阳离子碳氟表面活性剂DEFUMACl及其混合体系聚集特性的NMR研究
|
摘要
碳氟表面活性剂由于高电负性、大体积的氟原子的引入而具有较其相应碳氢表面活性剂独特的疏水、疏油性,表现出强的热稳定性、化学、生物稳定性、超高的气体解能力、高的表面活性、优异的铺展性以及好的流动性等,使其在工业生产、日常生活、医药等诸多领域具有不可替代的应用。然而,由于碳氟表面活性剂特殊的疏油性、合成困难和价格昂贵等缺点,单一的碳氟表面活性剂体系往往无法满足实际应用的需要。因此,在实际应用中,碳氟表面活性剂常与水溶性高分子、碳氢表面活性剂一起复配使用。通过复配,可以有效地减少碳氟表面活性剂的用量而保持其表面活性,显著提高体系的功能。
蛋白质和表面活性剂相互作用的研究多年来一直是人们十分感兴趣的课题。碳氟表面活性剂的独特特性使其与蛋白质复配体系不仅在生物工程、化学和药物等领域具有广泛的应用,而且有利于加快生物技术向化工、医药等传统领域的渗透和应用。
有关碳氟表面活性剂的聚集行为和物理化学性质的文献报道,研究体系主要集中在阴离子全氟羧酸类,阳离子碳氟表面活性剂的研究报道较少。其主要原因在于阳离子碳氟表面活性剂的合成和纯化困难。
论文利用~1H和~(19)F NMR波谱技术,结合表面张力测定、动态激光光散射和圆二色光谱测定研究了结构新颖的、部分氟代的阳离子碳氟表面活性剂,十七氟代-2-羟基十一烷基二乙羟基甲基氯化(DEFUMACl)水溶液的特性。对DEFUMACl与不同链长的阳离子碳氢表面活性剂十二烷基(DTACl)、十四烷基(TTACl)、十六烷基(CTACl)和十八烷基(OTACl)三甲基氯化铵、阳离子碳氢Gemini EO-PO-EO三嵌段共聚物以及牛血清蛋白质BSA之间的相互作用进行了较为系统深入的研究。并与传统的非离子EO-PO-EO嵌段共聚物F127(PEO_(99)-PPO_(67)-PEO_(99))、17R4(PO_(14)EO_(24)PO_(14))的作用进行了比较,获得了一些重要的结果。这些研究结果不论是在胶体化学的基础理论方面,还是在实际应用方面都具有指导作用。论文内容共分五部分:
第一部分概述了研究碳氟表面活性剂及其与碳氢表面活性剂、聚合物、蛋白质复配体系相互作用的重要意义,并综述了碳氟表面活性剂及其相关复配体系的研究进展和研究方法等。
第二部分利用表面张力测定、~(19)F NMR波谱技术研究了DEFUMACl水溶液的聚集特性,考察了温度、NaCl浓度对其临界胶束浓度的影响,获得了DEFUMACl的临界胶束浓度(cmc)、反离子结合常数等重要的物化参数。实验结果表明:阳离子碳氟表面活性剂具有较高的表面活性,室温下~(19)F NMR确定的cmc为3.40mmol·L~(-1),与表面张力法测定的值完全吻合;随着温度的升高,DEFUMACl的cmc呈现先降低后增加的变化趋势,且具有特殊的最低点现象;盐的加入显著影响DEFUMACl的表面活性。很少量NaCl的加入即可以诱导DEFUMACl发生自聚集,且随着盐浓度的增加,DEFUMACl的cmc显著降低。
第三部分利用~1H和~(19)F NMR波谱法研究了DEFUMACl与不同链长阳离子碳氢表面活性剂C_nTACl(n=12,DTACl;n=14,TTACl;n=16,CTAC及n=18,OTACl)的相互作用,考察了阳离子碳氢链长对形成碳氟-碳氢表面活性剂复合物聚集体的影响。~(19)F NMR结果表明:在DEFUMACl/DTACl、TTACl和CTACl三种混合体系中,不同摩尔分数α_F时,随着体系总浓度(c_T=c_F+c_H)的增加,~(19)F化学位移与浓度的关系曲线上呈现两个折点,即有两个cmc:在第一个折点,形成碳氢-碳氟表面活性剂的混合胶束;在第二个折点,则形成了单独的DEFUMACl胶束。而DEFUMACl/OTACl混合体系中,观察到了三个折点:分别形成了富-氢型混合胶束(OTACl-rich mixed micelles)、富-氟型混合胶束(DEFUMACl-richones)及单独的DEFUMACl胶束。~1H NMR测定结果表明:混合体系中,碳氢表面活性剂的-CH_3基团的质子化学位移△δ(~1H)与浓度的关系曲线呈现与~(19)F化学位移完全不同的变化趋势。对于DEFUACl/DTACl和DEFUMACl/TTACl混合体系,在第一个拐点首先形成了DEFUMACl/DTACl和DEFUMACl/TTACl混合胶束;于第二个拐点,当α_F较低时,形成富-氢型(DTACl-rich和TTACl-rich)混合胶束,并伴随着强烈的低场化学位移;然而,当α_F较高时,则形成富-氟型(DEFUMACl-rich)混合胶束,伴随着强的高场位移。对于DEFUMACl/CTACl和DEFUMAC/OTACl混合体系,只形成一种CH/CF混合胶束,且-CH_3的质子化学位移△δ(~1H)随体系总浓度的增加而增加。当总浓度较高时,DEFUMACl碳氟链对混合体系中碳氢链的影响较大,导致强的高场化学位移。结合混合体系的两种理论模型,研究发现:对于不同碳链长度的碳氢表面活性剂,在一定浓度范围内,混合体系内两组分能够发生相互作用,依据各组分的性质及cmc值的不同而以两种模式形成混合胶团:一种是形成互溶的混合胶束,如DEFUMACl/DTACl、TTACl体系;另一类则形成两种不同类型的富-氟型和富-氢型混合胶束,如DEFUMACl/CTACl及OTACl体系。但是,当体系浓度很高时,体系内两组分由于“互疏作用”和静电斥力等不利因素而倾向于各自形成胶束,即在高浓度时,四种混合体系均形成了单独的DEFUMACl胶束。这些实验结果为进一步了解水溶液中碳氢-碳氟表面活性剂的复配机理提供了有用的实验数据,为更好地理解非理想混合模型提供了较为详尽的信息。
第四部分采用~1H、~(19)F NMR波谱、表面张力测定和动态光散射技术研究了DEFUMACl与阳离子碳氢Gemini三嵌段共聚物(Cat-Gemini copolymer)的相互作用。测定结果表明:同SDS相似,DEFUMACl与Cat-Gemini copolymer之间发生了强烈的相互作用;在给定的阳离子Gemin共聚物浓度下,得到三个特征浓度,相应为:临界聚集浓度,P_1(critical association concentration);DEFUMACl与聚合物结合达到饱和的浓度,P~*;以及形成单独的DEFUMACl胶束的浓度,P_2。但是,SDS与阳离子Gemin共聚物的作用相对较弱。论文对比研究了DEFUMACl与直链型非离子EO-PO-EO型嵌段共聚物F127以及PO-EO-PO型17R4的相互作用。在F127、17R4与DEFUMACl的混合体系中,同样观测到相似的三个拐点。但是,Gemini型共聚物在与DEFUMACl的作用上同直链型共聚物F127、17R4存在着明显的区别。三个混合体系的P_1值依照Cat-Gemini polymer、F127和17R4的顺序依次增大,表明Cat-Gemini Copolymer与阳离子碳氟表面活性剂间具有最强烈的相互作用,而17R4与DEFUMACl的作用最弱。~(19)F图谱也较好地显示了碳氟表面活性剂与不同的共聚物的作用位置。动态光散射结果清楚表明:在有或没有DEFUMACl存在时,1.0 wt%Cat-Gemini copolymer水溶液均显示两种大小颗粒分布模式。当加入很少量的DEFUMACl后,表面活性剂与Gemini共聚物胶束相互作用,表面活性剂“吸附”在Gemini共聚物胶束上,形成了动力学半径较大的Cat-Gemini copolymer胶束/DEFUMACl复合物;随着DEFUMACl浓度的增加,表面活性剂分子、共聚物胶束及共聚物单分子间的静电排斥作用不断增强,阻止了DEFUMACl分子与共聚物胶束间的进一步作用,DEFUMACl分子倾向于形成单独的DEFUMACl胶束。本部分尝试性地探讨了DEFDUMACl与三种共聚物的作用机理,为深入理解表面活性剂与聚合物的作用机理提供了有效的实验数据。
第五部分采用NMR波谱和圆二色光谱技术(CD)研究了DEFUMACl与牛血清蛋白BSA的相互作用,考察了DEFUMACl对BSA分子结构的影响。结果证明:同传统的阳离子CH表面活性剂DTACl相比,很少量的DEFUMACl的加入即可诱导BSA柔性链舒展,使α-螺旋含量迅速降低,而β-折叠含量显著增加;破坏了蛋白质的二级结构,而导致蛋白质变性。同时,BSA的三级结构处于较为疏松的状态。在DEFUMACl/BSA体系中,没有观察到文献报道过的阴离子CH表面活性剂,如SDS、AOT和阳离子Gemini型CH表面活性剂对蛋白质的保护作用。相对于DEFUMACl而言,DTACl对BSA的变性作用较弱。~(19)F NMR研究结果从另一个侧面证实了DEFUMACl与BSA之间的强烈作用,并得到了三个临界浓度,P_1、P~*和P_2,相应于DEFUMACl与BSA开始作用的浓度、DEFUMACl分子在BSA分子上结合达到饱和的浓度以及形成单独的DEFUMACl胶束的浓度。DEFUMACl浓度较稀时,DEFUMACl与BSA间的作用力主要是静电力;当DEFUMACl的浓度达到P~*时,碳氟链间的疏水作用占据主导地位,DEFUMACl与BSA分子形成珠串式复合物;进而,随着DEFUMACl浓度的增加,混合体系中表面活性剂分子以单体,表面活性剂/蛋白质复合物以及表面活性剂胶束几种形态共存。NMR方法确定的P~*值与CD研究中使BSA分子链舒展完全,二级结构含量保持不变所对应的DEFUMACl浓度基本吻合。
Fluorinated surfactants,with partially or per-fluorinated tails,differ from hydrogenated surfactants in several respects.Because of the larger volume and higher electro-negativity of fluorine than hydrogen,the introduction of fluorine atoms instead of hydrogen results in the specific properties of fluorocarbon surfactants:exceptional activity,thermal and biological inertness,high gas-dissolving capacity,low surface tension,excellent spreading characteristics,and high fluidity.These properties have triggered wide applications of fluorocarbon surfactants in our daily life, pharmaceuticals,and various industrial fields.
Despite the wide technical interest of fluorocarbon surfactants due to their potential usefulness,with the large hydrophobicity and strong surface activity,the applications of pure fluorocarbon surfactants are quiet limited for the reason that a per-fluorinated surfactant uasually has not all the required properties for a given application,mainly because of its oleophobic properties.Hence,in practical applications,fluorocarbon surfactants are very often used in mixed systems with hydrocarbon surfactants and polymers to obtain some desired performance and unique features by playing with the surfactant ratio.
The interaction between protein and surfactant has triggered extensive interest for many years.The exceptional chemical and biological inertia and hydrophobic and oleophobic character of fluorocarbon surfactant influence the interaction with protein, hence the mixtures are not only of particular importance in numerous biotechnological applications,in pharmaceutics and chemistry etc.,but also important in simulating biological systems,which expedites the penetration of biological technology into chemical industry and medicine field.
The present knowledge of the aggregation behavior and physical chemistry in general of fluorinated surfactants reported was mainly about the per-fluorocarbon oxylates.Nonionic fluorocarbon surfaetants were dealt with in a serie of papers by Ravey.Very little has been published about cationic fluorocarbon surfactants.One reason is the difficulties in synthesis and purity.Cationic surfactants are scarce. Recently,with the rapid developments in synthetic technology and measurement methods,an increasing interest is directed towards the cationic fluorocarbon surfactants and their mixtures.The focus of this thesis has been on the properties of DEFUMACl,a novel-structured,partially fluorinated,cationic surfactant, diethanolheptadecafluoro-2-undecanolmethyl-ammonium chloride aqueous solutions; the interaction with conventional cationic hydrocarbon surfactants,C_nTACl(n=12, DTACl;n=14,TTACl;n=16,CTACl,and n=18,OTACl),as well as the interaction with water-soluble cationic Gemini EO-PO-EO triblocked copolymer and BSA by the combination of advanced techniques:~1H and ~(19)F NMR,DLS,CD and surface tension. For comparison,parallel measurements have also been made on the interaction between DEFUMACl and nonionic EO-PO-EO blocked Pluorinic copolymer,F127 (PEO_(99)-PPO_(67)-PEO_(99))and Pluorinic-R 17R4(PPO_(14)-PEO_(24)-PPO_(14)).Some important evidence for such complexation is obtained.These studies are of significance in making a good physical picture of the interaction between macromolecules and fluorocarbon surfactant.The present dissertation includes five sections.
In the first section,the importance of study on fluorocarbon surfactants and their mixtures with hydrocarbon surfactants,copolymers and proteins,and the study progress on fluorocarbon surfactants and its mixtures are summarized,including methods employed in such studies.
In the second section,the self-aggregation properties of DEFUMACl aqueous solutions are studied by surface tension and ~(19)F NMR spectroscopy measurements. The effects of temperature and NaCl on the aggregation behavior of DEFUMACl are also investigated,obtaining such important physicochemical parameters,as cmc values at different temperature and counter-ionic binding degree(β)of DEFUMACl. The results show that cationic surfactant DEFUMACl has higher surface activity,with the cmc of DEFUMACl by ~(19)F NMR is 3.40 mmol·L~(-1),which is completely consistent with that obtained by surface tension method.With the increase of temperature,the cmc value decreases slightly at first and then increases slowly at higher temperature, and the cmc values of DEMUAC1 have a minimum value at T=～308 K.The addition of NaC1 in surfactant aqueous solution strongly decreases the cmc values of DEFUMACl systems,and the more the sum of NaCl is,the lower the cmc value of DEFUMACl salt solution.
In the third section,the aggregation behavior and the interaction of four mixed systems for DEFUMACl mixing with cationic hydrocarbon surfactants, alkyltrimethylammonium chloride,C_nTAC1(n=12,14,16,and 18;where n=12, DTAC1;n=14,TTAC1;n=16,CTAC1,and n=18,OTAC1),were studied by ~1H and ~(19)F NMR in detail.The results of ~(19)F NMR measurements strongly indicate that in the three mixed systems of DEFUMACl/DTAC1,DEFUMACl/TTAC1,and DEFUMACl/CTAC1 at different molar fractions of fluorocarbon surfactantα_F (C_(DEFUMACl)/C_(DEFUMAC+C_(C_nTAC1))with an increase of the total concentration(C_T=C_F+C_H),the mixed micelles at the first break point and the individual DEFUMACl micelles at the second break point form.However,three different types of micelles were determined in DEFUMACl and OTAC1 mixtures by ~(19)F NMR measurements,the OTAC1-rich mixed micelles,the DEFUMACl-rich ones,and the individual DEFUMACl micelles, respectively.The chemical shifts of protonΔδ(~1H)for -CH_3 in the mixed systems of DEFUMACl/C_nTAC1(n=12,14,16,18)have different variation trends from ~(19)F NMR measurements.For the two systems of DEFUAC1/DTAC1 and DEFUMACl/TTAC1, the mixed micelles at the first break point form.At the second break point,for lowerα_F,the DTAC1-rich and TTAC1-rich mixed micelles form with a strong down-field shift;however,for higherα_F,DEFUMACl-rich mixed micelles form with a strong up-field.For the other two systems of DEFUMACl/CTAC1 and DEFUMAC/OTAC1, mixed CH/CF-surfactant micelles form.And the chemical shifts of protonΔδ(~1H)of -CH_3 increase with an increase of the total concentration for the two mixtures.At higher total concentration,the larger effect of fluorinated chains of DEFUMACl on CH-chains was obvious,resulting in the strong up-field chemical shifts.In cationic fluorocarbon/hydrocarbon surfactant mixtures,the different kinds of micelles observed by ~(19)F and ~1H NMR measurements could be caused by the increase in alkyl chain of hydrocarbon surfactants with different critical micelle concentration.In combination of the two theoretical models for mixing,it could be concluded that:for the four different chain-length hydrocarbon surfactants studied,in a certain range of total concentration,the two components of mixtures interacted with each other, forming mixed micelles in two completely different ways according to their molecular properties and cmc values:one is close to ideal mixing with the formation of one type of mixed micelles,such as DEFUMACl/DTAC1 and TTAC1 systems;the other is the demixing with the formation of two types of micelles,i.e.fluorocarbon-rich mixed micelles,and hydrocarbon-rich mixed miceUes,as DEFUMACl/CTAC1 and OTAC1 systems did.However,as the total concentration of the mixed systems were high enough,due to the initial respective interaction between fluorocarbon and hydrocarbon chains,the four systems tend to demix,forming individual micelles of corresponding component.That is to say,at high total concentration,there found individual DEFUMACl miceUes in all the four systems.These results may direct primarily toward acquiring an understanding of the mechanism of CF-CH mixtures in aqueous solution and secondarily to providing the more detail information on non-ideal mixing.
In the forth section,mixed solutions of DEFUMACl with a novel structured cationic EO-PO-EO triblocked copolymer(Cat-Gemini copolymer)were investigated by ~(19)F NMR spectroscopy,surface tension measurements and DLS techniques.The results show that DEFUMACl strongly interacts with Cat-Gemini copolymer,and three peculiar break points at given copolymer concentrations have been defined: corresponding to the critical association concentration of DEFUMACl,P_1;the concentration where cationic Gemini copolymer molecules become saturated by DEFUMACl micelles,P~*;and the concentration where DEFUMACl micelles and DEFUMACl/Cat-Gemini copolymer mixtures coexist,P_2.In contrast,anionic surfactant SDS shows relatively weaker interaction with the same copolymer.For comparison,two types of one-chain nonionic blocked copolymer EPE-type F127 and PEP-type 17R4 solutions mixed with DEFUMACl were also studied.For straight single chain copolymer F127 and 17R_4 mixed systems,one can observe the similar three break points.But there still existed some interesting differences between the Gemini branched-chain copolymer and the single chain ones.P_1 values for the three copolymers decrease along the sequence of 17R4,F127 and Cat-Gemini copolymer, suggesting Gemini copolymer demonstrate the most stronggest interaction with the cationic CF surfactant,while the 17R4 take relatively weaker interaction with DEFUMACl.The results also provided us useful information on the interaction sites between CF-surfactant with different copolymers.The distributions of hydrodynamic radius, from DLS clearly show that bimodal distributions are obtained in 1 wt% Cat-Gemini copolymer systems with and without DEFUMACl.Without DEFUMACl, the two modes originate from two types of diffusing complexes,one with the averaged ～3.4 nm,and the other～60 nm.On the other hand,in DEFUMACl/Cat-Gemini mixtures,the larger mode increased in to～134 nm. The observed results suggest that in pure 1 wt%Cat-Gemini copolymer aqueous solution,the fast mode corresponds to the monomer of copolymer,and the second mode to the copolymer micelle.A small amount of DEFUMACl could associate with copolymer forming larger complexes.These results obtained in this work should broaden the useful information for a better understanding of the mechanism of interaction and the behavior of surfactant-polymer mixtures.
In the fifth section,the interaction of DEFUMACl with bovine serum albumin (BSA)was investigated by Circular Dichrosium(CD)and ~(19)F NMR spectroscopy measurements at room temperature.As a combination of electrostatic and hydrophobic contributions,a quite complex behavior between DEFUMACl and BSA has been observed.Comparing to DTAC1,DEFUMACl has much stronger binding ability with BSA to induce the denaturation of BSA at very lower fluorocarbon surfactant concentration,reflected in a clear decrease in the ellipticity content,whereα-helix structure decreased sharply andβ-sheet conformation increased as the concentration of BSA is high enough(such as above 0.5 g/L).As the concentration of DEFUMACl increased up to its cmc,BSA chain becomes saturated by DEFUMACl molecules,then after the content ofα-helix andβ-sheet of BSA keep constant.While the tertiary structure lies in the relatively loose state as the secondary structure of BSA was disrupted.No protective effect was observed in present systems,which were well reported in conventional hydrocarbon anionic surfactant and some in cationic Gemini surfactant with protein systems.The above behavior is consistent with corresponding changes in the behavior of fluorocarbon surfactant in bulk solution by ~(19)F NMR measurements,and obtained three critical concentrations as DEFUMACl interacted with BSA,corresponding to the concentration at which DEFUMACl starts to bind on the BSA,P_1;the concentration where BSA molecules become saturated by DEFUMACl micelles,P~*,and the concentration where individual DEFUMACl micelles formed,P_2.At lower DEFUMACl concentration,DEFUMACl molecules interact with BSA mainly by electrostatic forces;as the concentration of DEFUMACl reached P~*,hydrophobic interaction between fluorocarbon chains of DEFUMACl took the main role,and bead-like complexes were formed between BSA and DEFUMACl aggregates.Further addition of DEFUMACl to P_2,individual DEFUMACl micelles formed,and DEFUMACl monomers,DEFUMACl/BSA complexes,and DEFUMACl micelles reached equilibrium.
蛋白质和表面活性剂相互作用的研究多年来一直是人们十分感兴趣的课题。碳氟表面活性剂的独特特性使其与蛋白质复配体系不仅在生物工程、化学和药物等领域具有广泛的应用,而且有利于加快生物技术向化工、医药等传统领域的渗透和应用。
有关碳氟表面活性剂的聚集行为和物理化学性质的文献报道,研究体系主要集中在阴离子全氟羧酸类,阳离子碳氟表面活性剂的研究报道较少。其主要原因在于阳离子碳氟表面活性剂的合成和纯化困难。
论文利用~1H和~(19)F NMR波谱技术,结合表面张力测定、动态激光光散射和圆二色光谱测定研究了结构新颖的、部分氟代的阳离子碳氟表面活性剂,十七氟代-2-羟基十一烷基二乙羟基甲基氯化(DEFUMACl)水溶液的特性。对DEFUMACl与不同链长的阳离子碳氢表面活性剂十二烷基(DTACl)、十四烷基(TTACl)、十六烷基(CTACl)和十八烷基(OTACl)三甲基氯化铵、阳离子碳氢Gemini EO-PO-EO三嵌段共聚物以及牛血清蛋白质BSA之间的相互作用进行了较为系统深入的研究。并与传统的非离子EO-PO-EO嵌段共聚物F127(PEO_(99)-PPO_(67)-PEO_(99))、17R4(PO_(14)EO_(24)PO_(14))的作用进行了比较,获得了一些重要的结果。这些研究结果不论是在胶体化学的基础理论方面,还是在实际应用方面都具有指导作用。论文内容共分五部分:
第一部分概述了研究碳氟表面活性剂及其与碳氢表面活性剂、聚合物、蛋白质复配体系相互作用的重要意义,并综述了碳氟表面活性剂及其相关复配体系的研究进展和研究方法等。
第二部分利用表面张力测定、~(19)F NMR波谱技术研究了DEFUMACl水溶液的聚集特性,考察了温度、NaCl浓度对其临界胶束浓度的影响,获得了DEFUMACl的临界胶束浓度(cmc)、反离子结合常数等重要的物化参数。实验结果表明:阳离子碳氟表面活性剂具有较高的表面活性,室温下~(19)F NMR确定的cmc为3.40mmol·L~(-1),与表面张力法测定的值完全吻合;随着温度的升高,DEFUMACl的cmc呈现先降低后增加的变化趋势,且具有特殊的最低点现象;盐的加入显著影响DEFUMACl的表面活性。很少量NaCl的加入即可以诱导DEFUMACl发生自聚集,且随着盐浓度的增加,DEFUMACl的cmc显著降低。
第三部分利用~1H和~(19)F NMR波谱法研究了DEFUMACl与不同链长阳离子碳氢表面活性剂C_nTACl(n=12,DTACl;n=14,TTACl;n=16,CTAC及n=18,OTACl)的相互作用,考察了阳离子碳氢链长对形成碳氟-碳氢表面活性剂复合物聚集体的影响。~(19)F NMR结果表明:在DEFUMACl/DTACl、TTACl和CTACl三种混合体系中,不同摩尔分数α_F时,随着体系总浓度(c_T=c_F+c_H)的增加,~(19)F化学位移与浓度的关系曲线上呈现两个折点,即有两个cmc:在第一个折点,形成碳氢-碳氟表面活性剂的混合胶束;在第二个折点,则形成了单独的DEFUMACl胶束。而DEFUMACl/OTACl混合体系中,观察到了三个折点:分别形成了富-氢型混合胶束(OTACl-rich mixed micelles)、富-氟型混合胶束(DEFUMACl-richones)及单独的DEFUMACl胶束。~1H NMR测定结果表明:混合体系中,碳氢表面活性剂的-CH_3基团的质子化学位移△δ(~1H)与浓度的关系曲线呈现与~(19)F化学位移完全不同的变化趋势。对于DEFUACl/DTACl和DEFUMACl/TTACl混合体系,在第一个拐点首先形成了DEFUMACl/DTACl和DEFUMACl/TTACl混合胶束;于第二个拐点,当α_F较低时,形成富-氢型(DTACl-rich和TTACl-rich)混合胶束,并伴随着强烈的低场化学位移;然而,当α_F较高时,则形成富-氟型(DEFUMACl-rich)混合胶束,伴随着强的高场位移。对于DEFUMACl/CTACl和DEFUMAC/OTACl混合体系,只形成一种CH/CF混合胶束,且-CH_3的质子化学位移△δ(~1H)随体系总浓度的增加而增加。当总浓度较高时,DEFUMACl碳氟链对混合体系中碳氢链的影响较大,导致强的高场化学位移。结合混合体系的两种理论模型,研究发现:对于不同碳链长度的碳氢表面活性剂,在一定浓度范围内,混合体系内两组分能够发生相互作用,依据各组分的性质及cmc值的不同而以两种模式形成混合胶团:一种是形成互溶的混合胶束,如DEFUMACl/DTACl、TTACl体系;另一类则形成两种不同类型的富-氟型和富-氢型混合胶束,如DEFUMACl/CTACl及OTACl体系。但是,当体系浓度很高时,体系内两组分由于“互疏作用”和静电斥力等不利因素而倾向于各自形成胶束,即在高浓度时,四种混合体系均形成了单独的DEFUMACl胶束。这些实验结果为进一步了解水溶液中碳氢-碳氟表面活性剂的复配机理提供了有用的实验数据,为更好地理解非理想混合模型提供了较为详尽的信息。
第四部分采用~1H、~(19)F NMR波谱、表面张力测定和动态光散射技术研究了DEFUMACl与阳离子碳氢Gemini三嵌段共聚物(Cat-Gemini copolymer)的相互作用。测定结果表明:同SDS相似,DEFUMACl与Cat-Gemini copolymer之间发生了强烈的相互作用;在给定的阳离子Gemin共聚物浓度下,得到三个特征浓度,相应为:临界聚集浓度,P_1(critical association concentration);DEFUMACl与聚合物结合达到饱和的浓度,P~*;以及形成单独的DEFUMACl胶束的浓度,P_2。但是,SDS与阳离子Gemin共聚物的作用相对较弱。论文对比研究了DEFUMACl与直链型非离子EO-PO-EO型嵌段共聚物F127以及PO-EO-PO型17R4的相互作用。在F127、17R4与DEFUMACl的混合体系中,同样观测到相似的三个拐点。但是,Gemini型共聚物在与DEFUMACl的作用上同直链型共聚物F127、17R4存在着明显的区别。三个混合体系的P_1值依照Cat-Gemini polymer、F127和17R4的顺序依次增大,表明Cat-Gemini Copolymer与阳离子碳氟表面活性剂间具有最强烈的相互作用,而17R4与DEFUMACl的作用最弱。~(19)F图谱也较好地显示了碳氟表面活性剂与不同的共聚物的作用位置。动态光散射结果清楚表明:在有或没有DEFUMACl存在时,1.0 wt%Cat-Gemini copolymer水溶液均显示两种大小颗粒分布模式。当加入很少量的DEFUMACl后,表面活性剂与Gemini共聚物胶束相互作用,表面活性剂“吸附”在Gemini共聚物胶束上,形成了动力学半径较大的Cat-Gemini copolymer胶束/DEFUMACl复合物;随着DEFUMACl浓度的增加,表面活性剂分子、共聚物胶束及共聚物单分子间的静电排斥作用不断增强,阻止了DEFUMACl分子与共聚物胶束间的进一步作用,DEFUMACl分子倾向于形成单独的DEFUMACl胶束。本部分尝试性地探讨了DEFDUMACl与三种共聚物的作用机理,为深入理解表面活性剂与聚合物的作用机理提供了有效的实验数据。
第五部分采用NMR波谱和圆二色光谱技术(CD)研究了DEFUMACl与牛血清蛋白BSA的相互作用,考察了DEFUMACl对BSA分子结构的影响。结果证明:同传统的阳离子CH表面活性剂DTACl相比,很少量的DEFUMACl的加入即可诱导BSA柔性链舒展,使α-螺旋含量迅速降低,而β-折叠含量显著增加;破坏了蛋白质的二级结构,而导致蛋白质变性。同时,BSA的三级结构处于较为疏松的状态。在DEFUMACl/BSA体系中,没有观察到文献报道过的阴离子CH表面活性剂,如SDS、AOT和阳离子Gemini型CH表面活性剂对蛋白质的保护作用。相对于DEFUMACl而言,DTACl对BSA的变性作用较弱。~(19)F NMR研究结果从另一个侧面证实了DEFUMACl与BSA之间的强烈作用,并得到了三个临界浓度,P_1、P~*和P_2,相应于DEFUMACl与BSA开始作用的浓度、DEFUMACl分子在BSA分子上结合达到饱和的浓度以及形成单独的DEFUMACl胶束的浓度。DEFUMACl浓度较稀时,DEFUMACl与BSA间的作用力主要是静电力;当DEFUMACl的浓度达到P~*时,碳氟链间的疏水作用占据主导地位,DEFUMACl与BSA分子形成珠串式复合物;进而,随着DEFUMACl浓度的增加,混合体系中表面活性剂分子以单体,表面活性剂/蛋白质复合物以及表面活性剂胶束几种形态共存。NMR方法确定的P~*值与CD研究中使BSA分子链舒展完全,二级结构含量保持不变所对应的DEFUMACl浓度基本吻合。
Fluorinated surfactants,with partially or per-fluorinated tails,differ from hydrogenated surfactants in several respects.Because of the larger volume and higher electro-negativity of fluorine than hydrogen,the introduction of fluorine atoms instead of hydrogen results in the specific properties of fluorocarbon surfactants:exceptional activity,thermal and biological inertness,high gas-dissolving capacity,low surface tension,excellent spreading characteristics,and high fluidity.These properties have triggered wide applications of fluorocarbon surfactants in our daily life, pharmaceuticals,and various industrial fields.
Despite the wide technical interest of fluorocarbon surfactants due to their potential usefulness,with the large hydrophobicity and strong surface activity,the applications of pure fluorocarbon surfactants are quiet limited for the reason that a per-fluorinated surfactant uasually has not all the required properties for a given application,mainly because of its oleophobic properties.Hence,in practical applications,fluorocarbon surfactants are very often used in mixed systems with hydrocarbon surfactants and polymers to obtain some desired performance and unique features by playing with the surfactant ratio.
The interaction between protein and surfactant has triggered extensive interest for many years.The exceptional chemical and biological inertia and hydrophobic and oleophobic character of fluorocarbon surfactant influence the interaction with protein, hence the mixtures are not only of particular importance in numerous biotechnological applications,in pharmaceutics and chemistry etc.,but also important in simulating biological systems,which expedites the penetration of biological technology into chemical industry and medicine field.
The present knowledge of the aggregation behavior and physical chemistry in general of fluorinated surfactants reported was mainly about the per-fluorocarbon oxylates.Nonionic fluorocarbon surfaetants were dealt with in a serie of papers by Ravey.Very little has been published about cationic fluorocarbon surfactants.One reason is the difficulties in synthesis and purity.Cationic surfactants are scarce. Recently,with the rapid developments in synthetic technology and measurement methods,an increasing interest is directed towards the cationic fluorocarbon surfactants and their mixtures.The focus of this thesis has been on the properties of DEFUMACl,a novel-structured,partially fluorinated,cationic surfactant, diethanolheptadecafluoro-2-undecanolmethyl-ammonium chloride aqueous solutions; the interaction with conventional cationic hydrocarbon surfactants,C_nTACl(n=12, DTACl;n=14,TTACl;n=16,CTACl,and n=18,OTACl),as well as the interaction with water-soluble cationic Gemini EO-PO-EO triblocked copolymer and BSA by the combination of advanced techniques:~1H and ~(19)F NMR,DLS,CD and surface tension. For comparison,parallel measurements have also been made on the interaction between DEFUMACl and nonionic EO-PO-EO blocked Pluorinic copolymer,F127 (PEO_(99)-PPO_(67)-PEO_(99))and Pluorinic-R 17R4(PPO_(14)-PEO_(24)-PPO_(14)).Some important evidence for such complexation is obtained.These studies are of significance in making a good physical picture of the interaction between macromolecules and fluorocarbon surfactant.The present dissertation includes five sections.
In the first section,the importance of study on fluorocarbon surfactants and their mixtures with hydrocarbon surfactants,copolymers and proteins,and the study progress on fluorocarbon surfactants and its mixtures are summarized,including methods employed in such studies.
In the second section,the self-aggregation properties of DEFUMACl aqueous solutions are studied by surface tension and ~(19)F NMR spectroscopy measurements. The effects of temperature and NaCl on the aggregation behavior of DEFUMACl are also investigated,obtaining such important physicochemical parameters,as cmc values at different temperature and counter-ionic binding degree(β)of DEFUMACl. The results show that cationic surfactant DEFUMACl has higher surface activity,with the cmc of DEFUMACl by ~(19)F NMR is 3.40 mmol·L~(-1),which is completely consistent with that obtained by surface tension method.With the increase of temperature,the cmc value decreases slightly at first and then increases slowly at higher temperature, and the cmc values of DEMUAC1 have a minimum value at T=～308 K.The addition of NaC1 in surfactant aqueous solution strongly decreases the cmc values of DEFUMACl systems,and the more the sum of NaCl is,the lower the cmc value of DEFUMACl salt solution.
In the third section,the aggregation behavior and the interaction of four mixed systems for DEFUMACl mixing with cationic hydrocarbon surfactants, alkyltrimethylammonium chloride,C_nTAC1(n=12,14,16,and 18;where n=12, DTAC1;n=14,TTAC1;n=16,CTAC1,and n=18,OTAC1),were studied by ~1H and ~(19)F NMR in detail.The results of ~(19)F NMR measurements strongly indicate that in the three mixed systems of DEFUMACl/DTAC1,DEFUMACl/TTAC1,and DEFUMACl/CTAC1 at different molar fractions of fluorocarbon surfactantα_F (C_(DEFUMACl)/C_(DEFUMAC+C_(C_nTAC1))with an increase of the total concentration(C_T=C_F+C_H),the mixed micelles at the first break point and the individual DEFUMACl micelles at the second break point form.However,three different types of micelles were determined in DEFUMACl and OTAC1 mixtures by ~(19)F NMR measurements,the OTAC1-rich mixed micelles,the DEFUMACl-rich ones,and the individual DEFUMACl micelles, respectively.The chemical shifts of protonΔδ(~1H)for -CH_3 in the mixed systems of DEFUMACl/C_nTAC1(n=12,14,16,18)have different variation trends from ~(19)F NMR measurements.For the two systems of DEFUAC1/DTAC1 and DEFUMACl/TTAC1, the mixed micelles at the first break point form.At the second break point,for lowerα_F,the DTAC1-rich and TTAC1-rich mixed micelles form with a strong down-field shift;however,for higherα_F,DEFUMACl-rich mixed micelles form with a strong up-field.For the other two systems of DEFUMACl/CTAC1 and DEFUMAC/OTAC1, mixed CH/CF-surfactant micelles form.And the chemical shifts of protonΔδ(~1H)of -CH_3 increase with an increase of the total concentration for the two mixtures.At higher total concentration,the larger effect of fluorinated chains of DEFUMACl on CH-chains was obvious,resulting in the strong up-field chemical shifts.In cationic fluorocarbon/hydrocarbon surfactant mixtures,the different kinds of micelles observed by ~(19)F and ~1H NMR measurements could be caused by the increase in alkyl chain of hydrocarbon surfactants with different critical micelle concentration.In combination of the two theoretical models for mixing,it could be concluded that:for the four different chain-length hydrocarbon surfactants studied,in a certain range of total concentration,the two components of mixtures interacted with each other, forming mixed micelles in two completely different ways according to their molecular properties and cmc values:one is close to ideal mixing with the formation of one type of mixed micelles,such as DEFUMACl/DTAC1 and TTAC1 systems;the other is the demixing with the formation of two types of micelles,i.e.fluorocarbon-rich mixed micelles,and hydrocarbon-rich mixed miceUes,as DEFUMACl/CTAC1 and OTAC1 systems did.However,as the total concentration of the mixed systems were high enough,due to the initial respective interaction between fluorocarbon and hydrocarbon chains,the four systems tend to demix,forming individual micelles of corresponding component.That is to say,at high total concentration,there found individual DEFUMACl miceUes in all the four systems.These results may direct primarily toward acquiring an understanding of the mechanism of CF-CH mixtures in aqueous solution and secondarily to providing the more detail information on non-ideal mixing.
In the forth section,mixed solutions of DEFUMACl with a novel structured cationic EO-PO-EO triblocked copolymer(Cat-Gemini copolymer)were investigated by ~(19)F NMR spectroscopy,surface tension measurements and DLS techniques.The results show that DEFUMACl strongly interacts with Cat-Gemini copolymer,and three peculiar break points at given copolymer concentrations have been defined: corresponding to the critical association concentration of DEFUMACl,P_1;the concentration where cationic Gemini copolymer molecules become saturated by DEFUMACl micelles,P~*;and the concentration where DEFUMACl micelles and DEFUMACl/Cat-Gemini copolymer mixtures coexist,P_2.In contrast,anionic surfactant SDS shows relatively weaker interaction with the same copolymer.For comparison,two types of one-chain nonionic blocked copolymer EPE-type F127 and PEP-type 17R4 solutions mixed with DEFUMACl were also studied.For straight single chain copolymer F127 and 17R_4 mixed systems,one can observe the similar three break points.But there still existed some interesting differences between the Gemini branched-chain copolymer and the single chain ones.P_1 values for the three copolymers decrease along the sequence of 17R4,F127 and Cat-Gemini copolymer, suggesting Gemini copolymer demonstrate the most stronggest interaction with the cationic CF surfactant,while the 17R4 take relatively weaker interaction with DEFUMACl.The results also provided us useful information on the interaction sites between CF-surfactant with different copolymers.The distributions of hydrodynamic radius,
In the fifth section,the interaction of DEFUMACl with bovine serum albumin (BSA)was investigated by Circular Dichrosium(CD)and ~(19)F NMR spectroscopy measurements at room temperature.As a combination of electrostatic and hydrophobic contributions,a quite complex behavior between DEFUMACl and BSA has been observed.Comparing to DTAC1,DEFUMACl has much stronger binding ability with BSA to induce the denaturation of BSA at very lower fluorocarbon surfactant concentration,reflected in a clear decrease in the ellipticity content,whereα-helix structure decreased sharply andβ-sheet conformation increased as the concentration of BSA is high enough(such as above 0.5 g/L).As the concentration of DEFUMACl increased up to its cmc,BSA chain becomes saturated by DEFUMACl molecules,then after the content ofα-helix andβ-sheet of BSA keep constant.While the tertiary structure lies in the relatively loose state as the secondary structure of BSA was disrupted.No protective effect was observed in present systems,which were well reported in conventional hydrocarbon anionic surfactant and some in cationic Gemini surfactant with protein systems.The above behavior is consistent with corresponding changes in the behavior of fluorocarbon surfactant in bulk solution by ~(19)F NMR measurements,and obtained three critical concentrations as DEFUMACl interacted with BSA,corresponding to the concentration at which DEFUMACl starts to bind on the BSA,P_1;the concentration where BSA molecules become saturated by DEFUMACl micelles,P~*,and the concentration where individual DEFUMACl micelles formed,P_2.At lower DEFUMACl concentration,DEFUMACl molecules interact with BSA mainly by electrostatic forces;as the concentration of DEFUMACl reached P~*,hydrophobic interaction between fluorocarbon chains of DEFUMACl took the main role,and bead-like complexes were formed between BSA and DEFUMACl aggregates.Further addition of DEFUMACl to P_2,individual DEFUMACl micelles formed,and DEFUMACl monomers,DEFUMACl/BSA complexes,and DEFUMACl micelles reached equilibrium.
引文
[1].Jennings,K.H.;Marshall,I.C.B.;Wilkinson,M.J.;Kremer,A.;Kirby,A.J.;Camilleri,P."Aggregation Properties of a Novel Class of Cationic Gemini Surfactants Correlate with Their Efficiency as Gene Transfeetion Agents" Langmuir 2002;18(6):2426-2429.
[2].Ryhanen,S.J.;Pakkanen,A.L.;Saily,M.J.;Bello,C.;Mancini,G.;Kinnunen,P.K.J."Impact of the Stereochemical Structure on the Thermal Phase Behavior of a Cationic Gemini Surfactant"J.Phys.Chem.B 2002;106(44):11694-11697.
[3].Bai,G;Yan,H;Thomas,R.S."Microcalorimetric Studies on the Thermodynamic Properties of Cationic Gemini Surfactants" Langmuir 2001;17(15):4501-4504.
[4].Putlitz,B.;Hentze,H.P.;Landfester,K.;Antonietti,M."New Cationic Surfactants with Sulfonium Headgroups" Langmuir 2000,16(7):3214-3220.
[5].Erhardt,R.;Boker,A.;Zettl,H.;Kaya,H.;Pyckhout-Hintzen,W.;Krausch,G.;Abetz,V.;Muller,A.H.E."Janus Micelles" Macromolecules 2001;34(4):1069-1075.
[6].Kissa,E."Fluorinated Surfactants and Repellents" Second Ed.Surfactant Science Series,Vol.97;Marcel Dekker,New York,2001,pp1-21.
[7].Guittard,F.;Geribaldi,S."Highly fluorinated molecular organised systems:strategy and concept" J.Fluorine Chem.2001,107(2):363-374.
[8].Vierling,P.;Santaella,C.;Greiner,J."Highly fluorinated amphiphiles as drug and gene carrier and delivery systems" J.Fluorine Chem.2001,107(2):337-354.
[9].Kraft,M.P.;Riess,J.G."Highly fluorinated amphiphiles and colloidal systems,and their applications in the biomedical field" Biochimie 1998,80:489-514.
[10].Riess,J.G "Fluorous micro- and nanophases with a biomedical perspective" Tetrahedron 2002,58(20):4113-4131.
[11].Emmanouil,V.;El Ghoul,M.;Andre-Barres,C.;Guidetti,B.;Rico-Lattes,I.;Lattes,A."Synthesis of New Long-Chain Fluoroalkyl Glyeolipids:Relation of Amphiphilic Properties to Morphology of Supramolecular Assemblies" Langmuir 1998,14(19):5389-5395.
[12].(a)Chang,T.M.S.;Geyer,R.P."Blood Substitutes";Marcel Dekker:New York,1989.
(b)Kissa,E."Fluorinated Surfactant Synthesis,Properties,Applications";Surfactant Science Series 50;Dekker:New York,1994;Chapter 8,p 35.
[13].(a)Sagisaka,M.;Ito,A.;Kondo,Y.;Yoshino,N.;Kwon,Ok K.;Sakai,H.;Abe,M." Effects of Fluoroalkyl Chain Length and Added Moles of Oxyethylene on Aggregate Formation of Branched-tailed Fluorinated Anionic Surfactants" Colloid Surface A:Physicochemical Eng.Aspects 2001,183-185:749-755.
(b)Myrtil,E.;Iarif,L.;Creiner,J.;Riess,G.J.;Pucci,B.;Paria,A.A.;"Double-tailed perfluoroalkyl telomeric surfactants derived from tris(hydroxymethyl)acylamidomethane for medical applications" Macromolecular chemistry and physics 1994,195(4):1289-1304.
[14].(a)肖进新;赵振国“表面活性剂应用原理”,化学工业出版社,北京,2003,Ch.8.
(b)赵国玺;朱步瑶“表面活性剂作用原理”中国轻工业出版社2003,Ch.15.
[15].Lindman,B.;Thalberg,K."Polymer-Surfactant interactions-Recent developments",in Interactions of Surfactants with Polymers and Proteins,Goddard,E.D.and Ananthapadmanabhan,K.P.(Eds),CRC Press,Boca Raton,FL,1993,Ch.5.
[16].Lindman,B."Surfactant-Polymer Systems",in Handbook of Applied Surface and Colloid Chemistry Vol.1,Holmberg,K.(Eds),John Wiley & Sons,Ltd.,Chichester,2002,Ch.20.
[17].Holmberg,K.;Jonsson,B.;Kronberg,B.;Lindman,B."Surfactants and Polymers in Aqueous solution",2nd Edition,Wiley & Sons Ltd.,2003,Ch.8.
[18].Huc,I.;Oda,R."Gemini Surfactants:Studying Micellisation by ~1H and ~(19)F NMR Spectroscopy" Chemcomm 1999,2025-2026.
[19].Stephenson,B.C.;Beers,K.J."Determination of the Interfacial Characteristics of a Series of Bolaamphiphilic Poly(fluorooxetane)Surfactants through Molecular Dynamics Simulation" J.Phys.Chem.B 2006,110(39):19393-19405.
[20].Ravey,J.C.;Stebeb,M.J "Properties of fluorinated non-ionic surfactant-based systems and comparison with non-fluorinated systems" Colloids Surf.A 1994,84:11-17.
[21].Monduzzi,M.J."Self-assembly in fluorocarbon surfacant systems" Curr.Opin.Colloid Interface Sci.1998,3:467-477.
[22].Shinoda,K.;Hato,M.;Hayashi,T."Physicochemical properties of aqueous solutions of fluorinated surfactants" J.Phys.Chem.1972;76(6):909-914.
[23].Wang,K.;Karlson,G.;Alngren,M."Aggregation Behavior of Cationic Fluorosurfactants in Water and Salt Solutions.A Cryo TEM Survey" J.Phys.Chem.B 1999,103(43):9237-9246.
[24].Israelachvili,J.N.;Mitchell,D.J.;Ninham,B.W."Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers" J.Chem.Soc.Faraday Trans,2,1976,72:1525-1568.
[25].Mitchell,D.J.;Ninham,B.W."Miclles,Vesicles and microemulsions" J Chem.Soc.,Faraday Trans,2,1981,77(4):601-629.
[26].Tanford,C."The Hydrophobic effect on Formation of micelles and Biological Membrances" 2~(nd)Eds.;John Wiley & Sons:New York,1980,Ch.7.
[27].Jacquemain,D.;Wolf,S.G.;Leveiller,F.;Frolow,F.;Eisenstein,M.Lahav,M.;Leiserowitz.L."Correlation between observed crystalline self-assembly of fluorocarbon and hydrocarbon amphiphiles at the air-water interface and calculated lattice energy.Determination of electrostatic properties of the CF_2 group from a low-temperature x-ray diffraction study of perfluoroglutaramide" J.Am.Chem.Soc.1992;114(25):9983-9989.
[28].Shin,S.;Collazo,N.;Rice,S.A.;"A molecular dynamics study of the packing structures in monolayers of partially fluorinated amphiphiles" J.Chem.Phys.1992,96:1352-1366.
[29].Barton,S.W.;Goudot,A.;Bouloussa,O.;Rondeleza,F.;Lin,B.;Novak,F.;Acero,A.;Rice,S.A."Structural transitions in a monolayer of fluorinated amphiphile molecules" J.Chem.Phys.1992,96:1343-1351.
[30].Krafft,M.P.;Goldmann,M."Monolayers made from fluorinated amphiphiles" Curr.Opin.In Colloid and Interface Sci.2003,8(3):243-250
[31].郝京诚,汪汉卿,鲁润华,“微乳液相行为和微观结构研究”,中国科学B 1997,27(2):131-139.
[32].Hoffmann,H.;Würtz,J."Unusual phenomena in perfluorosurfactants" J.Mol.Liq.1997,72(1-3):191-230.
[33].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~1H and ~(19)F NMR Study of the Counterion Effect on the Micellar Structures Formed by Tetraethylammonium and Lithium Perfluorooctylsulfonates.1.Neat Systems" J.Phys.Chem.B 1999;103(39):8251-8258.
[34].Bossev,D.P.;Matsumoto,M.;Sato,T.;Watanabe,H.;Nakahara,M."~1H and ~(19)F NMR Study of the Counterion Effect on the Micellar Structures Formed by Tetraethylammonium and Lithium Perfluorooctylsulfonates.2.Mixed Systems"J.Phys.Chem.B 1999;103(39):8259-8266.
[35].Yang,L.K.;Zhao,K.-S.;Xiao,J.X."Study of Tetrabutylammonium Perfluorooctanoate Aqueous Solutions with Two Cloud Points by Dielectric Relaxation Spectroscopy" Langmuir 2006;22(21):8655-8662
[36].Ravey,J.C.;Ghebi,A.;Stebeb,M."Comparative study of fluorinated and hydrogenated nonionic surfactants.I.Surface activity properties and critical concentrations" J.Prog Colloid Polym.Sci.1988,76:234-241.
[37].Matos,L.;Ravey,J.C.;Serratrice,G."Surface tension properties of aqueous new nonionic fluorinated surfactants" J.Colloid Interface Sci.1989,128:341-347..
[38].Kadi,M.;Dvinskikh,S.V.;Furo,I.Almgren,M."Molecular Mechanism of Lateral Diffusion of Fluorosurfactants.A ~(19)F NMR Study" Langmuir 2002;18(12):5015-5018.
[39].Kadi,M.;Hansson,P.;Almgren,M.;Furo,I."Demixing of Fluorinated and Hydrogenated Surfactants into Distinct Aggregates and into Distinct Regions within Aggregates.A Combined NMR,Fluorescence Quenching,and Cryo-TEM Study" Langmuir 2002;18(24):9243-9249.
[40].Almgren,M.;Garamus,V.M."Small Angle Neutron Scattering Study of Demixing in Micellar Solutions Containing CTAC and a Partially Fluorinated Cationic Surfactant" J.Phys.Chem.B 2005;109(22):11348-11353
[41].Esumi,K."Mixed micelles involving a cationic fluorocarbon surfactant" Colloids Surf.A:Physicochem.Eng.Aspects 1994,84(1):49-57.
[42].Takasugi,K.;Esumi,K."Micellar Surface Charge Modification for Regular Solution Theory:Application to Mixed System of Cationic Fluorocarbon-Nonionic Hydrocarbon Surfactants" J.Phys.Chem;1996,100(48):18802-18807.
[43].Kobayashi,F.;Yoshimura,T.;Esumi,K."Interactions of fluorocarbon-modified poly(acrylic acid)with a cationic fluorocarbon surfactant" Colloid and Surfaces A:Physicochem.Eng.Aspects 2003,214(1-3):271-278.
[44].Pasc-Banu,A.;Blanzat,M.;Belloni,B.;Perez,E.;Mingotaud,C.;Rico-Lattes,I."Spontaneous vesicles of single-chain sugar-based fluorocarbon surfactants" J.Fluorine Chem.2005,126(1):33-38.
[45].(a)Kunitake,T.;Tawaki,S.;Nakashima,N."Excimer Formation and Phase Separation of Hydrocarbon and Fluorocarbon Bilayer Membranes" Bull.Chem.Soc.Jpn 1983,56:3235-3242.
(b)Kunitake,T.;Higashi,N."Bilayer membranes of triple-chain fluorocarbon amphiphiles" J.Am.Chem.Soc.1985,107:692-696.
[46].Yoshino,N.;Hamano,K.;Omiya,Y.kondo,A.Ito,A.;Abe,M."Syntheses of Hybrid Anionic Surfactants Containing Fluorocarbon and Hydrocarbon Chains"Langmuir 1995,11(2):466-469.
[47].Danino,D.;Weihs,D.;Zana,R.;Oradd,G.;Lindblom,G.;Abe,M.;Talmon,Y."Microstructures in the aqueous solutions of a hybrid anionic fluorocarbon/hydrocarbon Surfactant" J.Colloid Inter Sci.2003,259(2):382-390
[48].Yoshino,N.;Kondo,Y."Hybrid fluorocarbon/hydrocarbon surfactants" Curr Opin.Colloid Inter Sci.2005,10(3-4):88-93
[49].Miyazawa,H.;Konso,Y.;yoshino,"Synthesis and Solution Properties of Sulfate-Type Hybrid Surfactants with an Ethylene Spacer" J.Oleo Sci.2005,54:167-178
[50].Omoto,N.;Nihei,T.;Kurata,Y.;Kondo,Y.;Umemoto,K.;Yoshino,N."Modification effect of novel phosphate type hybrid surfactant-modification effect of surfactants for hydroxyapatite plate" Jpn J Conserv.Dent.2005,48:128-136.
[51].Sadtler,M.V.;Kraft,P.M.;Riese,G.J."Achieving Stable,Reverse Water-in-Fluorocarbon Emulsions" Angew Chem,Int.Ed.Engl.1996,35(17):1976-7978
[52].Oda,R.;Huc,I.;Danino,D.;Talmon,Y."Aggregation Properties and Mixing Behavior of Hydrocarbon,Fluorocarbon,and Hybrid Hydrocarbon-Fluorocarbon Cationic Dimeric Surfactants" Langmuir 2000,16(25):9759-9769.
[53].Nagarajan,R."Molecular Theory for Mixed Micelles" Langmuir 1985,1(3):331-341.
[54].Clint,J.H."Micellization of mixed nonionic surface active agents" J.Chem.Soc.,Faraday Trans.I,1975,17:1327-1334.
[55].Holland,P.M.;Rubingh,D.N."Nonideal multicomponent mixed micelle model" J.Phys.Chem.1983,87(11):1984-1990.
[56].Hoffmann,H.;Possnecker,G."The Mixing Behavior of Surfactants" Langmuir 1994,10(2):381-389.
[57].Shinoda,K."Proc 4th Intern Congr Surface Active Substances".I.TH.G.Overbeek,ed.Vol 2.London & Pads:Gordon & Breach Sci.Pulb,1967,p527.
[58].Mukerjee,P.;Yang,Alex Y.S."Nonideality of mixing of micelles of fluorocarbon and hydrocarbon surfactants and evidence of partial miscibility from differential conductance data" J.Phys.Chem.1976,80(12):1388-1390.
[59].Suguhara,G."Surfactant in Solution";Mittal,K.L.,Ed.;Plenum:New York,1989;Vol.7,pp 397.
[60].Wada,Y.;Ikawa,Y.;Igimi,H.;Murata,Y.;Nagadome,S.;Sugihara,G."Mixed Micelle and Mixed Adsorbed Film Formations of Anionic Fluorocarbon-Nonionic Surfactant Mixtures:Sodium Perfluorooctanoate with MEGA-8,-9 and -10" J.Jpn.Oil Chem.Soc.Yukagaku,1990,39:548-554.
[61].Mysels,Karol J."Critical demicellization concentration?"J.Colloid Interface Sci.1978,66(2):331-334.
[62].丁慧君,陈新,赵国玺,“碳氟表面活性剂与碳氢表面活性剂混合水溶液的表面吸附与胶团形成(Ⅳ)”高校化学学报,1987,8:726-730.
[63].朱步瑶,赵国玺“关于碳氟链表面活性剂与碳氢链表面活性剂混合溶液的胶团形成”化学学报1981,6:493-496.
[64].Xiao,J.;Sivars,U.;Tjerneld,F."Phase behavior and protein partitioning in aqueous two-phase systems of cationic-anionic surfactant mixtures",J.Chromatography B 2000,743(1-2):327-333.
[65].Nilsson,S.;Blokhus,A.M.;Hellebust,S."Influence of hydrophobic cosolutes on the associative/segregative phase separation of aqueous cationic surfactant-polymer systems",Langmuir 2002,18(17):6504-6505.
[66].Allouche,J.;Tyrode,E.;Sadtler,V.;Choplin,L.;Salager,J.L."Single- and two-step emulsification to prepare a persistent multiple emulsion with a surfactant-polymer mixture",Ind.Eng.Chem.Res.2003,42(17):3982-3988.
[67].Robb,I.D.In "Anionic Surfactants Physical Chemistry of Surfactant Action";Surfactant Science series 11,E.H.L.Reynders(Eds),Marcel Dekker:New York,1981,p109-173.
[68].史立“关于碳氟链表面活性剂与碳氢链表面活性剂混合溶液的胶团形成”北京大学硕士研究生论文1984.
[69].Sesta,B.;Segre,A.L.;D'Aprano,A.;Proietti,N."~1H NMR,Surface Tension,Viscosity,and Volume Evidence of Micelle-Polymer Hydrophobic Interactions:LiPFN-PVP System" J.Phys.Chem.B 1997;101(2):198-204.
[70].Segre,A.L.;Proietti,N.;Sesta,B.;D'Aprano,A.;Amato,M.E."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies" J.Phys.Chem.B 1998,102(50):10248-10254.
[71].Stitch,H.;Willbold,D.;Ejchart,A.;Rossen-Arbesfeld.F.;Yaniv,A.;Gazit,A.;Rosch,P."Trifluoroethanol stabilizes a helix-turn-helix motif in equine infectious-anemia-virus trans-activator protein" Eur.J.Biochem 1994,225:855-861.
[72].Sesta,B.;Gente,G.;Iovino,A.;Laureti,F.;Michiotti,P.;Paiusco,O.;Palacios,A.C.;Persi,L.;Princi,A.;Sallustio,S.;Sarnthein-Graf,C.;Capalbi,A.;La Mesa,C."Supramolecular Association in the System Water-Lysozyme-Lithium Perfluorononanoate" J.Phys.Chem.B.2004;108(9):3036-3043.
[73].Messina,P.V.;Prieto,G.;Ruso,J.M.;Sarmiento,F."Conformational changes in human serum albumin induced by sodium perfluorooctanoate in aqueous solutions" J.Phys.Chem.B 2005,109(32):15566-15573.
[74].Asakawa,T.;Amada,K.;Miyagishi,S."Micellar Immiscibility of Lithium 1,1,2,2-Tetrahydroheptadecafluorodecyl Sulfate and Lithium Tetradecyl Sulfate Mixture"Langmuir 1997,13(17):4569-4573.
[75].Asakawa,T.;Shirashi,T.;Sunazaki,S.;Miyagishi,S."Critical Demicellization Concentration of Diethylammonium Perfluorononanoate and Diethylammonium Tetradecyl Sulfate Mixture in Aqueous Solution" Bull.Chem.Soc.Jpn.1995,68(9):2503-2509.
[76].Asakawa,T.;Ishikawa,K.;Miyagishi,S "Aqueous Solution Properties of Pyridinium-Type Perfluorinated Surfactants and Simulation of Mixture CMC" J.Colloid and Interfacs Sci.2001,240(1):365-367.
[77].Asakawa,T.;Miyagishi,S.;Nishida,M."Coexistence of two kinds of mixed micelles revealed by gel filtration" Langmuir 1987,3(5):821-827.
[78].Nakano,T.K.;Sugihara,G.;Nakashima,T.;Yu,S.C."Thermodynamic Study of Mixed Hydrocarbon/Fluorocarbon Surfactant System by Conductometric and Fluorimetric Techniques" Langmuir 2002,18(23):8777-8785.
[79]Sesta,B;Segre,A.L.;"~1H NMR,Surface Tension,Viscosity,and Volume Evidence of Micelle-Polymer Hydrophobic Tnteractions:LiPFN-PVP System" J.Phys.Chem.B 1997101(2):198-204.
[80].Asakawa,T.;Hisamatsu,H.;"Miyagishi,S."Micellar Pseudophase Separation Regions of ~1H,~1H,~2H,~2H-Perfluoroalkylpyridinium Chloride and Hydrocarbon Surfactants by Group Contribution Method" Langmuir 1995;11(2):478-482.
[81].Muto,Y.;Esumi,K.;Meguro,K.;Zana,R.Comments on "Pyrene fluorescence as a probe of fluorocarbon micelles and their mixed micelles with hydrocarbon surfactants" Langmuir 1989;5(3):885-886.
[82].Haegel,F.H.;Hoffmann,H."Selective incorporation of dyes with fluorocarbon and hydrocarbon chains into coexisting micellar phases of sodium perfluorooctanoate and dimethyl tetradecyl amino ixde" Prog.Colloid Polym.Sci.1988,76:132-139.
[83].Asakawa,T.;Miyagishi,S."Demicellization of Sodium Perfluorooctanoate and Dodecyl Sulfate Mixtures Revealed by Pyrene Fluorescence Quenching"Langmuir 1999,15(10):3464-3468
[84].Carlfors,J.;Stilbs,P."The composition of mixed micelles of fluorocarbon and hydrocarbon surfactants as derived from nuclear magnetic resonance self-diffusion measurements" J Phys.Chem.1984,88(19):4410-4414
[85].De Lisi,R.;Inglese,A.;Milioto,S.;Pellerito,A."Demixing of Mixed Micelles.Thermodynamics of Sodium Perfluorooctanoate-Sodium Dodecanoate Mixtures in Water"Langmuir 1997,13(2):92-202.
[86].Burkitt,S.J.;Ottewil,R.;H.;Hayter,J.B.;Ingrain,B.T."Small angle neutron scattering studies on micellar systems pan 2:Mixed systems of ammonium decanoate and ammonium perfluoro-octanoate" Colloid polym.Sci.1987,265:628-636.
[87].Clapperton,R.M.;Ottewil,R.H.;Ingrain,B.T.;"A study of fluorocarbon-hydrocarbon surface active agent mixtures by NMR spectroscopy" Langmuir 1994,10(1):51-56.
[88].Shinoda,K.;Nomura,T.;"Miscibility of fluorocarbon and hydrocarbon surfactants in micelles and liquid mixtures.Basic studies of oil repellent and fire extinguishing agents" J.Phys.Chem.1980;84(4):365-369.
[89].Caponetti,E.;Chillura Manino,D.;Floriano,M.A.;Triolo,R."Fluorinated,protonated,and mixed surfactant solutions:a small-angle neutron scattering study" Langmuir 1993,9(5):1193-1200.
[90].Pedone,L.;Chillura Martino,D.;Caponetti,E.;Floriano,M.A.;Triolo,R."Determination of the Composition of Mixed Hydrogenated and Fluorinated Micelles by Small Angle Neutron Scattering"J.Phys.Chem.B 1997,101(46):9525-9531.
[91].Amato,M.E.;Caponetti,E.;Cxhillura Martino,D.;Pedone,L."~1H and ~(19)F NMR Investigation on Mixed Hydrocarbon-Fluorocarbon Micelles" J.Phys.Chem.B.2003,107(37):10048-10056.
[92].Yekta,A.;Duhamel,J.;Brochard,P.;Adiwidjaja,H.;Winnik,M.A."A fluorescent probe study of micelle-like cluster formation in aqueous solutions of hydrophobically modified poly (ethylene oxide)" Macromolecules 1993,26(8):1829-1836.
[93].Colby,R.H.;Plucktaveesak,N.;Bromberg,L."Critcal Incorporation Concentration of Surfactants Added to Micellar Solutions of Hydrophobically Modified Polyelectrolytes of the Same Charge" Langmuir 2001,17(10):2931-2941.
[94].Griffiths,P.C.;Roe,J.A.;Bales,B.L.;Pitt,A.R.;Howe,A.M.;"Fluorescence Probe Studies of gelatin-Sodium Dodecyl Sulfate Interactions" Langmiur 2000,16(22):8248-8254.
[95].Asakawa,T.;Mouri,M.;Miyagishi,S.;Nishida,M."Probe methods for the second cmc of fluorocarbon and hydrocarbon surfactant mixtures" Langmuir 1989,5(2):43-348.
[96].Almgren,M.;Wang,K.;Asakawa,T."Fluorescence Quenching Studies of Micellization and Solubilization in Fluorocarbon-Hydrocarbon Surfactant Mixtures" Langmuir 1997,13(17):4535-4544.
[97].Asakawa,T.;Ishino,S.;Miyagishi,S.;Hansson,P.;Almgren,M.;Ohta,A.;Miyagishi,S."Appearance of Pure Fluorocarbon Micellea Surveyed by Fluorescence Quenching of Amphiphilic Quinoline Derivatives in Fluorocarbon and Hydrocarbon Surfactant Mixtures"Langmuir 2004,20(17):6998-7003.
[98].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~(19)F NMR Study of Molecular Aggregation of Lithium Perfluorooctylsulfonate in Water at Temperatures from 30 to 250℃" J Phys.Chem.B 2000,104(2):155-158.
[99].Barthelemy,P.;Tomao,V.;Selb,J.;Chaudier,Y.;Pucci,B."Fluorocarbon-Hydrocarbon Nonionic Surfactants Mixtures:A study of Their Miscibility" Langmuir 2002,18(7):2557-2563.
[100].Sesta,B;Segre,A.L."Influence of the Ploymer Molecular weight on the Surfactant-Polymer Interactions:LiPFN-PVP and SDS-PVP" Langmiur 1997,13(25):6612-6617.
[101].Segre,A.L.;Proietti,N."Supramolecular Structure of the LiPFN-PVP Systerm:~(19)F NMR Studies"J.Phys.Chem.B 1998,102(50):10248-10254.
[102].Iliopouios,I.;Furo,I."NMR Study of the Association of anionic Surfactants with an Anionic Polyelectrolyte Hydrophobically Modified with perfluorinated Side Chains" Langmuir 2001, 17(26):8049-8054.
[103].Miyazaki,M.;Torigoe,k.;Esumi,K."Interactions of Sugar Persubstituted Ploy (Amidoamine)Dendrimers with Anionic Surfactants" Langmiur 2000 16(4):1522-1528.
[104].Miller,R.;Fainerman,V.B.;Makievski,A.V.;Kragel,J.;Grigoriev,D.O.;Kazakov,V.N.;Sinyachenko,O.V."Dynamics of protein and mixed protein/surfactant adsorption layers at the water/fluid interface".Adv.Colloid Interface Sci.,2000,86:39-82.
[105].(a)吴丹,徐桂英“光谱法研究蛋白质与表面活性剂的相互作用”物理化学学报,2006,22(2):254-260.
(b)吴丹,徐桂英.“阳离子型Gemini表面活性剂与蛋白质的相互作用”山东大学博士学位论文2007,Chap.5-6.
[106].Moren,A;Regav,O.;Khan,A."A Cryo-TEM Study of Protein-Surfactant Gels and Solutions" J.Colloid Interface Sci.2000;222(2):170-178.
[107].(a)Provencher,S.W."A fourier method for the analysis of exponential decay curves"Biophy.J.1976,16(1),27-41.
(b)Provencher SW."An eigenfunction expansion method for the analysis of exponential decay curves".J.Chem.Phys.1976,64(7):2772-2777.
[108].Jansson,J.;Schillen,K.;Olofsson,G.;Cardoso da Silva,C.R.;Loh,W."The Interaction between PEO-PPO-PEO Triblock Copolymers and Ionic Surfactants in Aqueous Solution Studied Using Light Scattering And Calorimetry" J.Phys.Chem.B 2004,108(1):82-92.
[109].Cardoso da Silva,C.R.;Olofsson,G.;Schillen,K.;Loh,W."Influence of Ionic Surfactants on the Aggregation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide)Block Copolymers Studied by Diffrential Scanning and Isothermal Titration Calorimetry" J.Phys.Chem.B 2002,106(6):1239-1246.
[110].Jansson,J.;Schillen,K.;Nilsson,M.;Soderman,O.;Fritz,G.;Bergmann,A.;Glatter,O."Small-Angle X-ray Scattering,Light Scattering,and NMR Study of PEO-PPO-PEO Triblock Copolymer/Cationic Surfactant Complexes in Aqueous Solution" J.Phys.Chem.B 2005,109(15):7073-7083.
[111].Matsuoka,K.;Yoshimura,T.;Shikimoto,T.;Hamada,J.Yamawaki,M.;Honda,C.;Endo,K."Molecular Aggregates of Partially Fluorinated Quaternary Ammonium Salt Gemini Surfactants" Langmiur 2007,23(22):10990-10994.
[112].Buhler,E.;Oelschaeger,C.;Waton,G.;Candau,S.J."Viscoelastic Properties of Hydrocarbon/Fluorocarbon Mixed Wormlike Micelles at High Ionic Strengh" J.Phys.Chem.B 2004,108(30):11236-11243
[113].Li,X.;Dong,S.L.;Jia,X.F.;Song,A.X.;Hao,J.C."Vesicles of a New Salt-Free Cat-anionic Fluoro/Hydrocarbon Surfactant System" Chem.Eur J.2007,13(34):9495-9502
[1].Abe,M."Synthesis and applications of surfactants containing fluorine" Curr.Opin.Colloid Inter.Sci.1999,4(5):354-356
[2].Chang,T.M.S."Blood Substitutes";Geyer,R.P.(Eds),Marcel Dekker:New York,1959,pp421-438.
[3].Kraft,M.P.;Riess,J.G."Highly fluorinated amphiphiles and colloidal systems,and their applications in the biomedical field.A contribution" Biochimie 1998,80(5-6):489-514.
[4].Kissa,E."In Fluorinated surfactants,synthesis,properties,applications;Surfactant" Science Series 50;Kissa,E.Ed.;Marcel Dekker:New York,1994;Chap.8,p325.
[5].(a)Eastoe,J.;Cazelles,B.M.H.;Steyteler,D.C.;Holmes,J.D.;Pitt,A.R.;Wear,T.J.;Heenan,R.K."Water-in-CO_2 Microemulsions Studied by Small-Angle Neutron Scattering"Langmuir;1997,13(26):6980-6984.
(b)Eastoe,J;Downer,A.;Paul,A.;Steytler,D.C.;Rumsey,E.;Penfold,J.;Heenan,R.K."Fluoro-Surfactants At Air/Water And Water/CO_2Interfaces." PhysChemChemPhys 2000,2:5236-5242
[6].Oda,R.;Huc,I.;Danino,D.;Talmon,Y."Aggregation Properties and Mixing Behavior of Hydrocarbon,Fluorocarbon,and Hybrid Hydrocarbon-Fluorocarbon Cationic Dimeric Surfactants" Langmuir;2000;16(25):9759-9769.
[7].郝京诚,汪汉卿,鲁润华,“微乳液相行为和微观结构研究”,中国科学B 27(2),1997,131-139.
[8].Hoffmann,H.;Würtz,J."Unusual phenomena in perfluorosurfactants" J.Mol.Liq.1997,72(1-3):191-230.
[9].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~1H and ~(19)F NMR study of the Counter-ion Effect on the Micellar Structures Formed by Tetraethylammonium and Lithium Perlfuorooctylsulfonates.1.Neat Systems" J.Phys.Chem.B;1999,103(39):8251-8258.
[10].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~(19)F NMR Study of Molecular Aggregation of Lithium Perlfuorooctylsulfonate in Water at Temperature from 30 to 250℃" J.Phys.Chem.B;2000,104(2):155-158.
[11].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~1H and ~(19)F NMR Study of the Counterion Effect on the Micellar Structures Formed by Tetraethylammonium and Lithium Perfluorooctylsulfonates.2.Mixed Systems" J.Phys.Chem.B;1999,103(39):8259-8266.
[12].Monduzzi,M.J."self-assembly in fluorocarbon surfacant systems" Curr.Opin.Colloid Interface Sci.1998,3:467-477.
[13].Matos,L.;Ravey,J.C.;Serratrice,G."Surface tension properties of aqueous new nonionic fluorinated surfactants" J.Colloid Interface Sci.1989,128:341-347..
[14].Ravey,J.C.;Stebeb,M.J."Properties of fluorinated non-ionic surfactant-based systems and comparison with non-fluorinated systems" Colloids Surf.A 1994,84(1):11-31.
[15].Ravey,J.C.;Ghebi,A.;Stebeb,M."Comparative study of fluorinated and hydrogenated nonionic surfactants.I.Surface activity properties and critical concentrations" J.Prog Colloid Polym.Sci.1988,76:234-241.
[16].Asakawa,T.;Hisamatsu,H.;"Miyagishi,S."Micellar Pseudophase Separation Regions of ~1H,~1H,~2H,~2H-Perfluoroalkylpyridinium Chloride and Hydrocarbon Surfactants by Group Contribution Method" Langmuir;1995;11(2):478-482.
[17].(a)Nagai,K.;Esumi,K."Interaction between cationic fluorocarbon surfactant and polyoxyethylated surfactants having a sulfate group" Colloids Surfaces A:Physicochem.Eng.Aspects 1995,94:97-105.
(b)"Interaction of fluorocarbon modified poly(acrylic acid)with a cationic fluorocarbon surfactant" Colloids Surfaces A:Physicochem.Eng.Aspects 2003,213:271-278.
(c)Takasugi,K.;Esumi,K."Micellar Surface Charge Modification for Regular Solution Theory:Application to Mixed System of Cationic Fluorocarbon-Nonionic Hydrocarbon Surfactants" J.Phys.Chem.B 1996,100:18802-18807.
[18].Kadi,M.;Dvinskikh,S.V.;Furo,I.Almgren,M."Molecular Mechanism of Lateral Diffusion of Fluorosurfactants.A ~(19)F NMR Study" Langmuir;2002;18(12):5015-5018.
[19].Kadi,M.;Hansson,P.;Almgren,M.;Furo,I."Demixing of Fluorinated and Hydrogenated Surfactants into Distinct Aggregates and into Distinct Regions within Aggregates.A Combined NMR,Fluorescence Quenching,and Cryo-TEM Study" Langmuir;2002;18(24):9243-9249.
[20].Hoffmann,H.;Kalus,J.;Thur,H."Small angle neutron scattering measurements on micellar solutions of perfluor detergents" Colloid Poly.Sci.1983,261:1043-1049.
[21].Burkitt,S.J.;Ottewill,R.;H.;Hayter,J.B.;Ingram,B.T."Small angle neutron scattering studies on micellar systems part 1.Ammonium octanoate,ammonium decanoate and ammonium perfluoroocatanoate" J.Colloid Inter Sci.1987,265(7):619-627.
[22].Esumi,K."Mixed micelles involving a cationic fluorocarbon surfactant" Colloids Surf.A 1994,84(1):49-57.
[23].Mukerjee,P."Fluorocarbon-hydrocarbon interactions in micelles and other lipid assemblies,at interfaces,and in solutions" Colloids and Surfaces A." Physicochemical and Engineering Aspects 1994,84(1):1-10
[24].Holland,P.M.;Rubingh,D.N."Nonideal multicomponent mixed micelle model" J Phys.Chem.1983,87(11):1984-1990...
[25].Asakawa,T.;Amada,K.;Miyagishi,S."Micellar Immiscibility of Lithium 1,1,2,2-Tetrahydroheptadecafluorodecyl Sulfate and Lithium Tetradecyl Sulfate Mixture"Langmuir;1997;13(17):4569-4573.
[26].Asakawa,T.;Shirashi,T.;Sunazaki,S.;Miyagishi,S."Critical Demicellization Concentration of Diethylammonium Perfluorononanoate and Diethylammonium Tetradecyl Sulfate Mixture in Aqueous Solution" Bull.Chem.Soc.Jpn.1995,68(9):2503-2509.
[27].Asakawa,T.;Ishikawa,K.;Miyagishi,S."Aqueous Solution Properties of Pyridinium-Type Perfluorinated Surfactants and Simulation of Mixture CMC" J.Colloid and Interfacs Sci.2001,240(1):365-367.
[28].Asakawa,T.;Ishino,S.;Miyagishi,S.;Hansson,P.;Almgren,M.;Ohta,A.;Miyagishi,S."Appearance of Pure Fluorocarbon Micellea Surveyed by Fluorescence Quenching of Amphiphilic Quinoline Derivatives in Fluorocarbon and Hydrocarbon Surfactant Mixtures"Langmuir,2004,20(17):6998-7003.
[29].Barthelemy,P.;Tomao,V.;Selb,J.;Chaudier,Y.;Pucli,B."Fluorocarbon-Hydrocarbon Nonionic Surfactants Mixtures:A Study of Their Miscibility" Langmiur;2002;18(7):2557-2563
[30].Nakagawa,T.;Tokiwa,F."In Surface and Colloid Science";Matijevic,E.,Ed.;John Wiley &Sons:New York,1969;Vol.9:p69.
[31].Pople,J.A.;Schneide,W.E.G.;Bernstein,H.J."High-resolution Nuclear Magnetic Resonance";McGraw-Hill:New York,1959,pp98,119-123.
[32].Antalek,B.;Kowalczyk,J.;Chari,K."Interaction of Vinyl Pyrrolidone and Vinyl Acetate Copolymer with Surfactants" Langmur;2004;20(26):11818-11820.
[33].(a)Muller,N.;Birkhahn,R.H."Investigation of micelle structure by fluorine magnetic resonance.I.Sodiuml0,10,10-trifluorocaprate and related compounds" J.Phys.Chem.1967,71(4):957-962.
(b)Muller,N.;Birkhahn,R.H."Investigation of micelle structure by fluorine magnetic resonance.Ⅱ.Effects of temperature changes,added electrolyte,and counterion size" J.Phys.Chem.1968,72(2):583-588.
(c)Guo,W.;Brown,T.A.;Fung,B.M."Micelles and aggregates of fluorinated surfactants" J.Phys.Chem.1991,95(4):1829-1836.
(d)Iijima,H.;Koyama,S.;Fujio,K.;Uzu,Y."NMR Study of the Transformation of Perfluorinated Surfactant Solutions" Bull.Chem.Soc.Jpn.1999,72(2):171-177.
[34].Segre,A.;Proietti,N."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies" J.Phys.Chem.B;1998;102(50):10248-10254.
[35].Mazer,N.A.;Benedeck,G B.;Carey,M.C."An investigation of the micellar phase of sodium dodecyl sulfate in aqueous sodium chloride solutions using quasielastic light scattering spectroscopy"J.Phys.Chem.1976,80(10):1075-1085.
[36].Israelachvili,J.N.,Mitchell,D.J.,Ninham,B.W.,"Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers" J.Chem Soc.Faraday Trans Ⅱ,1976,72: 1525-1568.
[37].Dill,K.A.;Flory,P."Molecular Organization in Micelles and Vesicles" J.Proc.Nat.Acad.Sci.1981 78:676-680
[38].(a)Nakano,T.Y.;Sugihara,G.;Nakashima,T.;Yu,S.C."Thermodynamic Study of Mixed Hydrocarbon/Fluorocarbon Surfactant System by Conductometric and Fluorimetric Techniques" Langmuir;2002;18(23):8777-8785.
(b)Mukerjee,P.;Korematsu,K.;Sugihara,G."Effect of temperature on the electrical conductivity and the thermodynamics of micelle formation of sodium perfluorooctanoate" J.Phys.Chem.1985,89(24):5308-5312.
[39].Wang,K.;Karlson,G.;Alngren,M."Aggregation Behavior of Cationic Fluorosurfactants in Water and Salt solutions A CryoTEM Survey" J.Phys.Chem.B;1999;103(43):9237-9246.
[40].(a)Fujiwara,M,;Okano,T.;Nakashima,T.H.;Nakamura,A.A.;Sugihara,G."A temperature study on critical micellization concentration(CMC),solubility,and degree of counter-ion binding of α-sulfonatomyristic acid methyl ester in water by electroconductivity measurements" Colloid Polym.Sci.1997,275(5):474-478.
(b)Nakamura,A.A.;Okano,Lee,S.;Sugihara,G."On Micelle Formation and Degree of Countefion Binding of α-Sulfonatomyristic Acid Ethyl Ester in Water:A Study Performed by Comparing with α-Sulfonatomyristic Acid Methyl Ester" J.Surf.Sci.Technol.1998,14:23-30.
[41].赵国玺,朱荹瑶,表面活性剂作用原理,中国轻工业出版社,北京,2003,Chap.15.
[1].Abe,M."Synthesis and applications of surfactants containing fluorine" Curr Opin.Colloid Inter.Sci.1999,4(5):354-356
[2].(a)Eastoe,J.;Cazelles,B.M.H.;Steyteler,D.C.;Holmes,J.D.;Pitt,A.R.;Wear,T.J.;Heenan,R.K."Water-in-CO_2 Microemulsions Studied by Small-Angle Neutron Scattering"Langmuir;1997,13(26):6980-6984.
(b)Eastoe,J;Downer,A.;Paul,A.;Steytler,D.C.;Rumsey,E.;Penfold,J.;Heenan,R.K."Fluoro-Surfactants at Air/Water and Water/CO_2Interfaces." PhysChemChemPhys 2000,2:5236-5242
[3].(a)Chang,T.M.S.;Geyer,R.P."Blood Substitutes",Marcel Dekker:New York,1989,pp98,119-128.
(b)Riess,J.G."Blood substitutes:the fluorocarbon approach".Encyclopedia of Pharmaceutical Technology 《New York:Marcel Dekker》 2002,pp263-79.
[4].Krafft,M.P.;Riess,J.G."Highly fluorinated amphiphiles and colloidal systems,and their applications in the biomedical field.A contribution" Biochimie;1998,80(5-6):489-514.
[5].Kissa,E.In "Fluorinated surfactants,synthesis,properties,applications",Surfactant Science Series 50;Kissa,E.Ed.;Marcel Dekker:New York,1994;Chap.8,p325.
[6].赵国玺,朱荹瑶,表面活性剂作用原理,中国轻工业出版社,北京,2003,Chap.15.
[7].Sun,H.;Xu,G.;Li,Y.;Chen,Y.J "Mesoseopic simulation of the aggregation behavior of fluorinated surfactant in aqueous solution" Fluorine Chem.2006,127(2):187-192.
[8].Funasaki,N.In "Mixed Surfactant Systems";Ogino,K.,Abe,M.,Eds.;Surfactant Science Series 46;Marcel Dekker:New York,1993;pp145.
[9].Barthelemy,P.;Tomao,V.;Selb,J.;Chaudier,Y.;Pucli,B."Fluorocarbon-Hydrocarbon Nonionic Surfactants Mixtures:A study of Their Miscibility" Langmiur;2002;18(7):2577-2581.
[10].Amato,M.E.;Caponetti,D.;Chillura,M.;Pedone,L."~1H and ~(19)F Investigation on Mixed Hydrocarbon-Fluorocarbon Micelles" J.Phys.Chem.B;2003;107(37):10048-10056
[11].Knodo,Y.;Yoshino,N."Hybrid fluorocarbon/hydrocarbon surfactants" Curr Opin Colloid Inter.Sci.2005,10(3-4):88-93.
[12].Mukerjee,P.;Yang,Alex Y.S."Nonideality of mixing of micelles of fluorocarbon and hydrocarbon surfactants and evidence of partial miscibility from differential conductance data"JPhys.Chem.1976,80(12):1388-1390.
[13].Mysels,K.L."Critical demicellization concentration?" J Colloid interface Sci.1978,66(2):331-334.
[14].Haegel,F.H.;Hoffmann,H."Selective incorporation of dyes with fluorocarbon and hydrocarbon chains into coexisting micellar phases of sodium perfluorooctanoate and dimethyl tetradecyl aminoxide" Prog.Colloid Polym.Sci.1988,76:132-139.
[15].Askawa,T.;Miyagishi,S.;Nishida,M."Coexistence of two kinds of mixed micelles revealed by gel filtration" Langmuir 1987,3(5);821-827.
[16].Askawa,T.;Amada,K.;Miyagishi,S."Micellar Immiscibility of Lithium 1,1,2,2-Tetrahydroheptadecafluorodecyl Sulfate and Lithium Tetradecyl Sulfate Mixture"Langmiur;1997;13(17):4569-4573
[17].Askawa,T.;Miyagishi,S."Demicellization of Sodium Perfluorooctanoate and Dodecyl Sulfate Mixtures Revealed by Pyrene Fluorescence Quenching" Langmuir;1999;15(10):3464-3468.
[18].Asakawa,T.;Ishino,S.;Hansson,P.;Almgren,M.;Ohta,A.Miyagishi,S."Appearance of Pure Fluorocarbon Micelles Surveyed by Fluorescence Quenching of Amphiphilic Quinoline Derivatives in Fluorocarbon and Hydrocarbon Surfactant Mixtures" Langmuir;2004;20(17):6998-7003.
[19].(a)Asakawa,T.;Imae,T.;Ikeda,S.;Miyagishi,S.;Nishida,M.;"Hydrogen-1 NMR self-diffusion study for mixed micelles of fluorocarbon and hydrocarbon surfactants"Langmuir;1991,7(2):262-266.
(b)Kondo,Y.;Miyazawa,H.;Sakai,H.;Abe,M.;Yoshino,N."First Anionic Micelle with Unusually Long Lifetime:Self-Assembly of Fluorocarbon-Hydrocarbon Hybrid Surfactant" J.Am.Chem.Soc.;2002;124(23):6516-6517.
(c)Oda,R.;Huc,I.;Danino,D.;Talmon,Y."Aggregation Properties and Mixing Behavior of Hydrocarbon,Fluorocarbon,and Hybrid Hydrocarbon-Fluorocarbon Cationic Dimeric Surfactants" Langmuir;2000;16(25):9759-9769
[20].Song,A.;Dong,S.;Hao,J.;Liu,W.;Xu,G.;Wang,H.;"Functions of fluomsurfactants 1:Surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant" J.Fluorine Chem.2005,126(9):1266-1273.
[21].Dong,S.L.;Li,X.;Xu,G.Y.;Hoffman,H."A Cationic Fluorocarbon Surfactant DEFUMAC1and Its Mixed Systems with Cationic Surfactants:~(19)F NMR and Surface Tension Study" J.Phys.Chem.B;2007;111(21):5903-5910.
[22].Kadi,M.;Hansson,P.;Almgren,M."Mixed Micelles of Fluorocarbon and Hydrocarbon Surfactants.A Small Angle Neutron Scattering Study" Langmuir;2004;20(10):3933-3939.
[23].Almgren,M.;Garamus,V.M."Small Angle Neutron Scattering Study of Demixing in Micellar Solutions Containing CTAC and a Partially Fluorinated Cationic Surfactant" J.Phys.Chem.B;2005;109(22):11348-11353
[24].Shinoda,K.;Nomura,T."Miscibility of fluorocarbon and hydrocarbon surfactants in micelles and liquid mixtures.Basic studies of oil repellent and fire extinguishing agents" J.Phys.Chem.1980,84(4):365-369.
[25].Ceponetti,E.;Chillura Martino D.;Floriano,M.A.Triolo,R."Fluorinated,protonated,and mixed surfactant solutions:a small-angle neutron scattering study" Langmuir,1993,9(5):1193-1200.
[26].Pedone,L.;Chillura Martino,D.;Caponetti,E.;Floriano,M.A.;Triolo,R."Determination of the Composition of Mixed Hydrogenated and Fluorinated Micelles by Small Angle Neutron Scattering" J Phys.Chem.B;1997;101(46):9525-9531.
[27]Jung,H.T.;Lee,S.Y.;Kaler,E.W.;Coldren,B.;Zasadzinski,J.A."Gaussian curvature and the equilibrium among bilayer cylinders,spheres,and discs" PNAS 2002,99:15318-15322.
[28].Li,X.;Dong S.;Jia,X.;Song,A.;Hao,J."Vesicles of a New Salt-Free Catanionic Fluoro-Hydrocarbon Surfactant System" Chem.Eur J.2007,13(34):9495-9502.
[29].Segre,A.;Proietti,N."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies"J.Phys.Chem.B;1998;102(50):10248-10254.
[30].Bossev,D.P.;Mustumoto,M.;Nakahara,M."~(19)F NMR Study of Molecular Aggregation of Lithium Perfluorooctylsulfonate in Water at Temperatures from 30 to 250℃"J Phys.Chem.B;2000;104(2):155-158
[31].Sesta,B.;Gente,G.;Iovino,A.;lauret,F.;Michiotti,P.;Paiusco,O.;Palacios,A.C.;Persi,L.;Princi,A.;Sallustio,S."Supramoleeular Association in the System Water-Lysozyme-Lithium Perfluorononanoate" J.Phys.Chem.B;2004;108(9):3036-3043
[32].Robayashi,F.;Yoshimura,T.;Esumi,K."Interactions of fluorocarbon-modified poly(acrylic acid)with a cationic fluorocarbon surfactant" Colloids Sur.A:Physicochem.Eng.Aspects 2003,214(3):271-278.
[33].Nagai,K.;Esumi,K."Interaction between cationic fluorocarbon surfactant and polyoxyethylated surfactants having a sulfate group" Colloids Sur.A:Physicochem.Eng.Aspects 1995,94(1):97-105.
[34].Li,Y.;Li,P.;Wang,J.;Wang,Y.;Yan,H.;Dong,C.;Thomas,R.K."Thermodynamics of micellization for partially fluorinated cationic gemini surfactants and related single-chain surfactants in aqueous solution" J.Colloid Inter.Sci.2005,287(1):333-337.
[35].Asakawa,T.;Miyagishi,S.;Nishida,M."Fluorine nuclear magnetic resonance of fluorocarbon and hydrocarbon surfactant mixtures" J.Colloid Inter.Sci.1985,104(1):279-281.
[36].Clapperton,R.M.;Ottewill,R.H.;Ingram,B.T."A study of fluorocarbon-hydrocarbon surface active agent mixtures by NMR spectroscopy" Langmiur 1994,10(1):51-56.
[37].Guo,W.;Guzman,E.K.;Heavin,S.D.;Li,Z.;Fung,B.M.;Christian,S.D."Mixed surfactant systems of sodium perfluorooctanoate with nonionic,zwitterionic,and cationic hydrocarbon surfactants" Langmiu;1992,8(10):2368-2375.
[38].Suguhara,G."Surfactant in Solution";Mittal,K.L.Ed.;Plenum:New York,1989;Vol.7,pp 397.
[39].朱步瑶,赵国玺“关于碳氟链表面活性剂与碳氢链表面活性剂混合溶液的胶团形成”化学学报.1981,6:493-496.
[40].Shinoda,K.;Nomura,T."Miscibility of fluorocarbon and hydrocarbon surfactants in micelles and liquid mixtures.Basic studies of oil repellent and fire extinguishing agents" J.Phys.Chem.1980,84(4):365-369.
[41].(a)Li,F.;Rosen,M.J.;Sulthana,S.B."Surface Properties of Cationic Gemini Surfactants and Their Interaction with Alkylglucoside or -maltoside Surfactant" Langmuir;2001;17(4):1037-1042.(b)Zhao,G.-X.;Ding,F.-X.;and Zhu,B.-Y."Surface-chemical study of an aqueous mixture of α-sulfolauric acid salts with cationics" Colloids Surf.A,1998,132(1):1-7.(c)Siddiqui,F.A.;Franses,E.I."Equilibrium.Adsorption and Tension of Binary Surfactant Mixtures at the Air/Water Interface" Langmuir;1996;12(2):354-362.(d)Zhou;Q.;Rosen,M.J."Molecular Interactions of Surfactants in Mixed Monolayers at the Air/Aqueous Solution Interface and in Mixed Micelles in Aqueous Media:The Regular Solution Approach" Langmuir;2003;19(11):4555-4562.
[42].Unpublished data,Bayreuth University,1989.
[1].Hamley,I.W.ed."Developments in Block Copolymer Science and Technology",Publisher:John Wiley & Sons,2004
[2].Zheng,Y.;Davis,H.T."Mixed micelles of nonionic surfactants and uncharged block copolymers in aqueous solutions:microstructure seen by cryo-TEM" Langmuir;2000;16(16);6453-6459.
[3].Egger,H.;Nordskog,A.;Lang,P.;Brandt,A.;"Shape transformation of poly (butadiene)-b-poly(ethyleneoxide)plus DTAB compound micelles in aqueous solutions"Macromol.Symp.2000,162(1),291-302.
[4].Henze,H.P.;Kramer,E.;Berton,B.;Forster,S.;Antonietti,M.;Dreja,M."Lyotropic mesophases of PB-PEO diblock copolymers and their cross-linking to generate ordered gels",Macromolecules;1999;32(18);5803-5809.
[5].Sumeet Jain and Frank S.Bates,"On the origins of morphological complexity in block copolymer surfactants",Science 2003,300(5618),460-464.
[6].Katakam,M.;Bell,L.N.;Banga,A.K."Effect of surfactants on the physical stability of recombinant human growth hormone",J.Pharm.Sci.1995,84(6),713-716.
[7].Nostrum,van C.F."Polymeric micelles to deliver photosensitizers for photodynamic therapy"Adv.Drug Delivery Rev.2004,56(1),9-16.
[8].Kabanov,A.V.;Batrakova,E.V.;Miller,D.W."Pluronic(?)block copolymers as modulators of drug efflux transporter activity in the blood-brain barrier" Adv.Drug Delivery Rev.2003,55(1),151-164.
[9].Pinho,M.E.N.;Costa,F.D.M.L.;Filho,F.B.S.;Ricardo,N.M.P.S.;Yeates,S.G.;Attwood,D.;Booth,C."Mixtures of triblock copolymers E62P39E62 and E137S18E137 Potential for drug delivery from in situ gelling micellar formulations" Int.J.Pharm.2007,328,95-98.
[10].Chu,B.;Zhou,Z."Nonionic Surfactants:Polyoxyalkylene Block Copolymers":Nace,V.M.,Ed.;Marcel Dekker:New York,1996,Chapter 3.
[11].Wu,G.;Liu,T.;Chu,B.Schneider,D.K.Graziano,V."Characterization of the PEO-PPO-PEO Triblock Copolymer and Its Application as a Separation Medium in Capillary Electrophoresis" Macromolecules;1997;30(16);4574-4583.
[12].Jansson,J.;Schillen,K.;Nilsson,M.;Soderman,O.;Fritz,G.Bergmann,A.;Glatter,O."Small-Angle X-ray Acattering,Light Scattering,and NMR Study of PEO-PPO-PEO Triblock Coploymer/Cationic Surfactant Complexes in Aqueous Solution" J.Phys.Chem.B.2005,109,7073-7083.
[13].Alexandridis,P.;Holzwartch,J.F.;Hatton,T.A."Micellization of Poly(ethylene oxide)-Poly(propylene oxide)-Poly(ethylene oxide)Triblock Copolymers in Aqueous Solutions:Thermodynamics of Copolymer Association" Macromolecules 1994,27(9);2414-2425.
[14].Wanka,G;Hoffman,H.;Ulbricht,W."Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene)Triblock Copolymers in Aqueous Solutions" Macromolecules 1994,27(15);4145-4159.
[15].Dai,S.;Tam,K.C.;Li,L."Isothermal Titrition Calorimetric Studies on Interactions of lonic Surfactant and Poly(oxylpropylene)-Poly(oxyethylene)-Poly(oxypropylene)Triblock Copolymers in Aqueous Solutions" Macromolecules;2001;34(20);7049-7055.
[16].Ma,J.;Gao,C.Tang,Y.;Liu,H."~1H NMR Spectroscopic Investigations on the Miceilization and Gelation of PEO-PPO-PEO Block Coploymers in Aqueous solutios" Langmiur;2007;23(19);9596-9605
[17].Ma,J.H.;Gao,C.Tang,Y.L.;Xiang,J.F.;Chen,S.;Wang,J.;Liu,H.Z."Micellization in aqueous solution of an ethelene oxide-propylene oxide triblock copolymer,investigated with ~1H NMR spectroscopy,pulsed-field gradient NMR,and NMR relaxation" J.Colloid Interface Scie.2007,312(2),390-396.
[18].Chu,B."Structure and Dynamics of Block Copolymer Colloids" Langmiur 1995,11(2);414-421.
[19].Zhang,Z.Q.;Xu,G.Y.;Wang,F.;Dong,S.L.;Chen,Y-L."Demulsification by amphiphilic dendrimer copolymers" J.Colloid Inter.Sci.2005,282(1),1-4.
[20.]Dong,S.L.;Li,X.;Xu,G.Y.;Hoffman,H."A Cationic Fluorocarbon Surfactant DEFUMACl and Its Mixed Systems with Cationic Surfactants:~(19)F NMR and Surface Tension Study" J Phys.Chem.B;2007;111(21);5903-5910.
[21].Seng,W.P.;Tam,K.C.Jenkins,R.D.Bassett,D.R."Calorimetric Studies of Model Hydrophobically Modified Alkali-Soluble Emulsion Polymers with Varying Spacer Chain Length in Ionic Surfactant Solutions" Macromolecules;2000;33(5);1727-1733.
[22].Seng,W.P.;Tam,K.C.Jenkins,R.D.Bassett,D.R."Model Alkali- Soluble Associative (HASE)Polymers and Ionic Surfactant interaction Examined by Isothermal Titration Calorimetry "Langmuir,2000,16(5),2151-2156.
[23].(a)Bloor,D.M.;Li,Y.;Wyn-Jone,E."Binding of Sodium Alkyl Sulfates to a Polymer Labeled with a Covalently Bonded Solvatochromic Probe" Langmuir 1995,11(10);3778-3781.(b)Bloor,D.M.;Wan-Yunus,W.M.Z.;Wan-Badhi,W.A.;Li,Y.;Holzwarth,J.F.;Wyn-Jones,E."Equilibrium and Kinetic Studies Associated with the Binding of Sodium Dodecyl Sulfate to the Polymers Poly(propylene oxide)and Ethyl(hydroxyethyl)cellulos"Langrnuir 1995,11(9);3395-3400.(c)Ghoreishi,S.M.;Li,Y.;Bloor,D.M.;Warr,J.;Wyn-Jones,E."Electromotive Force Studies Associated with the Binding of Sodium Dodecyl Sulfate to a Range of Nonionic Polymers" Langmuir;1999;15(13);4380-4387.(d)Ghoreish,S.M.;Fox,G.A.;Bloor,D.M.;Holzwarth,J.F.;Wyn-Jones,E."EMF and Microcalorimetry Studies Associated with the Binding of the Cationic Surfactants to Neutral Polymers"Langmuir;1999;15(17);5474-5479
[24].Berraou,M.Bales,B.Zana,R."Effect of the Nature of the counterion on the interaction between cesium and tetraalymmonium dodecylsulfates and poly(ethylene oxide)or poly(v0nylprolidone)",J.Colloid Inter.Sci.2003,267(2),519-523.
[25].Ortana,O.;D'Errica,G.;Paduano,L.;Vitagliano,V."Interaction of cationic,anionic,and non-ionic surfactants with ABA block copolymer Pluronic PE6200 and with BAB reverse block copolymer Pluronic 25R4" J.Colloid Interface Sci.2006,31,63-77.
[26].Almgren,M.;Van,Stam,J.;Lindbald,C.;Li,P.;Stilbs,P.Bahadur,P."Aggregation of poly (ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide)triblock copolymers in the presence of sodium dodecyl sulfate in aqueous solution" J.Phys.Chem.1991,95(14);5677-5684.
[27].Desai,P.R.;Jain,N.j.;Sharma,R.K.;Bahadur,P."Effect of additives on the mieellization of PEO/PPO/PEO block copolymer F127 in aqueous solution" Colloid Surf.A 2001,178(2),57-69.
[28].Hecht,E.;Hoffmann,H.;"Interaction of ABA block copolymers with ionic surfactants in aqueous solution" Langmuir 1994,10(1);86-91.
[29].Hecht,E.;Mortensen,H.;Gradzielski,M.;Hoffmann,H."Interaction of ABA Block Copolymers with Ionic Surfactants:Influence on Micellization and Gelation" J.Phys.Chem.1995,99(13);4866-4874.
[30].Thurn,T.;Couderc,S.;Sidhu,J.;Bloor,D.M.;Penfold,J.;Holzwarth,J.F.;Wyn-Jones,E."Study of Mixed Micelles and Interaction Parameters for ABA Triblock Copolymers of the Type EOm-POn-EOm and Ionic Surfactants:Equilibrium and Structure" Langmuir;2002;18(24);9267-9275
[31].(a)Li,Y.;Xu,R.;Couderc,S.;Bloor,D.M.;Holzwaeth,J.F.;Wyn-Jones,E."Binding of Tetradecyltrimethylammonium Bromide to the ABA Block Copolymer Pluronic F127(EO97PO69 EO97):Electromotive Force,Microcalorimetry,and Light Scattering Studies"Langmuir;2001;17(19);5742-5747.(b)Li,Y.;Xu,R.;Couderc,S.;Bloor,D.M.;Wyn-Jones,E.Holzwaeth,J.F.;"Binding of Sodium Dodecyl Sulfate(SDS)to the ABA Block Copolymer Pluronic F 127(EO_(97)PO_(69)EO_(97)):F127 Aggregation Induced by SDS" Langmuir 2001,17(1);183-188.(c)Li,Y.;Xu,R.;Couderc,S.;Bloor,D.M.;Holzwaeth,J.F.; Wyn-Jones,E."The Binding of Sodium Dodecyl Sulfate to the ABA Block Copolymer Pluronic F127(EO_(97)PO_(69)EO_(97)):An Electromotive" Force,Microcalorimetry,and Light Scattering Investigation" Langmuir;2000;16(26);10515-10520.
[32].Kobayashi,F.;Yoshimura,T.;Esumi,K."Interactions of Fluorocarbon-modified poly(acryl acid)with a cationic fluorocarbon surfactant" Colloids and Surfaces A:Physicochem.Eng.Aspects 2003,214(1),271-278.
[33].Segre,A.L.;Proietti,N.;Sesta,B.D'Aprano,A."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies" J.Phys Chem.B;1998;102(50);10248-10254.
[34].Sesta,B.;Segre,A.L.;D'Aprano,A.;Proitti,N."~1H NMR,Surface Tention,Viscosity,and Volune Evidence of Micelle-Polymer Hydrophobic Interactions:LiPFN-PVP System" J.Phys.Chem.B;1997;101(2);198-204.
[35].Sesta,B.;D'Aprano,A.;Segre,A.L.;Proitti,N."Influence of the Polymer Molecular Weight on the Surfactant-Polymer Interactions:LiPFN-PVP and SDS-PVP Systems" Langmuir;1997;13(25);6612-6617
[36].Jeong,S.W.;An,Y.J."Interaction of Perfluorinated Surfactant with Polycyclic Aromatic Hydrocarbons:Critical Micelle Concentration and Solubility Enhancement Measurements" J.Colloid Interface Sci.2001,242(2),419-424.
[37].赵国玺,朱荹瑶,“表面活性剂作用原理”,中国轻工业出版社,北京,2003,Chap.15.
[38].Gianni,P.;Bernazzani,L.;Carosi,R.;Mollica,V."Micellization of Lithium Perfluoroheptanoate and Its Aggregation on Poly(ethylene glycol)Oligomers in Water"Langmiur 2007,23,8752-8759.
[39].Goddard,E.D.In "Interactions of Surfactants with Polymers and protein";Goddard,E.D.,Ananthapadmanabhan,K.P.,Eds.;CRC Press:Boca Raton,FL,1993.
[40].董姝丽,徐桂英“聚合物/表面活性剂相互作用、相行为及有序聚集体研究” 山东大学硕士论文 2004,第四章,
[41].(a)Provencher,S.W."A fourier method for the analysis of exponential decay curves" Biophy.J.1976,16(1):27-41.(b)Provencher S.W."An eigenfunction expansion method for the analysis of exponential decay curves".J.Chem.Phys.1976;64(7):2772-2777.
[42].Menger,F.M.;Keiper,J.S."Gemini surfactants" Angew.Chem.Int.Ed.,2000,39:1906-1920.
[43].Zana,R."Dimedc and oligomeric surfactants.Behavior at interfaces and in aqueous solution:a review" Adv.Colloid Interface Sci.,2002,97(1-3):203-251.
[44].Lu,Y.Y.;Yi,S.H.;Shon,J.K.;Chang,S.;Pu,L.S.;Lee,S.Y.;Yie,J.E.;Char,K.;Stucky,G.D.;Kim,J.M."Highly Stable Mesoporous Metal Oxides Using Nano-Propping Hybrid Gemini Surfactants" J.Amer.Chem.Soc.;2004,126(8),2310-2311.
[45].Olive,M."Pluronic and Tetronic Surfactants";Technical Brochure,BASF Performance Chemicals,BASF Corp.,New Jersey,1996.
[46].Touhami,Y.;Rana,D.;Neaie,G.H.;Hornof,V."Study of polymer-surfactant interactions via surface tension measurements" Colloid Polym.Sci.,2001,279:297-300.
[47].Griffiths,P.C.;Fallis,I.A.;Teerapornchaisit,P.;Grillo,I."Hydrophobically modified gelatin and its interaction in aqueous solution with sodium dodecyl sulfate." Langmuir;2001,17(9):2594-2601.
[48].Muller,D.;Malmsten,M.;Bergenstahl,B.;Hessing,J.;Olijve,J.;Mori,F."Competitive adsorption of gelatin and sodium dodecylbenzenesulfonate at hydrophobic surfaces"Langmuir;1998,14(11):3107-3114.
[49].Otsuka,H.;Esumi,K."Structure-Performance relationships in surfactants" Esumi,K.;Ueno,M.Eds.New York:Marcel Dekker,1997,Chapter 12,p509.
[50].Iliopoulos,I.;Furo,I."NMR Study of the Association of Anionic Surfactants with an Anionic Polyelectrolyte Hydrophobically Modified with Perfluorinated Side Chains" Langmuir;2001;17(26);8049-8054.
[51].Amato,M.E.;Caponetti,E.;Chillura,M.D.;Pedone,L."~1H and ~(19)F NMR Investigation on Mixed Hydrocarbon-Fluorocarbon Micelles" J.Phys.Chem.B;2003;107(37);10048-10056.
[52].Nivaggioli,T.;Tsao,B.;Alexandridis,P.;Hatton,T.A."Microviscosity in Pluronic and Tetronic Poly(ethylene oxide)-Poly(propylene oxide)Block Copolymer Micelles" Langmuir 1995,11(1);119-126.
[53].Hue,I.;Oda,R."Gemini surfactants:studing micellisation by ~1H and ~(19)F NMR spectroscopy"Chem.Commun.1999,2025-2026.
[54]Kaplan,J.I.;Fraenkel,G.,in "NMR of Chemically Exchanging systems",Academic Press,New York,1980.
[55].Kim,B.J.;Im,S.S.;Oh,S.G "Investigation on the Solubilization Locus of Aniline-HCl Salt in SDS Micelles with ~1H NMR Spectroscopy" Langmuir;2001;17(2);565-566.
[56].Jansson,J.;Schillen,K.;Nilsson,M.;Soderman,O.;Fritz,G.;Bergmann,A.;Glatter,O."Small-Angle X-ray Scattering,Light Scattering,and NMR Study of PEO-PPO-PEO Triblock Cpolymer/Cationic Surfactant Complexes in Aqueous Solution" J.Phys.Chem.B;2005;109(15);7073-7083
[57].董姝丽,徐桂英“激光光散射和电子自旋共振技术研究十二烷基硫酸钠(SDS)与聚乙烯吡咯烷酮(PVP)的相互作用”,化学学报,2004,62卷,第7期,674-675
[1].Mclements,D.J.In "'Food Emulsions:Practice and Technique "s,2~(nd)Eds:CRC Press:Boca Raton,FL,2004.
[2].Jones,M.N."Surfactant interactions with biomembrancs and proteins" Chem.Soc.Rev.1992,21:127-136.
[3].Jones,M.N.In "Food Polymers,Gels and Colloids";The Royal Society of Chemistry:Cambridge,UK,1991:pp 65-88
[4].Turro,N.J.;Lei,X.G.;Ananthapadmanabhan,K.P.;Aronson,M."Spectroscopic probe analysis of protein-surfactant interactions:The BSA/SDS system".Langmuir,1995,11(7):2525-2533
[5].Vasilescu M.;Angellescu D.;Almgren M.;Valstar A."Interaction of globular proteins with surfactants studied with fluorescence probe methods" Langmuir;1999;15(8):2635-2643.
[6].Guo,X.H.;Zhao,N.M.;Chen,S.H.;Teixeira,J."Small-angle neutron scattering study of the structure of protein / detergent complexes".Biopolymers,1990,29:335-346.
[7].Oakes,J."Protein-surfactant interactions.Nuclear magnetic resonance and binding isotherm studies of interactions between bovine serum albumin and sodium dodecyl sulphate." J.Chem. Soc..Faraday Trans.1,1974,2200-2209.
[8].刘静,徐桂英.“表面活性剂与蛋白质相互作用的研究进展”.日用化学工业,2003,33:29-32.
[9].Messina,P.V.;Prieto,G.;Ruso,J.M.;Sarmiento,F."Conformational changes in human serum albumin induced by sodium perfluorooctanoate in aqueous solutions",J.Phys.Chem.B,2005;109(32):15566-15573
[10].(a)Schwuger,M.J.;Bartnik,F.G.In Anionic Surfactants;Gloxhuber,C.,Ed.;"Surfaetant Science Series",Vol.10;Marcel Dekker:Chapter 1.(b)Ananthapadmanabhan,K.P."Interactions of Surfactants with polymers and proteins";Goddard,E.D.,Ananthapadmanabhan,K.P.Eds.;CRC Press:Boca Raton,1993;p319.
[11].Zanette,D.;Lima,C.F.;Ruza,A.A.;Belarmino,A.T.N.;Santos,D.de F.;Frescura,V.L.A.;Marconi,D.M.O.;"Interactions of anionic surfactants with poly(ethylene oxide)and bovine serum albumin polymers:effect of the counterion hydrophobicity" Colloids Surf.A.1999,147(1-2):89-105.
[12].Chatterjee A.,Moulik S.P.,Majhi P.R.,Sanyal S.K.,"Studies on surfactant-biopolymer interaction:I.Microcalorimetric investigation on the interaction of cetyltrimethylammoniumbromide(CTAB)and sodium dodecylsulfate(SDS)with gelatin (Gn),lysozyme(Lz)and deoxyribonucleic acid(DNA)",Biophysical Chemistry 2002,98:313-327.
[13].Moriyama,Y.;Kawasaka,Y.;Takeda,K."Protective effect of small amount of sodium dodecyl sulfate on the helical structure of bovine serum albumin in the thermal denaturation."J.Colloid Interface Sci.2003,257(1):41-46.
[14].Gelamon,E.L.;Tabak,M."Spectroscopic studies on the interaction of bovine(BSA)and human(HAS)serum albumins with ionic surfactants"[J]Spectrochimica Acta Part A,2000,56:2255-2271.
[15].Sun,C.X.;Yang J.H.;Wu X.;Huang X.R.;Wang F.;Liu S.F.;"Unfolding and refolding of bovine serum albumin included by cetylpyridinium bromide".Biophys.J.2005,88(5):3518-3524.
[16].(a)Wu,D.;Xu,G.Y;Sun,Y.H.;Zhang,H.X.;Mao,H.Z.“Interaction between Proteins and Cationic Gemini Surfactant”Biomacromolecules 2007,8(2),708-712.(b)吴丹,徐桂英“阳离子Gemini表面活性剂与蛋白质的相互作用”山东大学博士学位论文 2007.
[17].Moriyama,Y.;Takeda,K."Protective Effect of Small Amounts of Bis-(2-ethylhexyl)sulfosuccinate on the Helical Structures of Human and Bovine Serum Albumins in Their Thermal Denaturations" Langmiur;2005;21(12):5524-5528.
[18].Li,Y.J.;Wang,X.Y.;Wang,Y.L."Comparative Studies on Interactions of Bovine Serum Albumin with Cationic Gemini and Single-Chain Surfactants" J.Phys.Chem.B;2006;110(16):8499-8505.
[19].Messina,V.P.;Prieto,G.;Ruso,M.J.;Sarmiento,F."Conformational Changes in Human Serum Albumin Induced by Sodium Perfluorooctanoate in aqueous Solutions".J.Phys.Chem.B;2005;109(32):15566-15573.
[20].Messina,V.P.;Prieto,G.;Dodero,V.;Ruso,M.J.;Schulz,P.;Sarmiento,F."Ultravioletcircular Dichroism spectroscopy and Potentiometric Study of the Interaction between Human Serum AlBumin and Sodiun Perfluorooctanoate" Biopolymer 2005,79:300-309.
[21].Messina,V.P.;Prieto,G.;Dodero,V.;Gabrerizo-Valderrama M.A.;Maldonado-Valderrama,J.;Ruso,M.J.;Sarmiento,F."Surface characterization of human serum albumin and sodium perfluorooctanoate mixed solutions by pendant drop tensiometry and circular dichroism"Biopolymer 2006,82(3):261-271.
[22].Sesta,B.;Gente,G.;Iovino,A.;Laureti,F.;Michiotti,P.;Paiusco,O.;Palacios,C.A.;Persi,L.;Mesa La C."Supramolecular association in the System Water-Lysozyme-Lithium Perfluorononanoate" J,Phys.Chem.B;2004;108(9):3036-3043
[23].Ciurleo,A.;Cinelii,S.;Gunia,M.;Bonincontro,A.;Onori,G.;Mesa,La C."Some Properties of Lysozyme-Lithium Perfluorononanoate Compexes" Biomacromolecules;2007,8(2):399-405.
[24].Mazakova,L.;Nordstierna,L.;Karlsson,G.;Blomberg,E.;Furo,I."Lack of Association between a cationic Protein and a Cationic Fluorosurfactant" Langmiur;2007;23(2):771-775
[25].Clark,L.C.Jr.;Hoffmann,R.E.;Davis,S.L.;"Response of the Rabbit Lung as a Criterion of Safety for Fluorocarbon Breathing and Blood Substitutes" Biomater Artif.Cells Immobilization Biotechnol 1992,20(2-4):10851099.
[26].Lissi,E.;Abuin,E.;Lanio,M.E.;Alvarez,C."A new and simple procedure for the evaluation of the association of surfactants to proteins".J.Biochem.Biophys.Methods,2002,50:261-268.
[27].吴丹,徐桂英.“光谱法研究蛋白质与表面活性剂的相互作用”.物理化学学报,2006,22(2):254-260
[28].Lu,R.C.;Xiao,J.X.;Cao,A.N.;Lai,L.H.;Zhu,B.Y.;Zhao,G.X."Surfactant-induced refolding of lysozyme".Biochimica et.Biophysica Acta 2005,1722:271-281.
[29].Ruso,J.M.;Deo,N.;Somasundaran,P."Complexation between dodecyl sulfate surfactant and zein protein in solution".Langmuir;2004;20(21):8988-8991.
[30].Sesta,B.;Segre,A.L.;D'Aprano,A.;Proietti,N."~1H NMR,Surface Tension,Viscosity,and Volume Evidence of Micelle-Polymer Hydrophobic Interactions:LiPFN-PVP System" J.Phys.Chem.B.;1997;101(2):198-204.
[31].(a)Moren,A.K.;Nyden,M.;Soderman,O.;Khan,A."Microstructure of Protein-Surfaetant Complexes in Gel and Solution-An NMR Relaxation Study" Langmuir;1999;15(17):5480-5488(b)Valstar,A.;Vasilescu,M.;Vigouroux,C.;Stilbs,P.;Almgren,M "Heat-Set Bovine Serum Albumin-Sodium Dodecyl Sulfate Gels Studied by Fluorescence Probe Methods,NMR,and Light Scatterin" Langmuir;2001;17(11):3208-3215.(c)Mesa,La C."Polymer-surfactant and protein-surfactant interactions" J.Colloid Inter.Sci.2005,286(1): 148-157.
[32].沈星灿,梁宏,何锡文,王新省.“园二色光谱分析蛋白质构像的方法及研究进展”,分析化学,2004,32(3):388-394
[33].Yan L.F.;Sun Z.R."Molecular structure of protein"[M]Beijing:Tsinghua University Press,1999,11-17.
[34].Yang,P.;Gao,F."Principles of bioinorganie chemistry"[M].Beijing:Science Press,2002,22:352.
[35].Shimizu,M.;Kobayashi,K.;Morii,H.;Mitsui,K.;Knoll,W.;Nagamune,T.;"Secondary structure analyses of protein films on gold surfaces by circular dichroism".Biochemical and Biophysical Research Communications,2003,310:606-611.
[36].Dong,A.;Natsuura,J.;Allison,S.D.;Chrisman,E.;Manning,M.C.;Carpenter,J.F."Infrared and circular dichroism spectroscopic characterization of structural differences between β-Lactoglobulin A and B" Biochemistry,1996,35(5):1450-1457.
[37].Becker,H.C.;Norden,B."DNA bindingf properties of 2,7-Diazapyrene and its N-methylated cations studied by linear and circular dichroism spectroscopy and calorimetry".J.Am.Chem.Soc.,1997,119(25):5798-5803.
[38].Zhong,W.Y.;Liang,Y.Q.;Fan,K.Q.;Lai,L.H."Chlorobenzylidine-calf thymus DNA interaction:circular dichroism and nuclear magnetic resonance studies".Spectrochim Acta A,2004,60:2985-2992.
[39].Zheng,J.;Consantine,C.A.;Rastogi,V.K.;Cheng,T.-C.;DeFrank,J.J.;Lablance,R.M."Secondary structure of organophosphorus hydrolase in solution and in langmuir-biodgett film studied by circular dichroism spectroscopy" J Phys.Chem.B 2004,108(44):17238-17242.
[40].Vertessy,B.G.;Harmat,V.;Bocskei,Z.;Naray,-Szabo,G.;Orosz,F.;Ovadi,J."Simultaneous binding of drugs with diffent chemical structures to Ca+-calmodulin:crystallographic and spectroscopic studies".Biochemistry,1998,37(44):15300-15310.
[41].Powis,W.;Klimtchuk,E."Photoelectron spectroscopy and circular dichroism on chiral biomolecules:L-Alanine".J.Phys.Chem.A.,2000,104(5):878-882.
[42].Mouzopoulou,B.;Kozlowski,H.;Katsaros,N.;Ganier-suillerot,A."Structural characterization of Ru-bleomycin complexes by resonance raman,circular dichroism,and NMR spectroscopy".Inorg.Chem.2001,40(27):6923-6929.
[43].Yang,S.Li,L.;Cholli,A.L.;Kumar,J.;Tripathy,S.K."Azobenzene-modified poly (1-glutamic acid)(AZOPLGA)its conformational and photodynamic properties".Biomacromolecues,2003,4(2):366-371.
[44].Dockal,M.;Carter,D.C.;Ruker,F."Conformational transitions of the three recombinant domains of human serum albumin depending on pH." J.Biol.Chem.2000,275:3042-3050.
[45].Gelamon,E.L.,Tabak,M."Spectroscopic studies on the interaction of bovine(BSA)and human(HAS)serum albumins with ionic surfactants"[J].Spectrochimica Acta Part A,2000, 56:2255-2271.
[46].Moriyama,Y.;Kawasaka,Y.;Takeda,K."Protective effect of small amount of sodium dodyl sulfate on the helical structure of bovine serum albumin in the thermal denaturation" J.Colloid Interface Sci.2003,257:41-46.
[47].Price,N.C."Conformation issues in the characterization of proteins".Biotechnol.Appl.Biochem,2000,31:29-40.
[48].Dong,S.L.;Li,X.;Xu,G.Y.;Hoffman,H."A Cationic Fluorocarbon Surfactant DEFUMACl and Its Mixed Systems with Cationic Surfactants:~(19)F NMR and Surface Tension Study" J.Phys.Chem.B 2007,111:5903-5910.
[49].Agarraberes,Fernando A.and Dice,J.Fred "Protein translocation across membranes"Biochim.Biophys.Acta,Biomembr.2001,1513(1):1-24.
[50].Sreerama,N.;Venyaminov,S.Y.;Woody,R.W."Estimationb of Protein Secondary Structure from Circular Dichroism Spectra:Inclusion of Denatured Proteins with Native Proteins in the Anaysis" Anal.Biochem.,2000,287:243-251.
[51].Amato,M.E.;Caponetti,E.;Chillura,M.D.;Pedone,L."~1H and ~(19)F NMR Investigation on Mixed Hydrocarbon-Fluorocarbon Micelles" J.Phys.Chem.B;2003;107(37):10048-10056.
[52].Segre,A.;Proietti,N."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies" J.Phys.Chem.B;1998;102(50):10248-10254.
[53].(a)Menger,F.M.;Keiper,J.S."Gemini Surfactants" Angew.Chem.Int.Ed.2000,39(11):1906-1920.(b)Lyu,Y.Y.;Yi,S.H.;Shon,J.K.;Chang,S.;Pu,L.S.;Lee,S.Y.;Yie,J.E.;Char,K.;Stucky,G.D.;Kim,J.M."Highly Stable Mesoporous Metal Oxides Using Nano-Propping Hybrid Gemini Surfactants" J.Amer.Chem.Soc..;2004;126(8):2310-2311.
[54].(a)Nakagawa,T,;Tokiwa,F.In Surface and Colloid Science;Matijevic,E.,Ed.;John Wiley & Sons:New York,1969;Vol.9:p69.(b)Barthelemy,P.;Tomao,V.;Selb,J.;Chaudier,Y.;Pucli,B."Fluorocarbon-Hydrocarbon Nonionic Surfactants Mixtures:A Study of Their Miscibility" Langmiur;2002;18(7):2557-2563.
[55].Lima,F.C.;Nome,F.;Zanette,D."First Evidence of Poly(ethylene Oxide)-Mixed Sodium Dodecyl Sulfate/Sodium Decyl Phosphate Complexes" J.Colloid Interface Sci.1997,189(1):174-176.
[56].Pi,Y.Y.;Shang,Y.Z.;Peng,C.J.;Liu,H.L.;Hu,Y.;Jiang,J.W."Interactions between Bovine serum Albumin and Gemini Surfactant Alkanediyl-α,ω-Bis(Dimethyldodecyl-Ammonium Bromide" Biopolymer,2006,83:243-249.
[2].Ryhanen,S.J.;Pakkanen,A.L.;Saily,M.J.;Bello,C.;Mancini,G.;Kinnunen,P.K.J."Impact of the Stereochemical Structure on the Thermal Phase Behavior of a Cationic Gemini Surfactant"J.Phys.Chem.B 2002;106(44):11694-11697.
[3].Bai,G;Yan,H;Thomas,R.S."Microcalorimetric Studies on the Thermodynamic Properties of Cationic Gemini Surfactants" Langmuir 2001;17(15):4501-4504.
[4].Putlitz,B.;Hentze,H.P.;Landfester,K.;Antonietti,M."New Cationic Surfactants with Sulfonium Headgroups" Langmuir 2000,16(7):3214-3220.
[5].Erhardt,R.;Boker,A.;Zettl,H.;Kaya,H.;Pyckhout-Hintzen,W.;Krausch,G.;Abetz,V.;Muller,A.H.E."Janus Micelles" Macromolecules 2001;34(4):1069-1075.
[6].Kissa,E."Fluorinated Surfactants and Repellents" Second Ed.Surfactant Science Series,Vol.97;Marcel Dekker,New York,2001,pp1-21.
[7].Guittard,F.;Geribaldi,S."Highly fluorinated molecular organised systems:strategy and concept" J.Fluorine Chem.2001,107(2):363-374.
[8].Vierling,P.;Santaella,C.;Greiner,J."Highly fluorinated amphiphiles as drug and gene carrier and delivery systems" J.Fluorine Chem.2001,107(2):337-354.
[9].Kraft,M.P.;Riess,J.G."Highly fluorinated amphiphiles and colloidal systems,and their applications in the biomedical field" Biochimie 1998,80:489-514.
[10].Riess,J.G "Fluorous micro- and nanophases with a biomedical perspective" Tetrahedron 2002,58(20):4113-4131.
[11].Emmanouil,V.;El Ghoul,M.;Andre-Barres,C.;Guidetti,B.;Rico-Lattes,I.;Lattes,A."Synthesis of New Long-Chain Fluoroalkyl Glyeolipids:Relation of Amphiphilic Properties to Morphology of Supramolecular Assemblies" Langmuir 1998,14(19):5389-5395.
[12].(a)Chang,T.M.S.;Geyer,R.P."Blood Substitutes";Marcel Dekker:New York,1989.
(b)Kissa,E."Fluorinated Surfactant Synthesis,Properties,Applications";Surfactant Science Series 50;Dekker:New York,1994;Chapter 8,p 35.
[13].(a)Sagisaka,M.;Ito,A.;Kondo,Y.;Yoshino,N.;Kwon,Ok K.;Sakai,H.;Abe,M." Effects of Fluoroalkyl Chain Length and Added Moles of Oxyethylene on Aggregate Formation of Branched-tailed Fluorinated Anionic Surfactants" Colloid Surface A:Physicochemical Eng.Aspects 2001,183-185:749-755.
(b)Myrtil,E.;Iarif,L.;Creiner,J.;Riess,G.J.;Pucci,B.;Paria,A.A.;"Double-tailed perfluoroalkyl telomeric surfactants derived from tris(hydroxymethyl)acylamidomethane for medical applications" Macromolecular chemistry and physics 1994,195(4):1289-1304.
[14].(a)肖进新;赵振国“表面活性剂应用原理”,化学工业出版社,北京,2003,Ch.8.
(b)赵国玺;朱步瑶“表面活性剂作用原理”中国轻工业出版社2003,Ch.15.
[15].Lindman,B.;Thalberg,K."Polymer-Surfactant interactions-Recent developments",in Interactions of Surfactants with Polymers and Proteins,Goddard,E.D.and Ananthapadmanabhan,K.P.(Eds),CRC Press,Boca Raton,FL,1993,Ch.5.
[16].Lindman,B."Surfactant-Polymer Systems",in Handbook of Applied Surface and Colloid Chemistry Vol.1,Holmberg,K.(Eds),John Wiley & Sons,Ltd.,Chichester,2002,Ch.20.
[17].Holmberg,K.;Jonsson,B.;Kronberg,B.;Lindman,B."Surfactants and Polymers in Aqueous solution",2nd Edition,Wiley & Sons Ltd.,2003,Ch.8.
[18].Huc,I.;Oda,R."Gemini Surfactants:Studying Micellisation by ~1H and ~(19)F NMR Spectroscopy" Chemcomm 1999,2025-2026.
[19].Stephenson,B.C.;Beers,K.J."Determination of the Interfacial Characteristics of a Series of Bolaamphiphilic Poly(fluorooxetane)Surfactants through Molecular Dynamics Simulation" J.Phys.Chem.B 2006,110(39):19393-19405.
[20].Ravey,J.C.;Stebeb,M.J "Properties of fluorinated non-ionic surfactant-based systems and comparison with non-fluorinated systems" Colloids Surf.A 1994,84:11-17.
[21].Monduzzi,M.J."Self-assembly in fluorocarbon surfacant systems" Curr.Opin.Colloid Interface Sci.1998,3:467-477.
[22].Shinoda,K.;Hato,M.;Hayashi,T."Physicochemical properties of aqueous solutions of fluorinated surfactants" J.Phys.Chem.1972;76(6):909-914.
[23].Wang,K.;Karlson,G.;Alngren,M."Aggregation Behavior of Cationic Fluorosurfactants in Water and Salt Solutions.A Cryo TEM Survey" J.Phys.Chem.B 1999,103(43):9237-9246.
[24].Israelachvili,J.N.;Mitchell,D.J.;Ninham,B.W."Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers" J.Chem.Soc.Faraday Trans,2,1976,72:1525-1568.
[25].Mitchell,D.J.;Ninham,B.W."Miclles,Vesicles and microemulsions" J Chem.Soc.,Faraday Trans,2,1981,77(4):601-629.
[26].Tanford,C."The Hydrophobic effect on Formation of micelles and Biological Membrances" 2~(nd)Eds.;John Wiley & Sons:New York,1980,Ch.7.
[27].Jacquemain,D.;Wolf,S.G.;Leveiller,F.;Frolow,F.;Eisenstein,M.Lahav,M.;Leiserowitz.L."Correlation between observed crystalline self-assembly of fluorocarbon and hydrocarbon amphiphiles at the air-water interface and calculated lattice energy.Determination of electrostatic properties of the CF_2 group from a low-temperature x-ray diffraction study of perfluoroglutaramide" J.Am.Chem.Soc.1992;114(25):9983-9989.
[28].Shin,S.;Collazo,N.;Rice,S.A.;"A molecular dynamics study of the packing structures in monolayers of partially fluorinated amphiphiles" J.Chem.Phys.1992,96:1352-1366.
[29].Barton,S.W.;Goudot,A.;Bouloussa,O.;Rondeleza,F.;Lin,B.;Novak,F.;Acero,A.;Rice,S.A."Structural transitions in a monolayer of fluorinated amphiphile molecules" J.Chem.Phys.1992,96:1343-1351.
[30].Krafft,M.P.;Goldmann,M."Monolayers made from fluorinated amphiphiles" Curr.Opin.In Colloid and Interface Sci.2003,8(3):243-250
[31].郝京诚,汪汉卿,鲁润华,“微乳液相行为和微观结构研究”,中国科学B 1997,27(2):131-139.
[32].Hoffmann,H.;Würtz,J."Unusual phenomena in perfluorosurfactants" J.Mol.Liq.1997,72(1-3):191-230.
[33].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~1H and ~(19)F NMR Study of the Counterion Effect on the Micellar Structures Formed by Tetraethylammonium and Lithium Perfluorooctylsulfonates.1.Neat Systems" J.Phys.Chem.B 1999;103(39):8251-8258.
[34].Bossev,D.P.;Matsumoto,M.;Sato,T.;Watanabe,H.;Nakahara,M."~1H and ~(19)F NMR Study of the Counterion Effect on the Micellar Structures Formed by Tetraethylammonium and Lithium Perfluorooctylsulfonates.2.Mixed Systems"J.Phys.Chem.B 1999;103(39):8259-8266.
[35].Yang,L.K.;Zhao,K.-S.;Xiao,J.X."Study of Tetrabutylammonium Perfluorooctanoate Aqueous Solutions with Two Cloud Points by Dielectric Relaxation Spectroscopy" Langmuir 2006;22(21):8655-8662
[36].Ravey,J.C.;Ghebi,A.;Stebeb,M."Comparative study of fluorinated and hydrogenated nonionic surfactants.I.Surface activity properties and critical concentrations" J.Prog Colloid Polym.Sci.1988,76:234-241.
[37].Matos,L.;Ravey,J.C.;Serratrice,G."Surface tension properties of aqueous new nonionic fluorinated surfactants" J.Colloid Interface Sci.1989,128:341-347..
[38].Kadi,M.;Dvinskikh,S.V.;Furo,I.Almgren,M."Molecular Mechanism of Lateral Diffusion of Fluorosurfactants.A ~(19)F NMR Study" Langmuir 2002;18(12):5015-5018.
[39].Kadi,M.;Hansson,P.;Almgren,M.;Furo,I."Demixing of Fluorinated and Hydrogenated Surfactants into Distinct Aggregates and into Distinct Regions within Aggregates.A Combined NMR,Fluorescence Quenching,and Cryo-TEM Study" Langmuir 2002;18(24):9243-9249.
[40].Almgren,M.;Garamus,V.M."Small Angle Neutron Scattering Study of Demixing in Micellar Solutions Containing CTAC and a Partially Fluorinated Cationic Surfactant" J.Phys.Chem.B 2005;109(22):11348-11353
[41].Esumi,K."Mixed micelles involving a cationic fluorocarbon surfactant" Colloids Surf.A:Physicochem.Eng.Aspects 1994,84(1):49-57.
[42].Takasugi,K.;Esumi,K."Micellar Surface Charge Modification for Regular Solution Theory:Application to Mixed System of Cationic Fluorocarbon-Nonionic Hydrocarbon Surfactants" J.Phys.Chem;1996,100(48):18802-18807.
[43].Kobayashi,F.;Yoshimura,T.;Esumi,K."Interactions of fluorocarbon-modified poly(acrylic acid)with a cationic fluorocarbon surfactant" Colloid and Surfaces A:Physicochem.Eng.Aspects 2003,214(1-3):271-278.
[44].Pasc-Banu,A.;Blanzat,M.;Belloni,B.;Perez,E.;Mingotaud,C.;Rico-Lattes,I."Spontaneous vesicles of single-chain sugar-based fluorocarbon surfactants" J.Fluorine Chem.2005,126(1):33-38.
[45].(a)Kunitake,T.;Tawaki,S.;Nakashima,N."Excimer Formation and Phase Separation of Hydrocarbon and Fluorocarbon Bilayer Membranes" Bull.Chem.Soc.Jpn 1983,56:3235-3242.
(b)Kunitake,T.;Higashi,N."Bilayer membranes of triple-chain fluorocarbon amphiphiles" J.Am.Chem.Soc.1985,107:692-696.
[46].Yoshino,N.;Hamano,K.;Omiya,Y.kondo,A.Ito,A.;Abe,M."Syntheses of Hybrid Anionic Surfactants Containing Fluorocarbon and Hydrocarbon Chains"Langmuir 1995,11(2):466-469.
[47].Danino,D.;Weihs,D.;Zana,R.;Oradd,G.;Lindblom,G.;Abe,M.;Talmon,Y."Microstructures in the aqueous solutions of a hybrid anionic fluorocarbon/hydrocarbon Surfactant" J.Colloid Inter Sci.2003,259(2):382-390
[48].Yoshino,N.;Kondo,Y."Hybrid fluorocarbon/hydrocarbon surfactants" Curr Opin.Colloid Inter Sci.2005,10(3-4):88-93
[49].Miyazawa,H.;Konso,Y.;yoshino,"Synthesis and Solution Properties of Sulfate-Type Hybrid Surfactants with an Ethylene Spacer" J.Oleo Sci.2005,54:167-178
[50].Omoto,N.;Nihei,T.;Kurata,Y.;Kondo,Y.;Umemoto,K.;Yoshino,N."Modification effect of novel phosphate type hybrid surfactant-modification effect of surfactants for hydroxyapatite plate" Jpn J Conserv.Dent.2005,48:128-136.
[51].Sadtler,M.V.;Kraft,P.M.;Riese,G.J."Achieving Stable,Reverse Water-in-Fluorocarbon Emulsions" Angew Chem,Int.Ed.Engl.1996,35(17):1976-7978
[52].Oda,R.;Huc,I.;Danino,D.;Talmon,Y."Aggregation Properties and Mixing Behavior of Hydrocarbon,Fluorocarbon,and Hybrid Hydrocarbon-Fluorocarbon Cationic Dimeric Surfactants" Langmuir 2000,16(25):9759-9769.
[53].Nagarajan,R."Molecular Theory for Mixed Micelles" Langmuir 1985,1(3):331-341.
[54].Clint,J.H."Micellization of mixed nonionic surface active agents" J.Chem.Soc.,Faraday Trans.I,1975,17:1327-1334.
[55].Holland,P.M.;Rubingh,D.N."Nonideal multicomponent mixed micelle model" J.Phys.Chem.1983,87(11):1984-1990.
[56].Hoffmann,H.;Possnecker,G."The Mixing Behavior of Surfactants" Langmuir 1994,10(2):381-389.
[57].Shinoda,K."Proc 4th Intern Congr Surface Active Substances".I.TH.G.Overbeek,ed.Vol 2.London & Pads:Gordon & Breach Sci.Pulb,1967,p527.
[58].Mukerjee,P.;Yang,Alex Y.S."Nonideality of mixing of micelles of fluorocarbon and hydrocarbon surfactants and evidence of partial miscibility from differential conductance data" J.Phys.Chem.1976,80(12):1388-1390.
[59].Suguhara,G."Surfactant in Solution";Mittal,K.L.,Ed.;Plenum:New York,1989;Vol.7,pp 397.
[60].Wada,Y.;Ikawa,Y.;Igimi,H.;Murata,Y.;Nagadome,S.;Sugihara,G."Mixed Micelle and Mixed Adsorbed Film Formations of Anionic Fluorocarbon-Nonionic Surfactant Mixtures:Sodium Perfluorooctanoate with MEGA-8,-9 and -10" J.Jpn.Oil Chem.Soc.Yukagaku,1990,39:548-554.
[61].Mysels,Karol J."Critical demicellization concentration?"J.Colloid Interface Sci.1978,66(2):331-334.
[62].丁慧君,陈新,赵国玺,“碳氟表面活性剂与碳氢表面活性剂混合水溶液的表面吸附与胶团形成(Ⅳ)”高校化学学报,1987,8:726-730.
[63].朱步瑶,赵国玺“关于碳氟链表面活性剂与碳氢链表面活性剂混合溶液的胶团形成”化学学报1981,6:493-496.
[64].Xiao,J.;Sivars,U.;Tjerneld,F."Phase behavior and protein partitioning in aqueous two-phase systems of cationic-anionic surfactant mixtures",J.Chromatography B 2000,743(1-2):327-333.
[65].Nilsson,S.;Blokhus,A.M.;Hellebust,S."Influence of hydrophobic cosolutes on the associative/segregative phase separation of aqueous cationic surfactant-polymer systems",Langmuir 2002,18(17):6504-6505.
[66].Allouche,J.;Tyrode,E.;Sadtler,V.;Choplin,L.;Salager,J.L."Single- and two-step emulsification to prepare a persistent multiple emulsion with a surfactant-polymer mixture",Ind.Eng.Chem.Res.2003,42(17):3982-3988.
[67].Robb,I.D.In "Anionic Surfactants Physical Chemistry of Surfactant Action";Surfactant Science series 11,E.H.L.Reynders(Eds),Marcel Dekker:New York,1981,p109-173.
[68].史立“关于碳氟链表面活性剂与碳氢链表面活性剂混合溶液的胶团形成”北京大学硕士研究生论文1984.
[69].Sesta,B.;Segre,A.L.;D'Aprano,A.;Proietti,N."~1H NMR,Surface Tension,Viscosity,and Volume Evidence of Micelle-Polymer Hydrophobic Interactions:LiPFN-PVP System" J.Phys.Chem.B 1997;101(2):198-204.
[70].Segre,A.L.;Proietti,N.;Sesta,B.;D'Aprano,A.;Amato,M.E."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies" J.Phys.Chem.B 1998,102(50):10248-10254.
[71].Stitch,H.;Willbold,D.;Ejchart,A.;Rossen-Arbesfeld.F.;Yaniv,A.;Gazit,A.;Rosch,P."Trifluoroethanol stabilizes a helix-turn-helix motif in equine infectious-anemia-virus trans-activator protein" Eur.J.Biochem 1994,225:855-861.
[72].Sesta,B.;Gente,G.;Iovino,A.;Laureti,F.;Michiotti,P.;Paiusco,O.;Palacios,A.C.;Persi,L.;Princi,A.;Sallustio,S.;Sarnthein-Graf,C.;Capalbi,A.;La Mesa,C."Supramolecular Association in the System Water-Lysozyme-Lithium Perfluorononanoate" J.Phys.Chem.B.2004;108(9):3036-3043.
[73].Messina,P.V.;Prieto,G.;Ruso,J.M.;Sarmiento,F."Conformational changes in human serum albumin induced by sodium perfluorooctanoate in aqueous solutions" J.Phys.Chem.B 2005,109(32):15566-15573.
[74].Asakawa,T.;Amada,K.;Miyagishi,S."Micellar Immiscibility of Lithium 1,1,2,2-Tetrahydroheptadecafluorodecyl Sulfate and Lithium Tetradecyl Sulfate Mixture"Langmuir 1997,13(17):4569-4573.
[75].Asakawa,T.;Shirashi,T.;Sunazaki,S.;Miyagishi,S."Critical Demicellization Concentration of Diethylammonium Perfluorononanoate and Diethylammonium Tetradecyl Sulfate Mixture in Aqueous Solution" Bull.Chem.Soc.Jpn.1995,68(9):2503-2509.
[76].Asakawa,T.;Ishikawa,K.;Miyagishi,S "Aqueous Solution Properties of Pyridinium-Type Perfluorinated Surfactants and Simulation of Mixture CMC" J.Colloid and Interfacs Sci.2001,240(1):365-367.
[77].Asakawa,T.;Miyagishi,S.;Nishida,M."Coexistence of two kinds of mixed micelles revealed by gel filtration" Langmuir 1987,3(5):821-827.
[78].Nakano,T.K.;Sugihara,G.;Nakashima,T.;Yu,S.C."Thermodynamic Study of Mixed Hydrocarbon/Fluorocarbon Surfactant System by Conductometric and Fluorimetric Techniques" Langmuir 2002,18(23):8777-8785.
[79]Sesta,B;Segre,A.L.;"~1H NMR,Surface Tension,Viscosity,and Volume Evidence of Micelle-Polymer Hydrophobic Tnteractions:LiPFN-PVP System" J.Phys.Chem.B 1997101(2):198-204.
[80].Asakawa,T.;Hisamatsu,H.;"Miyagishi,S."Micellar Pseudophase Separation Regions of ~1H,~1H,~2H,~2H-Perfluoroalkylpyridinium Chloride and Hydrocarbon Surfactants by Group Contribution Method" Langmuir 1995;11(2):478-482.
[81].Muto,Y.;Esumi,K.;Meguro,K.;Zana,R.Comments on "Pyrene fluorescence as a probe of fluorocarbon micelles and their mixed micelles with hydrocarbon surfactants" Langmuir 1989;5(3):885-886.
[82].Haegel,F.H.;Hoffmann,H."Selective incorporation of dyes with fluorocarbon and hydrocarbon chains into coexisting micellar phases of sodium perfluorooctanoate and dimethyl tetradecyl amino ixde" Prog.Colloid Polym.Sci.1988,76:132-139.
[83].Asakawa,T.;Miyagishi,S."Demicellization of Sodium Perfluorooctanoate and Dodecyl Sulfate Mixtures Revealed by Pyrene Fluorescence Quenching"Langmuir 1999,15(10):3464-3468
[84].Carlfors,J.;Stilbs,P."The composition of mixed micelles of fluorocarbon and hydrocarbon surfactants as derived from nuclear magnetic resonance self-diffusion measurements" J Phys.Chem.1984,88(19):4410-4414
[85].De Lisi,R.;Inglese,A.;Milioto,S.;Pellerito,A."Demixing of Mixed Micelles.Thermodynamics of Sodium Perfluorooctanoate-Sodium Dodecanoate Mixtures in Water"Langmuir 1997,13(2):92-202.
[86].Burkitt,S.J.;Ottewil,R.;H.;Hayter,J.B.;Ingrain,B.T."Small angle neutron scattering studies on micellar systems pan 2:Mixed systems of ammonium decanoate and ammonium perfluoro-octanoate" Colloid polym.Sci.1987,265:628-636.
[87].Clapperton,R.M.;Ottewil,R.H.;Ingrain,B.T.;"A study of fluorocarbon-hydrocarbon surface active agent mixtures by NMR spectroscopy" Langmuir 1994,10(1):51-56.
[88].Shinoda,K.;Nomura,T.;"Miscibility of fluorocarbon and hydrocarbon surfactants in micelles and liquid mixtures.Basic studies of oil repellent and fire extinguishing agents" J.Phys.Chem.1980;84(4):365-369.
[89].Caponetti,E.;Chillura Manino,D.;Floriano,M.A.;Triolo,R."Fluorinated,protonated,and mixed surfactant solutions:a small-angle neutron scattering study" Langmuir 1993,9(5):1193-1200.
[90].Pedone,L.;Chillura Martino,D.;Caponetti,E.;Floriano,M.A.;Triolo,R."Determination of the Composition of Mixed Hydrogenated and Fluorinated Micelles by Small Angle Neutron Scattering"J.Phys.Chem.B 1997,101(46):9525-9531.
[91].Amato,M.E.;Caponetti,E.;Cxhillura Martino,D.;Pedone,L."~1H and ~(19)F NMR Investigation on Mixed Hydrocarbon-Fluorocarbon Micelles" J.Phys.Chem.B.2003,107(37):10048-10056.
[92].Yekta,A.;Duhamel,J.;Brochard,P.;Adiwidjaja,H.;Winnik,M.A."A fluorescent probe study of micelle-like cluster formation in aqueous solutions of hydrophobically modified poly (ethylene oxide)" Macromolecules 1993,26(8):1829-1836.
[93].Colby,R.H.;Plucktaveesak,N.;Bromberg,L."Critcal Incorporation Concentration of Surfactants Added to Micellar Solutions of Hydrophobically Modified Polyelectrolytes of the Same Charge" Langmuir 2001,17(10):2931-2941.
[94].Griffiths,P.C.;Roe,J.A.;Bales,B.L.;Pitt,A.R.;Howe,A.M.;"Fluorescence Probe Studies of gelatin-Sodium Dodecyl Sulfate Interactions" Langmiur 2000,16(22):8248-8254.
[95].Asakawa,T.;Mouri,M.;Miyagishi,S.;Nishida,M."Probe methods for the second cmc of fluorocarbon and hydrocarbon surfactant mixtures" Langmuir 1989,5(2):43-348.
[96].Almgren,M.;Wang,K.;Asakawa,T."Fluorescence Quenching Studies of Micellization and Solubilization in Fluorocarbon-Hydrocarbon Surfactant Mixtures" Langmuir 1997,13(17):4535-4544.
[97].Asakawa,T.;Ishino,S.;Miyagishi,S.;Hansson,P.;Almgren,M.;Ohta,A.;Miyagishi,S."Appearance of Pure Fluorocarbon Micellea Surveyed by Fluorescence Quenching of Amphiphilic Quinoline Derivatives in Fluorocarbon and Hydrocarbon Surfactant Mixtures"Langmuir 2004,20(17):6998-7003.
[98].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~(19)F NMR Study of Molecular Aggregation of Lithium Perfluorooctylsulfonate in Water at Temperatures from 30 to 250℃" J Phys.Chem.B 2000,104(2):155-158.
[99].Barthelemy,P.;Tomao,V.;Selb,J.;Chaudier,Y.;Pucci,B."Fluorocarbon-Hydrocarbon Nonionic Surfactants Mixtures:A study of Their Miscibility" Langmuir 2002,18(7):2557-2563.
[100].Sesta,B;Segre,A.L."Influence of the Ploymer Molecular weight on the Surfactant-Polymer Interactions:LiPFN-PVP and SDS-PVP" Langmiur 1997,13(25):6612-6617.
[101].Segre,A.L.;Proietti,N."Supramolecular Structure of the LiPFN-PVP Systerm:~(19)F NMR Studies"J.Phys.Chem.B 1998,102(50):10248-10254.
[102].Iliopouios,I.;Furo,I."NMR Study of the Association of anionic Surfactants with an Anionic Polyelectrolyte Hydrophobically Modified with perfluorinated Side Chains" Langmuir 2001, 17(26):8049-8054.
[103].Miyazaki,M.;Torigoe,k.;Esumi,K."Interactions of Sugar Persubstituted Ploy (Amidoamine)Dendrimers with Anionic Surfactants" Langmiur 2000 16(4):1522-1528.
[104].Miller,R.;Fainerman,V.B.;Makievski,A.V.;Kragel,J.;Grigoriev,D.O.;Kazakov,V.N.;Sinyachenko,O.V."Dynamics of protein and mixed protein/surfactant adsorption layers at the water/fluid interface".Adv.Colloid Interface Sci.,2000,86:39-82.
[105].(a)吴丹,徐桂英“光谱法研究蛋白质与表面活性剂的相互作用”物理化学学报,2006,22(2):254-260.
(b)吴丹,徐桂英.“阳离子型Gemini表面活性剂与蛋白质的相互作用”山东大学博士学位论文2007,Chap.5-6.
[106].Moren,A;Regav,O.;Khan,A."A Cryo-TEM Study of Protein-Surfactant Gels and Solutions" J.Colloid Interface Sci.2000;222(2):170-178.
[107].(a)Provencher,S.W."A fourier method for the analysis of exponential decay curves"Biophy.J.1976,16(1),27-41.
(b)Provencher SW."An eigenfunction expansion method for the analysis of exponential decay curves".J.Chem.Phys.1976,64(7):2772-2777.
[108].Jansson,J.;Schillen,K.;Olofsson,G.;Cardoso da Silva,C.R.;Loh,W."The Interaction between PEO-PPO-PEO Triblock Copolymers and Ionic Surfactants in Aqueous Solution Studied Using Light Scattering And Calorimetry" J.Phys.Chem.B 2004,108(1):82-92.
[109].Cardoso da Silva,C.R.;Olofsson,G.;Schillen,K.;Loh,W."Influence of Ionic Surfactants on the Aggregation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide)Block Copolymers Studied by Diffrential Scanning and Isothermal Titration Calorimetry" J.Phys.Chem.B 2002,106(6):1239-1246.
[110].Jansson,J.;Schillen,K.;Nilsson,M.;Soderman,O.;Fritz,G.;Bergmann,A.;Glatter,O."Small-Angle X-ray Scattering,Light Scattering,and NMR Study of PEO-PPO-PEO Triblock Copolymer/Cationic Surfactant Complexes in Aqueous Solution" J.Phys.Chem.B 2005,109(15):7073-7083.
[111].Matsuoka,K.;Yoshimura,T.;Shikimoto,T.;Hamada,J.Yamawaki,M.;Honda,C.;Endo,K."Molecular Aggregates of Partially Fluorinated Quaternary Ammonium Salt Gemini Surfactants" Langmiur 2007,23(22):10990-10994.
[112].Buhler,E.;Oelschaeger,C.;Waton,G.;Candau,S.J."Viscoelastic Properties of Hydrocarbon/Fluorocarbon Mixed Wormlike Micelles at High Ionic Strengh" J.Phys.Chem.B 2004,108(30):11236-11243
[113].Li,X.;Dong,S.L.;Jia,X.F.;Song,A.X.;Hao,J.C."Vesicles of a New Salt-Free Cat-anionic Fluoro/Hydrocarbon Surfactant System" Chem.Eur J.2007,13(34):9495-9502
[1].Abe,M."Synthesis and applications of surfactants containing fluorine" Curr.Opin.Colloid Inter.Sci.1999,4(5):354-356
[2].Chang,T.M.S."Blood Substitutes";Geyer,R.P.(Eds),Marcel Dekker:New York,1959,pp421-438.
[3].Kraft,M.P.;Riess,J.G."Highly fluorinated amphiphiles and colloidal systems,and their applications in the biomedical field.A contribution" Biochimie 1998,80(5-6):489-514.
[4].Kissa,E."In Fluorinated surfactants,synthesis,properties,applications;Surfactant" Science Series 50;Kissa,E.Ed.;Marcel Dekker:New York,1994;Chap.8,p325.
[5].(a)Eastoe,J.;Cazelles,B.M.H.;Steyteler,D.C.;Holmes,J.D.;Pitt,A.R.;Wear,T.J.;Heenan,R.K."Water-in-CO_2 Microemulsions Studied by Small-Angle Neutron Scattering"Langmuir;1997,13(26):6980-6984.
(b)Eastoe,J;Downer,A.;Paul,A.;Steytler,D.C.;Rumsey,E.;Penfold,J.;Heenan,R.K."Fluoro-Surfactants At Air/Water And Water/CO_2Interfaces." PhysChemChemPhys 2000,2:5236-5242
[6].Oda,R.;Huc,I.;Danino,D.;Talmon,Y."Aggregation Properties and Mixing Behavior of Hydrocarbon,Fluorocarbon,and Hybrid Hydrocarbon-Fluorocarbon Cationic Dimeric Surfactants" Langmuir;2000;16(25):9759-9769.
[7].郝京诚,汪汉卿,鲁润华,“微乳液相行为和微观结构研究”,中国科学B 27(2),1997,131-139.
[8].Hoffmann,H.;Würtz,J."Unusual phenomena in perfluorosurfactants" J.Mol.Liq.1997,72(1-3):191-230.
[9].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~1H and ~(19)F NMR study of the Counter-ion Effect on the Micellar Structures Formed by Tetraethylammonium and Lithium Perlfuorooctylsulfonates.1.Neat Systems" J.Phys.Chem.B;1999,103(39):8251-8258.
[10].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~(19)F NMR Study of Molecular Aggregation of Lithium Perlfuorooctylsulfonate in Water at Temperature from 30 to 250℃" J.Phys.Chem.B;2000,104(2):155-158.
[11].Bossev,D.P.;Matsumoto,M.;Nakahara,M."~1H and ~(19)F NMR Study of the Counterion Effect on the Micellar Structures Formed by Tetraethylammonium and Lithium Perfluorooctylsulfonates.2.Mixed Systems" J.Phys.Chem.B;1999,103(39):8259-8266.
[12].Monduzzi,M.J."self-assembly in fluorocarbon surfacant systems" Curr.Opin.Colloid Interface Sci.1998,3:467-477.
[13].Matos,L.;Ravey,J.C.;Serratrice,G."Surface tension properties of aqueous new nonionic fluorinated surfactants" J.Colloid Interface Sci.1989,128:341-347..
[14].Ravey,J.C.;Stebeb,M.J."Properties of fluorinated non-ionic surfactant-based systems and comparison with non-fluorinated systems" Colloids Surf.A 1994,84(1):11-31.
[15].Ravey,J.C.;Ghebi,A.;Stebeb,M."Comparative study of fluorinated and hydrogenated nonionic surfactants.I.Surface activity properties and critical concentrations" J.Prog Colloid Polym.Sci.1988,76:234-241.
[16].Asakawa,T.;Hisamatsu,H.;"Miyagishi,S."Micellar Pseudophase Separation Regions of ~1H,~1H,~2H,~2H-Perfluoroalkylpyridinium Chloride and Hydrocarbon Surfactants by Group Contribution Method" Langmuir;1995;11(2):478-482.
[17].(a)Nagai,K.;Esumi,K."Interaction between cationic fluorocarbon surfactant and polyoxyethylated surfactants having a sulfate group" Colloids Surfaces A:Physicochem.Eng.Aspects 1995,94:97-105.
(b)"Interaction of fluorocarbon modified poly(acrylic acid)with a cationic fluorocarbon surfactant" Colloids Surfaces A:Physicochem.Eng.Aspects 2003,213:271-278.
(c)Takasugi,K.;Esumi,K."Micellar Surface Charge Modification for Regular Solution Theory:Application to Mixed System of Cationic Fluorocarbon-Nonionic Hydrocarbon Surfactants" J.Phys.Chem.B 1996,100:18802-18807.
[18].Kadi,M.;Dvinskikh,S.V.;Furo,I.Almgren,M."Molecular Mechanism of Lateral Diffusion of Fluorosurfactants.A ~(19)F NMR Study" Langmuir;2002;18(12):5015-5018.
[19].Kadi,M.;Hansson,P.;Almgren,M.;Furo,I."Demixing of Fluorinated and Hydrogenated Surfactants into Distinct Aggregates and into Distinct Regions within Aggregates.A Combined NMR,Fluorescence Quenching,and Cryo-TEM Study" Langmuir;2002;18(24):9243-9249.
[20].Hoffmann,H.;Kalus,J.;Thur,H."Small angle neutron scattering measurements on micellar solutions of perfluor detergents" Colloid Poly.Sci.1983,261:1043-1049.
[21].Burkitt,S.J.;Ottewill,R.;H.;Hayter,J.B.;Ingram,B.T."Small angle neutron scattering studies on micellar systems part 1.Ammonium octanoate,ammonium decanoate and ammonium perfluoroocatanoate" J.Colloid Inter Sci.1987,265(7):619-627.
[22].Esumi,K."Mixed micelles involving a cationic fluorocarbon surfactant" Colloids Surf.A 1994,84(1):49-57.
[23].Mukerjee,P."Fluorocarbon-hydrocarbon interactions in micelles and other lipid assemblies,at interfaces,and in solutions" Colloids and Surfaces A." Physicochemical and Engineering Aspects 1994,84(1):1-10
[24].Holland,P.M.;Rubingh,D.N."Nonideal multicomponent mixed micelle model" J Phys.Chem.1983,87(11):1984-1990...
[25].Asakawa,T.;Amada,K.;Miyagishi,S."Micellar Immiscibility of Lithium 1,1,2,2-Tetrahydroheptadecafluorodecyl Sulfate and Lithium Tetradecyl Sulfate Mixture"Langmuir;1997;13(17):4569-4573.
[26].Asakawa,T.;Shirashi,T.;Sunazaki,S.;Miyagishi,S."Critical Demicellization Concentration of Diethylammonium Perfluorononanoate and Diethylammonium Tetradecyl Sulfate Mixture in Aqueous Solution" Bull.Chem.Soc.Jpn.1995,68(9):2503-2509.
[27].Asakawa,T.;Ishikawa,K.;Miyagishi,S."Aqueous Solution Properties of Pyridinium-Type Perfluorinated Surfactants and Simulation of Mixture CMC" J.Colloid and Interfacs Sci.2001,240(1):365-367.
[28].Asakawa,T.;Ishino,S.;Miyagishi,S.;Hansson,P.;Almgren,M.;Ohta,A.;Miyagishi,S."Appearance of Pure Fluorocarbon Micellea Surveyed by Fluorescence Quenching of Amphiphilic Quinoline Derivatives in Fluorocarbon and Hydrocarbon Surfactant Mixtures"Langmuir,2004,20(17):6998-7003.
[29].Barthelemy,P.;Tomao,V.;Selb,J.;Chaudier,Y.;Pucli,B."Fluorocarbon-Hydrocarbon Nonionic Surfactants Mixtures:A Study of Their Miscibility" Langmiur;2002;18(7):2557-2563
[30].Nakagawa,T.;Tokiwa,F."In Surface and Colloid Science";Matijevic,E.,Ed.;John Wiley &Sons:New York,1969;Vol.9:p69.
[31].Pople,J.A.;Schneide,W.E.G.;Bernstein,H.J."High-resolution Nuclear Magnetic Resonance";McGraw-Hill:New York,1959,pp98,119-123.
[32].Antalek,B.;Kowalczyk,J.;Chari,K."Interaction of Vinyl Pyrrolidone and Vinyl Acetate Copolymer with Surfactants" Langmur;2004;20(26):11818-11820.
[33].(a)Muller,N.;Birkhahn,R.H."Investigation of micelle structure by fluorine magnetic resonance.I.Sodiuml0,10,10-trifluorocaprate and related compounds" J.Phys.Chem.1967,71(4):957-962.
(b)Muller,N.;Birkhahn,R.H."Investigation of micelle structure by fluorine magnetic resonance.Ⅱ.Effects of temperature changes,added electrolyte,and counterion size" J.Phys.Chem.1968,72(2):583-588.
(c)Guo,W.;Brown,T.A.;Fung,B.M."Micelles and aggregates of fluorinated surfactants" J.Phys.Chem.1991,95(4):1829-1836.
(d)Iijima,H.;Koyama,S.;Fujio,K.;Uzu,Y."NMR Study of the Transformation of Perfluorinated Surfactant Solutions" Bull.Chem.Soc.Jpn.1999,72(2):171-177.
[34].Segre,A.;Proietti,N."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies" J.Phys.Chem.B;1998;102(50):10248-10254.
[35].Mazer,N.A.;Benedeck,G B.;Carey,M.C."An investigation of the micellar phase of sodium dodecyl sulfate in aqueous sodium chloride solutions using quasielastic light scattering spectroscopy"J.Phys.Chem.1976,80(10):1075-1085.
[36].Israelachvili,J.N.,Mitchell,D.J.,Ninham,B.W.,"Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers" J.Chem Soc.Faraday Trans Ⅱ,1976,72: 1525-1568.
[37].Dill,K.A.;Flory,P."Molecular Organization in Micelles and Vesicles" J.Proc.Nat.Acad.Sci.1981 78:676-680
[38].(a)Nakano,T.Y.;Sugihara,G.;Nakashima,T.;Yu,S.C."Thermodynamic Study of Mixed Hydrocarbon/Fluorocarbon Surfactant System by Conductometric and Fluorimetric Techniques" Langmuir;2002;18(23):8777-8785.
(b)Mukerjee,P.;Korematsu,K.;Sugihara,G."Effect of temperature on the electrical conductivity and the thermodynamics of micelle formation of sodium perfluorooctanoate" J.Phys.Chem.1985,89(24):5308-5312.
[39].Wang,K.;Karlson,G.;Alngren,M."Aggregation Behavior of Cationic Fluorosurfactants in Water and Salt solutions A CryoTEM Survey" J.Phys.Chem.B;1999;103(43):9237-9246.
[40].(a)Fujiwara,M,;Okano,T.;Nakashima,T.H.;Nakamura,A.A.;Sugihara,G."A temperature study on critical micellization concentration(CMC),solubility,and degree of counter-ion binding of α-sulfonatomyristic acid methyl ester in water by electroconductivity measurements" Colloid Polym.Sci.1997,275(5):474-478.
(b)Nakamura,A.A.;Okano,Lee,S.;Sugihara,G."On Micelle Formation and Degree of Countefion Binding of α-Sulfonatomyristic Acid Ethyl Ester in Water:A Study Performed by Comparing with α-Sulfonatomyristic Acid Methyl Ester" J.Surf.Sci.Technol.1998,14:23-30.
[41].赵国玺,朱荹瑶,表面活性剂作用原理,中国轻工业出版社,北京,2003,Chap.15.
[1].Abe,M."Synthesis and applications of surfactants containing fluorine" Curr Opin.Colloid Inter.Sci.1999,4(5):354-356
[2].(a)Eastoe,J.;Cazelles,B.M.H.;Steyteler,D.C.;Holmes,J.D.;Pitt,A.R.;Wear,T.J.;Heenan,R.K."Water-in-CO_2 Microemulsions Studied by Small-Angle Neutron Scattering"Langmuir;1997,13(26):6980-6984.
(b)Eastoe,J;Downer,A.;Paul,A.;Steytler,D.C.;Rumsey,E.;Penfold,J.;Heenan,R.K."Fluoro-Surfactants at Air/Water and Water/CO_2Interfaces." PhysChemChemPhys 2000,2:5236-5242
[3].(a)Chang,T.M.S.;Geyer,R.P."Blood Substitutes",Marcel Dekker:New York,1989,pp98,119-128.
(b)Riess,J.G."Blood substitutes:the fluorocarbon approach".Encyclopedia of Pharmaceutical Technology 《New York:Marcel Dekker》 2002,pp263-79.
[4].Krafft,M.P.;Riess,J.G."Highly fluorinated amphiphiles and colloidal systems,and their applications in the biomedical field.A contribution" Biochimie;1998,80(5-6):489-514.
[5].Kissa,E.In "Fluorinated surfactants,synthesis,properties,applications",Surfactant Science Series 50;Kissa,E.Ed.;Marcel Dekker:New York,1994;Chap.8,p325.
[6].赵国玺,朱荹瑶,表面活性剂作用原理,中国轻工业出版社,北京,2003,Chap.15.
[7].Sun,H.;Xu,G.;Li,Y.;Chen,Y.J "Mesoseopic simulation of the aggregation behavior of fluorinated surfactant in aqueous solution" Fluorine Chem.2006,127(2):187-192.
[8].Funasaki,N.In "Mixed Surfactant Systems";Ogino,K.,Abe,M.,Eds.;Surfactant Science Series 46;Marcel Dekker:New York,1993;pp145.
[9].Barthelemy,P.;Tomao,V.;Selb,J.;Chaudier,Y.;Pucli,B."Fluorocarbon-Hydrocarbon Nonionic Surfactants Mixtures:A study of Their Miscibility" Langmiur;2002;18(7):2577-2581.
[10].Amato,M.E.;Caponetti,D.;Chillura,M.;Pedone,L."~1H and ~(19)F Investigation on Mixed Hydrocarbon-Fluorocarbon Micelles" J.Phys.Chem.B;2003;107(37):10048-10056
[11].Knodo,Y.;Yoshino,N."Hybrid fluorocarbon/hydrocarbon surfactants" Curr Opin Colloid Inter.Sci.2005,10(3-4):88-93.
[12].Mukerjee,P.;Yang,Alex Y.S."Nonideality of mixing of micelles of fluorocarbon and hydrocarbon surfactants and evidence of partial miscibility from differential conductance data"JPhys.Chem.1976,80(12):1388-1390.
[13].Mysels,K.L."Critical demicellization concentration?" J Colloid interface Sci.1978,66(2):331-334.
[14].Haegel,F.H.;Hoffmann,H."Selective incorporation of dyes with fluorocarbon and hydrocarbon chains into coexisting micellar phases of sodium perfluorooctanoate and dimethyl tetradecyl aminoxide" Prog.Colloid Polym.Sci.1988,76:132-139.
[15].Askawa,T.;Miyagishi,S.;Nishida,M."Coexistence of two kinds of mixed micelles revealed by gel filtration" Langmuir 1987,3(5);821-827.
[16].Askawa,T.;Amada,K.;Miyagishi,S."Micellar Immiscibility of Lithium 1,1,2,2-Tetrahydroheptadecafluorodecyl Sulfate and Lithium Tetradecyl Sulfate Mixture"Langmiur;1997;13(17):4569-4573
[17].Askawa,T.;Miyagishi,S."Demicellization of Sodium Perfluorooctanoate and Dodecyl Sulfate Mixtures Revealed by Pyrene Fluorescence Quenching" Langmuir;1999;15(10):3464-3468.
[18].Asakawa,T.;Ishino,S.;Hansson,P.;Almgren,M.;Ohta,A.Miyagishi,S."Appearance of Pure Fluorocarbon Micelles Surveyed by Fluorescence Quenching of Amphiphilic Quinoline Derivatives in Fluorocarbon and Hydrocarbon Surfactant Mixtures" Langmuir;2004;20(17):6998-7003.
[19].(a)Asakawa,T.;Imae,T.;Ikeda,S.;Miyagishi,S.;Nishida,M.;"Hydrogen-1 NMR self-diffusion study for mixed micelles of fluorocarbon and hydrocarbon surfactants"Langmuir;1991,7(2):262-266.
(b)Kondo,Y.;Miyazawa,H.;Sakai,H.;Abe,M.;Yoshino,N."First Anionic Micelle with Unusually Long Lifetime:Self-Assembly of Fluorocarbon-Hydrocarbon Hybrid Surfactant" J.Am.Chem.Soc.;2002;124(23):6516-6517.
(c)Oda,R.;Huc,I.;Danino,D.;Talmon,Y."Aggregation Properties and Mixing Behavior of Hydrocarbon,Fluorocarbon,and Hybrid Hydrocarbon-Fluorocarbon Cationic Dimeric Surfactants" Langmuir;2000;16(25):9759-9769
[20].Song,A.;Dong,S.;Hao,J.;Liu,W.;Xu,G.;Wang,H.;"Functions of fluomsurfactants 1:Surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant" J.Fluorine Chem.2005,126(9):1266-1273.
[21].Dong,S.L.;Li,X.;Xu,G.Y.;Hoffman,H."A Cationic Fluorocarbon Surfactant DEFUMAC1and Its Mixed Systems with Cationic Surfactants:~(19)F NMR and Surface Tension Study" J.Phys.Chem.B;2007;111(21):5903-5910.
[22].Kadi,M.;Hansson,P.;Almgren,M."Mixed Micelles of Fluorocarbon and Hydrocarbon Surfactants.A Small Angle Neutron Scattering Study" Langmuir;2004;20(10):3933-3939.
[23].Almgren,M.;Garamus,V.M."Small Angle Neutron Scattering Study of Demixing in Micellar Solutions Containing CTAC and a Partially Fluorinated Cationic Surfactant" J.Phys.Chem.B;2005;109(22):11348-11353
[24].Shinoda,K.;Nomura,T."Miscibility of fluorocarbon and hydrocarbon surfactants in micelles and liquid mixtures.Basic studies of oil repellent and fire extinguishing agents" J.Phys.Chem.1980,84(4):365-369.
[25].Ceponetti,E.;Chillura Martino D.;Floriano,M.A.Triolo,R."Fluorinated,protonated,and mixed surfactant solutions:a small-angle neutron scattering study" Langmuir,1993,9(5):1193-1200.
[26].Pedone,L.;Chillura Martino,D.;Caponetti,E.;Floriano,M.A.;Triolo,R."Determination of the Composition of Mixed Hydrogenated and Fluorinated Micelles by Small Angle Neutron Scattering" J Phys.Chem.B;1997;101(46):9525-9531.
[27]Jung,H.T.;Lee,S.Y.;Kaler,E.W.;Coldren,B.;Zasadzinski,J.A."Gaussian curvature and the equilibrium among bilayer cylinders,spheres,and discs" PNAS 2002,99:15318-15322.
[28].Li,X.;Dong S.;Jia,X.;Song,A.;Hao,J."Vesicles of a New Salt-Free Catanionic Fluoro-Hydrocarbon Surfactant System" Chem.Eur J.2007,13(34):9495-9502.
[29].Segre,A.;Proietti,N."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies"J.Phys.Chem.B;1998;102(50):10248-10254.
[30].Bossev,D.P.;Mustumoto,M.;Nakahara,M."~(19)F NMR Study of Molecular Aggregation of Lithium Perfluorooctylsulfonate in Water at Temperatures from 30 to 250℃"J Phys.Chem.B;2000;104(2):155-158
[31].Sesta,B.;Gente,G.;Iovino,A.;lauret,F.;Michiotti,P.;Paiusco,O.;Palacios,A.C.;Persi,L.;Princi,A.;Sallustio,S."Supramoleeular Association in the System Water-Lysozyme-Lithium Perfluorononanoate" J.Phys.Chem.B;2004;108(9):3036-3043
[32].Robayashi,F.;Yoshimura,T.;Esumi,K."Interactions of fluorocarbon-modified poly(acrylic acid)with a cationic fluorocarbon surfactant" Colloids Sur.A:Physicochem.Eng.Aspects 2003,214(3):271-278.
[33].Nagai,K.;Esumi,K."Interaction between cationic fluorocarbon surfactant and polyoxyethylated surfactants having a sulfate group" Colloids Sur.A:Physicochem.Eng.Aspects 1995,94(1):97-105.
[34].Li,Y.;Li,P.;Wang,J.;Wang,Y.;Yan,H.;Dong,C.;Thomas,R.K."Thermodynamics of micellization for partially fluorinated cationic gemini surfactants and related single-chain surfactants in aqueous solution" J.Colloid Inter.Sci.2005,287(1):333-337.
[35].Asakawa,T.;Miyagishi,S.;Nishida,M."Fluorine nuclear magnetic resonance of fluorocarbon and hydrocarbon surfactant mixtures" J.Colloid Inter.Sci.1985,104(1):279-281.
[36].Clapperton,R.M.;Ottewill,R.H.;Ingram,B.T."A study of fluorocarbon-hydrocarbon surface active agent mixtures by NMR spectroscopy" Langmiur 1994,10(1):51-56.
[37].Guo,W.;Guzman,E.K.;Heavin,S.D.;Li,Z.;Fung,B.M.;Christian,S.D."Mixed surfactant systems of sodium perfluorooctanoate with nonionic,zwitterionic,and cationic hydrocarbon surfactants" Langmiu;1992,8(10):2368-2375.
[38].Suguhara,G."Surfactant in Solution";Mittal,K.L.Ed.;Plenum:New York,1989;Vol.7,pp 397.
[39].朱步瑶,赵国玺“关于碳氟链表面活性剂与碳氢链表面活性剂混合溶液的胶团形成”化学学报.1981,6:493-496.
[40].Shinoda,K.;Nomura,T."Miscibility of fluorocarbon and hydrocarbon surfactants in micelles and liquid mixtures.Basic studies of oil repellent and fire extinguishing agents" J.Phys.Chem.1980,84(4):365-369.
[41].(a)Li,F.;Rosen,M.J.;Sulthana,S.B."Surface Properties of Cationic Gemini Surfactants and Their Interaction with Alkylglucoside or -maltoside Surfactant" Langmuir;2001;17(4):1037-1042.(b)Zhao,G.-X.;Ding,F.-X.;and Zhu,B.-Y."Surface-chemical study of an aqueous mixture of α-sulfolauric acid salts with cationics" Colloids Surf.A,1998,132(1):1-7.(c)Siddiqui,F.A.;Franses,E.I."Equilibrium.Adsorption and Tension of Binary Surfactant Mixtures at the Air/Water Interface" Langmuir;1996;12(2):354-362.(d)Zhou;Q.;Rosen,M.J."Molecular Interactions of Surfactants in Mixed Monolayers at the Air/Aqueous Solution Interface and in Mixed Micelles in Aqueous Media:The Regular Solution Approach" Langmuir;2003;19(11):4555-4562.
[42].Unpublished data,Bayreuth University,1989.
[1].Hamley,I.W.ed."Developments in Block Copolymer Science and Technology",Publisher:John Wiley & Sons,2004
[2].Zheng,Y.;Davis,H.T."Mixed micelles of nonionic surfactants and uncharged block copolymers in aqueous solutions:microstructure seen by cryo-TEM" Langmuir;2000;16(16);6453-6459.
[3].Egger,H.;Nordskog,A.;Lang,P.;Brandt,A.;"Shape transformation of poly (butadiene)-b-poly(ethyleneoxide)plus DTAB compound micelles in aqueous solutions"Macromol.Symp.2000,162(1),291-302.
[4].Henze,H.P.;Kramer,E.;Berton,B.;Forster,S.;Antonietti,M.;Dreja,M."Lyotropic mesophases of PB-PEO diblock copolymers and their cross-linking to generate ordered gels",Macromolecules;1999;32(18);5803-5809.
[5].Sumeet Jain and Frank S.Bates,"On the origins of morphological complexity in block copolymer surfactants",Science 2003,300(5618),460-464.
[6].Katakam,M.;Bell,L.N.;Banga,A.K."Effect of surfactants on the physical stability of recombinant human growth hormone",J.Pharm.Sci.1995,84(6),713-716.
[7].Nostrum,van C.F."Polymeric micelles to deliver photosensitizers for photodynamic therapy"Adv.Drug Delivery Rev.2004,56(1),9-16.
[8].Kabanov,A.V.;Batrakova,E.V.;Miller,D.W."Pluronic(?)block copolymers as modulators of drug efflux transporter activity in the blood-brain barrier" Adv.Drug Delivery Rev.2003,55(1),151-164.
[9].Pinho,M.E.N.;Costa,F.D.M.L.;Filho,F.B.S.;Ricardo,N.M.P.S.;Yeates,S.G.;Attwood,D.;Booth,C."Mixtures of triblock copolymers E62P39E62 and E137S18E137 Potential for drug delivery from in situ gelling micellar formulations" Int.J.Pharm.2007,328,95-98.
[10].Chu,B.;Zhou,Z."Nonionic Surfactants:Polyoxyalkylene Block Copolymers":Nace,V.M.,Ed.;Marcel Dekker:New York,1996,Chapter 3.
[11].Wu,G.;Liu,T.;Chu,B.Schneider,D.K.Graziano,V."Characterization of the PEO-PPO-PEO Triblock Copolymer and Its Application as a Separation Medium in Capillary Electrophoresis" Macromolecules;1997;30(16);4574-4583.
[12].Jansson,J.;Schillen,K.;Nilsson,M.;Soderman,O.;Fritz,G.Bergmann,A.;Glatter,O."Small-Angle X-ray Acattering,Light Scattering,and NMR Study of PEO-PPO-PEO Triblock Coploymer/Cationic Surfactant Complexes in Aqueous Solution" J.Phys.Chem.B.2005,109,7073-7083.
[13].Alexandridis,P.;Holzwartch,J.F.;Hatton,T.A."Micellization of Poly(ethylene oxide)-Poly(propylene oxide)-Poly(ethylene oxide)Triblock Copolymers in Aqueous Solutions:Thermodynamics of Copolymer Association" Macromolecules 1994,27(9);2414-2425.
[14].Wanka,G;Hoffman,H.;Ulbricht,W."Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene)Triblock Copolymers in Aqueous Solutions" Macromolecules 1994,27(15);4145-4159.
[15].Dai,S.;Tam,K.C.;Li,L."Isothermal Titrition Calorimetric Studies on Interactions of lonic Surfactant and Poly(oxylpropylene)-Poly(oxyethylene)-Poly(oxypropylene)Triblock Copolymers in Aqueous Solutions" Macromolecules;2001;34(20);7049-7055.
[16].Ma,J.;Gao,C.Tang,Y.;Liu,H."~1H NMR Spectroscopic Investigations on the Miceilization and Gelation of PEO-PPO-PEO Block Coploymers in Aqueous solutios" Langmiur;2007;23(19);9596-9605
[17].Ma,J.H.;Gao,C.Tang,Y.L.;Xiang,J.F.;Chen,S.;Wang,J.;Liu,H.Z."Micellization in aqueous solution of an ethelene oxide-propylene oxide triblock copolymer,investigated with ~1H NMR spectroscopy,pulsed-field gradient NMR,and NMR relaxation" J.Colloid Interface Scie.2007,312(2),390-396.
[18].Chu,B."Structure and Dynamics of Block Copolymer Colloids" Langmiur 1995,11(2);414-421.
[19].Zhang,Z.Q.;Xu,G.Y.;Wang,F.;Dong,S.L.;Chen,Y-L."Demulsification by amphiphilic dendrimer copolymers" J.Colloid Inter.Sci.2005,282(1),1-4.
[20.]Dong,S.L.;Li,X.;Xu,G.Y.;Hoffman,H."A Cationic Fluorocarbon Surfactant DEFUMACl and Its Mixed Systems with Cationic Surfactants:~(19)F NMR and Surface Tension Study" J Phys.Chem.B;2007;111(21);5903-5910.
[21].Seng,W.P.;Tam,K.C.Jenkins,R.D.Bassett,D.R."Calorimetric Studies of Model Hydrophobically Modified Alkali-Soluble Emulsion Polymers with Varying Spacer Chain Length in Ionic Surfactant Solutions" Macromolecules;2000;33(5);1727-1733.
[22].Seng,W.P.;Tam,K.C.Jenkins,R.D.Bassett,D.R."Model Alkali- Soluble Associative (HASE)Polymers and Ionic Surfactant interaction Examined by Isothermal Titration Calorimetry "Langmuir,2000,16(5),2151-2156.
[23].(a)Bloor,D.M.;Li,Y.;Wyn-Jone,E."Binding of Sodium Alkyl Sulfates to a Polymer Labeled with a Covalently Bonded Solvatochromic Probe" Langmuir 1995,11(10);3778-3781.(b)Bloor,D.M.;Wan-Yunus,W.M.Z.;Wan-Badhi,W.A.;Li,Y.;Holzwarth,J.F.;Wyn-Jones,E."Equilibrium and Kinetic Studies Associated with the Binding of Sodium Dodecyl Sulfate to the Polymers Poly(propylene oxide)and Ethyl(hydroxyethyl)cellulos"Langrnuir 1995,11(9);3395-3400.(c)Ghoreishi,S.M.;Li,Y.;Bloor,D.M.;Warr,J.;Wyn-Jones,E."Electromotive Force Studies Associated with the Binding of Sodium Dodecyl Sulfate to a Range of Nonionic Polymers" Langmuir;1999;15(13);4380-4387.(d)Ghoreish,S.M.;Fox,G.A.;Bloor,D.M.;Holzwarth,J.F.;Wyn-Jones,E."EMF and Microcalorimetry Studies Associated with the Binding of the Cationic Surfactants to Neutral Polymers"Langmuir;1999;15(17);5474-5479
[24].Berraou,M.Bales,B.Zana,R."Effect of the Nature of the counterion on the interaction between cesium and tetraalymmonium dodecylsulfates and poly(ethylene oxide)or poly(v0nylprolidone)",J.Colloid Inter.Sci.2003,267(2),519-523.
[25].Ortana,O.;D'Errica,G.;Paduano,L.;Vitagliano,V."Interaction of cationic,anionic,and non-ionic surfactants with ABA block copolymer Pluronic PE6200 and with BAB reverse block copolymer Pluronic 25R4" J.Colloid Interface Sci.2006,31,63-77.
[26].Almgren,M.;Van,Stam,J.;Lindbald,C.;Li,P.;Stilbs,P.Bahadur,P."Aggregation of poly (ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide)triblock copolymers in the presence of sodium dodecyl sulfate in aqueous solution" J.Phys.Chem.1991,95(14);5677-5684.
[27].Desai,P.R.;Jain,N.j.;Sharma,R.K.;Bahadur,P."Effect of additives on the mieellization of PEO/PPO/PEO block copolymer F127 in aqueous solution" Colloid Surf.A 2001,178(2),57-69.
[28].Hecht,E.;Hoffmann,H.;"Interaction of ABA block copolymers with ionic surfactants in aqueous solution" Langmuir 1994,10(1);86-91.
[29].Hecht,E.;Mortensen,H.;Gradzielski,M.;Hoffmann,H."Interaction of ABA Block Copolymers with Ionic Surfactants:Influence on Micellization and Gelation" J.Phys.Chem.1995,99(13);4866-4874.
[30].Thurn,T.;Couderc,S.;Sidhu,J.;Bloor,D.M.;Penfold,J.;Holzwarth,J.F.;Wyn-Jones,E."Study of Mixed Micelles and Interaction Parameters for ABA Triblock Copolymers of the Type EOm-POn-EOm and Ionic Surfactants:Equilibrium and Structure" Langmuir;2002;18(24);9267-9275
[31].(a)Li,Y.;Xu,R.;Couderc,S.;Bloor,D.M.;Holzwaeth,J.F.;Wyn-Jones,E."Binding of Tetradecyltrimethylammonium Bromide to the ABA Block Copolymer Pluronic F127(EO97PO69 EO97):Electromotive Force,Microcalorimetry,and Light Scattering Studies"Langmuir;2001;17(19);5742-5747.(b)Li,Y.;Xu,R.;Couderc,S.;Bloor,D.M.;Wyn-Jones,E.Holzwaeth,J.F.;"Binding of Sodium Dodecyl Sulfate(SDS)to the ABA Block Copolymer Pluronic F 127(EO_(97)PO_(69)EO_(97)):F127 Aggregation Induced by SDS" Langmuir 2001,17(1);183-188.(c)Li,Y.;Xu,R.;Couderc,S.;Bloor,D.M.;Holzwaeth,J.F.; Wyn-Jones,E."The Binding of Sodium Dodecyl Sulfate to the ABA Block Copolymer Pluronic F127(EO_(97)PO_(69)EO_(97)):An Electromotive" Force,Microcalorimetry,and Light Scattering Investigation" Langmuir;2000;16(26);10515-10520.
[32].Kobayashi,F.;Yoshimura,T.;Esumi,K."Interactions of Fluorocarbon-modified poly(acryl acid)with a cationic fluorocarbon surfactant" Colloids and Surfaces A:Physicochem.Eng.Aspects 2003,214(1),271-278.
[33].Segre,A.L.;Proietti,N.;Sesta,B.D'Aprano,A."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies" J.Phys Chem.B;1998;102(50);10248-10254.
[34].Sesta,B.;Segre,A.L.;D'Aprano,A.;Proitti,N."~1H NMR,Surface Tention,Viscosity,and Volune Evidence of Micelle-Polymer Hydrophobic Interactions:LiPFN-PVP System" J.Phys.Chem.B;1997;101(2);198-204.
[35].Sesta,B.;D'Aprano,A.;Segre,A.L.;Proitti,N."Influence of the Polymer Molecular Weight on the Surfactant-Polymer Interactions:LiPFN-PVP and SDS-PVP Systems" Langmuir;1997;13(25);6612-6617
[36].Jeong,S.W.;An,Y.J."Interaction of Perfluorinated Surfactant with Polycyclic Aromatic Hydrocarbons:Critical Micelle Concentration and Solubility Enhancement Measurements" J.Colloid Interface Sci.2001,242(2),419-424.
[37].赵国玺,朱荹瑶,“表面活性剂作用原理”,中国轻工业出版社,北京,2003,Chap.15.
[38].Gianni,P.;Bernazzani,L.;Carosi,R.;Mollica,V."Micellization of Lithium Perfluoroheptanoate and Its Aggregation on Poly(ethylene glycol)Oligomers in Water"Langmiur 2007,23,8752-8759.
[39].Goddard,E.D.In "Interactions of Surfactants with Polymers and protein";Goddard,E.D.,Ananthapadmanabhan,K.P.,Eds.;CRC Press:Boca Raton,FL,1993.
[40].董姝丽,徐桂英“聚合物/表面活性剂相互作用、相行为及有序聚集体研究” 山东大学硕士论文 2004,第四章,
[41].(a)Provencher,S.W."A fourier method for the analysis of exponential decay curves" Biophy.J.1976,16(1):27-41.(b)Provencher S.W."An eigenfunction expansion method for the analysis of exponential decay curves".J.Chem.Phys.1976;64(7):2772-2777.
[42].Menger,F.M.;Keiper,J.S."Gemini surfactants" Angew.Chem.Int.Ed.,2000,39:1906-1920.
[43].Zana,R."Dimedc and oligomeric surfactants.Behavior at interfaces and in aqueous solution:a review" Adv.Colloid Interface Sci.,2002,97(1-3):203-251.
[44].Lu,Y.Y.;Yi,S.H.;Shon,J.K.;Chang,S.;Pu,L.S.;Lee,S.Y.;Yie,J.E.;Char,K.;Stucky,G.D.;Kim,J.M."Highly Stable Mesoporous Metal Oxides Using Nano-Propping Hybrid Gemini Surfactants" J.Amer.Chem.Soc.;2004,126(8),2310-2311.
[45].Olive,M."Pluronic and Tetronic Surfactants";Technical Brochure,BASF Performance Chemicals,BASF Corp.,New Jersey,1996.
[46].Touhami,Y.;Rana,D.;Neaie,G.H.;Hornof,V."Study of polymer-surfactant interactions via surface tension measurements" Colloid Polym.Sci.,2001,279:297-300.
[47].Griffiths,P.C.;Fallis,I.A.;Teerapornchaisit,P.;Grillo,I."Hydrophobically modified gelatin and its interaction in aqueous solution with sodium dodecyl sulfate." Langmuir;2001,17(9):2594-2601.
[48].Muller,D.;Malmsten,M.;Bergenstahl,B.;Hessing,J.;Olijve,J.;Mori,F."Competitive adsorption of gelatin and sodium dodecylbenzenesulfonate at hydrophobic surfaces"Langmuir;1998,14(11):3107-3114.
[49].Otsuka,H.;Esumi,K."Structure-Performance relationships in surfactants" Esumi,K.;Ueno,M.Eds.New York:Marcel Dekker,1997,Chapter 12,p509.
[50].Iliopoulos,I.;Furo,I."NMR Study of the Association of Anionic Surfactants with an Anionic Polyelectrolyte Hydrophobically Modified with Perfluorinated Side Chains" Langmuir;2001;17(26);8049-8054.
[51].Amato,M.E.;Caponetti,E.;Chillura,M.D.;Pedone,L."~1H and ~(19)F NMR Investigation on Mixed Hydrocarbon-Fluorocarbon Micelles" J.Phys.Chem.B;2003;107(37);10048-10056.
[52].Nivaggioli,T.;Tsao,B.;Alexandridis,P.;Hatton,T.A."Microviscosity in Pluronic and Tetronic Poly(ethylene oxide)-Poly(propylene oxide)Block Copolymer Micelles" Langmuir 1995,11(1);119-126.
[53].Hue,I.;Oda,R."Gemini surfactants:studing micellisation by ~1H and ~(19)F NMR spectroscopy"Chem.Commun.1999,2025-2026.
[54]Kaplan,J.I.;Fraenkel,G.,in "NMR of Chemically Exchanging systems",Academic Press,New York,1980.
[55].Kim,B.J.;Im,S.S.;Oh,S.G "Investigation on the Solubilization Locus of Aniline-HCl Salt in SDS Micelles with ~1H NMR Spectroscopy" Langmuir;2001;17(2);565-566.
[56].Jansson,J.;Schillen,K.;Nilsson,M.;Soderman,O.;Fritz,G.;Bergmann,A.;Glatter,O."Small-Angle X-ray Scattering,Light Scattering,and NMR Study of PEO-PPO-PEO Triblock Cpolymer/Cationic Surfactant Complexes in Aqueous Solution" J.Phys.Chem.B;2005;109(15);7073-7083
[57].董姝丽,徐桂英“激光光散射和电子自旋共振技术研究十二烷基硫酸钠(SDS)与聚乙烯吡咯烷酮(PVP)的相互作用”,化学学报,2004,62卷,第7期,674-675
[1].Mclements,D.J.In "'Food Emulsions:Practice and Technique "s,2~(nd)Eds:CRC Press:Boca Raton,FL,2004.
[2].Jones,M.N."Surfactant interactions with biomembrancs and proteins" Chem.Soc.Rev.1992,21:127-136.
[3].Jones,M.N.In "Food Polymers,Gels and Colloids";The Royal Society of Chemistry:Cambridge,UK,1991:pp 65-88
[4].Turro,N.J.;Lei,X.G.;Ananthapadmanabhan,K.P.;Aronson,M."Spectroscopic probe analysis of protein-surfactant interactions:The BSA/SDS system".Langmuir,1995,11(7):2525-2533
[5].Vasilescu M.;Angellescu D.;Almgren M.;Valstar A."Interaction of globular proteins with surfactants studied with fluorescence probe methods" Langmuir;1999;15(8):2635-2643.
[6].Guo,X.H.;Zhao,N.M.;Chen,S.H.;Teixeira,J."Small-angle neutron scattering study of the structure of protein / detergent complexes".Biopolymers,1990,29:335-346.
[7].Oakes,J."Protein-surfactant interactions.Nuclear magnetic resonance and binding isotherm studies of interactions between bovine serum albumin and sodium dodecyl sulphate." J.Chem. Soc..Faraday Trans.1,1974,2200-2209.
[8].刘静,徐桂英.“表面活性剂与蛋白质相互作用的研究进展”.日用化学工业,2003,33:29-32.
[9].Messina,P.V.;Prieto,G.;Ruso,J.M.;Sarmiento,F."Conformational changes in human serum albumin induced by sodium perfluorooctanoate in aqueous solutions",J.Phys.Chem.B,2005;109(32):15566-15573
[10].(a)Schwuger,M.J.;Bartnik,F.G.In Anionic Surfactants;Gloxhuber,C.,Ed.;"Surfaetant Science Series",Vol.10;Marcel Dekker:Chapter 1.(b)Ananthapadmanabhan,K.P."Interactions of Surfactants with polymers and proteins";Goddard,E.D.,Ananthapadmanabhan,K.P.Eds.;CRC Press:Boca Raton,1993;p319.
[11].Zanette,D.;Lima,C.F.;Ruza,A.A.;Belarmino,A.T.N.;Santos,D.de F.;Frescura,V.L.A.;Marconi,D.M.O.;"Interactions of anionic surfactants with poly(ethylene oxide)and bovine serum albumin polymers:effect of the counterion hydrophobicity" Colloids Surf.A.1999,147(1-2):89-105.
[12].Chatterjee A.,Moulik S.P.,Majhi P.R.,Sanyal S.K.,"Studies on surfactant-biopolymer interaction:I.Microcalorimetric investigation on the interaction of cetyltrimethylammoniumbromide(CTAB)and sodium dodecylsulfate(SDS)with gelatin (Gn),lysozyme(Lz)and deoxyribonucleic acid(DNA)",Biophysical Chemistry 2002,98:313-327.
[13].Moriyama,Y.;Kawasaka,Y.;Takeda,K."Protective effect of small amount of sodium dodecyl sulfate on the helical structure of bovine serum albumin in the thermal denaturation."J.Colloid Interface Sci.2003,257(1):41-46.
[14].Gelamon,E.L.;Tabak,M."Spectroscopic studies on the interaction of bovine(BSA)and human(HAS)serum albumins with ionic surfactants"[J]Spectrochimica Acta Part A,2000,56:2255-2271.
[15].Sun,C.X.;Yang J.H.;Wu X.;Huang X.R.;Wang F.;Liu S.F.;"Unfolding and refolding of bovine serum albumin included by cetylpyridinium bromide".Biophys.J.2005,88(5):3518-3524.
[16].(a)Wu,D.;Xu,G.Y;Sun,Y.H.;Zhang,H.X.;Mao,H.Z.“Interaction between Proteins and Cationic Gemini Surfactant”Biomacromolecules 2007,8(2),708-712.(b)吴丹,徐桂英“阳离子Gemini表面活性剂与蛋白质的相互作用”山东大学博士学位论文 2007.
[17].Moriyama,Y.;Takeda,K."Protective Effect of Small Amounts of Bis-(2-ethylhexyl)sulfosuccinate on the Helical Structures of Human and Bovine Serum Albumins in Their Thermal Denaturations" Langmiur;2005;21(12):5524-5528.
[18].Li,Y.J.;Wang,X.Y.;Wang,Y.L."Comparative Studies on Interactions of Bovine Serum Albumin with Cationic Gemini and Single-Chain Surfactants" J.Phys.Chem.B;2006;110(16):8499-8505.
[19].Messina,V.P.;Prieto,G.;Ruso,M.J.;Sarmiento,F."Conformational Changes in Human Serum Albumin Induced by Sodium Perfluorooctanoate in aqueous Solutions".J.Phys.Chem.B;2005;109(32):15566-15573.
[20].Messina,V.P.;Prieto,G.;Dodero,V.;Ruso,M.J.;Schulz,P.;Sarmiento,F."Ultravioletcircular Dichroism spectroscopy and Potentiometric Study of the Interaction between Human Serum AlBumin and Sodiun Perfluorooctanoate" Biopolymer 2005,79:300-309.
[21].Messina,V.P.;Prieto,G.;Dodero,V.;Gabrerizo-Valderrama M.A.;Maldonado-Valderrama,J.;Ruso,M.J.;Sarmiento,F."Surface characterization of human serum albumin and sodium perfluorooctanoate mixed solutions by pendant drop tensiometry and circular dichroism"Biopolymer 2006,82(3):261-271.
[22].Sesta,B.;Gente,G.;Iovino,A.;Laureti,F.;Michiotti,P.;Paiusco,O.;Palacios,C.A.;Persi,L.;Mesa La C."Supramolecular association in the System Water-Lysozyme-Lithium Perfluorononanoate" J,Phys.Chem.B;2004;108(9):3036-3043
[23].Ciurleo,A.;Cinelii,S.;Gunia,M.;Bonincontro,A.;Onori,G.;Mesa,La C."Some Properties of Lysozyme-Lithium Perfluorononanoate Compexes" Biomacromolecules;2007,8(2):399-405.
[24].Mazakova,L.;Nordstierna,L.;Karlsson,G.;Blomberg,E.;Furo,I."Lack of Association between a cationic Protein and a Cationic Fluorosurfactant" Langmiur;2007;23(2):771-775
[25].Clark,L.C.Jr.;Hoffmann,R.E.;Davis,S.L.;"Response of the Rabbit Lung as a Criterion of Safety for Fluorocarbon Breathing and Blood Substitutes" Biomater Artif.Cells Immobilization Biotechnol 1992,20(2-4):10851099.
[26].Lissi,E.;Abuin,E.;Lanio,M.E.;Alvarez,C."A new and simple procedure for the evaluation of the association of surfactants to proteins".J.Biochem.Biophys.Methods,2002,50:261-268.
[27].吴丹,徐桂英.“光谱法研究蛋白质与表面活性剂的相互作用”.物理化学学报,2006,22(2):254-260
[28].Lu,R.C.;Xiao,J.X.;Cao,A.N.;Lai,L.H.;Zhu,B.Y.;Zhao,G.X."Surfactant-induced refolding of lysozyme".Biochimica et.Biophysica Acta 2005,1722:271-281.
[29].Ruso,J.M.;Deo,N.;Somasundaran,P."Complexation between dodecyl sulfate surfactant and zein protein in solution".Langmuir;2004;20(21):8988-8991.
[30].Sesta,B.;Segre,A.L.;D'Aprano,A.;Proietti,N."~1H NMR,Surface Tension,Viscosity,and Volume Evidence of Micelle-Polymer Hydrophobic Interactions:LiPFN-PVP System" J.Phys.Chem.B.;1997;101(2):198-204.
[31].(a)Moren,A.K.;Nyden,M.;Soderman,O.;Khan,A."Microstructure of Protein-Surfaetant Complexes in Gel and Solution-An NMR Relaxation Study" Langmuir;1999;15(17):5480-5488(b)Valstar,A.;Vasilescu,M.;Vigouroux,C.;Stilbs,P.;Almgren,M "Heat-Set Bovine Serum Albumin-Sodium Dodecyl Sulfate Gels Studied by Fluorescence Probe Methods,NMR,and Light Scatterin" Langmuir;2001;17(11):3208-3215.(c)Mesa,La C."Polymer-surfactant and protein-surfactant interactions" J.Colloid Inter.Sci.2005,286(1): 148-157.
[32].沈星灿,梁宏,何锡文,王新省.“园二色光谱分析蛋白质构像的方法及研究进展”,分析化学,2004,32(3):388-394
[33].Yan L.F.;Sun Z.R."Molecular structure of protein"[M]Beijing:Tsinghua University Press,1999,11-17.
[34].Yang,P.;Gao,F."Principles of bioinorganie chemistry"[M].Beijing:Science Press,2002,22:352.
[35].Shimizu,M.;Kobayashi,K.;Morii,H.;Mitsui,K.;Knoll,W.;Nagamune,T.;"Secondary structure analyses of protein films on gold surfaces by circular dichroism".Biochemical and Biophysical Research Communications,2003,310:606-611.
[36].Dong,A.;Natsuura,J.;Allison,S.D.;Chrisman,E.;Manning,M.C.;Carpenter,J.F."Infrared and circular dichroism spectroscopic characterization of structural differences between β-Lactoglobulin A and B" Biochemistry,1996,35(5):1450-1457.
[37].Becker,H.C.;Norden,B."DNA bindingf properties of 2,7-Diazapyrene and its N-methylated cations studied by linear and circular dichroism spectroscopy and calorimetry".J.Am.Chem.Soc.,1997,119(25):5798-5803.
[38].Zhong,W.Y.;Liang,Y.Q.;Fan,K.Q.;Lai,L.H."Chlorobenzylidine-calf thymus DNA interaction:circular dichroism and nuclear magnetic resonance studies".Spectrochim Acta A,2004,60:2985-2992.
[39].Zheng,J.;Consantine,C.A.;Rastogi,V.K.;Cheng,T.-C.;DeFrank,J.J.;Lablance,R.M."Secondary structure of organophosphorus hydrolase in solution and in langmuir-biodgett film studied by circular dichroism spectroscopy" J Phys.Chem.B 2004,108(44):17238-17242.
[40].Vertessy,B.G.;Harmat,V.;Bocskei,Z.;Naray,-Szabo,G.;Orosz,F.;Ovadi,J."Simultaneous binding of drugs with diffent chemical structures to Ca+-calmodulin:crystallographic and spectroscopic studies".Biochemistry,1998,37(44):15300-15310.
[41].Powis,W.;Klimtchuk,E."Photoelectron spectroscopy and circular dichroism on chiral biomolecules:L-Alanine".J.Phys.Chem.A.,2000,104(5):878-882.
[42].Mouzopoulou,B.;Kozlowski,H.;Katsaros,N.;Ganier-suillerot,A."Structural characterization of Ru-bleomycin complexes by resonance raman,circular dichroism,and NMR spectroscopy".Inorg.Chem.2001,40(27):6923-6929.
[43].Yang,S.Li,L.;Cholli,A.L.;Kumar,J.;Tripathy,S.K."Azobenzene-modified poly (1-glutamic acid)(AZOPLGA)its conformational and photodynamic properties".Biomacromolecues,2003,4(2):366-371.
[44].Dockal,M.;Carter,D.C.;Ruker,F."Conformational transitions of the three recombinant domains of human serum albumin depending on pH." J.Biol.Chem.2000,275:3042-3050.
[45].Gelamon,E.L.,Tabak,M."Spectroscopic studies on the interaction of bovine(BSA)and human(HAS)serum albumins with ionic surfactants"[J].Spectrochimica Acta Part A,2000, 56:2255-2271.
[46].Moriyama,Y.;Kawasaka,Y.;Takeda,K."Protective effect of small amount of sodium dodyl sulfate on the helical structure of bovine serum albumin in the thermal denaturation" J.Colloid Interface Sci.2003,257:41-46.
[47].Price,N.C."Conformation issues in the characterization of proteins".Biotechnol.Appl.Biochem,2000,31:29-40.
[48].Dong,S.L.;Li,X.;Xu,G.Y.;Hoffman,H."A Cationic Fluorocarbon Surfactant DEFUMACl and Its Mixed Systems with Cationic Surfactants:~(19)F NMR and Surface Tension Study" J.Phys.Chem.B 2007,111:5903-5910.
[49].Agarraberes,Fernando A.and Dice,J.Fred "Protein translocation across membranes"Biochim.Biophys.Acta,Biomembr.2001,1513(1):1-24.
[50].Sreerama,N.;Venyaminov,S.Y.;Woody,R.W."Estimationb of Protein Secondary Structure from Circular Dichroism Spectra:Inclusion of Denatured Proteins with Native Proteins in the Anaysis" Anal.Biochem.,2000,287:243-251.
[51].Amato,M.E.;Caponetti,E.;Chillura,M.D.;Pedone,L."~1H and ~(19)F NMR Investigation on Mixed Hydrocarbon-Fluorocarbon Micelles" J.Phys.Chem.B;2003;107(37):10048-10056.
[52].Segre,A.;Proietti,N."Supramolecular Structure of the LiPFN-PVP System:~(19)F NMR Studies" J.Phys.Chem.B;1998;102(50):10248-10254.
[53].(a)Menger,F.M.;Keiper,J.S."Gemini Surfactants" Angew.Chem.Int.Ed.2000,39(11):1906-1920.(b)Lyu,Y.Y.;Yi,S.H.;Shon,J.K.;Chang,S.;Pu,L.S.;Lee,S.Y.;Yie,J.E.;Char,K.;Stucky,G.D.;Kim,J.M."Highly Stable Mesoporous Metal Oxides Using Nano-Propping Hybrid Gemini Surfactants" J.Amer.Chem.Soc..;2004;126(8):2310-2311.
[54].(a)Nakagawa,T,;Tokiwa,F.In Surface and Colloid Science;Matijevic,E.,Ed.;John Wiley & Sons:New York,1969;Vol.9:p69.(b)Barthelemy,P.;Tomao,V.;Selb,J.;Chaudier,Y.;Pucli,B."Fluorocarbon-Hydrocarbon Nonionic Surfactants Mixtures:A Study of Their Miscibility" Langmiur;2002;18(7):2557-2563.
[55].Lima,F.C.;Nome,F.;Zanette,D."First Evidence of Poly(ethylene Oxide)-Mixed Sodium Dodecyl Sulfate/Sodium Decyl Phosphate Complexes" J.Colloid Interface Sci.1997,189(1):174-176.
[56].Pi,Y.Y.;Shang,Y.Z.;Peng,C.J.;Liu,H.L.;Hu,Y.;Jiang,J.W."Interactions between Bovine serum Albumin and Gemini Surfactant Alkanediyl-α,ω-Bis(Dimethyldodecyl-Ammonium Bromide" Biopolymer,2006,83:243-249.