基于硫酸盐硫同位素的伊洛河流域河水溶解性重金属来源
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摘要
借助伊洛河河水硫酸盐硫同位素(δ~(34)S_(SO4))和溶解性重金属含量水平,研究伊洛河流域不同形式人类活动对河水溶解性重金属的影响.结果表明:伊洛河流域上游干流和支流河水溶解组分受金属矿山开采废水影响较大,洛河河水中溶解性硫酸盐浓度(SO_4~(2-))和δ~(34)S_(SO4)均值分别为(173±108)mg/L和(3.1±2.1)‰(n=8),河水中Co、Fe、Mn、Ni、Zn、Mo、Cd、Pb和U等含量较高,伊河河水中SO_4~(2-)和δ~(34)S_(SO4)均值为(169±89)mg/L和(3.7±1.2)‰(n=6),河水中Cr、Co、Fe、Ni、Zn、Mo、Cd、W、Hg、Pb和U等含量较高.伊洛河流域下游河水溶解性重金属受生活污水和工业废水影响较大,洛河河水中SO_4~(2-)和δ~(34)S_(SO4)均值分别为(121±30)mg/L和(9.4±0.8)‰(n=4),河水中V、Cr、Ni、As、W和Hg等含量较高,伊河河水中SO_4~(2-)和δ~(34)S_(SO4)均值分别为(122±22)mg/L和(10.5±2.4)‰(n=3),河水中V、U、Ni和As等含量较高.伊洛河流域源头河水溶解性重金属含量低,河水溶解组分来自大气降水,河水δ~(34)S_(SO4)值范围为(6.7‰～8.2‰).伊洛河流域河水溶解性重金属含量以及δ~(34)S_(SO4)值具有一致的空间差异性,δ~(34)S_(SO4)可以很好地说明河水中溶解性重金属以及硫酸盐来源.
Sulfur isotopic values of riverine sulfate and dissolved heavy metal(DHM)contents were adopt to illustrate the effect of different human activities on the DHM contents in the Yiluo River(YLR).The results indicated that dissolved components in the upstream of YRB were heavily affected by the sulfide minerals exploration.In the upstream of Luo River,high average SO_4~(2-)content of(173±108)mg/L(n=8)and low averageδ~(34)S_(SO4) value of(3.1±2.1)‰(n=8)were detected in the river water,and heavy metals as Co,Fe,Mn,Ni,Zn,Mo,Cd,Pb and U had high concentrations in this reach.While in the upstream of Yi River,high mean SO_4~(2-)content of(169±89)mg/L(n=6)and low meanδ~(34)S_(SO4) value of(3.7±1.2)‰(n=6)were also detected,and heavy metals as Cr,Co,Fe,Ni,Zn,Mo,Cd,W,Hg,Pb and U had relatively high contents.Dissolved contents in the downstream of YRB were primarily affected by sewage and industrial wastewater.Average SO_4~(2-)content of(121±30)mg/L andδ~(34)S_(SO4) value of(9.4±0.8)‰(n=4)were monitored in the downstream of Luo River along with the increasing concentrations of V,Cr,Ni,As,W and Hg.Correspondingly,in the downstream of Yi River,average SO_4~(2-)content of(122±22)mg/L andδ~(34)S_(SO4) value of(10.5±2.4)‰(n=3)with the increasing concentrations of V,U,Ni,and As were found.Dissolved components in the source water of YLR were mainly derived from atmospheric deposition,and the river water was characterized with low level of DHMs and moderateδ~(34)S values ranging from 6.7‰to 8.2‰.The contents of DHMs andδ~(34)S_(SO4) values in YRB had the same spatial variations,so that theδ~(34)S_(SO4) can well interpret the sources of dissolved heavy metals and sulfate in the river water.
Sulfur isotopic values of riverine sulfate and dissolved heavy metal(DHM)contents were adopt to illustrate the effect of different human activities on the DHM contents in the Yiluo River(YLR).The results indicated that dissolved components in the upstream of YRB were heavily affected by the sulfide minerals exploration.In the upstream of Luo River,high average SO_4~(2-)content of(173±108)mg/L(n=8)and low averageδ~(34)S_(SO4) value of(3.1±2.1)‰(n=8)were detected in the river water,and heavy metals as Co,Fe,Mn,Ni,Zn,Mo,Cd,Pb and U had high concentrations in this reach.While in the upstream of Yi River,high mean SO_4~(2-)content of(169±89)mg/L(n=6)and low meanδ~(34)S_(SO4) value of(3.7±1.2)‰(n=6)were also detected,and heavy metals as Cr,Co,Fe,Ni,Zn,Mo,Cd,W,Hg,Pb and U had relatively high contents.Dissolved contents in the downstream of YRB were primarily affected by sewage and industrial wastewater.Average SO_4~(2-)content of(121±30)mg/L andδ~(34)S_(SO4) value of(9.4±0.8)‰(n=4)were monitored in the downstream of Luo River along with the increasing concentrations of V,Cr,Ni,As,W and Hg.Correspondingly,in the downstream of Yi River,average SO_4~(2-)content of(122±22)mg/L andδ~(34)S_(SO4) value of(10.5±2.4)‰(n=3)with the increasing concentrations of V,U,Ni,and As were found.Dissolved components in the source water of YLR were mainly derived from atmospheric deposition,and the river water was characterized with low level of DHMs and moderateδ~(34)S values ranging from 6.7‰to 8.2‰.The contents of DHMs andδ~(34)S_(SO4) values in YRB had the same spatial variations,so that theδ~(34)S_(SO4) can well interpret the sources of dissolved heavy metals and sulfate in the river water.
引文
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[10]Rock L,Mayer B.Identifying the influence of geology,land use,and anthropogenic activities on riverine sulfate on a watershed scale by combining hydrometric,chemical and isotopic approaches[J].Chemical Geology,2009,262(3/4):121-130.
[11]李干蓉,刘丛强,陈椽,等.丰水期乌江上游干流水库-河流体系硫同位素组成[J].长江流域资源与环境,2009,18(4):350-355.Li G R,Liu C Q,Chen C,et al.Sulfur isotope composition of river channel and reservoir water in upper reaches of Wujiang River in high flow season[J].Resources and Environment in the Yangtze Basin,2009,18(4):350-355.
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[13]张东,黄兴宇,李成杰.硫和氧同位素示踪黄河及支流河水硫酸盐来源[J].水科学进展,2013,24(3):418-426.Zhang D,Huang X Y,Li C J.Sources of riverine sulfate in Yellow River and its tributaries determined by sulfur and oxygen isotopes[J].Advances in Water Science,2013,24(3):418-426.
[14]Zhang D,Li X D.,Zhao Z Q,et al.2015.Using dual isotopic data to track the sources and behaviors of dissolved sulfate in the western North China Plain[J].Applied Geochemistry,52:43-56.
[15]Bai L,Wang Z L 2014.Anthropogenic influence on rainwater in the Xi'an City,Northwest China:Constraints from sulfur isotope and trace elements analyses[J].Journal of Geochemical Exploration,137:65-72.
[16]Turchyn A V,Tipper E T,Galy A,et al.Isotope evidence for secondary sulfide precipitation along the Marsyandi River,Nepal,Himalayas[J].Earth and Planetary Science Letters,2013,374:36-46.
[17]黄典豪,王义昌,聂凤军,等.黄龙铺碳酸岩脉型钼(铅)矿床的硫、碳、氧同位素组成及成矿物质来源[J].地质学报,1984,(3):78-90.Huang D H,Wang Y C,Nie F J,et al.Isotopic composition of sulfur,carbon and oxygen and source material of the Huanglongpu carbonatite veig-type of molyboenum(lead)deposits[J].Acta Geologica Sinica,1984,(3):78-90.
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[20]贾英,方明,吴友军,等.上海河流沉积物重金属的污染特征与潜在生态风险[J].中国环境科学,2013,33(1):147-153.Jia Y,Fang M,Wu Y J,et al.Pollution characteristics and potential ecological risk of heavy metals in river sediments of Shanghai[J].China Environmental Science,2013,33(1):147-153.
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