碳纳米管/聚合物纳米复合材料研究进展
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摘要
碳纳米管/聚合物纳米复合材料作为材料领域的研究热点,受到人们的广泛关注.本文从制备方法、性能研究以及应用等方面出发,阐述了近年来国内外学者对碳纳米管/聚合物纳米复合材料的研究成果,最后对碳纳米管/聚合物基复合材料的应用前景进行了展望,以期对后续碳纳米管/聚合物纳米复合材料研究工作有指导性作用.
Carbon nanotubes(CNTs)/polymer nanocomposites have attracted much attention in materials research field. In this paper, the aspects of preparation method, performance research and application, recent research results of CNTs/polymer nanocomposites were expounded. And finally the application prospects of CNTs/polymer nanocomposites were carried out, hoping to have a guiding role in the subsequent research work of CNTs/polymer nanocomposites.
Carbon nanotubes(CNTs)/polymer nanocomposites have attracted much attention in materials research field. In this paper, the aspects of preparation method, performance research and application, recent research results of CNTs/polymer nanocomposites were expounded. And finally the application prospects of CNTs/polymer nanocomposites were carried out, hoping to have a guiding role in the subsequent research work of CNTs/polymer nanocomposites.
引文
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[7] TREACY M M J,EBBESEN T W.Exceptionally high young′s modulus observed for individual carbon nanotubes[J].Nature,1996,381(6584):678-680.
[8] WALTERS D A,ERICSON L M,CASAVANT M J,et al.Elastic strain of freely suspended single-wall carbon nanotube ropes[J].Appl phys lett,1999,74(25):3803-3805.
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[12] ZHU J,PENG H Q,RODRIGUEZ-MACIAS F,et al.Reinforcing epoxy polymer composites through covalent integration of functionalized nanotubes[J].Adv Funct Mater,2004,14(7):643-648.
[13] VELASCO-SANTOS C,MARTíNEZ-HERNáNDEZ A L,FISHER F T,et al.Improvement of thermal and mechanical properties of carbon nanotube composites through chemical functionalization[J].Chem Mater,2003,15(23):4470-4475.
[14] HAGGENMUELLER R,GOMMANS H H,RINZLER A G,et al.Aligned single-wall carbon nanotubes meltprocessing methods chem[J].Chem Phys Lett,2000,330(3-4):219-225.
[15] BRYNING M B,ISLAM M F,KIKKAWA J M,et al.Very low conductivity threshold in bulk isotropic single wall carbon nanotube epoxy composites[J].Adv Mater,2005,17(9):1186-1191.
[16] JI L J,STEVENS M M,ZHU Y F,et al.Preparation and properties of multi-walled carbon nanotube/carbon/polystyrene composites[J].Carbon,2009,47(11):2733-2741.
[17] GRUNLAN J C,MEHRABI A R,BANNON M V,et al.Water based single walled nanotube filled polymer composite with an exceptionally low percolation threshold[J].Adv Mater,2004,16(2):150-153.
[18] LIANG L,GAO C,CHEN G,et al.Large-area,stretchable,super flexible and mechanically stable thermoelectric films of polymer/carbon nanotube composites[J].J Mater Chem C,2016,4(3):526-532.
[19] WU G,ZHANG Z G,LI Y,et al.Exploring high-performance n-type thermoelectric composites using amino-substituted rylene dimides and carbon nanotube[J].ACS Nano,2017,11(6):5746-5752.
[20] 张宪华,高艳秋,赵龙,等.碳纳米管/连续碳纤维增强树脂基复合材料进展及其应用[J].复合材料构件制造技术,2014,15:71-73.
[21] 李小兵,曹正华.碳纳米管及其复合材料的研究进展和应用前景[J].材料导报,2005,19(4):162-165.
[2] 白春礼.纳米科学与技术[M].昆明:云南科学技术出版社,1995.
[3] IIJIMA S.Helical microtubules of graphitic carbon[J].Nature,1991,354:56-58.
[4] AJAYAN P M,STEPHAN O,COLLIEX C,et al.Aligned carbon nanotubearrays formed by cutting a polymer resin-nanotube composite[J].Science,1994,265(5176):1212-1214.
[5] TJONG S C.Nanocrystalline materials and coating[J].Mater Sci & Eng R,2006,53(3-4):73-197.
[6] THESS A,LEE R,NIKOLAEV P,et al.Crystalline ropes of metallic carbon nanotubes[J].Science,1996,273(5274):483-487.
[7] TREACY M M J,EBBESEN T W.Exceptionally high young′s modulus observed for individual carbon nanotubes[J].Nature,1996,381(6584):678-680.
[8] WALTERS D A,ERICSON L M,CASAVANT M J,et al.Elastic strain of freely suspended single-wall carbon nanotube ropes[J].Appl phys lett,1999,74(25):3803-3805.
[9] WONG E W,SHEEHAN P E,LIEBER C M.Nanobeam mechanics elasticity,strength,and toughness of nanorods and nanotubes[J].Science,1997,277(5334):1971-1975.
[10] COOPER C A,YOUNG R J,HALSALL M.Investigation into the deformation of carbon nanotubes and their composites through the use of raman spectroscopy[J].Compos Part A-Appl S,2001,32(3-4):401-411.
[11] 贾志杰,王正元.原位法制取碳纳米管/尼龙6复合材料[J].清华大学学报(自然科学版),2000,40(4):14-16.
[12] ZHU J,PENG H Q,RODRIGUEZ-MACIAS F,et al.Reinforcing epoxy polymer composites through covalent integration of functionalized nanotubes[J].Adv Funct Mater,2004,14(7):643-648.
[13] VELASCO-SANTOS C,MARTíNEZ-HERNáNDEZ A L,FISHER F T,et al.Improvement of thermal and mechanical properties of carbon nanotube composites through chemical functionalization[J].Chem Mater,2003,15(23):4470-4475.
[14] HAGGENMUELLER R,GOMMANS H H,RINZLER A G,et al.Aligned single-wall carbon nanotubes meltprocessing methods chem[J].Chem Phys Lett,2000,330(3-4):219-225.
[15] BRYNING M B,ISLAM M F,KIKKAWA J M,et al.Very low conductivity threshold in bulk isotropic single wall carbon nanotube epoxy composites[J].Adv Mater,2005,17(9):1186-1191.
[16] JI L J,STEVENS M M,ZHU Y F,et al.Preparation and properties of multi-walled carbon nanotube/carbon/polystyrene composites[J].Carbon,2009,47(11):2733-2741.
[17] GRUNLAN J C,MEHRABI A R,BANNON M V,et al.Water based single walled nanotube filled polymer composite with an exceptionally low percolation threshold[J].Adv Mater,2004,16(2):150-153.
[18] LIANG L,GAO C,CHEN G,et al.Large-area,stretchable,super flexible and mechanically stable thermoelectric films of polymer/carbon nanotube composites[J].J Mater Chem C,2016,4(3):526-532.
[19] WU G,ZHANG Z G,LI Y,et al.Exploring high-performance n-type thermoelectric composites using amino-substituted rylene dimides and carbon nanotube[J].ACS Nano,2017,11(6):5746-5752.
[20] 张宪华,高艳秋,赵龙,等.碳纳米管/连续碳纤维增强树脂基复合材料进展及其应用[J].复合材料构件制造技术,2014,15:71-73.
[21] 李小兵,曹正华.碳纳米管及其复合材料的研究进展和应用前景[J].材料导报,2005,19(4):162-165.
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