用户名: 密码: 验证码:
离子液体萃取精馏分离甲醇-甲乙酮共沸物的模拟及优化
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:Simulation and Optimization of Extractive Distillation Process for Methanol and Methyl Ethyl Ketone System Using Ion Liquids
  • 作者:韩东 ; 王世威
  • 英文作者:Han Dongmin;Wang Shiwei;Department of Chemical Engineering,Shengli College China University of Petroleum;
  • 关键词:萃取精馏 ; 甲醇 ; 甲乙酮 ; 离子液体
  • 英文关键词:extractive distillation;;methanol;;methyl ethyl ketone;;ion liquid
  • 中文刊名:山东化工
  • 英文刊名:Shandong Chemical Industry
  • 机构:中国石油大学胜利学院化学工程学院;
  • 出版日期:2019-08-23
  • 出版单位:山东化工
  • 年:2019
  • 期:16
  • 语种:中文;
  • 页:149-151
  • 页数:3
  • CN:37-1212/TQ
  • ISSN:1008-021X
  • 分类号:TQ028.31
摘要
采用模拟软件Aspen Plus,以离子液体[HMIM][NTf_2]为萃取剂,对甲醇-甲乙酮共沸物的萃取精馏进行了模拟优化。确定了离子液体作为甲醇-甲乙酮萃取精馏萃取剂的可行性,分析考察了萃取精馏塔的塔板数、萃取剂流量、闪蒸罐压力等因素对年总费用TAC的影响,并对流程进行了热集成分析,结果表明,与常规萃取精馏相比,热集成流程的TAC下降了18.7%。
        Aspen Plus was used to simulate and optimize the process of extractive distillation for methanol and methyl ethyl ketone system with ion liquid [HMIM][NTf_2] as the solvent.The feasibility of the extractive distillation process with [HMIM][NTf_2] as solvent was analyzed using the residual curve.To find the optimal design of the extractive distillation systems,total annual cost(TAC) was used as the objective function to be minimized.In addition,heat integration technology was used to reduce the TAC.The results showed that the TAC was reduced by 18.7% after using heat integration technology.
引文
[1] 李群生,孙雪婷,曹玲,等.甲醇-甲乙酮-1-辛基-3-甲基咪唑六氟磷酸盐物系等压汽液平衡数据的测定[J].北京化工大学(自然科学版),2014,41(1):14-18.
    [2] 李卓,李群生,朱久娟,等.甲醇-甲乙酮-1-乙基-3-甲基咪唑双三氟甲磺酰亚胺盐物系等压汽液相平衡数据的测定及分析[J].北京化工大学学报(自然科学版),2017,44(2):8-12.
    [3] Britton E C,Nutting H S,Horsley L H,et al.Vapor-liquid equilibrum diagrams of alcohol-ketone azeotropes as a function of pressure[J].Anal Chem,1947,19(8):601-602.
    [4] 李静,王克良,连明磊,等.[Emim].AC萃取精馏分离乙酸甲酯和甲醇工艺模拟[J].化学工程,2018,46(05):69-72.
    [5] 田征,崔现宝,彭艳枚.离子液体萃取精馏分离乙酸甲酯-甲醇共沸物[J].石油化工,2013,42(5):537-541.
    [6] 王祥祥,韩东敏,张倩,等.低共熔溶剂萃取精馏分离乙醇-水共沸物的研究[J].现代化工,2019,39(03):223-226.
    [7] Han D M,Chen Y H.Combining the preconcentration column and recovery column for the extractive distillation of ethanol dehydration with low transition temperature mixtures as entrainers[J].Chemical Engineering and Processing:Process Intensification,2018,131:203-214.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700