与天然气化工),2011,40(5):494-498.
[21]Guo Hui(郭辉),Zhuang Yuwei(庄玉伟),Chu Yanhong(褚艳红),et al.Research progress of gemini surfactant clean fracturing fluid[J].Chemical Industry and Engineering Progress(化工进展),2018,37(8):3155-3163.
[22]Tang Shanfa(唐善法),Zhao Chengyang(赵成洋),Tian Lei(田磊),et al.Carboxylate gemini surfactant temperature resistant cleaning fracturing fluid--Take the application of tight sandstone gas reservoir in tarim basin as an example[J].Natural Gas Industry(天然气工业),2016,45(6):45-1.
[23]Yan Meng(闫梦),Zhang Zhiquan(张志全),Wu Yuhao(吴俣昊),et al.Study on performance of clean fracturing fluid[J].China Energy and Environmental Protection(能源与环保),2017,39(12):131-134.
[24]Zhou Tianyuan(周天元).Construction and performance evaluation of temperature-resistant anionic gemini surfactant cleaning fracturing fluid[D].Jingzhou:Yangtze University(长江大学),2017.
[25]Gao B,Sharma M M.A new family of anionic surfactants for enhanced-oil-recovery applications[J].Society of Petroleum Engineers,2013,18(5):829-840.
[26]Han L,Chen H,Luo P.Viscosity behavior of cationic gemini surfactants with long alkyl chains[J].Surface Science,2004,564(1):141-148.
[27]Muhammad S K.A review of gemini surfactants:Potential application in enhanced oil recovery[J].Journal of Surfactants and Detergents,2016,19:223-236.
[28]Zheng Y H,Tang S F,Wang J X,et al.Effect of micelle structure on the viscosity of sulfonate gemini surfactant solution[J].Arabian Journal for Science and Engineering,2019,44(1):259-267.
[29]Huang T P,James B C.Nanotechnology applications in viscoelastic surfactant stimulation fluids[C]//.SPE Production and Operations,2008:512-517.
[30]Zhang Lei(张磊).Status quo of research and application of clean fracturing fluids[J].Advances in Fine Petrochemicals(精细石油化工进展),2012,13(8):12-15.
[31]Shiv S S,Prahlad K Y,Huang T P,et al.Improved fluid efficiency for high-temperature viscoelastic surfactant based stimulation fluids using synergistic effects of nanoparticles[C]//SPE Kingdom of Saudi Arabia Annual Technical Symposium.Saudi Arabia:Society of Petroleum Engineers,2016:1-7.
[32]Sehmus O,Li L,Chaithan A,et al.Nanomaterials-enhanced hightemperature viscoelastic surfactant VES well treatment fluids[C]//SPE International Conference on Oilfield Chemistry.USA:SPEInternational Conference on Oilfield Chemistry,2017:1-10.
[33]Lei Xiaoyang(雷小洋),Tang Shanfa(唐善法),Yu Jiliang(余吉良),et al.Preparation and performance study of GA-16 composite clean fracturing fluid[J].Journal of Changjiang University(长江大学学报),2015,12(31):34-36.
[34]Luo Mingliang(罗明良),Gao Zunmei(高遵美),Huang Bo(黄波),et al.Study on properties of fibrous nano-composite clean fracturing fluid[J].Applied Chemical Industry(应用化工),2012,41(12):2060-2063.
[35]Gurmen M N,Fredd C N.Viscoelastic surfactant rheology modification:US 38008052[P].2006-11-28.
[36]Pitanen I,Suuronen J,Nurmi J.Partial molar volume,ionization,viscosity and structure of glycogen betaine in aqueous solutions[J].Journal Solution Chemistry,2010,39:1609-1626.
[37]Shiv S S,Baker H,Prahlad Y,et al.Surface modified nanoparticles as internal breakers for viscoelastic surfactant based fracturing fluids for high temperature operations[C]//SPE Kingdom of saudi arabia annual technical symposium.Saudi Arabia:Society of Petroleum Engineers,2017:1-7.
[38]Qu H,Ren L C,He W H,et al.Successful application of clean fracturing fluid replacing guan gum fluid to stimulate tuffstone in San Jorage basin,Argentina[C]//SPE International conference and exhibition on formation damage control.USA:Society of Petroleum Engineers,2018:1-14.
[39]Gaillard N,Thomas A,Favero C.Novel associative acrylamidebased polymers for proppant transport in hydraulic fracturing fluid[C]//SPE International symposium on oilfield chemistry.Texas:Society of Petroleum Engineers,2013:8-10.
[40]Gupta D V,Carman P S.Associative polymer system extends the temperature range of surfactant gel fracturing fluids[C]//SPEInternational symposium on oilfield chemistry.Texas:Society of Petroleum Engineers,2011:11-13.
[41]Akashdeep D,Geetanjali C,Amit V,et al.Rheological and breaking studies of a novel single-phase surfactantpolymeric gel system for hydraulic fracturing application[J].Journal of Petroleum Science and Engineering,2018,167:559-567.
[42]Zhou Yining(周逸凝).Research and development of polymers and surfactants[D].Xi'an:Xi'an Petroleum University(西安石油大学),2015.
[43]Yang J,Cui W,Dua Y,et al.Successful application of a new fracturing fluid with supramolecular complex structure[C]//SPEAnnual technical conference and exhibition.Texas:Society of Petroleum Engineers,2015:28-30.
[44]Yang Y,Cui W X,Guan B S,et al.Supramolecular fluid of associative polymer and viscoelastic surfactant for hydraulic fracturing[J].SPE Production and Operation,2016:318-324.
[45]Fang Feifei(方飞飞),Tang Shanfa(唐善法),Tian Lei(田磊),et al.Research on application of clean fracturing fluids domestically[J].Advances in Fine Petrochemicals(精细石油化工进展),2012,13(10):5-9.
[46]Yuan Guangyu(苑光宇),Hou Jirui(侯吉瑞),Luo Huan(罗焕),et al.Current situation and development trend with respect to research and application of clean fracturing fluid[J].China Surfactant Detergent and Cosmetics(日用化学工业),2012,42(4):288-297.
[47]Wang Guoqiang(王国强),Feng Sanli(冯三利),Cui Huijie(崔会杰).Application of cleaning fracturing fluid in coalbed gas well fracturing[J].Natural Gas Industry(天然气工业),2006,26(11):104-106.
[48]Sun Yanbo(孙彦波),Zhao Xianjun(赵贤俊),Yu Keli(于克利),et al.Application of cleaning fracturing fluid in Daqing oil field[J].Chemical Engineer(化学工程师),2007,142(7):35-36.
[2]Huang T P,Crews J B.Nanotechnology applications in viscoelasticsurfactant stimulation fluids[C]//SPE Production and Operation.America:Society of Petroleum Engineers,2008:512-517.
[3]Liu Mingshu(刘明书),Tang Shanfa(唐善法),Fang Feifei(方飞飞),et al.Progress of research on ionic surfactant system for use in clean fracturing fluids[J].Advances in Fine Petrochemicals(精细石油化工进展),2012,13(6):38-41.
[4]Wang Jiaxin(王嘉欣),Tang Shanfa(唐善法).Research progress of ionic surfactant system for cleaning fracturing fluid[J].Contemporary Chemical Industry(当代化工),2018,47(2):334-337.
[5]Wang Tongyu(王瞳煜),Yang Shuangchun(杨双春),Pan Yi(潘一),et al.Research progress on temperature resistance of cationic surfactant cleaning fracturing fluid[J].Chemical Industry and Engineering Progress(化工进展),2017,36(12):97-100.
[6]Bajpai P,Singh J P,Mandal A,et al.The synthesis and characterization of a clean hydrofracturing fluid[J].Petroleum Science and Technology,2010,28(17):1750-1760.
[7]Han Xiuling(韩秀玲),Zhang Jin(张劲),Mou Shanbo(牟善波),et al.Study on the properties of new anionic surfactant D3F-AS05fracturing fluid[J].Oilfield Chemistry(油田化学),2014,31(1):33-37.
[8]Zhang Lei(张磊).Status of research and application of clean fracturing fluids[J].Advances in Fine Petrochemicals(精细石油化工进展),2012,13(8):12-15.
[9]Gao Zunmei(高遵美).Study on gel breaking method and reusing of clear fracturing fluid in shallow oil and gas reservoirs[D].Qingdao:China University of Petroleum,2014.
[10]Duan Yuxiu(段玉秀),Du Haijun(杜海军),Shen Feng(申峰),et al.Study on a kind of anionic surfactant cleaning fracturing fluid[J].Journal of Changjiang University(长江大学学报),2014,11(16):66-67.
[11]Feng Wenyong(冯文勇).Study on the method and reuse of clean fracturing fluid in shallow oil and gas reservoirs[D].Xi'an:Xi'an Petroleum University(西安石油大学),2015.
[12]Li L,Nasrelgin H A,Cawiezel K E.Rheological properties of a new class of viscoelastic surfanctant[J].SPE Production Operations,2010,25(3):355-366.
[13]Huang Rong(黄嵘),Tang Shanfa(唐善法),Fang Feifei(方飞飞),et al.Research and application progress of medium and high temperature clean fracturing fluid[J].Chemical production and technology(化工生产与技术),2012,19(3):28-32.
[14]Apui M,Cawiezei K,Gupta D V,et al.Viscoelastic evaluation of a surfactant gel for fydraulic fracturing[C]//SPE European Formation Damage Conference.Texas,Society of Petroleum Engineers,2015:28-30.
[15]Zhao Jun(赵军),Zhang Jin(张劲),Xiao Lijia(肖丽佳),et al.Performance evaluation and field application of high temperature resistant anionic surfactant fracturing fluid[J].Drilling and Production Technology(钻采工艺),2015,38(1):86-90.
[16]Zhang J,Zhang M,Zhang S C,et al.Development and field pilot test of a novel viscoelastic anionic-surfactant(VAS)fracturing fluid[C]//Western North America Regional Meeting.USA:Society of Petroleum Engineers,2018:1-9.
[17]Ding Li(丁里),Lv Haiyan(吕海燕),Zhao Wen(赵文),et al.Development and application of anionic surfactant fracturing fluid in sulige gas field[J].Oilfield Chemistry(油田化学),2010,39(4):316-319.
[18]Khair E M,Zhang S C,Mou S B,et al.Performance and application of new anionic D3F-AS05 viscoelastic fracturing fluid[J].Journal of Petroleum Science and Engineering,2011,78:131-138.
[19]Cristian F,Enrique M,Daniel P,et al.Successful application of a high temperature viscoelastic surfactant(VES)fracturing fluids under extreme conditions in patagonian wells,San Jorge basin[C]//SPEEuropec/EAGE Annual Conference.United Kingdom:Society of Petroleum Engineers,2007:1-15.
[20]Hu Xiaodong(胡小冬),Hou Mingming(侯明明),Hu Wenting(胡文庭),et al.Synthesis and application of anionic gemini surfactant in oil field[J].Chemical Engineering of Oil and Gas(石油与天然气化工),2011,40(5):494-498.
[21]Guo Hui(郭辉),Zhuang Yuwei(庄玉伟),Chu Yanhong(褚艳红),et al.Research progress of gemini surfactant clean fracturing fluid[J].Chemical Industry and Engineering Progress(化工进展),2018,37(8):3155-3163.
[22]Tang Shanfa(唐善法),Zhao Chengyang(赵成洋),Tian Lei(田磊),et al.Carboxylate gemini surfactant temperature resistant cleaning fracturing fluid--Take the application of tight sandstone gas reservoir in tarim basin as an example[J].Natural Gas Industry(天然气工业),2016,45(6):45-1.
[23]Yan Meng(闫梦),Zhang Zhiquan(张志全),Wu Yuhao(吴俣昊),et al.Study on performance of clean fracturing fluid[J].China Energy and Environmental Protection(能源与环保),2017,39(12):131-134.
[24]Zhou Tianyuan(周天元).Construction and performance evaluation of temperature-resistant anionic gemini surfactant cleaning fracturing fluid[D].Jingzhou:Yangtze University(长江大学),2017.
[25]Gao B,Sharma M M.A new family of anionic surfactants for enhanced-oil-recovery applications[J].Society of Petroleum Engineers,2013,18(5):829-840.
[26]Han L,Chen H,Luo P.Viscosity behavior of cationic gemini surfactants with long alkyl chains[J].Surface Science,2004,564(1):141-148.
[27]Muhammad S K.A review of gemini surfactants:Potential application in enhanced oil recovery[J].Journal of Surfactants and Detergents,2016,19:223-236.
[28]Zheng Y H,Tang S F,Wang J X,et al.Effect of micelle structure on the viscosity of sulfonate gemini surfactant solution[J].Arabian Journal for Science and Engineering,2019,44(1):259-267.
[29]Huang T P,James B C.Nanotechnology applications in viscoelastic surfactant stimulation fluids[C]//.SPE Production and Operations,2008:512-517.
[30]Zhang Lei(张磊).Status quo of research and application of clean fracturing fluids[J].Advances in Fine Petrochemicals(精细石油化工进展),2012,13(8):12-15.
[31]Shiv S S,Prahlad K Y,Huang T P,et al.Improved fluid efficiency for high-temperature viscoelastic surfactant based stimulation fluids using synergistic effects of nanoparticles[C]//SPE Kingdom of Saudi Arabia Annual Technical Symposium.Saudi Arabia:Society of Petroleum Engineers,2016:1-7.
[32]Sehmus O,Li L,Chaithan A,et al.Nanomaterials-enhanced hightemperature viscoelastic surfactant VES well treatment fluids[C]//SPE International Conference on Oilfield Chemistry.USA:SPEInternational Conference on Oilfield Chemistry,2017:1-10.
[33]Lei Xiaoyang(雷小洋),Tang Shanfa(唐善法),Yu Jiliang(余吉良),et al.Preparation and performance study of GA-16 composite clean fracturing fluid[J].Journal of Changjiang University(长江大学学报),2015,12(31):34-36.
[34]Luo Mingliang(罗明良),Gao Zunmei(高遵美),Huang Bo(黄波),et al.Study on properties of fibrous nano-composite clean fracturing fluid[J].Applied Chemical Industry(应用化工),2012,41(12):2060-2063.
[35]Gurmen M N,Fredd C N.Viscoelastic surfactant rheology modification:US 38008052[P].2006-11-28.
[36]Pitanen I,Suuronen J,Nurmi J.Partial molar volume,ionization,viscosity and structure of glycogen betaine in aqueous solutions[J].Journal Solution Chemistry,2010,39:1609-1626.
[37]Shiv S S,Baker H,Prahlad Y,et al.Surface modified nanoparticles as internal breakers for viscoelastic surfactant based fracturing fluids for high temperature operations[C]//SPE Kingdom of saudi arabia annual technical symposium.Saudi Arabia:Society of Petroleum Engineers,2017:1-7.
[38]Qu H,Ren L C,He W H,et al.Successful application of clean fracturing fluid replacing guan gum fluid to stimulate tuffstone in San Jorage basin,Argentina[C]//SPE International conference and exhibition on formation damage control.USA:Society of Petroleum Engineers,2018:1-14.
[39]Gaillard N,Thomas A,Favero C.Novel associative acrylamidebased polymers for proppant transport in hydraulic fracturing fluid[C]//SPE International symposium on oilfield chemistry.Texas:Society of Petroleum Engineers,2013:8-10.
[40]Gupta D V,Carman P S.Associative polymer system extends the temperature range of surfactant gel fracturing fluids[C]//SPEInternational symposium on oilfield chemistry.Texas:Society of Petroleum Engineers,2011:11-13.
[41]Akashdeep D,Geetanjali C,Amit V,et al.Rheological and breaking studies of a novel single-phase surfactantpolymeric gel system for hydraulic fracturing application[J].Journal of Petroleum Science and Engineering,2018,167:559-567.
[42]Zhou Yining(周逸凝).Research and development of polymers and surfactants[D].Xi'an:Xi'an Petroleum University(西安石油大学),2015.
[43]Yang J,Cui W,Dua Y,et al.Successful application of a new fracturing fluid with supramolecular complex structure[C]//SPEAnnual technical conference and exhibition.Texas:Society of Petroleum Engineers,2015:28-30.
[44]Yang Y,Cui W X,Guan B S,et al.Supramolecular fluid of associative polymer and viscoelastic surfactant for hydraulic fracturing[J].SPE Production and Operation,2016:318-324.
[45]Fang Feifei(方飞飞),Tang Shanfa(唐善法),Tian Lei(田磊),et al.Research on application of clean fracturing fluids domestically[J].Advances in Fine Petrochemicals(精细石油化工进展),2012,13(10):5-9.
[46]Yuan Guangyu(苑光宇),Hou Jirui(侯吉瑞),Luo Huan(罗焕),et al.Current situation and development trend with respect to research and application of clean fracturing fluid[J].China Surfactant Detergent and Cosmetics(日用化学工业),2012,42(4):288-297.
[47]Wang Guoqiang(王国强),Feng Sanli(冯三利),Cui Huijie(崔会杰).Application of cleaning fracturing fluid in coalbed gas well fracturing[J].Natural Gas Industry(天然气工业),2006,26(11):104-106.
[48]Sun Yanbo(孙彦波),Zhao Xianjun(赵贤俊),Yu Keli(于克利),et al.Application of cleaning fracturing fluid in Daqing oil field[J].Chemical Engineer(化学工程师),2007,142(7):35-36.
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