电化学氧化工艺处理焦化废水研究
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摘要
通过基础电极筛选、表面预处理、稀土金属掺杂和析氧材料涂覆等研究工作,制备了具有竞争力的用于电化学法处理焦化废水的高活性、高稳定性的高效电极。同时对比了二维电极和以焦粉为粒子电极的三维电极法处理焦化废水中COD和NH4+-N的效果,研究优化了电化学氧化工艺的运行参数,并探索了两种工艺对污染物的降解机理。在此基础上,通过对焦粉粒子改性使其具有良好的电氧化性能,强化三维电极系统的电解效率。通过筛选对比可知,采用Fe(NO3)2改性焦粉的三维电极对于焦化废水的生化出水具有较好的处理效果,且在实验室条件下实现了高效低成本地采用重金属修饰焦粉三维电极电化学氧化处理焦化废水,并初步探讨了重金属修饰焦粉三维电极电化学氧化去除COD和NH4--N的机制。
High activity, stability, efficient electrodes was prepared by foundation electrodes screening, surface pretreatment, rare-earth metal addition and oxygen evolution materialscoating for the electrochemical oxidation of coking wastewater using three-dimensional electrode system. In order to optimize the electrochemical performance of the three-dimensional electrode process, the electrolysis tests of the coking wastewater using Ti/RuO2-IrO2anodes and the coke with or without modified were carried out, which included the optimizing of the structural and operating parameters. And the mechanism of COD and NH4+-N degradation was also studied. On that basis, the effect of supported components on COD and NH4+-N removal was investigated to optimize the electrochemical treatment of coking wastewater using three-dimensional electrode process combined with modified coke. Studies have demonstrated that the particle electrode with supported components improved the electrolysis efficiency, which could generate additional free hydroxyl radicals and greatly improve the removal rate. In addition,The results showed that the coke modified with Fe(NO3)2has the lowest energy consumption and higher COD removal rate on the same condition, and the modified coke have good surface characteristics for the purpose of this study. In addition, the kinetic constant was also calculated. Results showed that the three-dimensional electrode system with Fe (N03)2-modified coke gave a satisfied solution in biologically pretreated coking wastewater.
High activity, stability, efficient electrodes was prepared by foundation electrodes screening, surface pretreatment, rare-earth metal addition and oxygen evolution materialscoating for the electrochemical oxidation of coking wastewater using three-dimensional electrode system. In order to optimize the electrochemical performance of the three-dimensional electrode process, the electrolysis tests of the coking wastewater using Ti/RuO2-IrO2anodes and the coke with or without modified were carried out, which included the optimizing of the structural and operating parameters. And the mechanism of COD and NH4+-N degradation was also studied. On that basis, the effect of supported components on COD and NH4+-N removal was investigated to optimize the electrochemical treatment of coking wastewater using three-dimensional electrode process combined with modified coke. Studies have demonstrated that the particle electrode with supported components improved the electrolysis efficiency, which could generate additional free hydroxyl radicals and greatly improve the removal rate. In addition,The results showed that the coke modified with Fe(NO3)2has the lowest energy consumption and higher COD removal rate on the same condition, and the modified coke have good surface characteristics for the purpose of this study. In addition, the kinetic constant was also calculated. Results showed that the three-dimensional electrode system with Fe (N03)2-modified coke gave a satisfied solution in biologically pretreated coking wastewater.
引文
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