非芳香性磺酸盐驱油剂的设计、合成及应用研究
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摘要
随着经济的快速发展,我国对能源的需求量越来越大,能源的需求与产出矛盾日益突出。在新型能源还无法大规模应用、传统能源又日趋紧张的情况下,能大幅度提高原油采收率的三次采油技术已成为石油开采研究的重大课题,而表面活性剂.即驱油剂驱油是三次采油的重要研究内容之一。
目前,在大量应用的三次采油驱油剂中,大部分都含有芳环,特别是有的还含有稠环结构,生物降解性差、环境毒性大,对环境不友好。同时,这些在各油田广泛应用的驱油剂都需要与碱、助表面活性剂等复配使用才能达到降低油水界面张力至超低值、提高采收率的目的。本论文的主要目的是针对现有驱油剂的缺陷,有针对性地研究环保、高效、经济的新型表面活性剂并运用在三次采油中,使其在不加碱和其它任何助剂的情况下能降低油水界面张力至超低值,达到大幅度提高原油采收率的目的。
经过大量文献查阅,本论文选用一系列的不含芳香环的原料进行磺化、中和,期望得到具有较高活性的磺酸盐驱油剂。经过大量的的原料筛选和工艺优化后,本论文成功用不含芳香环结构的环烷基油和生物油做为原料,用发烟浓硫酸做为磺化试剂分别磺化两种原料,最后经氨水中和,得到了两种非芳香性磺酸盐驱油剂:环烷基石油磺酸盐和生物油磺酸盐。该制备方法工艺成熟简单,易于工业化生产。所合成的两种磺酸盐经过硅胶柱层析分离提纯后,分别做了红外和核磁共振氢谱分析,经过与两种合成原料的红外和核磁共振氢谱对比分析后,证实了两种非芳香性磺酸盐驱油剂的存在。
这两种非芳香性磺酸盐驱油剂都表现出优良的界面活性。在不加碱及其它任何助剂的情况下,能降低胜利油田采油一区、采油二区及孤东、孤岛的多数采油区块的油水界面张力至10~(-3)mN/m以下,最低至5×10~(-4)mN/m,表现出较好的界面活性和一定的普适性。
同时,合成的两种非芳香性磺酸盐具有较好的抗盐及抗Ca~(2+)、Mg~(2+)能力。其中环烷基石油磺酸盐在总矿化度为2000～50000mg/L范围内,生物油磺酸盐在盐度2000mg/L～130000mg/L范围内都具有较高的界面活性。环烷基石油磺酸盐在Ca~(2+)、Mg~(2+)浓度为40～450mg/L范围内,生物油磺酸盐在Ca~(2+)、Mg~(2+)浓度500mg/L以下时都具有较好的界面活性。
本论文测试了胜利油田部分采油区块原油的等效烷烃数(EACN)和两种非芳香性磺酸盐的最低碳数值(n_(min)),分析了EACN与n_(min)之间内在的关系;同时从两种非芳香性磺酸盐的分子结构特点出发,从分子结构和界面活性关系上探讨了两种磺酸盐具有较高界面活性、较广普适性的原因,从理论上拓展了驱油剂的界面行为研究,得出了具有普遍意义的规律,为以后进一步研究新型、高效的驱油剂提供了理论上的依据和支持。
With the rapid economic developing,China's growing energy demand has become increasingly conspicuous.Now,large-scale application of new energy can't be realized and traditional energy is becoming shortage.Under this situation,greatly enhance oil recovery technology has become a major oil research topics.Obviously,the surfactant which is used in tertiary oil recovery,become one of the important research focuses.
Presently,the main surfactants used in enhanced oil recovery usually possess aromatic rings and can not be bi-degraded and be harmful to environment.The primary object of this dissertation is to design and synthesize some novel nonaromatic sulphonates which can be used in enhanced oil recovery.The novel sulphonates should be environment-friendly and biodegradable.Additionally,they have excellent ability to reduce the interfacial tension between crude oil and water.
The novel sulphonates which are ester sulphonate and naphthenic petroleum sulphonate,through many experiments and reaction rout optimization,were designed and prepared in laboratory using ester or naphthenic oil reacted with fuming sulfuric acid followed by hydrolysis.The structures of two products were characterized by infrared spectra and ~1H nuclear magnetic resonancemain,at the same time,the main functional groups were approved.The results showed that the double bonds in ester were sulphonated and then converted into the corresponding saturated hydroxy ester sulphonate followed by hydrolysis when ester reacted with fuming sulfuric acid and naphthenic petroleum sulphonate was obtained through substitution reaction after naphthenic oil reacted with fuming sulfuric acid.
The interfacial activities of the two products were evaluated.It revealed that the two products had excellent capacities and efficiencies to lower the tensions of oil-water interface of block 1.and block 2.in Shengli oilfield to ultra-low without alkaline and any other additives.The interfacial tension between crude oil and water could be reduced as low as 10~(-3)mN/m and the minimum interfacial tension was up to 5×10~(-4)mN/m.Furthermore,the two products possessed outstanding salt-resisting capacitis as well.The ester sulphonate could reduce interfacial tension between oil and water to 10~(-3) mN/m even with the concentration of NaCl between 2000mg/L～130000 mg/L or with the concentration of Ca~(2+)、Mg~(2+) below 500mg/L,and the naphthenic petroleum sulphonate could reduce interfacial tension between oil and water to 10~(-3) mN/m even with the concentration of NaCl between 2000mg/L～50000mg/L or with the concentration of Ca~(2+)、Mg~(2+) below 500mg/L.The two products were expected to be used in enhanced oil recovery applications.
The equivalent alkane carbon number(EACN) was tested in part of Shengli Oilfield Area and the minimum number of alkane carbon(n_(min)) of the two surfactants were measured.The relationships between surfactant molecular structure and ability in lowering surface tension were investigated.All of this could provide theoretical fundamentals for designing new surfactant molecules in enhanced oil recovery.
目前,在大量应用的三次采油驱油剂中,大部分都含有芳环,特别是有的还含有稠环结构,生物降解性差、环境毒性大,对环境不友好。同时,这些在各油田广泛应用的驱油剂都需要与碱、助表面活性剂等复配使用才能达到降低油水界面张力至超低值、提高采收率的目的。本论文的主要目的是针对现有驱油剂的缺陷,有针对性地研究环保、高效、经济的新型表面活性剂并运用在三次采油中,使其在不加碱和其它任何助剂的情况下能降低油水界面张力至超低值,达到大幅度提高原油采收率的目的。
经过大量文献查阅,本论文选用一系列的不含芳香环的原料进行磺化、中和,期望得到具有较高活性的磺酸盐驱油剂。经过大量的的原料筛选和工艺优化后,本论文成功用不含芳香环结构的环烷基油和生物油做为原料,用发烟浓硫酸做为磺化试剂分别磺化两种原料,最后经氨水中和,得到了两种非芳香性磺酸盐驱油剂:环烷基石油磺酸盐和生物油磺酸盐。该制备方法工艺成熟简单,易于工业化生产。所合成的两种磺酸盐经过硅胶柱层析分离提纯后,分别做了红外和核磁共振氢谱分析,经过与两种合成原料的红外和核磁共振氢谱对比分析后,证实了两种非芳香性磺酸盐驱油剂的存在。
这两种非芳香性磺酸盐驱油剂都表现出优良的界面活性。在不加碱及其它任何助剂的情况下,能降低胜利油田采油一区、采油二区及孤东、孤岛的多数采油区块的油水界面张力至10~(-3)mN/m以下,最低至5×10~(-4)mN/m,表现出较好的界面活性和一定的普适性。
同时,合成的两种非芳香性磺酸盐具有较好的抗盐及抗Ca~(2+)、Mg~(2+)能力。其中环烷基石油磺酸盐在总矿化度为2000～50000mg/L范围内,生物油磺酸盐在盐度2000mg/L～130000mg/L范围内都具有较高的界面活性。环烷基石油磺酸盐在Ca~(2+)、Mg~(2+)浓度为40～450mg/L范围内,生物油磺酸盐在Ca~(2+)、Mg~(2+)浓度500mg/L以下时都具有较好的界面活性。
本论文测试了胜利油田部分采油区块原油的等效烷烃数(EACN)和两种非芳香性磺酸盐的最低碳数值(n_(min)),分析了EACN与n_(min)之间内在的关系;同时从两种非芳香性磺酸盐的分子结构特点出发,从分子结构和界面活性关系上探讨了两种磺酸盐具有较高界面活性、较广普适性的原因,从理论上拓展了驱油剂的界面行为研究,得出了具有普遍意义的规律,为以后进一步研究新型、高效的驱油剂提供了理论上的依据和支持。
With the rapid economic developing,China's growing energy demand has become increasingly conspicuous.Now,large-scale application of new energy can't be realized and traditional energy is becoming shortage.Under this situation,greatly enhance oil recovery technology has become a major oil research topics.Obviously,the surfactant which is used in tertiary oil recovery,become one of the important research focuses.
Presently,the main surfactants used in enhanced oil recovery usually possess aromatic rings and can not be bi-degraded and be harmful to environment.The primary object of this dissertation is to design and synthesize some novel nonaromatic sulphonates which can be used in enhanced oil recovery.The novel sulphonates should be environment-friendly and biodegradable.Additionally,they have excellent ability to reduce the interfacial tension between crude oil and water.
The novel sulphonates which are ester sulphonate and naphthenic petroleum sulphonate,through many experiments and reaction rout optimization,were designed and prepared in laboratory using ester or naphthenic oil reacted with fuming sulfuric acid followed by hydrolysis.The structures of two products were characterized by infrared spectra and ~1H nuclear magnetic resonancemain,at the same time,the main functional groups were approved.The results showed that the double bonds in ester were sulphonated and then converted into the corresponding saturated hydroxy ester sulphonate followed by hydrolysis when ester reacted with fuming sulfuric acid and naphthenic petroleum sulphonate was obtained through substitution reaction after naphthenic oil reacted with fuming sulfuric acid.
The interfacial activities of the two products were evaluated.It revealed that the two products had excellent capacities and efficiencies to lower the tensions of oil-water interface of block 1.and block 2.in Shengli oilfield to ultra-low without alkaline and any other additives.The interfacial tension between crude oil and water could be reduced as low as 10~(-3)mN/m and the minimum interfacial tension was up to 5×10~(-4)mN/m.Furthermore,the two products possessed outstanding salt-resisting capacitis as well.The ester sulphonate could reduce interfacial tension between oil and water to 10~(-3) mN/m even with the concentration of NaCl between 2000mg/L～130000 mg/L or with the concentration of Ca~(2+)、Mg~(2+) below 500mg/L,and the naphthenic petroleum sulphonate could reduce interfacial tension between oil and water to 10~(-3) mN/m even with the concentration of NaCl between 2000mg/L～50000mg/L or with the concentration of Ca~(2+)、Mg~(2+) below 500mg/L.The two products were expected to be used in enhanced oil recovery applications.
The equivalent alkane carbon number(EACN) was tested in part of Shengli Oilfield Area and the minimum number of alkane carbon(n_(min)) of the two surfactants were measured.The relationships between surfactant molecular structure and ability in lowering surface tension were investigated.All of this could provide theoretical fundamentals for designing new surfactant molecules in enhanced oil recovery.
引文
[1]肖进新,赵振国.表面活性剂应用原理.北京:化学工业出版社,2004年,4-6.
[2]赵国玺,朱埗瑶.表面活性剂作用原理.北京:中国轻工业出版社,2003年,1-5.
[3]孙岩,殷福珊,宋湛谦,王墨林.新表面活性剂.北京:化学工业出版社,2003年,2-3.
[4]梁文杰.石油化学.山东东营:石油大学出版社,1995年.
[5]王子军,石油沥青质的化学和物理Ⅱ-沥青质的化学组成和结构,石油沥青,1996,10(1):26-36.
[6]王子军,石油沥青质的化学和物理Ⅳ-石油沥青质溶液的胶体化学,石油沥青,1996,10(3):36-49.
[7]杨小莉,陆婉珍.有关原油乳状液稳定性的研究,油田化学,I998,15(2):87-96
[8]樊西惊.石油胶态分散体的稳定性,油田化学,1999,16<1):72-76.
[9]Peramanu S,Clarke P F,Pmden B B.Flow loop apparatus to study the effect of solvent,temperature and additives on asphaltene preciptation,J of Petroleum Science and Engineering,1999,23:133-143.
[10]李干佐,翟利民.三次采油.科学,2000 52(1):10-12.
[11]牟建海,李干佐.三次采油技术的发展现状及展望.化工科技市场,2000,23(7):17-20.
[12]Enrique Carrero,Nestor V.Queipo,Salvador Pintos,Luis E.Zerpa.Global sensitivity analysis of Alkali-Surfactant-Polymer enhanced oil recovery processes.Journal of Petroleum Science and Engineering,58(2007):30-42.
[13]Da-Kuang Han,Cheng-Zhi Yang,Zheng-Qing Zhang.Recent development of enhanced oil recovery in China.Journal of Petroleum Science and Engineering 22.1999:181-188
[14]Zheng-Bo Yue,Han-Qing Yu,Zhen-Hu Hu.Surfactant-enhanced anaerobic acidogenesis of Canna indica L.by rumen cultures.Bioresource Technology 99(2008):3418-3423
[15]DeGroot M.Flooding process for recovering oil from subterranean oil bearing strata.US Patentl,823,439.Sept.15,1931.
[16]DeGroot M,Monson L T.Flooding process for recovering fixed oil from subterranean oil bearingstrata.US Patent 1,823,440.Sept.15,1931.
[17]Blair C M,Groves W,Lehmann S.Process for increasing productivity of subterranean oil-bearing stratr.US Patent 2,356,205.Aug.22,1944.
[18]Holbrook O C.Surfactant-water secondary recovery process.US Patent 3,006,411.Oct.31,1961.
[19]Holm L W,Bernard G Q Secondary recovery water-flood process.US Patent 3,082,822.Mar.26 1963.
[20]Csaszar A K.Solvent-waterflood oil recovery process.US Patent 3,163,214.Dec.29,1964.
[21]Gogarty W B,Olson R W.Use of microemulsions in miscible-type oil recovery produce.US Patent 3,254,714.June 7,1966.
[22]Jones S C.High water content oil-external micellar dispersions.US Patent 3,497,006.Feb.24,1970.
[23]Gale W W,Puerto M C,Ashcraft T Let al.Propoxylated ethoxylated surfactants and method of recovering oil therewith.US Patent 4,293,428.Oct.6,1981.
[24]韩东,沈平平 表面活性剂驱油原理及应用。北京,石油工业出版社,2001年,94
[25]Shubiao Zhang,Yingmei Xu,Weihong Qiao.Interfacial tensions upon the addition of alcohols to phenylalkane sulfonate monoisomer systems.Fuel 83(2004):2059-2063
[26]Mingyuan Li,Meiqin Lin,Zhaoliang Wu.The influence of NaOH on the stability of paraffinic crude oil emulsion.Fuel 84(2004):183-187
[27]孙新春,向湘兴.环烷酸盐作为ASP驱油体系中表面活性剂的研究.新疆石油科技,19977(2):54-59.
[28]李干佐,沈强,郑立强.新型驱油用表面活性剂天然混合羧酸盐.油田化学,1999 19(1):57.
[29]黄宏度.从烷烃汽相氧化产物直接制备(不磺化)驱油用活性剂.油田化学,1987,4(3):191
[30]丁颖,袁英同,吕少军.表面活性剂在三次采油中的应用及进展。内蒙古石油化工,2004,30(2):121-123.
[31]S.Ma,M.Dong,Z.Li,E.Shirif.Evaluation of the effectiveness of chemical flooding using heterogeneous sandpack flood test.Journal of Petroleum Science and Engineering 55(2007):294-300.
[32]赵有刚,梁成浩,张志军 三才采油用便面活性剂的制备及应用,化工技术与开发,2005,34(2):18-21
[33]韩东,沈平平.表面活性剂驱油原理及应用。北京,石油工业出版社,2001年,24-29.
[34]Tayfun Babadagli.Evaluation of EOR methods for heavy-oil recovery in naturally fractured reservoirs.Journal of Petroleum Science and Engineering 37(2003):25-37.
[35]朱友益,沈平平,曲景奎 三次采油用烷基本磺酸盐结构与性能的关系研究 石油勘探与开发。2004,31(增刊),9-12.
[36]将蒿,张淑芬,杨锦宗 磺化反应新进展 精细与专用化学品,2003,11:16-19.
[37]郑延成,韩东,杨普华。磺酸盐表面活性剂研究进展。精细化工,2005,22(8):578-582.
[38]崔正刚,张天林,邹文华等.重烷基苯磺酸盐的合成及其在提高石油采收率中的应用研究.表面活性剂/洗涤剂技术与经济进展(第五届国际表面活性剂耽涤剂研讨会论文集),1998:95-102.
[39]赵宇,董雅红,毕彩丰。系列烷基苯磺酸盐对烷烃的动态张力界面张力研究。化学学报,2008,66(7):799-802.
[40]Beger P D,Berger C H,Hsu I K.Anionic surfactants based on alkene sulfonic acid.US patent6,043,391.Mar.28,2000.
[41]Berger P D,Lee C H.New anionic alkylaryl surfactants basing on olefin sulfonic acids.Journal of Surfactants and Detergent,2002,5(1):39-43.
[42]黄宏度,驱油用石油羧酸盐的研制,油田化学,1991,8(3):235-239.
[43]黄宏度,赵林,石油羧酸盐复合体系中各组分的影响,江汉石油学院学报,1992,14(13):53-56.
[44]黄宏度,姬中复,吴一慧等,石油狡酸盐和大庆原油间的界面张力,江汉石油学院学报,1992 14(4):53-57.
[45]刘德新,黄宏度,岳湘安.石油氧化皂界面活性研究.石油与天然气化工,2005,34(1):56-58.
[46]李干佐,林元,徐桂英等,天然混合羧酸(盐)复合驱油体系的研究,日用化学工业,1994,11(1):61-65
[47]李干佐,徐桂英,毛宏志等,开发天然羧酸盐在油田中的应用,日用化学工业,1998(5):26-30
[48]李干佐,沈强,郑立强,新型驱油用表面活性剂天然羧酸盐,油田化学,1999} 16(1):57-59.
[49]王业飞,李继勇,赵福麟,高矿化度条件下应用的表面活性剂驱油体系,油气地质与采收率,2001,8(1):67-69.
[50]王磊,谢益民.木质素及及衍生物在三次采油中的应用进展.上海造纸,2008,39(3):63-69.
[51]王晓红,郝臣,木质素磺酸盐与丙稀酸接枝改性.江苏大学学报(自然科学版),2007,28(6):528-531.
[52]Kalfoglou Q.Lignosulfonates as sacrificial agents in oil recovery processes.US Patent,4d006,779.Feb.8,1977.
[53]Kalfoglou G..Oxidized lignosulfonates as additives in oil recovery processes involving chemical recovery agents.US Patent 4,133,385.Jan.9,1979.
[54]Kalfoglou G..Oxidized lignosulfonates as additives in oil recovery processes involving chemical recovery agents.US Patent 4,196,777.April 8,1980.
[55]Kalfoglou G..Sulfomethylated lignosulfonates as additives in oil recovery processes involving chemical recovery agents.US Patent 4,269,270.May 26,1981。
[56]Neale Q,Hornof V.,Chiwetelu C.,Canadian Journal of Chemistry,1981,59(13):1938-1943
[57]Chiwetelu C.,Neale Q,Hornof V,The Journal of Canadian Petroleum Technology,1980,19(3):91-99
[58]Hornof V,Neale G.,Bourgeois P.,The Canadian Journal Chemical Engineering,1981,59(4):554-556
[59]Hornof V,Neale G.,Jacovella F.,The Canadian Journal Chemical Engineering 1982,60(2):331-332
[60]Chiweteiu C.,Hornof V,Neale G.,Transactions of Institution Chemical Engineers 1982,60(3):177-182
[61]DeBons F E,Whittington L E,Pedersen L D.Method of enhanced oil recovery and compositions useful therein.US Patent 4,548,721.Oct.22,1985.
[62]Naae D G.,DeBons F E.Recovering hydrocarbons with water soluble alkylphenol lignin surfactants.US Patent 4,781,251.Nov.1,1988.
[63]DeBons F E,Pedersen L D,Whittington L E.Use of lignin/amine/surfactant blends in enhanced oilrecovery.US Patent 4,822,501.April 18,1989.
[64]Naae D G,Davis C A.Enhanced oil recovery using oil soluble sulfonates from lignin and benzyl alcohol.US Patent 5,095,986.March 17,1992.
[65]陈文求,孙争光.生物表面活性剂的生产与应用.胶体与聚合物,2007,25(3):45-46.
[66]张良晓,杨祥,陈艳玲.生物油表面活性剂在采油工程中的研究及应用.四川化工,2005,8(4):13-15
[67]伍小林,陈坚.生物油表面活性剂在提高原油采收率方面的应用.生物学杂志,2000,17(6):25-28.
[68]童正新,王芳,吴庆红.鼠李糖脂发酵液与OP类非离子表面活性剂复配驱油体系的研究.油气采收率技术,1998,5(2):6-20.
[69]杨金华,曹亚,李惠林.高分子表面活性剂与原油形成超低界面张力的研究,精细化工,1999(2):3.
[70]田志著,邓启刚,孙宏.双子表面活性剂的性能、合成及应用.化工时刊,2008,1:61-63.
[71]冯玉军,孙玉海,陈志.双子表面活性剂结构对性能的影响.日用化学工业,2007,37(2):107-111.
[72]李小丽.双子表面活性剂的研究概况.河北化工,2007,30(6):29-30.
[73]胡延峰,郭详峰,贾丽华.阳离子双子表面活性剂的应用研究进展.精细与专用化学品.2006,14(11):1-4.
[74]刘琪,孙雷,刘登峰.凝析尤其体系相态特征研究现状.砖采工艺,2008,3(1):112-113.
[75]Rudin J,Wasan D T.Mechanisms for lowering of interfacial tension in alkali/acidic oil systems:Effect of added surfactant.Industrial and Engineering Chemistry Research,1992,31(8):1899-1906_
[76]刘小辛,徐桂英,李干佐等.油酸一油酸钠水溶油原油间的瞬时界面张力.物理化学学报,1995,11(11):1040-1043.
[77]徐桂英,刘小辛,李干佐等.影响羧酸盐驱油体系界面张力因素的研究.山东大学学报(自然科学版),1996,31(1):71-75.
[78]Bansal V K,Chan K S,McCallough R et al.The effect of caustic concentration on interface charge,interfacial tension and droplet size:a sump test for optimum caustic concentration for crude oils.The Journal of Canadian Petroleum Technology,1978,17(1):69-72.
[79]Krumrine P H,Falcone J S,Campbell T C.Surfactant flooding 1:The effect of alkaline additives on IFT,surfactant adsorption,and recovery efficiency.Society of Petroleum Engineers Journal,1982,22(4):503-513.
[80]Krumrine P H,Falcone J S,Campbell T C.Surfactant flooding 2:The effect of alkaline additives on permeability and sweep efficiency.Society of Petroleum Engineers Journal,1982,22(6):983-992.
[81]Mahammad A K,Mahammad A s,Role of asphaltene and resin in oil field emulsions,J of Petroleum Sciences and Engineering,1999,23:213-221.
[82]Taylor K C,Hawkins B F,Islam M R.Dynamic interfacial tension in surfactant enhanced alkaline flooding.The Journal of Canadian Petroleum Technology,1990,29(1):50-55.
[83]Chiwetelu C I,Hornof V,Neale G H.A dynamic model for the interaction of caustic reagents with acidic oils.AIChE Journal,1990,36(2):233-241.
[84]Borwankar R P,Wasan D T.Dynamic interfacial tensions in acidic crude oil/caustic systems Part Ⅰ:A chemical diffusion-kinetic model.AIChE Journal,1986,32(3):455-466.
[85]Borwankar R P,Wasan D T.Dynamic interfacial tensions in acidic crude oil/caustic systems Part Ⅱ:Role of dynamic effects in alkaline flooding for enhanced oil recovery.AIChE Journal,1986,32(3):467-476.
[86]JNeale G H,Khulbe K C,Hornof V Effects of oil phase viscosity on interracial tension behaviour of oil/alkaline systems as measured by the spinning drop tensiometer.The Canadian Journal of Chemical Engineering,1987,65(4):700-703.
[87]Chiwetelu C I,Neale G H,Hornof V Dynamic tensions in finite oil droplets.Chemical Engineering Communications,1989,84:13-20.
[88]Chiwetelu C I,Hornof V,Neale G H.Use of mixed surfactants to improve the transient interfacial tension behaviour of heavy oil/alkaline systems.The Canadian Journal of Chemical Engineering,1994,72(3):534-540.,
[89]Wilson P M D,Brandner C F.Aqueous surfactant solutions which exhibit ultra-low tensions at the oil- water interface.Journal of Colloid and Interface Science,1977,60(3):473-479.
[90]Cayias J L,Schechter R S,Wade W H.The utilization of petroleum sulfonates for producing low interracial tensions between hydrocarbons and water.Journal of Colloid and Interface Science,1977,59(1):31-38.
[91]绳德强,杨普华,刘彦丽.偷聚合物相互作用与碱+聚合物/原油界面张力研究.油田化学,1993,10(1):46-50.
[92]康万利,吴文样,宋文玲等.石油羧酸盐及其复配体系/大庆原油间的界面张力.大庆石油学院学报,1995,19(1):123-127.
[93]黄宏度,吴一慧,吕军等.石油羧酸盐复配体系的协同效应.江汉石油学院学报,1994,16(2):64-67.
[94]张立德,牟季美著.纳米材料和那里结构[M].北京:科学出版社,2001.
[95]王芳辉,朱红,邹静.纳米材料在石油行业中应用[J].西安石油大学学报:自然科学版,2006,21(6):87-91.
[96]高芒来,王建设.分子沉寂膜驱油对油藏矿物润湿性的影响J].西安石油大学学报:自然科学版,2004,19(6):48-51.
[97]李文魁,刘长松,林平,等.纳米润滑材料的研究及其在石油管连接中的应用展望西安石油学院学报:自然科学版,2002,17(4):59-63.
[98]Patrick F,Valerie A,Jens R,et al.Nano-emulslon formation by emulsion phasse inversion[J].Colloids and surfaces A:Physicochemical and Engineering Aspects,2004,251(1-3):53-58.
[99]Paqui I,Jordi E,Tharward T,et al.Phase behavior and nano-emulsion formation by the phase invertion temperature method[J].Langmuir,2004,20(16):6594-6598.
[100]Morales D,Gutierrez J M,Solans Y C,et al.A study of the relation between bicontinuous microemulsions and oil|/water nano-emulsion formation[J].Langrnuir,2003,19(18):7196-7200.
[101]Tadros T,Izquierdo P,Esquena J,et al.Formation and stablility of nano-emulsions[J].Advances in Colloid and Interface Science,2004,108-109(5):303-318.
[102]Porras M,Solans C,Gonzalez C,et al.Studies of formation of W/O nano-emulsions[J].Colloids and surfaces A:Physicochemical and Engineering Aspects,2004,249(1-3):115-118.
[103]Forgiarini A,Esquena J,Gonzalez C,et al.Formation of nano-emulsions by low-energy emulsification methods at constant temperature[J].Langrnuir,2001,17(7):2076-2083.
[104]Lomber R F T,Martins C M,et al.Drill in fluids:Identifing invation mechanisms[J].Journal of petrolun Technology,2002,54(11):47-48.
[105]梁大川.硅酸盐砖井液稳定井壁机理分析[J].西南石油学院学报,1998,20(2):53-57.
[106]陆先亮,吕广忠,栾志安,等.纳米聚硅材料在低渗透油田中的应用[J].石油勘探与开发,2003,30(6):110-112.
[107]徐国财,张立德.纳米复合材料[M].北京:化学工业出版社.2002.
[108]Ma scia L,Tang T.Curing and morphology of epoxyresin-silia hybrids[J].Journal of Materials Chemistry,1998,8(11):2417-2441.
[109]John Mackenzie D,Chung Y J,Hu Y.Organically modified silicates by the Sol-Gel Method[J].Journal of non-Crystal.1992,147:271-278.
[110]Armes S P,Maeda S,Gill M.Inorganic/organic hybrid materials:conducting polymer-silica nanocomposite particles[J].Polym.Mater.Sci.Eng,1993,70:352-353.
[111]Chan K S,Shah D O.The molecular mechanism for achieving ultra low interfacial tension minimum in a petroleum sulfonate/oil/brine system.Journal of Dispersion Science and Technology,1980,1:55-57.
[112]袁红,杨承志.表面活性剂-碱-聚合物联合驱替与羧酸及其盐类表面活性剂在EOR中的应用.油田化学,1990,7(4):373-379.
[113]赵国玺,朱步瑶.表面活性剂作用原理.北京:中国轻工业出版社,2003.
[114]绳德强,杨普华,刘彦丽.偷聚合物相互作用与碱+聚合物/原油界面张力研究.油田化学,1993,10(1):46-50.
[115]张路,赵滩,罗澜等.碱/表面活性剂复合驱油体系与胜利孤东原油间协同效应的研究.油田化学,1998 15(1):348-353.
[116]Cash L,Cayias J L,Fournier G et al.The application of low interfacial tension scaling rules to binary hydrocarbon mixtures.Journal of Colloid and Interface Science,1977,59(1):39-44.
[117]徐桂英,竺和平,袁云龙等.石油磺酸盐/部分水解聚丙烯酞胺体系界面张力的研究.油田化学,1989,6(4):332-336.
[118]徐桂英,王富华,刘木辛等.PS,LS和煤油体系的界面张力.油田化学,1993}10(1):57-61.
[119]李千佐,林元,徐桂英等.天然混合羧酸(盐)复合驱油体系的研究.油田化学,199411(1):61-65.
[120]李干佐,林元,王秀文等。Tween80表面活性剂复合驱油体系研究.油田化学,1994,11(2):152-156.
[121]Baumgartner F N,Cranford N J.Sulfonate detergent blend.US Patent 2,712,530.July 5,1955.
[122]藤本武彦.新表面活性剂入门[M].北京:化学工业出版社,1989:354-356.
[123]Matthew J.Scott,Malcolm N.Jones.The biodegradation of surfactants in the environment[J].Biochimica et Biophysica Acta(BBA) - Biomembranes,2000,1508:235-251.
[124]罗明良,蒲春生,卢凤纪,等.利用植物油下脚料制备烷醇酰胺型驱油剂[J].石油学报(石油加工),2002,18(2):6-13.
[125]郭万奎,杨振宇,伍晓林,等.用于三次采油的新型弱碱表面活性剂[J].石油学报,2006,27(5):75-78.
[126]邢其毅,徐瑞秋,周政,裴伟伟.基础有机化学.北京,高等教育出版社,2004.69-70.
[127]程斌,张志军,梁成浩.驱油用石油磺酸盐的分析研究进展.化工技术与开发.2004,33(5):27-30.
[128]朱莉,王丽平,秦昉.红外光谱法测定石油磺酸盐含量.无锡轻工大学学报.1997,16(2):76-78.
[129]赵亮,曹绪龙,王红艳,刘霞.离子交换色谱测定原油中的单双石油磺酸盐.分析测试学报.2007,26(4):496-499.
[130]丛爱芬,钱玲,黄金龙.液相色谱法测定石油磺酸盐的组成.大庆石油与地质开发.1991,11(1):20-24.
[131]赵有刚,梁成浩,张志军.三次采油用抗盐性表面活性剂的制备及应用[J].化工技术与开发,2005,34(2):18-21.
[132]李伟,朱红.有机硅-无机硅纳米复合物的制备及结构表征[J].西安石油大学学报(自然科学版),2008,203(3):61-64.
[133]徐军,孙文起,李干佐,等.DSB显著提高羧酸盐驱油体系抗钙镁离子能力研究[J].高等 学校化学学报,2007,28(3):496-501.
[134]Robert M.Silverstein,Francis X.Webster,David J Kiemle.Pectrometric identification of organic compounds[M].7thEdition.U.S.A:John Wiley & Sons,Inc,2005:83-99.
[135]MATTHEW J.Scott,MALCOLM N.Jones.The biodegradation of surfactants in the environment[J].Biochimica et Biophysica Acta(BBA) - Biomembranes,2000,1508(1):235-251.
[136]李干佐,林元,王秀文等.Tween80表面活性剂复合驱油体系研究.油田化学,1994,11(2):152-156.
[137]Baumgartner F N,Cranford N J.Sulfonate detergent blend.US Patent 2,712,530.July 5,1955.
[138]Wade W H,Morgan J C,Jacobson J K et al.Low interfacial tensions involving mixtures of surfactants.Society of Petroleum Engineers Journal,1977,17(2):122-128.
[139]Doe P H,Wade W H,Schechter R S.Alkyl benzene sulfonates for producing low interfacial tensions between hydrocarbons and water.Journal of Colloid and Interface Science,1977,59(3):525-531.
[140]Doe P H,El-Emary M,Wade W H et al.Surfactants for producing low interfacial tensions Ⅰ:Linear alkyl benzene sulfonates.Journal of the American Oil Chemists' Society,1977,54(12):570-577.
[141]Doe P H,El-Emary M,Wade W H et al.Surfactants for producing low interfacial tensions Ⅱ:Linear alkylbenzenesulfonates with additional alkyl substituents.Journal of the American Oil Chemists' Society,1978,55(5):505-512.
[142]Doe P H,EI-Emary M,Wade W H et al.Surfactants for producing low interfacial tensions Ⅲ:Di and Tri n-alkylbenzenesulfonates.Journal of the American Oil Chemists' Society,1978,55(5):S 13-520.
[143]Wade W H,Morgan J C,Schechter R S et al.Interfacial tensions and phase behavior of surfactant systems.Society of Petroleum Engineers Journal,1978,18(4):242-252.
[2]赵国玺,朱埗瑶.表面活性剂作用原理.北京:中国轻工业出版社,2003年,1-5.
[3]孙岩,殷福珊,宋湛谦,王墨林.新表面活性剂.北京:化学工业出版社,2003年,2-3.
[4]梁文杰.石油化学.山东东营:石油大学出版社,1995年.
[5]王子军,石油沥青质的化学和物理Ⅱ-沥青质的化学组成和结构,石油沥青,1996,10(1):26-36.
[6]王子军,石油沥青质的化学和物理Ⅳ-石油沥青质溶液的胶体化学,石油沥青,1996,10(3):36-49.
[7]杨小莉,陆婉珍.有关原油乳状液稳定性的研究,油田化学,I998,15(2):87-96
[8]樊西惊.石油胶态分散体的稳定性,油田化学,1999,16<1):72-76.
[9]Peramanu S,Clarke P F,Pmden B B.Flow loop apparatus to study the effect of solvent,temperature and additives on asphaltene preciptation,J of Petroleum Science and Engineering,1999,23:133-143.
[10]李干佐,翟利民.三次采油.科学,2000 52(1):10-12.
[11]牟建海,李干佐.三次采油技术的发展现状及展望.化工科技市场,2000,23(7):17-20.
[12]Enrique Carrero,Nestor V.Queipo,Salvador Pintos,Luis E.Zerpa.Global sensitivity analysis of Alkali-Surfactant-Polymer enhanced oil recovery processes.Journal of Petroleum Science and Engineering,58(2007):30-42.
[13]Da-Kuang Han,Cheng-Zhi Yang,Zheng-Qing Zhang.Recent development of enhanced oil recovery in China.Journal of Petroleum Science and Engineering 22.1999:181-188
[14]Zheng-Bo Yue,Han-Qing Yu,Zhen-Hu Hu.Surfactant-enhanced anaerobic acidogenesis of Canna indica L.by rumen cultures.Bioresource Technology 99(2008):3418-3423
[15]DeGroot M.Flooding process for recovering oil from subterranean oil bearing strata.US Patentl,823,439.Sept.15,1931.
[16]DeGroot M,Monson L T.Flooding process for recovering fixed oil from subterranean oil bearingstrata.US Patent 1,823,440.Sept.15,1931.
[17]Blair C M,Groves W,Lehmann S.Process for increasing productivity of subterranean oil-bearing stratr.US Patent 2,356,205.Aug.22,1944.
[18]Holbrook O C.Surfactant-water secondary recovery process.US Patent 3,006,411.Oct.31,1961.
[19]Holm L W,Bernard G Q Secondary recovery water-flood process.US Patent 3,082,822.Mar.26 1963.
[20]Csaszar A K.Solvent-waterflood oil recovery process.US Patent 3,163,214.Dec.29,1964.
[21]Gogarty W B,Olson R W.Use of microemulsions in miscible-type oil recovery produce.US Patent 3,254,714.June 7,1966.
[22]Jones S C.High water content oil-external micellar dispersions.US Patent 3,497,006.Feb.24,1970.
[23]Gale W W,Puerto M C,Ashcraft T Let al.Propoxylated ethoxylated surfactants and method of recovering oil therewith.US Patent 4,293,428.Oct.6,1981.
[24]韩东,沈平平 表面活性剂驱油原理及应用。北京,石油工业出版社,2001年,94
[25]Shubiao Zhang,Yingmei Xu,Weihong Qiao.Interfacial tensions upon the addition of alcohols to phenylalkane sulfonate monoisomer systems.Fuel 83(2004):2059-2063
[26]Mingyuan Li,Meiqin Lin,Zhaoliang Wu.The influence of NaOH on the stability of paraffinic crude oil emulsion.Fuel 84(2004):183-187
[27]孙新春,向湘兴.环烷酸盐作为ASP驱油体系中表面活性剂的研究.新疆石油科技,19977(2):54-59.
[28]李干佐,沈强,郑立强.新型驱油用表面活性剂天然混合羧酸盐.油田化学,1999 19(1):57.
[29]黄宏度.从烷烃汽相氧化产物直接制备(不磺化)驱油用活性剂.油田化学,1987,4(3):191
[30]丁颖,袁英同,吕少军.表面活性剂在三次采油中的应用及进展。内蒙古石油化工,2004,30(2):121-123.
[31]S.Ma,M.Dong,Z.Li,E.Shirif.Evaluation of the effectiveness of chemical flooding using heterogeneous sandpack flood test.Journal of Petroleum Science and Engineering 55(2007):294-300.
[32]赵有刚,梁成浩,张志军 三才采油用便面活性剂的制备及应用,化工技术与开发,2005,34(2):18-21
[33]韩东,沈平平.表面活性剂驱油原理及应用。北京,石油工业出版社,2001年,24-29.
[34]Tayfun Babadagli.Evaluation of EOR methods for heavy-oil recovery in naturally fractured reservoirs.Journal of Petroleum Science and Engineering 37(2003):25-37.
[35]朱友益,沈平平,曲景奎 三次采油用烷基本磺酸盐结构与性能的关系研究 石油勘探与开发。2004,31(增刊),9-12.
[36]将蒿,张淑芬,杨锦宗 磺化反应新进展 精细与专用化学品,2003,11:16-19.
[37]郑延成,韩东,杨普华。磺酸盐表面活性剂研究进展。精细化工,2005,22(8):578-582.
[38]崔正刚,张天林,邹文华等.重烷基苯磺酸盐的合成及其在提高石油采收率中的应用研究.表面活性剂/洗涤剂技术与经济进展(第五届国际表面活性剂耽涤剂研讨会论文集),1998:95-102.
[39]赵宇,董雅红,毕彩丰。系列烷基苯磺酸盐对烷烃的动态张力界面张力研究。化学学报,2008,66(7):799-802.
[40]Beger P D,Berger C H,Hsu I K.Anionic surfactants based on alkene sulfonic acid.US patent6,043,391.Mar.28,2000.
[41]Berger P D,Lee C H.New anionic alkylaryl surfactants basing on olefin sulfonic acids.Journal of Surfactants and Detergent,2002,5(1):39-43.
[42]黄宏度,驱油用石油羧酸盐的研制,油田化学,1991,8(3):235-239.
[43]黄宏度,赵林,石油羧酸盐复合体系中各组分的影响,江汉石油学院学报,1992,14(13):53-56.
[44]黄宏度,姬中复,吴一慧等,石油狡酸盐和大庆原油间的界面张力,江汉石油学院学报,1992 14(4):53-57.
[45]刘德新,黄宏度,岳湘安.石油氧化皂界面活性研究.石油与天然气化工,2005,34(1):56-58.
[46]李干佐,林元,徐桂英等,天然混合羧酸(盐)复合驱油体系的研究,日用化学工业,1994,11(1):61-65
[47]李干佐,徐桂英,毛宏志等,开发天然羧酸盐在油田中的应用,日用化学工业,1998(5):26-30
[48]李干佐,沈强,郑立强,新型驱油用表面活性剂天然羧酸盐,油田化学,1999} 16(1):57-59.
[49]王业飞,李继勇,赵福麟,高矿化度条件下应用的表面活性剂驱油体系,油气地质与采收率,2001,8(1):67-69.
[50]王磊,谢益民.木质素及及衍生物在三次采油中的应用进展.上海造纸,2008,39(3):63-69.
[51]王晓红,郝臣,木质素磺酸盐与丙稀酸接枝改性.江苏大学学报(自然科学版),2007,28(6):528-531.
[52]Kalfoglou Q.Lignosulfonates as sacrificial agents in oil recovery processes.US Patent,4d006,779.Feb.8,1977.
[53]Kalfoglou G..Oxidized lignosulfonates as additives in oil recovery processes involving chemical recovery agents.US Patent 4,133,385.Jan.9,1979.
[54]Kalfoglou G..Oxidized lignosulfonates as additives in oil recovery processes involving chemical recovery agents.US Patent 4,196,777.April 8,1980.
[55]Kalfoglou G..Sulfomethylated lignosulfonates as additives in oil recovery processes involving chemical recovery agents.US Patent 4,269,270.May 26,1981。
[56]Neale Q,Hornof V.,Chiwetelu C.,Canadian Journal of Chemistry,1981,59(13):1938-1943
[57]Chiwetelu C.,Neale Q,Hornof V,The Journal of Canadian Petroleum Technology,1980,19(3):91-99
[58]Hornof V,Neale G.,Bourgeois P.,The Canadian Journal Chemical Engineering,1981,59(4):554-556
[59]Hornof V,Neale G.,Jacovella F.,The Canadian Journal Chemical Engineering 1982,60(2):331-332
[60]Chiweteiu C.,Hornof V,Neale G.,Transactions of Institution Chemical Engineers 1982,60(3):177-182
[61]DeBons F E,Whittington L E,Pedersen L D.Method of enhanced oil recovery and compositions useful therein.US Patent 4,548,721.Oct.22,1985.
[62]Naae D G.,DeBons F E.Recovering hydrocarbons with water soluble alkylphenol lignin surfactants.US Patent 4,781,251.Nov.1,1988.
[63]DeBons F E,Pedersen L D,Whittington L E.Use of lignin/amine/surfactant blends in enhanced oilrecovery.US Patent 4,822,501.April 18,1989.
[64]Naae D G,Davis C A.Enhanced oil recovery using oil soluble sulfonates from lignin and benzyl alcohol.US Patent 5,095,986.March 17,1992.
[65]陈文求,孙争光.生物表面活性剂的生产与应用.胶体与聚合物,2007,25(3):45-46.
[66]张良晓,杨祥,陈艳玲.生物油表面活性剂在采油工程中的研究及应用.四川化工,2005,8(4):13-15
[67]伍小林,陈坚.生物油表面活性剂在提高原油采收率方面的应用.生物学杂志,2000,17(6):25-28.
[68]童正新,王芳,吴庆红.鼠李糖脂发酵液与OP类非离子表面活性剂复配驱油体系的研究.油气采收率技术,1998,5(2):6-20.
[69]杨金华,曹亚,李惠林.高分子表面活性剂与原油形成超低界面张力的研究,精细化工,1999(2):3.
[70]田志著,邓启刚,孙宏.双子表面活性剂的性能、合成及应用.化工时刊,2008,1:61-63.
[71]冯玉军,孙玉海,陈志.双子表面活性剂结构对性能的影响.日用化学工业,2007,37(2):107-111.
[72]李小丽.双子表面活性剂的研究概况.河北化工,2007,30(6):29-30.
[73]胡延峰,郭详峰,贾丽华.阳离子双子表面活性剂的应用研究进展.精细与专用化学品.2006,14(11):1-4.
[74]刘琪,孙雷,刘登峰.凝析尤其体系相态特征研究现状.砖采工艺,2008,3(1):112-113.
[75]Rudin J,Wasan D T.Mechanisms for lowering of interfacial tension in alkali/acidic oil systems:Effect of added surfactant.Industrial and Engineering Chemistry Research,1992,31(8):1899-1906_
[76]刘小辛,徐桂英,李干佐等.油酸一油酸钠水溶油原油间的瞬时界面张力.物理化学学报,1995,11(11):1040-1043.
[77]徐桂英,刘小辛,李干佐等.影响羧酸盐驱油体系界面张力因素的研究.山东大学学报(自然科学版),1996,31(1):71-75.
[78]Bansal V K,Chan K S,McCallough R et al.The effect of caustic concentration on interface charge,interfacial tension and droplet size:a sump test for optimum caustic concentration for crude oils.The Journal of Canadian Petroleum Technology,1978,17(1):69-72.
[79]Krumrine P H,Falcone J S,Campbell T C.Surfactant flooding 1:The effect of alkaline additives on IFT,surfactant adsorption,and recovery efficiency.Society of Petroleum Engineers Journal,1982,22(4):503-513.
[80]Krumrine P H,Falcone J S,Campbell T C.Surfactant flooding 2:The effect of alkaline additives on permeability and sweep efficiency.Society of Petroleum Engineers Journal,1982,22(6):983-992.
[81]Mahammad A K,Mahammad A s,Role of asphaltene and resin in oil field emulsions,J of Petroleum Sciences and Engineering,1999,23:213-221.
[82]Taylor K C,Hawkins B F,Islam M R.Dynamic interfacial tension in surfactant enhanced alkaline flooding.The Journal of Canadian Petroleum Technology,1990,29(1):50-55.
[83]Chiwetelu C I,Hornof V,Neale G H.A dynamic model for the interaction of caustic reagents with acidic oils.AIChE Journal,1990,36(2):233-241.
[84]Borwankar R P,Wasan D T.Dynamic interfacial tensions in acidic crude oil/caustic systems Part Ⅰ:A chemical diffusion-kinetic model.AIChE Journal,1986,32(3):455-466.
[85]Borwankar R P,Wasan D T.Dynamic interfacial tensions in acidic crude oil/caustic systems Part Ⅱ:Role of dynamic effects in alkaline flooding for enhanced oil recovery.AIChE Journal,1986,32(3):467-476.
[86]JNeale G H,Khulbe K C,Hornof V Effects of oil phase viscosity on interracial tension behaviour of oil/alkaline systems as measured by the spinning drop tensiometer.The Canadian Journal of Chemical Engineering,1987,65(4):700-703.
[87]Chiwetelu C I,Neale G H,Hornof V Dynamic tensions in finite oil droplets.Chemical Engineering Communications,1989,84:13-20.
[88]Chiwetelu C I,Hornof V,Neale G H.Use of mixed surfactants to improve the transient interfacial tension behaviour of heavy oil/alkaline systems.The Canadian Journal of Chemical Engineering,1994,72(3):534-540.,
[89]Wilson P M D,Brandner C F.Aqueous surfactant solutions which exhibit ultra-low tensions at the oil- water interface.Journal of Colloid and Interface Science,1977,60(3):473-479.
[90]Cayias J L,Schechter R S,Wade W H.The utilization of petroleum sulfonates for producing low interracial tensions between hydrocarbons and water.Journal of Colloid and Interface Science,1977,59(1):31-38.
[91]绳德强,杨普华,刘彦丽.偷聚合物相互作用与碱+聚合物/原油界面张力研究.油田化学,1993,10(1):46-50.
[92]康万利,吴文样,宋文玲等.石油羧酸盐及其复配体系/大庆原油间的界面张力.大庆石油学院学报,1995,19(1):123-127.
[93]黄宏度,吴一慧,吕军等.石油羧酸盐复配体系的协同效应.江汉石油学院学报,1994,16(2):64-67.
[94]张立德,牟季美著.纳米材料和那里结构[M].北京:科学出版社,2001.
[95]王芳辉,朱红,邹静.纳米材料在石油行业中应用[J].西安石油大学学报:自然科学版,2006,21(6):87-91.
[96]高芒来,王建设.分子沉寂膜驱油对油藏矿物润湿性的影响J].西安石油大学学报:自然科学版,2004,19(6):48-51.
[97]李文魁,刘长松,林平,等.纳米润滑材料的研究及其在石油管连接中的应用展望西安石油学院学报:自然科学版,2002,17(4):59-63.
[98]Patrick F,Valerie A,Jens R,et al.Nano-emulslon formation by emulsion phasse inversion[J].Colloids and surfaces A:Physicochemical and Engineering Aspects,2004,251(1-3):53-58.
[99]Paqui I,Jordi E,Tharward T,et al.Phase behavior and nano-emulsion formation by the phase invertion temperature method[J].Langmuir,2004,20(16):6594-6598.
[100]Morales D,Gutierrez J M,Solans Y C,et al.A study of the relation between bicontinuous microemulsions and oil|/water nano-emulsion formation[J].Langrnuir,2003,19(18):7196-7200.
[101]Tadros T,Izquierdo P,Esquena J,et al.Formation and stablility of nano-emulsions[J].Advances in Colloid and Interface Science,2004,108-109(5):303-318.
[102]Porras M,Solans C,Gonzalez C,et al.Studies of formation of W/O nano-emulsions[J].Colloids and surfaces A:Physicochemical and Engineering Aspects,2004,249(1-3):115-118.
[103]Forgiarini A,Esquena J,Gonzalez C,et al.Formation of nano-emulsions by low-energy emulsification methods at constant temperature[J].Langrnuir,2001,17(7):2076-2083.
[104]Lomber R F T,Martins C M,et al.Drill in fluids:Identifing invation mechanisms[J].Journal of petrolun Technology,2002,54(11):47-48.
[105]梁大川.硅酸盐砖井液稳定井壁机理分析[J].西南石油学院学报,1998,20(2):53-57.
[106]陆先亮,吕广忠,栾志安,等.纳米聚硅材料在低渗透油田中的应用[J].石油勘探与开发,2003,30(6):110-112.
[107]徐国财,张立德.纳米复合材料[M].北京:化学工业出版社.2002.
[108]Ma scia L,Tang T.Curing and morphology of epoxyresin-silia hybrids[J].Journal of Materials Chemistry,1998,8(11):2417-2441.
[109]John Mackenzie D,Chung Y J,Hu Y.Organically modified silicates by the Sol-Gel Method[J].Journal of non-Crystal.1992,147:271-278.
[110]Armes S P,Maeda S,Gill M.Inorganic/organic hybrid materials:conducting polymer-silica nanocomposite particles[J].Polym.Mater.Sci.Eng,1993,70:352-353.
[111]Chan K S,Shah D O.The molecular mechanism for achieving ultra low interfacial tension minimum in a petroleum sulfonate/oil/brine system.Journal of Dispersion Science and Technology,1980,1:55-57.
[112]袁红,杨承志.表面活性剂-碱-聚合物联合驱替与羧酸及其盐类表面活性剂在EOR中的应用.油田化学,1990,7(4):373-379.
[113]赵国玺,朱步瑶.表面活性剂作用原理.北京:中国轻工业出版社,2003.
[114]绳德强,杨普华,刘彦丽.偷聚合物相互作用与碱+聚合物/原油界面张力研究.油田化学,1993,10(1):46-50.
[115]张路,赵滩,罗澜等.碱/表面活性剂复合驱油体系与胜利孤东原油间协同效应的研究.油田化学,1998 15(1):348-353.
[116]Cash L,Cayias J L,Fournier G et al.The application of low interfacial tension scaling rules to binary hydrocarbon mixtures.Journal of Colloid and Interface Science,1977,59(1):39-44.
[117]徐桂英,竺和平,袁云龙等.石油磺酸盐/部分水解聚丙烯酞胺体系界面张力的研究.油田化学,1989,6(4):332-336.
[118]徐桂英,王富华,刘木辛等.PS,LS和煤油体系的界面张力.油田化学,1993}10(1):57-61.
[119]李千佐,林元,徐桂英等.天然混合羧酸(盐)复合驱油体系的研究.油田化学,199411(1):61-65.
[120]李干佐,林元,王秀文等。Tween80表面活性剂复合驱油体系研究.油田化学,1994,11(2):152-156.
[121]Baumgartner F N,Cranford N J.Sulfonate detergent blend.US Patent 2,712,530.July 5,1955.
[122]藤本武彦.新表面活性剂入门[M].北京:化学工业出版社,1989:354-356.
[123]Matthew J.Scott,Malcolm N.Jones.The biodegradation of surfactants in the environment[J].Biochimica et Biophysica Acta(BBA) - Biomembranes,2000,1508:235-251.
[124]罗明良,蒲春生,卢凤纪,等.利用植物油下脚料制备烷醇酰胺型驱油剂[J].石油学报(石油加工),2002,18(2):6-13.
[125]郭万奎,杨振宇,伍晓林,等.用于三次采油的新型弱碱表面活性剂[J].石油学报,2006,27(5):75-78.
[126]邢其毅,徐瑞秋,周政,裴伟伟.基础有机化学.北京,高等教育出版社,2004.69-70.
[127]程斌,张志军,梁成浩.驱油用石油磺酸盐的分析研究进展.化工技术与开发.2004,33(5):27-30.
[128]朱莉,王丽平,秦昉.红外光谱法测定石油磺酸盐含量.无锡轻工大学学报.1997,16(2):76-78.
[129]赵亮,曹绪龙,王红艳,刘霞.离子交换色谱测定原油中的单双石油磺酸盐.分析测试学报.2007,26(4):496-499.
[130]丛爱芬,钱玲,黄金龙.液相色谱法测定石油磺酸盐的组成.大庆石油与地质开发.1991,11(1):20-24.
[131]赵有刚,梁成浩,张志军.三次采油用抗盐性表面活性剂的制备及应用[J].化工技术与开发,2005,34(2):18-21.
[132]李伟,朱红.有机硅-无机硅纳米复合物的制备及结构表征[J].西安石油大学学报(自然科学版),2008,203(3):61-64.
[133]徐军,孙文起,李干佐,等.DSB显著提高羧酸盐驱油体系抗钙镁离子能力研究[J].高等 学校化学学报,2007,28(3):496-501.
[134]Robert M.Silverstein,Francis X.Webster,David J Kiemle.Pectrometric identification of organic compounds[M].7thEdition.U.S.A:John Wiley & Sons,Inc,2005:83-99.
[135]MATTHEW J.Scott,MALCOLM N.Jones.The biodegradation of surfactants in the environment[J].Biochimica et Biophysica Acta(BBA) - Biomembranes,2000,1508(1):235-251.
[136]李干佐,林元,王秀文等.Tween80表面活性剂复合驱油体系研究.油田化学,1994,11(2):152-156.
[137]Baumgartner F N,Cranford N J.Sulfonate detergent blend.US Patent 2,712,530.July 5,1955.
[138]Wade W H,Morgan J C,Jacobson J K et al.Low interfacial tensions involving mixtures of surfactants.Society of Petroleum Engineers Journal,1977,17(2):122-128.
[139]Doe P H,Wade W H,Schechter R S.Alkyl benzene sulfonates for producing low interfacial tensions between hydrocarbons and water.Journal of Colloid and Interface Science,1977,59(3):525-531.
[140]Doe P H,El-Emary M,Wade W H et al.Surfactants for producing low interfacial tensions Ⅰ:Linear alkyl benzene sulfonates.Journal of the American Oil Chemists' Society,1977,54(12):570-577.
[141]Doe P H,El-Emary M,Wade W H et al.Surfactants for producing low interfacial tensions Ⅱ:Linear alkylbenzenesulfonates with additional alkyl substituents.Journal of the American Oil Chemists' Society,1978,55(5):505-512.
[142]Doe P H,EI-Emary M,Wade W H et al.Surfactants for producing low interfacial tensions Ⅲ:Di and Tri n-alkylbenzenesulfonates.Journal of the American Oil Chemists' Society,1978,55(5):S 13-520.
[143]Wade W H,Morgan J C,Schechter R S et al.Interfacial tensions and phase behavior of surfactant systems.Society of Petroleum Engineers Journal,1978,18(4):242-252.
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