石墨烯改性及其吸附性能的研究进展
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摘要
石墨烯由于具有独特的构型、较大的比表面积和较强的化学活性,使其具有较好的吸附能力,受到环境工作者的广泛关注。但未经处理的石墨烯由于存在较强的π-π相互作用、且粒径小,易团聚,限制了其在环境领域中的应用,为了解决这个问题,常对石墨烯进行改性。文章综述了石墨烯的一些改性方法,同时也综述了改性石墨烯对水中有机污染物和重金属离子的吸附机制,以及对气体吸附方面的研究进展。
The graphene has received wide attentions in environment field as a new nanomaterial. It had good performance of adsorption ability because of a unique pore structure, the larger specific surface area and strong chemical activity. But, graphene development in environment field is limited cause of the structure. Graphene modification can be used to solve the problem. This review introduces the preparation method of graphene modification, and its application in removal of organic pollutants and heavy metal ions, and gas adsorption.
The graphene has received wide attentions in environment field as a new nanomaterial. It had good performance of adsorption ability because of a unique pore structure, the larger specific surface area and strong chemical activity. But, graphene development in environment field is limited cause of the structure. Graphene modification can be used to solve the problem. This review introduces the preparation method of graphene modification, and its application in removal of organic pollutants and heavy metal ions, and gas adsorption.
引文
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[24] LIU M,CHEN C,HU J,et al.Synthesis of magnetite/graphene oxide composite and application for cobalt(II) removal[J].The Journal of Physical Chemistry C,2011,115(51):25234-25240.
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[28] TANG C Y,YU P,TANG L S,et al.Tannic acid functionalized graphene hydrogel for organic dye adsorption[J].Ecotox.Environ.Safe.,2018,16:299-306.
[29] BAI H,ZHOU J,ZHANG H,et al.Enhanced adsorbability and photocatalytic activity of TiO2-graphene composite for polycyclic aromatic hydrocarbons removal in aqueous phase [J].Colloid.Surfaces B,2017,150:68-77.
[30] LI Y H,DU Q J,LIU T H,et al.Equilibrium,kinetic and thermodynamic studies on the adsorption of phenol onto graphene[J].Mater.Res.Bull.,2012,47(8):1898-1904.
[31] UEDA YAMAGUCHI N,BERGAMASCO R,HAMOUDI S.Magnetic MnFe2O4-graphene hybrid composite for efficient removal of glyphosate from water[J].Chem.Eng.J.,2016,295:391-402.
[32] KOUSHIK D,SEN G S,MALIYEKKAL S M,et al.Rapid dehalogenation of pesticides and organics at the interface of reduced graphene oxide-silver nanocomposite[J].J.Hazard.Mater.,2016,308:192-198.
[33] ZHOU D,LIU Q,CHENG Q Y,et al.Graphene-manganese oxide hybrid porous material and its application in carbon dioxideadsorption[J].Chinese Sci.Bull.,2012,57(23):3059-3064.
[34] 张鹏飞.渗杂Pt/Pd的石墨烯体系气体吸附性的研究[D].北京:华北电力大学,2015:22.
[35] 刘晓东,田之悦,储伟,等.CH4,CO2和H2O在非金属原子修饰石墨烯表面的吸附[J].物理化学,2014,30(2):251-256.
[2] NETO A C,GUINEA F,PERES N M R,et al.The electronic properties of graphene[J].Rev.Mod.Phys,2009,81:109-162.
[3] 张芸秋,梁勇明,周建新.石墨烯掺杂的研究进展[J].化学学报,2014,72:367-377.
[4] RISTEIN J.Surface transfer doping of semiconductors[J].Science,2006,313:1057-1058.
[5] YAVARI F,KRITZINGER C,GAIRE C,et al.Tunable bandgap in graphene by the controlled adsorption of water molecules[J].Small,2010,6(22):2535-2538.
[6] WEI D C,LIU Y Q,WANG Y,et al.Synthesis of N-dopted Graphene by Chemical Vapor Deposition and Its Electrical Properties[J].Nano Letters,2009,9(5):1752-1758.
[7] DOCHERTY C J,LIN C T,JOYCE H J,et al.Extreme sensitivity of graphene photoconductivlty to environmental gases[J].Nat.Commun.,2012,3:1228-1235.
[8] CROWTHER A C,GHASSAEI A,JUNG N,et al.Strong charge-transfer dopting of 1 to 10 layer graphene by NO2[J].ACS Nano,2012,6(2),1865-1875.
[9] 刘学杰,贾颖,姜永军,等.Li吸附对石墨烯、BC3＼C3N电学性质影响的第一性原理研究[J].功能材料,2015,46(7):7056-7061.
[10] LEE W H,SUK J W,LEE J,et al.Simultaneous transfer and doping of CVD-grown graphene [J].Acs Nano,2012,6(2):1284-1290.
[11] 刘颖,戴丹,江南.三嗪对CVD石墨烯n型掺杂的研究[J].无机材料学报,2017,32(5):517- 522.
[12] 刘扬,安立宝,龚亮.Fe掺杂石墨烯表面吸附Au:第一性原理[J].南京工业大学学报(自然科学版),2018,40(3):109-114.
[13] 戴宪起,王宁,赵宝,等.Bi,Se和Te吸附n/p型石墨烯电子结构研究[J].河南师范大学学报(自然科学版),2014,42(6):26-31.
[14] 许帅,赵媛,解飞,等.S/N共掺杂石墨烯的制备及其电催化性能[J].材料导报,2018,32(z1):5-9.
[15] DAS S,IRIN F,AHMED H S T,et al.Non-covalent functionalization of pristine few-layer graphene using triphenylene derivatives for conductive poly (vinyl alcohol) composites[J].Polymer,2012,53:2485-2494.
[16] ZHANG M,GAO B,YAO Y,et al.Synthesis,characterization,and environmental implications of graphene coated biochar[J].Sci.Total Environ.,2012,435-436(7):567-572.
[17] FAN L,LUO C,LI X,et al.Fabrication of novel magnetic chitosan grafted with graphene oxide to enhance adsorption properties for methyl blue[J].J.Hazard.Mater,2012,215-216(10):272-279.
[18] DEKA M J,CHOWDHURY D.Surface charge induced tuning of electrical properties of CVD assisted graphene and functionalized graphene sheets[J].J.Mater.Sci.Technol.,2019,35(1):151-158.
[19] NIKDEL M,SALAMI-KALAJAHI M,HOSSEINI M S.Synthesis of poly(2-hydroxyethyl methacrylate- co-acrylic acid)-grafted graphene oxide nanosheets?via reversible addition-fragmentation chain transfer polymerization[J].RSC Advances,2014,4(32):16743-16750.
[20] ZHANG S,SHAO Y Y,LIU J,et al.Graphene-Polypyrrole Nanocomposite as a Highly Efficient and Low Cost Electrically Switched Ion Exchanger for Removing ClO-4 from Wastewater[J].ACS Appl.Mater.Inter.,2011,3(9):3633-3637.
[21] ZHU J,WEI S,GU H,et al.One-pot synthesis of magnetic graphene nanocomposites decorated with core@double-shell nanoparticles for fast chromium removal[J].Environ.Sci.Technol.,2011,46(2):977-985.
[22] MADADRANG C J,KIM H Y,GAO G,et al.Adsorption behavior of EDTA-graphene oxide for Pb(Ⅱ) removal[J].ACS Appl.Mater.Inter.,2012,4(3):1186-1193.
[23] LI J,ZHANG S,CHEN C,et al.Removal of Cu(II)and fulvic acid by graphene oxide nanosheets decorated with Fe3O4 nanoparticles[J].ACS Appl.Mater.Inter.,2012,4(9):4991- 5000.
[24] LIU M,CHEN C,HU J,et al.Synthesis of magnetite/graphene oxide composite and application for cobalt(II) removal[J].The Journal of Physical Chemistry C,2011,115(51):25234-25240.
[25] ZOU J P,LIU H L,LUO J,et al.Three-dimensional reduced graphene oxide coupled with Mn3O4 for highly efficient removal of Sb(III) and Sb(V) from water[J].ACS Appl.Mater.Inter.,2016,8(28):18140-18149.
[26] 方伟.改性石墨烯/聚吡咯复合材料对水中Cr(VI)及刚果红的吸附研究[D].广州:华南理工大学,2018:41-45.
[27] LIU L,DING L,WU X,et al.Enhancing the Hg(II) removal efficiency from real wastewater by novel thymine-grafted reduced graphene oxide complexes[J].Ind.Eng.Chem.Res.,2016,55(24):6845-6853.
[28] TANG C Y,YU P,TANG L S,et al.Tannic acid functionalized graphene hydrogel for organic dye adsorption[J].Ecotox.Environ.Safe.,2018,16:299-306.
[29] BAI H,ZHOU J,ZHANG H,et al.Enhanced adsorbability and photocatalytic activity of TiO2-graphene composite for polycyclic aromatic hydrocarbons removal in aqueous phase [J].Colloid.Surfaces B,2017,150:68-77.
[30] LI Y H,DU Q J,LIU T H,et al.Equilibrium,kinetic and thermodynamic studies on the adsorption of phenol onto graphene[J].Mater.Res.Bull.,2012,47(8):1898-1904.
[31] UEDA YAMAGUCHI N,BERGAMASCO R,HAMOUDI S.Magnetic MnFe2O4-graphene hybrid composite for efficient removal of glyphosate from water[J].Chem.Eng.J.,2016,295:391-402.
[32] KOUSHIK D,SEN G S,MALIYEKKAL S M,et al.Rapid dehalogenation of pesticides and organics at the interface of reduced graphene oxide-silver nanocomposite[J].J.Hazard.Mater.,2016,308:192-198.
[33] ZHOU D,LIU Q,CHENG Q Y,et al.Graphene-manganese oxide hybrid porous material and its application in carbon dioxideadsorption[J].Chinese Sci.Bull.,2012,57(23):3059-3064.
[34] 张鹏飞.渗杂Pt/Pd的石墨烯体系气体吸附性的研究[D].北京:华北电力大学,2015:22.
[35] 刘晓东,田之悦,储伟,等.CH4,CO2和H2O在非金属原子修饰石墨烯表面的吸附[J].物理化学,2014,30(2):251-256.
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