碳硅负载氧化铌催化果糖制备5-羟甲基糠醛的研究
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摘要
制备了碳硅负载氧化铌催化剂,并对其催化生物质糖转化为5-羟甲基糠醛(HMF)进行研究,对铌负载量、反应时间、反应温度、催化剂质量等影响因素进行考察。结果表明,铌负载量对催化剂酸量和催化活性及HMF选择性均有重要影响:催化剂酸量随铌质量分数增加而增加,果糖转化率也随之增加; HMF选择性随着铌质量分数增加呈现先上升后下降的变化趋势,铌负载量为5%时,HMF收率最大可达82. 8%。
Nb_2O_5/C-Si is prepared and its catalytic properties in conversion of biomass sugar to 5-hydroxymethylfurfural( HMF) are studied.The factors such as niobium oxide loading amount,reaction time,temperature and catalyst dosage are investigated. It is found the niobium oxide loading amount has important impact on the acidity amount and catalytic properties of the catalyst,and the selectivity of HMF. With the increase of niobium oxide loading amount,both the acidity amount of catalyst and the conversion rate of fructose increase while the selectivity of HMF increases firstly and decreases then.The highest yield of HMF can reach 82. 8% over 5% Nb_2O_5/P-C-Si catalyst.
Nb_2O_5/C-Si is prepared and its catalytic properties in conversion of biomass sugar to 5-hydroxymethylfurfural( HMF) are studied.The factors such as niobium oxide loading amount,reaction time,temperature and catalyst dosage are investigated. It is found the niobium oxide loading amount has important impact on the acidity amount and catalytic properties of the catalyst,and the selectivity of HMF. With the increase of niobium oxide loading amount,both the acidity amount of catalyst and the conversion rate of fructose increase while the selectivity of HMF increases firstly and decreases then.The highest yield of HMF can reach 82. 8% over 5% Nb_2O_5/P-C-Si catalyst.
引文
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[21]Grobelny M,Kalisz M,Mazur M,et al.Functional Nb2O5film and Nb2O5+CuO,Nb2O5+Graphene,Nb2O5+CuO+Graphene composite films to modify the properties of Ti6Al4V titanium alloy[J].Thin Solid Films,2016,616:64-72．
[22]Huang F M,Su Y W,Long Z Y,et al.Enhanced formation of 5-hydroxymethylfurfural from glucose using a silica-supported phosphate and iron phosphate heterogeneous catalyst[J].Industrial&Engineering Chemistry Research,2018,57(31):10198-10205．
[23]Sudarsan V,Muthe K P,Vyas J C,et al.PO3-4tetrahedra in SbPO4and SbOPO4:a31PNMR and XPS study[J].Journal of Alloys and Compounds,2002,336(1-2):119-123．
[24]Qi X H,Watanabe M,Aida T M,et al.Catalytic dehydration of fructose into 5-hydroxymethylfurfural by ion-exchange resin in mixed-aqueous system by microwave heating[J].Green Chemistry,2008,10(7):799-805．
[25]Qi X H,Watanabe M,Aida T M,et al.Sulfated zirconia as a solid acid catalyst for the dehydration of fructose to 5-hydroxymethylfurfural[J].Catalysis Communications,2009,10(13):1771-1775．
[26]Antonetti C,Melloni M,Licursi D,et al.Microwave-assisted dehydration of fructose and inulin to HMF catalyzed by niobium and zirconium phosphate catalysts[J].Applied Catalysis B-Environmental,2017,206:364-377．
[27]Matharu A S,Ahmed S,Almonthery B,et al.Starbon/high-amylose corn starch-supported N-heterocyclic carbene-iron(Ⅲ)catalyst for conversion of fructose into 5-hydroxymethylfurfural[J].Chemsuschem,2018,11(4):716-725．
[28]Yu I K M,Tsang D C W.Conversion of biomass to hydroxymethylfurfural:A review of catalytic systems and underlying mechanisms[J].Bioresource Technology,2017,238:716-732．
[29]Song Y,Zhang L L,Li G D,et al.ZSM-5 extrudates modified with phosphorus as a super effective MTP catalyst:Impact of the acidity on binder[J].Fuel Processing Technology,2017,168:105-115．
[2]Agarwal B,Kailasam K,Sangwan R S,et al.Traversing the history of solid catalysts for heterogeneous synthesis of 5-hydroxymethylfurfural from carbohydrate sugars:A review[J].Renewable&Sustainable Energy Reviews,2018,82:2408-2425．
[3]Tan-Soetedjo J N M,van de Bovenkamp H H,Abdilla R M,et al.Experimental and kinetic modeling studies on the conversion of sucrose to levulinic acid and 5-hydroxymethylfurfural using sulfuric acid in water[J].Industrial&Engineering Chemistry Research,2017,56(45):13229-13240．
[4]Villanueva N I,Marzialetti T G,Mechanism and kinetic parameters of glucose and fructose dehydration to 5-hydroxymethylfurfural over solid phosphate catalysts in water[J].Catalysis Today,2018,302:100-107．
[5]Li H,Fang Z,Smith R L,et al.Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials[J].Progress in Energy and Combustion Science,2016,55:98-194．
[6]Chareonlimkun A,Champreda V,Shotipruk A,et al.Catalytic conversion of sugarcane bagasse,rice husk and corncob in the presence of Ti O2,Zr O2and mixed-oxide Ti O2-Zr O2under hot compressed water(HCW)condition[J].Bioresource Technology,2010,101(11):4179-4186．
[7]Ventura M,Dibenedetto A,Aresta M,Heterogeneous catalysts for the selective aerobic oxidation of 5-hydroxymethylfurfural to added value products in water[J].Inorganica Chimica Acta,2018,470:11-21．
[8]Carniti P,Gervasini A,Bossola F,et al.Cooperative action of Bronsted and Lewis acid sites of niobium phosphate catalysts for cellobiose conversion in water[J].Applied Catalysis B-Environmental,2016,193:93-102．
[9]Chan X J,Pu T C,Chen X Y,et al.Effect of niobium oxide phase on the furfuryl alcohol dehydration[J].Catalysis Communications,2017,97:65-69．
[10]Guo J,Zhu S H,Cen Y L,et al.Ordered mesoporous Nb-W oxides for the conversion of glucose to fructose,mannose and 5-hydroxymethylfurfural[J].Applied Catalysis B-Environmental,2017,200:611-619．
[11]Kreissl H T,Nakagawa K,Peng Y K,et al.Niobium oxides:Correlation of acidity with structure and catalytic performance in sucrose conversion to 5-hydroxymethylfurfural[J].Journal of Catalysis,2016,338:329-339．
[12]Li X C,Peng K H,Xia Q N,et al.Efficient conversion of cellulose into 5-hydroxymethylfurfural over niobia/carbon composites[J].Chemical Engineering Journal,2018,332:528-536．
[13]Van de Vyver S,Peng L,Geboers J,et al.Sulfonated silica/carbon nanocomposites as novel catalysts for hydrolysis of cellulose to glucose[J].Green Chemistry,2010,12(9):1560-1563．
[14]Wu S,Ju H X,and Liu Y,Conductive mesocellular silica-carbon nanocomposite foams for immobilization,direct electrochemistry,and biosensing of proteins[J].Advanced Functional Materials,2007,17(4):585-592．
[15]Wan Y,Wang H Y,Zhao Q F,et al.Ordered mesoporous Pd/silicacarbon as a highly active heterogeneous catalyst for coupling reaction of chlorobenzene in aqueous media[J].Journal of the A-merican Chemical Society,2009,131(12):4541-4550．
[16]Malaika A,Rechnia-Goracy P,Kot M,et al.Selective and efficient dimerization of isobutene over H-3 PO4/activated carbon catalysts[J].Catalysis Today,2018,301:266-273．
[17]Puziy A M,Poddubnaya O I,Gawdzik B,et al.Functionalization of carbon and silica gel by phosphoric acid[J].Adsorption Science&Technology,2007,25(8):531-542．
[18]Puziy A M,Poddubnaya O I,Martinez-Alonso A,et al.Synthetic carbons activated with phosphoric acid-I.Surface chemistry and ion binding properties[J].Carbon,2002,40(9):1493-1505．
[19]Puziy A M,Poddubnaya O I,Martinez-Alonso A,et al.Synthetic carbons activated with phosphoric acidⅢ．Carbons prepared in air[J].Carbon,2003,41(6):1181-1191．
[20]Chai S H,Wang H P,Liang Y,et al.Sustainable production of acrolein:Gas-phase dehydration of glycerol over Nb2O5catalyst[J].Journal of Catalysis,2007,250(2):342-349．
[21]Grobelny M,Kalisz M,Mazur M,et al.Functional Nb2O5film and Nb2O5+CuO,Nb2O5+Graphene,Nb2O5+CuO+Graphene composite films to modify the properties of Ti6Al4V titanium alloy[J].Thin Solid Films,2016,616:64-72．
[22]Huang F M,Su Y W,Long Z Y,et al.Enhanced formation of 5-hydroxymethylfurfural from glucose using a silica-supported phosphate and iron phosphate heterogeneous catalyst[J].Industrial&Engineering Chemistry Research,2018,57(31):10198-10205．
[23]Sudarsan V,Muthe K P,Vyas J C,et al.PO3-4tetrahedra in SbPO4and SbOPO4:a31PNMR and XPS study[J].Journal of Alloys and Compounds,2002,336(1-2):119-123．
[24]Qi X H,Watanabe M,Aida T M,et al.Catalytic dehydration of fructose into 5-hydroxymethylfurfural by ion-exchange resin in mixed-aqueous system by microwave heating[J].Green Chemistry,2008,10(7):799-805．
[25]Qi X H,Watanabe M,Aida T M,et al.Sulfated zirconia as a solid acid catalyst for the dehydration of fructose to 5-hydroxymethylfurfural[J].Catalysis Communications,2009,10(13):1771-1775．
[26]Antonetti C,Melloni M,Licursi D,et al.Microwave-assisted dehydration of fructose and inulin to HMF catalyzed by niobium and zirconium phosphate catalysts[J].Applied Catalysis B-Environmental,2017,206:364-377．
[27]Matharu A S,Ahmed S,Almonthery B,et al.Starbon/high-amylose corn starch-supported N-heterocyclic carbene-iron(Ⅲ)catalyst for conversion of fructose into 5-hydroxymethylfurfural[J].Chemsuschem,2018,11(4):716-725．
[28]Yu I K M,Tsang D C W.Conversion of biomass to hydroxymethylfurfural:A review of catalytic systems and underlying mechanisms[J].Bioresource Technology,2017,238:716-732．
[29]Song Y,Zhang L L,Li G D,et al.ZSM-5 extrudates modified with phosphorus as a super effective MTP catalyst:Impact of the acidity on binder[J].Fuel Processing Technology,2017,168:105-115．
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