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过氧化氢改性花生壳对铬(Ⅵ)的吸附
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  • 英文篇名:Adsorption of Cr(Ⅵ) on peanut shells modified by H_2O_2
  • 作者:李倩 ; 张宇 ; 任欢杰
  • 英文作者:LI Qian;ZHANG Yu;REN Huan-jie;Hubei Key Laboratory of Purification and Application of Plant Anti-cancer Active Ingredients,Hubei University of Education;
  • 关键词:花生壳 ; 过氧化氢 ; 改性 ; 吸附 ;
  • 英文关键词:peanut shells;;hydrogen peroxide;;modified;;adsorption;;Cr(Ⅵ)
  • 中文刊名:应用化工
  • 英文刊名:Applied Chemical Industry
  • 机构:植物抗癌活性物质提纯及应用湖北省级重点实验室湖北第二师范学院;
  • 出版日期:2018-11-29 17:22
  • 出版单位:应用化工
  • 年:2019
  • 期:02
  • 基金:国家自然科学基金(51573066);; 湖北省教育厅中青年人才项目(Q20173001);湖北省教育厅团队项目(T201718);; 湖北第二师范学院人才启动基金项目;; 武汉市工程科学技术研究院工科梧桐计划项目
  • 语种:中文;
  • 页:36-39
  • 页数:4
  • CN:61-1370/TQ
  • ISSN:1671-3206
  • 分类号:X703
摘要
用过氧化氢改性花生壳吸附六价铬,考察了改性花生壳投加量、吸附温度和铬的初始浓度等影响。结果表明,当花生壳的投加量为1.0 g,吸附时间为2 h,温度为60℃,50 mL铬的初始浓度为50 mg/L的吸附效果为最佳,吸附率为80%。红外分析表明,过氧化氢改性花生壳吸附铬的官能团主要为羟基、羧基,包含物理吸附和化学吸附。
        The adsorption of chromium on peanut shell which was modified by hydrogen peroxide was studied.The effects of modified peanut shell dosage,adsorption temperature and initial chromium concentration were investigated.The results showed that when the dosage of peanut shell was 1.0 g,the adsorption time was 2 h,the temperature was 60 ℃,50 mL the initial chromium concentration was 50 mg/L,and the adsorption rate was 80%.Infrared analysis showed that the functional groups involved are mainly hydroxyl and carboxyl groups,including chemisorption and physisorption.
引文
[1]王梅,王智潇.铁矿石烧结烟气脱硫灰处理含铬废水[J].化工环保,2017,37(2):243-247.
    [2]王剑南,黄俊旗,李晶.对废水中Cr6+治理的研究进展[J].安徽化工,2016,42(5):8-10.
    [3]Liu Weifeng,Zhang Jian,Zhang Chenglu,et al.Adsorptive removal of Cr(Ⅵ)by Fe-modified activated carbon prepared from Trapanatans husk[J].Chemical Engineering Journal,2010,162:667-684.
    [4]王晓,夏良树,郑伟娜,等.改性麦秸对U(Ⅵ)的吸附性能及机理[J].过程工程学报,2010,10(6):1084-1090.
    [5]张庆芳,朱宇斌,李金平,等.改性花生壳和改性玉米芯吸附重金属的对比实验研究[J].花生学报,2009,38(2):6-10.
    [6]Tong X J,Li J Y,Yuan J H,et al.Adsorption of Cu(II)by biochars generated from three crop straws[J].Chemical Engineering Journal,2011,172(2/3):828-834.
    [7]钟璐.核桃壳与改性花生壳对模拟废水中Cr(Ⅵ)的吸附特性研究[D].南昌:华东交通大学,2012.
    [8]Espinosa-Ortiz E J,Rene E R,Pakshirajan K,et al.Fungal pelleted reactors in wastewater treatment:Applications and perspectives[J].Chemical Engineering Journal,2016,283:553-571.
    [9]李山.改性花生壳对水中重金属离子和染料的吸附特性研究[D].西安:西北大学,2009.
    [10]Luo Lei,Xu Chuang,Chen Zien,et al.Properties of biomass-derived biochars:Combined effects of operating conditions and biomass types[J].Bioresource Technology,2015,192:83-89.
    [11]耿乙文.过氧化氢法制备改性苹果渣膳食纤维及其降脂功能的研究[D].北京:中国农业大学,2015.
    [12]韩鹏,任爱玲,郭斌,等.过氧化氢改性活性炭对三甲胺废气的吸附[J].河北科技大学学报,2013,34(2):159-165.
    [13]国家环境保护局.GB 7467-1987水质六价铬的测定二苯碳酰二肼分光光度法[S].北京:中国标准出版社,1987.
    [14]赵晖,冯丽军,冯梦思,等.改性花生壳对重金属含铬废水的吸附研究[J].武汉纺织大学学报,2011,24(6):44-47.
    [15]刘智峰,李旭.改性花生壳吸附废水中Cr(Ⅵ)条件的优选实验[J].安徽农业科学,2010,38(29):16498-16500.
    [16]许波,商育伟,赵丹,等.超临界CO2提取青竹木质素的红外和1H NMR光谱分析[J].北京石油化工学院学报,2014,22(4):4-6.
    [17]Bian Yu,Bian Zhaoyong,Zhang Junxiao,et al.Adsorption of cadmium ions from aqueous solutions by activated carbon with oxygen-containing functional groups[J].Chinese Journal of Chemical Engineering,2015,23(10):1705-1711.
    [18]裘国华,章乐,申屠南瑛.天然纤维素太赫兹和红外光谱分析研究[J].光谱学与光谱分析,2016,36(3):682-684.
    [19]刘荣厚,袁海荣,李金洋.花生壳热解试验及其剩余物特性红外光谱分析[J].农业工程学报,2007,23(12):197-202.
    [20]Sartape Ashish,Mandhare Aniruddha,Salvi Prathmesh,et al.Removal of Bi(Ⅲ)with adsorption technique using coconut shell activated carbon[J].Chinese Journal of Chemical Engineering,2012,20(4):768-775.

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