北京市郊农田土壤中多环芳烃污染特征及风险评价
|
摘要
对北京市郊农田土壤中多环芳烃(PAHs)的种类、含量进行研究,并对其来源和生态风险进行探讨,以期了解京郊农田土壤中PAHs的污染现状和潜在风险,为农业环境保护提供科学依据和理论支持。结果表明:16种PAHs全部检出的检出率为74.4%,PAHs总含量(∑PAHs)范围为7.19～1 811.99 ng·g~(-1),平均值为460.75 ng·g~(-1);土壤中PAHs的组成结构主要以2～4环为主,占总含量的78.2%,主要来源为石油和煤的高温燃烧。风险评价结果显示,京郊农田土壤已受到PAHs污染,并具有潜在生态风险。
The PAHs were used as the goal pollutant in order to study the species, content, main source and ecological risk of PAHs in agricultural soil in suburbs of Beijing. This study can not only understand the pollution characteristics and potential risk of PAHs in agricultural soil in suburbs of Beijing, but also provide support for the decision making of agricultural environmental protection. The results showed that 16 PAHs were generally detected, with the detection ratio of 74.4%. The total PAHs concentrations was in range of 7.19～1 811.99 ng·g~(-1), with an average value of 460.75 ng·g~(-1). The dominant compounds were 2～4 ring PAHs, which accounted for 78.2%. PAHs in soil were mainly derived from the fossil oil and the combustion of coal. The analysis of risk assessment showed that the agricultural soil in suburbs of Beijing had been polluted by PAHs and had potential ecological risk.
The PAHs were used as the goal pollutant in order to study the species, content, main source and ecological risk of PAHs in agricultural soil in suburbs of Beijing. This study can not only understand the pollution characteristics and potential risk of PAHs in agricultural soil in suburbs of Beijing, but also provide support for the decision making of agricultural environmental protection. The results showed that 16 PAHs were generally detected, with the detection ratio of 74.4%. The total PAHs concentrations was in range of 7.19～1 811.99 ng·g~(-1), with an average value of 460.75 ng·g~(-1). The dominant compounds were 2～4 ring PAHs, which accounted for 78.2%. PAHs in soil were mainly derived from the fossil oil and the combustion of coal. The analysis of risk assessment showed that the agricultural soil in suburbs of Beijing had been polluted by PAHs and had potential ecological risk.
引文
[1]Lynch S M,Rebbeck T R.Bridging the gap between biologic,individual,and macro environmental factors in cancer:A multilevel approach[J].Cancer Epidemiology,Biomarkers&Prevention,2013,22(4):485-495.
[2]Wild S R,Jones K C.Polynuclear aromatic hydrocarbons in the United Kingdom environment:A preliminary source inventory and budget[J].Environmental Pollution,1995,88(1):91-108.
[3]汤莉莉.北京城市土壤中多环芳烃的污染研究[D].南京:南京气象学院,2004.TANG Li-li.Contamination of polycyclic aromatic hydrocarbons in urban soils in Beijing[D].Nanjing:Nanjing Institute of Meteorology,2004.
[4]USEPA.Semivolatile organic compounds by gas chromatography/mass spectrometry(GC/MS)[EB/OL].[2018-08-08].http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/8270d.pdf.
[5]葛蔚,程琪琪,柴超,等.山东省农田土壤多环芳烃的污染特征及源解析[J].环境科学,2017,38(4):1587-1595.GE Wei,CHENG Qi-qi,CHAI Chao,et al.Pollution characteristics and source analysis of polycyclic aromatic hydrocarbons in agricultural soils from Shandong[J].Environmental Science,2017,38(4):1587-1595.
[6]曹云者,柳晓娟,谢云峰,等.我国主要地区表层土壤中多环芳烃组成及含量特征分析[J].环境科学学报,2012,32(1):197-203.CAO Yun-zhe,LIU Xiao-juan,XIE Yun-feng,et al.Patterns of PAHs concentrations and components in surface soils of main areas in China[J].Acta Scientiae Circumstantiae,2012,32(1):197-203.
[7]Readman J W,Fillmann G,Tolosa I,et al.Petroleum and PAH contamination of the Black Sea[J].Marine Pollution Bulletin,2002,44(1):48-62.
[8]李恭臣,夏星辉,王然,等.黄河中下游水体中多环芳烃的分布及来源[J].环境科学,2006,27(9):1738-1743.LI Gong-chen,XIA Xing-hui,WANG Ran,et al.Pollution of polycyclic aromatic hydrocarbons(PAHs)in middle and lower reaches of the Yellow River[J].Environmental Science,2006,27(9):1738-1743.
[9]Men B,He M,Tan L,et al.Distributions of polycyclic aromatic hydrocarbons in the Daliao River estuary of Liaodong Bay,Bohai Sea(China)[J].Marine Pollution Bulletin,2009,58(6):818-826.
[10]Yu X Z,Gao Y,Wu S C,et al.Distribution of polycyclic aromatic hydrocarbons in soils at Guiyu area of China,affected by recycling of electronic waste using primitive technologies[J].Chemosphere,2006,65(9):1500-1509.
[11]Edwards N T.Polycyclic aromatic hydrocarbons(PAHs)in the terrestrial environmental review[J].Journal of Environmental Quality,1983,12:427-441.
[12]Luca G D,Furesi A,Leardi R,et al.Polycyclic aromatic hydrocarbons assessment in the sediments of the Proto Torres Harbor(Northern Sardinia,Italy)[J].Marine Chemistry,2004,86(1/2):15-32.
[13]Atanassova I,Brummer G W.Polycyclic aromatic hydrocarbons of anthropogenic and biopedogenic origin in a colluviated hydromorphic soil of western Europe[J].Geoderma,2004,120(1/2):27-34.
[14]Yunker M B,Macdonald R W,Vingarzan R,et al.PAHs in the Fraser River basin:A critical appraisal of PAH ratios as indicators of PAHsource and composition[J].Organic Geochemistry,2002,33(4):489-515.
[15]冯承莲,夏星辉,周追,等.长江武汉段水体中多环芳烃的分布及来源分析[J].环境科学学报,2007,27(11):1900-1908.FENG Cheng-lian,XIA Xing-hui,ZHOU Zhui,et al.Distribution and sources of polycyclic aromatic hydrocarbons in the Wuhan section of the Yangtze River[J].Acta Scientiae Circumstantiae,2007,27(11):1900-1908.
[16]杨清书,雷亚平,欧素英,等.珠江广州河段水环境中多环芳烃的组成及其垂直分布特征[J].海洋通报,2008,27(6):34-43.YANG Qing-shu,LEI Ya-ping,OU Su-ying,et al.Vertical distribution,composition of polycyclic aromatic hydrocarbons in water column from Guangzhou channel in the Pearl River[J].Marine Science Bulletin,2008,27(6):34-43.
[17]张枝焕,卢另,贺光秀,等.北京地区表层土壤中多环芳烃的分布特征及污染源分析[J].生态环境学报,2011,20(4):668-675.ZHAN Zhi-huan,LU Ling,HE Guang-xiu,et al.Distribution and sources of polycyclic aromatic hydrocarbon compounds in topsoil of Beijing,China[J].Ecology and Environmental Sciences,2011,20(4):668-675.
[18]张敬锁,周洁,刘晓霞,等.京郊灌渠水体和底泥中多环芳烃污染特征[J].环境污染与防治,2017,39(3):236-243.ZHANG Jing-suo,ZHOU Jie,LIU Xiao-xia,et al.Pollution characteristics of PAHs in water and sediments of irrigation canal in suburb of Beijing[J].Environmental Pollution and Control,2017,39(3):236-243.
[19]邹正禹,唐海龙,刘阳生.北京市郊农业土壤中多环芳烃的污染分布和来源[J].环境化学,2013,32(5):874-880.ZOU Zheng-yu,TANG Hai-long,LIU Yang-sheng.Distribution and sources of polycyclic aromatic hydrocarbon compounds in topsoil of Beijing,China[J].Environmental Chemistry,2013,32(5):874-880.
[20]李艳,顾华,黄冠华,等.北京东南郊灌区多环芳烃污染风险与人体健康风险评估[J].农业机械学报.2017,48(9):237-249.LI Yan,GU Hua,HUANG Guan-hua,et al.Contamination and health risk assessment of PAHs in irrigation district in southeastern suburb of Beijing[J].Transactions of the Chinese Society for Agricultural Machinery,2017,48(9):237-249.
[21]丁爱芳,潘根兴,李恋卿.江苏省部分地区农田表土多环芳烃含量比较及来源分析[J].生态与农村环境学报,2007,23(2):71-75.DING Ai-fang,PAN Gen-xing,LI Lian-qing.Contents and sources of PAHs in top soils of farm lands in parts of Jiangsu,China[J].Journal of Ecology and Rural Environment,2007,23(2):71-75.
[22]周玲莉,薛南冬,李发生,等.黄淮平原农田土壤中多环芳烃的分布、风险及来源[J].中国环境科学,2012,32(7):1250-1256.ZHOU Ling-li,XUE Nan-dong,LI Fa-sheng,et al.Distribution,source analysis and risk assessment of polycyclic aromatic hydrocarbons in farmland soils in Huanghuai Plain[J].China Environmental Science,2012,32(7):1250-1256.
[23]刘增俊,滕应,黄标,等.长江三角洲典型地区农田土壤多环芳烃分布特征与源解析[J].土壤学报,2010,47(6):1110-1117.LIU Zeng-jun,TENG Ying,HUANG Biao,et al.Distribution and sources analysis of PAHs in farmland soils in areas typical of the Yangtze River Delta,China[J].Acta Pedologica Sinica,2010,47(6):1110-1117.
[24]徐慧洁,杨静慧,刘艳军.盐胁迫对野生樱桃幼苗生长的影响及其耐盐性分析[J].中国南方果树,2014,43(3):39-42.XU Hui-jie,YANG Jing-hui,LIU Yan-jun.Effect of salt stress on growth of wild cherry seedlings and analysis of their salt tolerance[J].South China Fruits,2014,43(3):39-42.
[25]李久海,董元华,曹志洪,等.慈溪市农田表层、亚表层土壤中多环芳烃(PAHs)的分布特征[J].环境科学学报,2007,27(11):1909-1914.LI Jiu-hai,DONG Yuan-hua,CAO Zhi-hong,et al.Distribution of polycyclic aromatic hydrocarbons(PAHs)in the surface and subsurface soils in Cixi County[J].Acta Scientiae Circumstantiae,2007,27(11):1909-1914.
[26]Nam J J,Song B H,Eom K C,et al.Distribution of polycyclic aromatic hydrocarbons in agricultural soils in South Korea[J].Chemosphere,2003,50(10):1281-1289.
[27]杨国义,张天彬,高淑涛,等.珠江三角洲典型区域农业土壤中多环芳烃的含量分布特征及其污染来源[J].环境科学,2007,28(10):2350-2354.YANG Guo-yi,ZHANG Tian-bin,GAO Shu-tao,et al.Source and distribution characteristics of polycyclic aromatic hydrocarbons in agricultural soils in the Pearl River Delta[J].Environmental Science,2007,28(10):2350-2354.
[28]Maliszewska-Kordybach B.Polycyclic aromatic hydrocarbons in agricultural soils in Poland:Preliminary proposals for criteria to evaluate the level of soil contamination[J].Applied Geochemistry,1996,11(1/2):121-127.
[29]樊孝俊,刘忠马,夏新,等.南昌市周边农田土壤中多环芳烃的污染特征及来源分析[J].中国环境监测,2009,25(6):109-112.FAN Xiao-jun,LIU Zhong-ma,XIA Xin,et al.Analysis of pollution characteristics and sources of PAHs in farmland soil around Nanchang City[J].Environmental Monitoring in China,2009,25(6):109-112.
[30]Ping L F,Luo Y M,Zhang H B,et al.Distribution of polycyclic aromatic hydrocarbons in thirty typical soil profiles in the Yangtze River Delta region,east China[J].Environmental Pollution,2007,147(2):358-367.
[31]赵健,周怀东,陆瑾,等.大清河流域表层土壤中多环芳烃的污染特征及来源分析[J].环境科学学报,2009,29(7):1452-1458.ZHAO Jian,ZHOU Huai-dong,LU Jin,et al.Concentration and origin of polycyclic aromatic hydrocarbons in surface soil in the Daqing River basin[J].Acta Scientiae Circumstantiae,2009,29(7):1452-1458.
[32]韩志刚,杨玉盛,杨红玉,等.福州市农业土壤多环芳烃的含量、来源及生态风险[J].亚热带资源与环境学报,2008,3(2):34-41.HAN Zhi-gang,YANG Yu-sheng,YANG Hong-yu,et al.Concentrations,sources and ecological risks of polycyclic aromatic hydrocarbons in agricultural soils of Fuzhou City[J].Journal of Subtropical Resources and Environment,2008,3(2):34-41.
[33]于国光,张志恒,叶雪珠,等.杭州市郊区表层土壤中的多环芳烃[J].生态环境学报,2009,18(3):925-928.YU Guo-guang,ZHANG Zhi-heng,YE Xue-zhu,et al.Polycyclic aromatic hydrocarbons in topsoil of suburban Hangzhou[J].Ecology and Environmental Sciences,2009,18(3):925-928.
[34]曲健,宋云横,苏娜.沈抚灌区上游土壤中多环芳烃的含量分析[J].中国环境监测,2006,22(3):29-31.QU Jian,SONG Yun-heng,SU Na.Analysis of polycyclic aromatic hydrocarbons in upriver soil of Shen Fu irrigation area[J].Environmental Monitoring in China,2006,22(3):29-31.
[35]赵颖,张丽.太原小店污灌区农田土壤多环芳烃的污染特征及其来源[J].水土保持通报,2017,37(4):99-105.ZHAO Ying,ZHANG Li.Pollution characteristics and sources of polycyclic aromatic hydrocarbons in farmland soil of sewage irrigation area[J].Bulletin of Soil and Water Conservation,2017,37(4):99-105.
[36]Van B T,Verweij R,Wedzinga S,et al.Enrichment of polycyclic aromatic hydrocarbons in forest soils near a blast furnace plant[J].Chemosphere,1996,32(2):293-314.
[37]Maliszewska-Kordybach B,Smreczak B,Klimkowowicz-Pawlas A,et al.Monitoring of the total content of polycyclic aromatic hydrocarbons(PAHs)in arable soils in Poland[J].Chemosphere,2008,73(8):1284-1291.
[2]Wild S R,Jones K C.Polynuclear aromatic hydrocarbons in the United Kingdom environment:A preliminary source inventory and budget[J].Environmental Pollution,1995,88(1):91-108.
[3]汤莉莉.北京城市土壤中多环芳烃的污染研究[D].南京:南京气象学院,2004.TANG Li-li.Contamination of polycyclic aromatic hydrocarbons in urban soils in Beijing[D].Nanjing:Nanjing Institute of Meteorology,2004.
[4]USEPA.Semivolatile organic compounds by gas chromatography/mass spectrometry(GC/MS)[EB/OL].[2018-08-08].http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/8270d.pdf.
[5]葛蔚,程琪琪,柴超,等.山东省农田土壤多环芳烃的污染特征及源解析[J].环境科学,2017,38(4):1587-1595.GE Wei,CHENG Qi-qi,CHAI Chao,et al.Pollution characteristics and source analysis of polycyclic aromatic hydrocarbons in agricultural soils from Shandong[J].Environmental Science,2017,38(4):1587-1595.
[6]曹云者,柳晓娟,谢云峰,等.我国主要地区表层土壤中多环芳烃组成及含量特征分析[J].环境科学学报,2012,32(1):197-203.CAO Yun-zhe,LIU Xiao-juan,XIE Yun-feng,et al.Patterns of PAHs concentrations and components in surface soils of main areas in China[J].Acta Scientiae Circumstantiae,2012,32(1):197-203.
[7]Readman J W,Fillmann G,Tolosa I,et al.Petroleum and PAH contamination of the Black Sea[J].Marine Pollution Bulletin,2002,44(1):48-62.
[8]李恭臣,夏星辉,王然,等.黄河中下游水体中多环芳烃的分布及来源[J].环境科学,2006,27(9):1738-1743.LI Gong-chen,XIA Xing-hui,WANG Ran,et al.Pollution of polycyclic aromatic hydrocarbons(PAHs)in middle and lower reaches of the Yellow River[J].Environmental Science,2006,27(9):1738-1743.
[9]Men B,He M,Tan L,et al.Distributions of polycyclic aromatic hydrocarbons in the Daliao River estuary of Liaodong Bay,Bohai Sea(China)[J].Marine Pollution Bulletin,2009,58(6):818-826.
[10]Yu X Z,Gao Y,Wu S C,et al.Distribution of polycyclic aromatic hydrocarbons in soils at Guiyu area of China,affected by recycling of electronic waste using primitive technologies[J].Chemosphere,2006,65(9):1500-1509.
[11]Edwards N T.Polycyclic aromatic hydrocarbons(PAHs)in the terrestrial environmental review[J].Journal of Environmental Quality,1983,12:427-441.
[12]Luca G D,Furesi A,Leardi R,et al.Polycyclic aromatic hydrocarbons assessment in the sediments of the Proto Torres Harbor(Northern Sardinia,Italy)[J].Marine Chemistry,2004,86(1/2):15-32.
[13]Atanassova I,Brummer G W.Polycyclic aromatic hydrocarbons of anthropogenic and biopedogenic origin in a colluviated hydromorphic soil of western Europe[J].Geoderma,2004,120(1/2):27-34.
[14]Yunker M B,Macdonald R W,Vingarzan R,et al.PAHs in the Fraser River basin:A critical appraisal of PAH ratios as indicators of PAHsource and composition[J].Organic Geochemistry,2002,33(4):489-515.
[15]冯承莲,夏星辉,周追,等.长江武汉段水体中多环芳烃的分布及来源分析[J].环境科学学报,2007,27(11):1900-1908.FENG Cheng-lian,XIA Xing-hui,ZHOU Zhui,et al.Distribution and sources of polycyclic aromatic hydrocarbons in the Wuhan section of the Yangtze River[J].Acta Scientiae Circumstantiae,2007,27(11):1900-1908.
[16]杨清书,雷亚平,欧素英,等.珠江广州河段水环境中多环芳烃的组成及其垂直分布特征[J].海洋通报,2008,27(6):34-43.YANG Qing-shu,LEI Ya-ping,OU Su-ying,et al.Vertical distribution,composition of polycyclic aromatic hydrocarbons in water column from Guangzhou channel in the Pearl River[J].Marine Science Bulletin,2008,27(6):34-43.
[17]张枝焕,卢另,贺光秀,等.北京地区表层土壤中多环芳烃的分布特征及污染源分析[J].生态环境学报,2011,20(4):668-675.ZHAN Zhi-huan,LU Ling,HE Guang-xiu,et al.Distribution and sources of polycyclic aromatic hydrocarbon compounds in topsoil of Beijing,China[J].Ecology and Environmental Sciences,2011,20(4):668-675.
[18]张敬锁,周洁,刘晓霞,等.京郊灌渠水体和底泥中多环芳烃污染特征[J].环境污染与防治,2017,39(3):236-243.ZHANG Jing-suo,ZHOU Jie,LIU Xiao-xia,et al.Pollution characteristics of PAHs in water and sediments of irrigation canal in suburb of Beijing[J].Environmental Pollution and Control,2017,39(3):236-243.
[19]邹正禹,唐海龙,刘阳生.北京市郊农业土壤中多环芳烃的污染分布和来源[J].环境化学,2013,32(5):874-880.ZOU Zheng-yu,TANG Hai-long,LIU Yang-sheng.Distribution and sources of polycyclic aromatic hydrocarbon compounds in topsoil of Beijing,China[J].Environmental Chemistry,2013,32(5):874-880.
[20]李艳,顾华,黄冠华,等.北京东南郊灌区多环芳烃污染风险与人体健康风险评估[J].农业机械学报.2017,48(9):237-249.LI Yan,GU Hua,HUANG Guan-hua,et al.Contamination and health risk assessment of PAHs in irrigation district in southeastern suburb of Beijing[J].Transactions of the Chinese Society for Agricultural Machinery,2017,48(9):237-249.
[21]丁爱芳,潘根兴,李恋卿.江苏省部分地区农田表土多环芳烃含量比较及来源分析[J].生态与农村环境学报,2007,23(2):71-75.DING Ai-fang,PAN Gen-xing,LI Lian-qing.Contents and sources of PAHs in top soils of farm lands in parts of Jiangsu,China[J].Journal of Ecology and Rural Environment,2007,23(2):71-75.
[22]周玲莉,薛南冬,李发生,等.黄淮平原农田土壤中多环芳烃的分布、风险及来源[J].中国环境科学,2012,32(7):1250-1256.ZHOU Ling-li,XUE Nan-dong,LI Fa-sheng,et al.Distribution,source analysis and risk assessment of polycyclic aromatic hydrocarbons in farmland soils in Huanghuai Plain[J].China Environmental Science,2012,32(7):1250-1256.
[23]刘增俊,滕应,黄标,等.长江三角洲典型地区农田土壤多环芳烃分布特征与源解析[J].土壤学报,2010,47(6):1110-1117.LIU Zeng-jun,TENG Ying,HUANG Biao,et al.Distribution and sources analysis of PAHs in farmland soils in areas typical of the Yangtze River Delta,China[J].Acta Pedologica Sinica,2010,47(6):1110-1117.
[24]徐慧洁,杨静慧,刘艳军.盐胁迫对野生樱桃幼苗生长的影响及其耐盐性分析[J].中国南方果树,2014,43(3):39-42.XU Hui-jie,YANG Jing-hui,LIU Yan-jun.Effect of salt stress on growth of wild cherry seedlings and analysis of their salt tolerance[J].South China Fruits,2014,43(3):39-42.
[25]李久海,董元华,曹志洪,等.慈溪市农田表层、亚表层土壤中多环芳烃(PAHs)的分布特征[J].环境科学学报,2007,27(11):1909-1914.LI Jiu-hai,DONG Yuan-hua,CAO Zhi-hong,et al.Distribution of polycyclic aromatic hydrocarbons(PAHs)in the surface and subsurface soils in Cixi County[J].Acta Scientiae Circumstantiae,2007,27(11):1909-1914.
[26]Nam J J,Song B H,Eom K C,et al.Distribution of polycyclic aromatic hydrocarbons in agricultural soils in South Korea[J].Chemosphere,2003,50(10):1281-1289.
[27]杨国义,张天彬,高淑涛,等.珠江三角洲典型区域农业土壤中多环芳烃的含量分布特征及其污染来源[J].环境科学,2007,28(10):2350-2354.YANG Guo-yi,ZHANG Tian-bin,GAO Shu-tao,et al.Source and distribution characteristics of polycyclic aromatic hydrocarbons in agricultural soils in the Pearl River Delta[J].Environmental Science,2007,28(10):2350-2354.
[28]Maliszewska-Kordybach B.Polycyclic aromatic hydrocarbons in agricultural soils in Poland:Preliminary proposals for criteria to evaluate the level of soil contamination[J].Applied Geochemistry,1996,11(1/2):121-127.
[29]樊孝俊,刘忠马,夏新,等.南昌市周边农田土壤中多环芳烃的污染特征及来源分析[J].中国环境监测,2009,25(6):109-112.FAN Xiao-jun,LIU Zhong-ma,XIA Xin,et al.Analysis of pollution characteristics and sources of PAHs in farmland soil around Nanchang City[J].Environmental Monitoring in China,2009,25(6):109-112.
[30]Ping L F,Luo Y M,Zhang H B,et al.Distribution of polycyclic aromatic hydrocarbons in thirty typical soil profiles in the Yangtze River Delta region,east China[J].Environmental Pollution,2007,147(2):358-367.
[31]赵健,周怀东,陆瑾,等.大清河流域表层土壤中多环芳烃的污染特征及来源分析[J].环境科学学报,2009,29(7):1452-1458.ZHAO Jian,ZHOU Huai-dong,LU Jin,et al.Concentration and origin of polycyclic aromatic hydrocarbons in surface soil in the Daqing River basin[J].Acta Scientiae Circumstantiae,2009,29(7):1452-1458.
[32]韩志刚,杨玉盛,杨红玉,等.福州市农业土壤多环芳烃的含量、来源及生态风险[J].亚热带资源与环境学报,2008,3(2):34-41.HAN Zhi-gang,YANG Yu-sheng,YANG Hong-yu,et al.Concentrations,sources and ecological risks of polycyclic aromatic hydrocarbons in agricultural soils of Fuzhou City[J].Journal of Subtropical Resources and Environment,2008,3(2):34-41.
[33]于国光,张志恒,叶雪珠,等.杭州市郊区表层土壤中的多环芳烃[J].生态环境学报,2009,18(3):925-928.YU Guo-guang,ZHANG Zhi-heng,YE Xue-zhu,et al.Polycyclic aromatic hydrocarbons in topsoil of suburban Hangzhou[J].Ecology and Environmental Sciences,2009,18(3):925-928.
[34]曲健,宋云横,苏娜.沈抚灌区上游土壤中多环芳烃的含量分析[J].中国环境监测,2006,22(3):29-31.QU Jian,SONG Yun-heng,SU Na.Analysis of polycyclic aromatic hydrocarbons in upriver soil of Shen Fu irrigation area[J].Environmental Monitoring in China,2006,22(3):29-31.
[35]赵颖,张丽.太原小店污灌区农田土壤多环芳烃的污染特征及其来源[J].水土保持通报,2017,37(4):99-105.ZHAO Ying,ZHANG Li.Pollution characteristics and sources of polycyclic aromatic hydrocarbons in farmland soil of sewage irrigation area[J].Bulletin of Soil and Water Conservation,2017,37(4):99-105.
[36]Van B T,Verweij R,Wedzinga S,et al.Enrichment of polycyclic aromatic hydrocarbons in forest soils near a blast furnace plant[J].Chemosphere,1996,32(2):293-314.
[37]Maliszewska-Kordybach B,Smreczak B,Klimkowowicz-Pawlas A,et al.Monitoring of the total content of polycyclic aromatic hydrocarbons(PAHs)in arable soils in Poland[J].Chemosphere,2008,73(8):1284-1291.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |