不同修复技术去除水中锑的研究进展
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摘要
为了研究锑修复技术,综述了国内外近10年的研究。本综述首先介绍了环境中锑的化学形态和锑的污染来源,从这些相关方面了解和发展锑修复技术。锑的常见去除技术包括:吸附法、混凝沉淀法、电化学法,它们的优点和缺点都有提及。文章主要汇总吸附法的进展详情。近几年的研究主要聚焦在有效且廉价的吸附剂上,例如碳材料、生物质、矿物和金属氧化物,各种材料吸附Sb(Ⅲ, Ⅴ)的吸附容量和其他的详情都准确罗列于表中,其他方面包括经济性和吸附机制都已进行讨论。目前的修复方法难以满足需求,今后应加强对锑的吸附研究。因此,高效吸附剂的开发和制备是非常重要的。
The paper aims to study the remediation techniques of antimony(Sb), and summarize the concerning research in recent 10 years. The paper introduces the chemical forms and contamination sources of Sb which are relevant aspects to understand and develop remediation techniques. The most common removal techniques of Sb(adsorption, coagulation/flocculation and electrochemical methods) are presented with discussion on their advantages and drawbacks. Literature review on adsorption focuses on detail. Recent researches have focused especially on available low-cost adsorbents, such as carbon materials, biosorbents, minerals and metallic oxides. Maximum adsorption capacities and other details are accurately compiled for Sb(Ⅲ, Ⅴ) species. Some aspects related to economic aspects and adsorption mechanisms are also discussed. The present removal techniques can hardly meet the demands, and some researches in adsorption of Sb should be strengthened in the future. Therefore, the development and preparation of new efficient adsorbents is very important.
The paper aims to study the remediation techniques of antimony(Sb), and summarize the concerning research in recent 10 years. The paper introduces the chemical forms and contamination sources of Sb which are relevant aspects to understand and develop remediation techniques. The most common removal techniques of Sb(adsorption, coagulation/flocculation and electrochemical methods) are presented with discussion on their advantages and drawbacks. Literature review on adsorption focuses on detail. Recent researches have focused especially on available low-cost adsorbents, such as carbon materials, biosorbents, minerals and metallic oxides. Maximum adsorption capacities and other details are accurately compiled for Sb(Ⅲ, Ⅴ) species. Some aspects related to economic aspects and adsorption mechanisms are also discussed. The present removal techniques can hardly meet the demands, and some researches in adsorption of Sb should be strengthened in the future. Therefore, the development and preparation of new efficient adsorbents is very important.
引文
[1]An Y J,Kim M.Effect of antimony on the microbial growth and the activities of soil enzymes[J].Chemosphere,2009,74(5):654-659.
[2]Filella M,Belzile N,Chen Y W.Antimony in the environment:a review focused on natural waters:I.Occurrence[J].Earth-Science Reviews,2002,57(1/2):125-176.
[3]Krachler M,Emons H,Zheng J.Speciation of antimony for the 21st century:promises and pitfalls[J].Trac Trends in Analytical Chemistry,2001,20(2):79-90.
[4]Fu Y,Peng L,Zeng Q,et al.High efficient removal of tetracycline from solution by degradation and flocculation with nanoscale zerovalent iron[J].Chemical Engineering Journal,2015,270:631-640.
[5]符云聪,黎红亮,彭亮,等.FeOOH/MnO2的制备与快速吸附去除水体中低浓度砷的试验[J].净水技术,2015(5):39-43.
[6]Ungureanu G,Santos S,Boaventura R,et al.Arsenic and antimony in water and wastewater:overview of removal techniques with special reference to latest advances in adsorption[J].Journal of Environmental Management,2015,151:326-342.
[7]Reimann C,Matschullat J,Birke M,et al.Antimony in the environment:lessons from geochemical mapping[J].Applied Geochemistry,2010,25(2):175-198.
[8]Biswas B K,Inoue J I,Kawakita H,et al.Effective removal and recovery of antimony using metal-loaded saponified orange waste[J].Journal of Hazardous Materials,2009,172(2/3):721-728.
[9]Amarasiriwardena D,Wu F.Antimony:Emerging toxic contaminant in the environment[J].Microchemical Journal,2011,97(1):1-3.
[10]Johnson C A,Moench H,Wersin P,et al.Solubility of antimony and other elements in samples taken from shooting ranges[J].Journal of Environmental Quality,2005,34(1):248-254.
[11]Ceriotti G,Amarasiriwardena D.A study of antimony complexed to soil-derived humic acids and inorganic antimony species along a Massachusetts highway[J].Microchemical Journal,2009,91(1):85-93.
[12]He M,Wang X,Wu F,et al.Antimony pollution in China[J].Science of the Total Environment,2012,421-422(3):41-50.
[13]陈臻,吕文英,姚琨.超声协助活性炭去除水中锑的研究[J].安徽农业科学,2014(12):3647-3649.
[14]黄国忠,周建情.酸改性活性炭对含锑矿坑废水的吸附研究[J].Advances in Environmental Protection,2014,04:245-254.
[15]Yu T,Zeng C,Ye M,et al.The adsorption of Sb(III)in aqueous solution by Fe2O3-modified carbon nanotubes[J].Water Science&Technology A Journal of the International Association on Water Pollution Research,2013,68(3):658-64.
[16]Wang Y,Liang Y,Jiao L,et al.Removal of antimony(III)from aqueous solution by graphene as an adsorbent[J].Chemical Engineering Journal,2012,211-212(47):406-411.
[17]孙福红,廖海清,陈艳卿,等.微囊藻对锑(V)生物吸附作用研究[J].中国环境科学,2016,36(11):3383-3389.
[18]Sun F,Wu F,Liao H,et al.Biosorption of antimony(V)by freshwater cyanobacteria Microcystis,biomass:Chemical modification and biosorption mechanisms[J].Chemical Engineering Journal,2011,171(3):1082-1090.
[19]Vijayaraghavan K,Balasubramanian R.Antimonite Removal Using Marine Algal Species[J].Industrial&Engineering Chemistry Research,2011,50(17):9864-9869.
[20]Uluozlu O D,Sar?A,Tuzen M.Biosorption of antimony from aqueous solution by lichen(Physcia tribacia)biomass[J].Chemical Engineering Journal,2010,163(3):382-388.
[21]邱罡,吴双桃,陈少瑾.水浮莲干体吸附去除水中的锑(Ⅲ)[J].环境工程学报,2012,6(8):2683-2688.
[22]Iqbal M,Saeed A,Edyvean R G J.Bioremoval of antimony(III)from contaminated water using several plant wastes:Optimization of batch and dynamic flow conditions for sorption by green bean husk(Vigna radiata)[J].Chemical Engineering Journal,2013,225(3):192-201.
[23]朱宗强,莫超,韦文慧,等.毛竹遗态Fe2O3/Fe3O4/C复合材料对水中锑(III)的吸附研究[J].工业安全与环保,2016,42(6).
[24]许光眉,施周,邓军.石英砂负载氧化铁的表征及其除锑吸附性能研究[J].环境科学学报,2006,26(4):607-612.
[25]叶鸣,曾嵘,张先斌,等.锰改性石英砂的表征及其对水中三价锑的吸附性能初探[J].广东化工,2013,40(16):44-46.
[26]张道勇,潘响亮,穆桂金,等.铝渣吸附去除水中锑的研究[J].水处理技术,2008,34(10):39-42.
[27]Shan C,Ma Z,Tong M.Efficient removal of trace antimony(III)through adsorption by hematite modified magnetic nanoparticles[J].Journal of Hazardous Materials,2014,268(3):229-236.
[28]Sar?A,??tak D,Tuzen M.Equilibrium,thermodynamic and kinetic studies on adsorption of Sb(III)from aqueous solution using low-cost natural diatomite[J].Chemical Engineering Journal,2010,162(2):521-527.
[29]李双双,戴友芝,于磊,等.铁改性海泡石除锑的影响因素研究[J].环境工程学报,2009,3(3):485-488.
[30]李双双,戴友芝,李娜,等.铁改性海泡石的研制及吸附锑特性[J].水处理技术,2009,35(5):49-52.
[31]Xi J,He M,Lin C.Adsorption of antimony(III)and antimony(V)on bentonite:Kinetics,thermodynamics and anion competition[J].Microchemical Journal,2011,97(1):85-91.
[32]徐伟,刘锐平,曲久辉,等.铁锰复合氧化物吸附去除五价锑性能研究[J].环境科学学报,2012,32(2):270-275.
[33]Xu W,Wang H,Liu R,et al.The mechanism of antimony(III)removal and its reactions on the surfaces of Fe-Mn binary oxide[J].Journal of Colloid&Interface Science,2011,363(1):320-326.
[34]Wang X,He M,Lin C,et al.Antimony(III)oxidation and antimony(V)adsorption reactions on synthetic manganite[J].Chemie der ErdeGeochemistry,2012,72(3):41-47.
[35]Guo X,Wu Z,He M,et al.Adsorption of antimony onto iron oxyhydroxides:adsorption behavior and surface structure[J].Journal of Hazardous Materials,2014,276(9):339-345.
[36]Lan B,Wang Y,Wang X,et al.Aqueous arsenic(As)and antimony(Sb)removal by potassium ferrate[J].Chemical Engineering Journal,2016,292:389-397.
[37]Nishad P A,Bhaskarapillai A,Velmurugan S.Enhancing the antimony sorption properties of nano titania-chitosan beads using epichlorohydrin as the crosslinker[J].Journal of Hazardous Materials,2017,334:160-167.
[38]贺维鹏,高源,童丽,等.强化混凝过程絮体形态对锑(Ⅴ)去除效果的影响[J].环境工程学报,2015,9(10):4773-4779.
[39]Du X,Qu F,Liang H,et al.Removal of antimony(III)from polluted surfacewaterusingahybridcoagulation-flocculation-ultrafiltration(CF-UF)process[J].ChemicalEngineering Journal,2014,254(4):293-301.
[40]Guo X J,Wu Z J,He M C.Removal of antimony(V)and antimony(III)from drinking water by coagulation-flocculation-sedimentation(CFS)[J].Water Research,2009,43(17):4327-4335.
[41]张家兴,王超,杨波,等.电混凝去除水中锑污染物[J].环境工程学报,2014,8(10):4244-4248.
[42]赵旭,曲久辉,刘会娟,等.一种电化学方法去除水中五价锑污染物的方法[P].CN103159300A,2013.
[43]Zhu J,Wu F,Pan X,et al.Removal of antimony from antimony mine flotation wastewater by electrocoagulation with aluminum electrodes[J].Journal of Environmental Sciences,2011,23(7):1066-1071.
[44]吴丰昌,朱静.用铁电极-电絮凝法处理含锑工业废水的方法[P].CN101781042A,2010.
[2]Filella M,Belzile N,Chen Y W.Antimony in the environment:a review focused on natural waters:I.Occurrence[J].Earth-Science Reviews,2002,57(1/2):125-176.
[3]Krachler M,Emons H,Zheng J.Speciation of antimony for the 21st century:promises and pitfalls[J].Trac Trends in Analytical Chemistry,2001,20(2):79-90.
[4]Fu Y,Peng L,Zeng Q,et al.High efficient removal of tetracycline from solution by degradation and flocculation with nanoscale zerovalent iron[J].Chemical Engineering Journal,2015,270:631-640.
[5]符云聪,黎红亮,彭亮,等.FeOOH/MnO2的制备与快速吸附去除水体中低浓度砷的试验[J].净水技术,2015(5):39-43.
[6]Ungureanu G,Santos S,Boaventura R,et al.Arsenic and antimony in water and wastewater:overview of removal techniques with special reference to latest advances in adsorption[J].Journal of Environmental Management,2015,151:326-342.
[7]Reimann C,Matschullat J,Birke M,et al.Antimony in the environment:lessons from geochemical mapping[J].Applied Geochemistry,2010,25(2):175-198.
[8]Biswas B K,Inoue J I,Kawakita H,et al.Effective removal and recovery of antimony using metal-loaded saponified orange waste[J].Journal of Hazardous Materials,2009,172(2/3):721-728.
[9]Amarasiriwardena D,Wu F.Antimony:Emerging toxic contaminant in the environment[J].Microchemical Journal,2011,97(1):1-3.
[10]Johnson C A,Moench H,Wersin P,et al.Solubility of antimony and other elements in samples taken from shooting ranges[J].Journal of Environmental Quality,2005,34(1):248-254.
[11]Ceriotti G,Amarasiriwardena D.A study of antimony complexed to soil-derived humic acids and inorganic antimony species along a Massachusetts highway[J].Microchemical Journal,2009,91(1):85-93.
[12]He M,Wang X,Wu F,et al.Antimony pollution in China[J].Science of the Total Environment,2012,421-422(3):41-50.
[13]陈臻,吕文英,姚琨.超声协助活性炭去除水中锑的研究[J].安徽农业科学,2014(12):3647-3649.
[14]黄国忠,周建情.酸改性活性炭对含锑矿坑废水的吸附研究[J].Advances in Environmental Protection,2014,04:245-254.
[15]Yu T,Zeng C,Ye M,et al.The adsorption of Sb(III)in aqueous solution by Fe2O3-modified carbon nanotubes[J].Water Science&Technology A Journal of the International Association on Water Pollution Research,2013,68(3):658-64.
[16]Wang Y,Liang Y,Jiao L,et al.Removal of antimony(III)from aqueous solution by graphene as an adsorbent[J].Chemical Engineering Journal,2012,211-212(47):406-411.
[17]孙福红,廖海清,陈艳卿,等.微囊藻对锑(V)生物吸附作用研究[J].中国环境科学,2016,36(11):3383-3389.
[18]Sun F,Wu F,Liao H,et al.Biosorption of antimony(V)by freshwater cyanobacteria Microcystis,biomass:Chemical modification and biosorption mechanisms[J].Chemical Engineering Journal,2011,171(3):1082-1090.
[19]Vijayaraghavan K,Balasubramanian R.Antimonite Removal Using Marine Algal Species[J].Industrial&Engineering Chemistry Research,2011,50(17):9864-9869.
[20]Uluozlu O D,Sar?A,Tuzen M.Biosorption of antimony from aqueous solution by lichen(Physcia tribacia)biomass[J].Chemical Engineering Journal,2010,163(3):382-388.
[21]邱罡,吴双桃,陈少瑾.水浮莲干体吸附去除水中的锑(Ⅲ)[J].环境工程学报,2012,6(8):2683-2688.
[22]Iqbal M,Saeed A,Edyvean R G J.Bioremoval of antimony(III)from contaminated water using several plant wastes:Optimization of batch and dynamic flow conditions for sorption by green bean husk(Vigna radiata)[J].Chemical Engineering Journal,2013,225(3):192-201.
[23]朱宗强,莫超,韦文慧,等.毛竹遗态Fe2O3/Fe3O4/C复合材料对水中锑(III)的吸附研究[J].工业安全与环保,2016,42(6).
[24]许光眉,施周,邓军.石英砂负载氧化铁的表征及其除锑吸附性能研究[J].环境科学学报,2006,26(4):607-612.
[25]叶鸣,曾嵘,张先斌,等.锰改性石英砂的表征及其对水中三价锑的吸附性能初探[J].广东化工,2013,40(16):44-46.
[26]张道勇,潘响亮,穆桂金,等.铝渣吸附去除水中锑的研究[J].水处理技术,2008,34(10):39-42.
[27]Shan C,Ma Z,Tong M.Efficient removal of trace antimony(III)through adsorption by hematite modified magnetic nanoparticles[J].Journal of Hazardous Materials,2014,268(3):229-236.
[28]Sar?A,??tak D,Tuzen M.Equilibrium,thermodynamic and kinetic studies on adsorption of Sb(III)from aqueous solution using low-cost natural diatomite[J].Chemical Engineering Journal,2010,162(2):521-527.
[29]李双双,戴友芝,于磊,等.铁改性海泡石除锑的影响因素研究[J].环境工程学报,2009,3(3):485-488.
[30]李双双,戴友芝,李娜,等.铁改性海泡石的研制及吸附锑特性[J].水处理技术,2009,35(5):49-52.
[31]Xi J,He M,Lin C.Adsorption of antimony(III)and antimony(V)on bentonite:Kinetics,thermodynamics and anion competition[J].Microchemical Journal,2011,97(1):85-91.
[32]徐伟,刘锐平,曲久辉,等.铁锰复合氧化物吸附去除五价锑性能研究[J].环境科学学报,2012,32(2):270-275.
[33]Xu W,Wang H,Liu R,et al.The mechanism of antimony(III)removal and its reactions on the surfaces of Fe-Mn binary oxide[J].Journal of Colloid&Interface Science,2011,363(1):320-326.
[34]Wang X,He M,Lin C,et al.Antimony(III)oxidation and antimony(V)adsorption reactions on synthetic manganite[J].Chemie der ErdeGeochemistry,2012,72(3):41-47.
[35]Guo X,Wu Z,He M,et al.Adsorption of antimony onto iron oxyhydroxides:adsorption behavior and surface structure[J].Journal of Hazardous Materials,2014,276(9):339-345.
[36]Lan B,Wang Y,Wang X,et al.Aqueous arsenic(As)and antimony(Sb)removal by potassium ferrate[J].Chemical Engineering Journal,2016,292:389-397.
[37]Nishad P A,Bhaskarapillai A,Velmurugan S.Enhancing the antimony sorption properties of nano titania-chitosan beads using epichlorohydrin as the crosslinker[J].Journal of Hazardous Materials,2017,334:160-167.
[38]贺维鹏,高源,童丽,等.强化混凝过程絮体形态对锑(Ⅴ)去除效果的影响[J].环境工程学报,2015,9(10):4773-4779.
[39]Du X,Qu F,Liang H,et al.Removal of antimony(III)from polluted surfacewaterusingahybridcoagulation-flocculation-ultrafiltration(CF-UF)process[J].ChemicalEngineering Journal,2014,254(4):293-301.
[40]Guo X J,Wu Z J,He M C.Removal of antimony(V)and antimony(III)from drinking water by coagulation-flocculation-sedimentation(CFS)[J].Water Research,2009,43(17):4327-4335.
[41]张家兴,王超,杨波,等.电混凝去除水中锑污染物[J].环境工程学报,2014,8(10):4244-4248.
[42]赵旭,曲久辉,刘会娟,等.一种电化学方法去除水中五价锑污染物的方法[P].CN103159300A,2013.
[43]Zhu J,Wu F,Pan X,et al.Removal of antimony from antimony mine flotation wastewater by electrocoagulation with aluminum electrodes[J].Journal of Environmental Sciences,2011,23(7):1066-1071.
[44]吴丰昌,朱静.用铁电极-电絮凝法处理含锑工业废水的方法[P].CN101781042A,2010.
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