DOPO基阻燃剂的研究进展
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- 英文论文题名：Research Progress of DOPO-based Flame Retardant
- 论文作者：霍国洋
- 英文论文作者：Huo Guoyang ; Sheng Yi Technology(Shaan Xi) CO. ; LTD
- 年：2017
- 作者机构：陕西生益科技有限公司;
- 论文关键词：DOPO ; 阻燃剂 ; 协同阻燃 ; 研究进展
- 英文论文关键词：DOPO ; flame retardants ; synergistic flame retardant ; research progress
- 会议召开时间：2017-04-21
- 会议录名称：全国阻燃剂研发与应用技术交流研讨会论文集
- 语种：中文
- 分类号：TQ314.248
- 学会代码：CJGL
- 会议名称：全国阻燃剂研发与应用技术交流研讨会
- 会议地点：中国浙江杭州
- 主办单位：中国国际科技促进会
- 学会名称：北京城建联企业管理咨询中心
- 页数：12
- 文件大小：994k
- 原文格式：D
- 会议级别：全国
摘要
简述了DOPO(9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物)的合成及DOPO基阻燃剂的作用机理;重点介绍了DOPO基含磷阻燃剂、P-N协同阻燃剂、P-Si协同阻燃剂及DOPO基无机物的研究进展,并展望了DOPO基阻燃剂的发展前景。
The synthesis mechanism of DOPO(9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) and the flame-retardant mechanism of DOPO-based flame retardants were briefly summarized.The research progress of DOPO-based flame retardants such as phosphorus-containing flame retardants,P-N synergistic flame retardants,P-Si synergistic flame retardants and DOPO-based inorganic materials were emphatically introduced.The future research tendency of DOPO-based flame retardants was presented.
The synthesis mechanism of DOPO(9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) and the flame-retardant mechanism of DOPO-based flame retardants were briefly summarized.The research progress of DOPO-based flame retardants such as phosphorus-containing flame retardants,P-N synergistic flame retardants,P-Si synergistic flame retardants and DOPO-based inorganic materials were emphatically introduced.The future research tendency of DOPO-based flame retardants was presented.
引文
[1]周燕雪.DOPO及其衍生物在高分子材料的阻燃研究[J].广东化工,2014,41(10):83-84.
[2]Wang X,Hu Y,Song L,et al.Thermal degradation mechanism of flame retarded epoxy resins with a DOPO-substitued organophosphorus oligomer by TG–FTIR and DP-MS[J].Journal of Analytical and Applied Pyrolysis,2011,92:164-170.
[3]Wang X,Hu Y,Song L,et al.Flame retardancy and thermal degradation mechanism of epoxy resin composites based on a DOPO substituted organophosphorus oligomer[J].Polymer,2010,51:2435-2445.
[4]Christoph,Klinkowski,Lin Zang,Manfred D(o)ring,et al.DOPO.Based Flame Retardants:Synthesis And Flame Retardant Efficiency In Polymers[J].Materials China,2013,32(3):144-158.
[5]支肖琼,黄杰,唐安斌,等.DOPO制备方法的比较与选择[J].绝缘材料,2005,(3):55-59.
[6]赖华,刘兴,朱小明,等.阻燃剂9,10-二氢-9-氧杂-10-膦杂菲-10-氧化物合成中酯化反应和酰基化反应的优化[J].应用化学,2017,34(2):151-156.
[7]Morgan B.A.,Jeffrey W.Gilman.An overview of flame retardant of polymeric materials:application,technology,and future directions[J].Fire and Materials,2013,(37):259-279.
[8]Lu H.D.,L.Song,Y.Hu.A review on flame retardant technology in China.PartⅡ:flame retardant polymeric nanocomposites and coatings[J].Polymer Advance Technologies,2011,(12):379-394.
[9]Feng F.F.,L.J.Qian.The flame retardant behaviors and synergistic effect of expandable graphite and dimethyl methylphosphonate in grid polyurethane foams[J].Polym.Composite,2014,35(2):301-309.
[10]郑玉婴.一种基于磷杂菲基团的无卤阻燃剂的合成及其应用研究[J].功能材料,2015(6):06081-06085.
[11]徐晓强.DOPO衍生物的合成及其在阻燃P BT中的应用[J].工程塑料应用,2015,43(3):108-110.
[12]韩明轩,许苗军,李斌.新型含磷阻燃剂D OPO-PPO的合成及其阻燃性能[J].合成化学,2016,24(2):98-101.
[13]李霈,付海,赵欧,等.聚磷酸酯阻燃剂复配聚磷酸铵对环氧树脂阻燃性能的影响[J].高等学校化学学报,2017,38(2):294-302.
[14]冯国东,胡云,周永红,等.含磷型聚合甘油脂肪酸酯阻燃增塑剂的制备与应用[J].林产化学与工业,2016,36(1):77-83.
[15]闫晓红.一种10-(2,5-二羟基苯基)-10-氢-9-氧杂-10-磷杂菲-10-氧化物的制备方法:中国,CN103214522B[P].2015-06-03.
[16]钱立军.基于磷杂菲和磷腈基团的双基化合物、制备方法及应用:中国,CN104262399B[P].2016-04-20.
[17]董全霄.一种有机高分子含磷阻燃剂:中国,CN103936971B[P].2016-04-06.
[18]Lin C.H.,Y.W.Tian.Monofunctional,bifunctional,and multifunctional phosphinated phenols and their derivatives and preparation method thereof[P].US:20130012668 A1,2013-01-10.
[19]Ma S.Q.,X.Q.Liu,Y.H.Jiang,et al.Synthesis and properties of phosphorus-containing bio-based epoxy resin from itaconic acid[J].Sci.China Chem.2013,57(3):379-388.
[20]邱勇,钱立军.一种基于磷杂菲和三嗪基团的无卤阻燃剂的制备及表征[J].化工新型材料,2013,41(8):75-77.
[21]代云利,陈妤红,蔡春飞,等.一种新型氮磷阻燃剂的合成与表征[J].江汉大学学报(自然科学版),2016,44(1):34-39.
[22]李焰.一种D OPO衍生磷氮阻燃剂及其制备方法和应用:中国,CN103881134B[P].2017-2-5.
[23]姚有为.一种高效磷氮系阻燃剂及制备方法:中国,CN103865101B[P].2016-08-17.
[24]史铁钧.一种具有阻燃性的潜伏性固化剂及其制备方法:中国,CN103755922B[P].2016-02-24.
[25]赵建青.DOPO基均三嗪环氢化苯并咪唑环氧固化剂及其制备方法:中国,CN104086751B[P].2016-10-05.
[26]刘胜平.一种含磷含氮酚醛树脂及其制备方法:中国,CN103254379B[P].2015-07-01.
[27]Chang H.C.,H.T.Lin,C.H.Lin,et al.Facile preparation of a phosphinated bisphenol and its low waterabsorption epoxy resins for halogen-free copper clad laminates[J].Ploym.Degrad.and Stab.2013,98(1):102-108.
[28]李运涛,郭荣誉,范娇娇,等.新型有机硅阻燃剂的合成及其表征[J].陕西科技大学学报,2015,33(1):90-94.
[29]闫莉.一种含D OPO侧基的聚合型磷-硅阻燃剂及其制备方法:中国,CN103897104B[P].2016-01-06.
[30]戴李宗.一种含磷硅嵌段共聚物及其制备方法:中国,CN103819634B[P].2016-6-1.
[31]戴李宗.一种含磷硅反应型大分子阻燃剂及其制备方法与应用:中国,CN104262538B[P].2016-08-03.
[32]李东阵.DOPO改性无机阻燃剂及其制备方法:中国,CN103788408B[P].2016-09-28.
[33]张胜.一种含磷杂菲环化合物插层改性水滑石及其制备方法.中国:CN103865102B[P].2016-12-07.
[34]高卫卫,俞科静,曹海建,等.DOPO-氢氧化铝复合型阻燃剂的研究与制备[J].现代化工,2012,32(2):52-55.
[2]Wang X,Hu Y,Song L,et al.Thermal degradation mechanism of flame retarded epoxy resins with a DOPO-substitued organophosphorus oligomer by TG–FTIR and DP-MS[J].Journal of Analytical and Applied Pyrolysis,2011,92:164-170.
[3]Wang X,Hu Y,Song L,et al.Flame retardancy and thermal degradation mechanism of epoxy resin composites based on a DOPO substituted organophosphorus oligomer[J].Polymer,2010,51:2435-2445.
[4]Christoph,Klinkowski,Lin Zang,Manfred D(o)ring,et al.DOPO.Based Flame Retardants:Synthesis And Flame Retardant Efficiency In Polymers[J].Materials China,2013,32(3):144-158.
[5]支肖琼,黄杰,唐安斌,等.DOPO制备方法的比较与选择[J].绝缘材料,2005,(3):55-59.
[6]赖华,刘兴,朱小明,等.阻燃剂9,10-二氢-9-氧杂-10-膦杂菲-10-氧化物合成中酯化反应和酰基化反应的优化[J].应用化学,2017,34(2):151-156.
[7]Morgan B.A.,Jeffrey W.Gilman.An overview of flame retardant of polymeric materials:application,technology,and future directions[J].Fire and Materials,2013,(37):259-279.
[8]Lu H.D.,L.Song,Y.Hu.A review on flame retardant technology in China.PartⅡ:flame retardant polymeric nanocomposites and coatings[J].Polymer Advance Technologies,2011,(12):379-394.
[9]Feng F.F.,L.J.Qian.The flame retardant behaviors and synergistic effect of expandable graphite and dimethyl methylphosphonate in grid polyurethane foams[J].Polym.Composite,2014,35(2):301-309.
[10]郑玉婴.一种基于磷杂菲基团的无卤阻燃剂的合成及其应用研究[J].功能材料,2015(6):06081-06085.
[11]徐晓强.DOPO衍生物的合成及其在阻燃P BT中的应用[J].工程塑料应用,2015,43(3):108-110.
[12]韩明轩,许苗军,李斌.新型含磷阻燃剂D OPO-PPO的合成及其阻燃性能[J].合成化学,2016,24(2):98-101.
[13]李霈,付海,赵欧,等.聚磷酸酯阻燃剂复配聚磷酸铵对环氧树脂阻燃性能的影响[J].高等学校化学学报,2017,38(2):294-302.
[14]冯国东,胡云,周永红,等.含磷型聚合甘油脂肪酸酯阻燃增塑剂的制备与应用[J].林产化学与工业,2016,36(1):77-83.
[15]闫晓红.一种10-(2,5-二羟基苯基)-10-氢-9-氧杂-10-磷杂菲-10-氧化物的制备方法:中国,CN103214522B[P].2015-06-03.
[16]钱立军.基于磷杂菲和磷腈基团的双基化合物、制备方法及应用:中国,CN104262399B[P].2016-04-20.
[17]董全霄.一种有机高分子含磷阻燃剂:中国,CN103936971B[P].2016-04-06.
[18]Lin C.H.,Y.W.Tian.Monofunctional,bifunctional,and multifunctional phosphinated phenols and their derivatives and preparation method thereof[P].US:20130012668 A1,2013-01-10.
[19]Ma S.Q.,X.Q.Liu,Y.H.Jiang,et al.Synthesis and properties of phosphorus-containing bio-based epoxy resin from itaconic acid[J].Sci.China Chem.2013,57(3):379-388.
[20]邱勇,钱立军.一种基于磷杂菲和三嗪基团的无卤阻燃剂的制备及表征[J].化工新型材料,2013,41(8):75-77.
[21]代云利,陈妤红,蔡春飞,等.一种新型氮磷阻燃剂的合成与表征[J].江汉大学学报(自然科学版),2016,44(1):34-39.
[22]李焰.一种D OPO衍生磷氮阻燃剂及其制备方法和应用:中国,CN103881134B[P].2017-2-5.
[23]姚有为.一种高效磷氮系阻燃剂及制备方法:中国,CN103865101B[P].2016-08-17.
[24]史铁钧.一种具有阻燃性的潜伏性固化剂及其制备方法:中国,CN103755922B[P].2016-02-24.
[25]赵建青.DOPO基均三嗪环氢化苯并咪唑环氧固化剂及其制备方法:中国,CN104086751B[P].2016-10-05.
[26]刘胜平.一种含磷含氮酚醛树脂及其制备方法:中国,CN103254379B[P].2015-07-01.
[27]Chang H.C.,H.T.Lin,C.H.Lin,et al.Facile preparation of a phosphinated bisphenol and its low waterabsorption epoxy resins for halogen-free copper clad laminates[J].Ploym.Degrad.and Stab.2013,98(1):102-108.
[28]李运涛,郭荣誉,范娇娇,等.新型有机硅阻燃剂的合成及其表征[J].陕西科技大学学报,2015,33(1):90-94.
[29]闫莉.一种含D OPO侧基的聚合型磷-硅阻燃剂及其制备方法:中国,CN103897104B[P].2016-01-06.
[30]戴李宗.一种含磷硅嵌段共聚物及其制备方法:中国,CN103819634B[P].2016-6-1.
[31]戴李宗.一种含磷硅反应型大分子阻燃剂及其制备方法与应用:中国,CN104262538B[P].2016-08-03.
[32]李东阵.DOPO改性无机阻燃剂及其制备方法:中国,CN103788408B[P].2016-09-28.
[33]张胜.一种含磷杂菲环化合物插层改性水滑石及其制备方法.中国:CN103865102B[P].2016-12-07.
[34]高卫卫,俞科静,曹海建,等.DOPO-氢氧化铝复合型阻燃剂的研究与制备[J].现代化工,2012,32(2):52-55.
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