非金属天然矿物吸附材料在土壤重金属污染修复中的应用
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摘要
随着土壤重金属污染日趋严重,非金属天然矿物吸附材料以其低价、无二次污染的独特优势,在土壤修复中得到应用。本文在介绍我国土壤重金属污染现状、天然矿物材料吸附性能的基础上,回顾了该类吸附材料的应用发展历程,着重突出了应用该吸附材料作为反应介质的渗透反应墙(PRB)、地球化学障(GB)技术,而水土一体化联合修复是一种较好的修复方式。对天然矿物吸附材料在土壤重金属污染修复中的应用研究提出了一些展望,包括吸附转化、影响条件、微观对比、多技术联合等。
With the increasing pollution of heavy metals in soil,non-metallic natural mineral adsorbents have been applied in soil remediation because of their unique advantages of low price and no secondary pollution.On the basis of introducing the present situation of soil heavy metal pollution and the adsorption properties of natural mineral materials in China,we review the application and development of this kind of adsorption materials.The permeable reactive barrier(PRB),and geochemical barrier(GB)technique using the adsorbed material as the reaction medium is emphasized,and the combined remediation of soil and water is a better method.Some prospects for the application of natural mineral adsorption materials in remediation of soil heavy metal pollution were put forward,including adsorption and transformation,influence conditions,microcosmic comparison,multi-technology combination and so on.
With the increasing pollution of heavy metals in soil,non-metallic natural mineral adsorbents have been applied in soil remediation because of their unique advantages of low price and no secondary pollution.On the basis of introducing the present situation of soil heavy metal pollution and the adsorption properties of natural mineral materials in China,we review the application and development of this kind of adsorption materials.The permeable reactive barrier(PRB),and geochemical barrier(GB)technique using the adsorbed material as the reaction medium is emphasized,and the combined remediation of soil and water is a better method.Some prospects for the application of natural mineral adsorption materials in remediation of soil heavy metal pollution were put forward,including adsorption and transformation,influence conditions,microcosmic comparison,multi-technology combination and so on.
引文
[1]LIU Z,HAMUTI A,ABDULLA H,et al.Accumulation of metallic elements by native species thriving in two mine tailings in Aletai,China[J].Environmental Earth Sciences,2016,75(9):1-9.
[2]SHAH K.Cadmium metal detoxification and hyperaccumulators[M]∥Detoxification of Heavy Metals.Springer Berlin Heidelberg,2011:181-203.
[3]FARCASANU I C,MATACHE M,IORDACHE V,et al.Hyperaccummulation:a key to heavy metal bioremediation[M]∥Bio-Geo Interactions in Metal-Contaminated Soils.Springer Berlin Heidelberg,2012:251-278.
[4]赵婉雨,杨雨寒.土壤重金属污染修复技术分析[J].高科技与产业化,2015,11(9):64-69.ZHAO Wanyu,YANG Yuhan.Analysis on remediation technology of heavy metal pollution in soil[J].High Technology and Industrialization,2015,11(9):64-69.
[5]任凌伟.典型矿物材料钝化修复重金属污染农田土壤的作用及机理研究[D].杭州:浙江大学,2017.
[6]李宁,任伯帜,周莹莹,等.土壤重金属污染危害及修复方法研究[J].广州化工,2017,45(9):30-32.LI Ning,REN Bozhi,ZHOU Yingying,et al.Study on pollution and remediation of heavy metals in soil[J].Guangzhou Chemical Industry,2017,45(9):30-32.
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[8]闫丰.环境矿物材料改良土壤的研究进展[J].安徽农业科学,2015,43(21):95-96.YAN Feng.Research progress of soil amelioration with environmental mineral materials[J].Journal of Anhui Agricultural Sciences,2015,43(21):95-96.
[9]BOLAN N,KUNHIKRISHNAN A,THANGARAJAN R,et al.Remediation of heavy metals contaminated soils-to mobilize or to immobilize[J].Journal of Hazardous Materials,2014,266(4):141-166.
[10]郝大程,周建强,王闯,等.重金属污染土壤的植物仿生和植物修复比较研究[J].生物技术通报,2017,33(2):66-71.HAO Dacheng,ZHOU Jianqiang,WANG Chuang,et al.Plant bionic remediation and phytoremediation of heavy metalcontaminated soil[J].Biotechnology Bulletin,2017,33(2):66-71.
[11]蒋婷婷.不同改性蒙脱土的制备及其对土壤中重金属的稳定化作用研究[D].上海:华东理工大学,2016.
[12]杨文弢,周航,邓贵友,等.组配改良剂对污染稻田中铅、镉和砷生物有效性的影响[J].环境科学学报,2016,36(1):257-263.YANG Wentao,ZHOU Hang,DENG Guiyou,et al.Effects of combined amendment on bioavailability of Pb,Cd and As in polluted paddy soil[J].Acta Scientiae Circumstantiae,2016,36(1):257-263.
[13]邹紫今,周航,吴玉俊,等.羟基磷灰石+沸石对稻田土壤中铅镉有效性及糙米中铅镉累积的影响[J].农业环境科学学报,2016,35(1):45-52.ZOU Zijin,ZHOU Hang,WU Yujun,et al.Effects of hydroxyapatite plus zeolite on bioavailability and rice bioaccumulation of Pb and Cd in soils[J].Journal of Agro-Environment Science,2016,35(1):45-52.
[14]曾卉,徐超,周航,等.几种固化剂组配修复重金属污染土壤[J].环境化学,2012,31(9):1368-1374.ZENG Hui,XU Chao,ZHOU Hang,et al.Effects of mixed curing agents on the remediation of soils with heavy metal pollution[J].Environmental Chemistry,2012,31(9):1368-1374.
[15]CONCAS A,MONTINARO S,PISU M,et al.Mechanochemical remediation of heavy metals contaminated soils:modelling and experiments[J].Chemical Engineering Science,2007,62(18):5186-5192.
[16]韩君,梁学峰,徐应明,等.黏土矿物原位修复镉污染稻田及其对土壤氮磷和酶活性的影响[J].环境科学学报,2014,34(11):2853-2860.HAN Jun,LIANG Xuefeng,XU Yingming,et al.In-situ remediation of Cd-polluted paddy soil by clay minerals and their effects on nitrogen,phosphorus and enzymatic activities[J].2014,34(11):2853-2860.
[17]孙国红,李剑睿,梁学峰,等.钝化修复对不同水稻品种镉累积效应及土壤特性的影响[J].灌溉排水学报,2017,36(2):25-31.SUN Guohong,LI Jianrui,LIANG Xuefeng,et al.Effects of Immobilization remediation of cadmium contaminated paddy soil on cadmium accumulation and soil properties in different rice varieties[J].Journal of Irrigation and Drainage,2017,36(2):25-31.
[18]SUN Y,SUN G,XU Y,et al.Evaluation of the effectiveness of sepiolite,bentonite,and phosphate amendments on the stabilization remediation of cadmium-contaminated soils[J].Journal of Environmental Management,2016,166(6):204-210.
[19]陈刚,罗志祥,施伏芝,等.一种新型硅肥在两系杂交水稻上的增产效果研究[J].中国土壤与肥料,2016(2):109-113.CHEN Gang,LUO Zhixiang,SHI Fuzhi,et al.Effect of a new type silicon fertilizer application on yield of two-line hybrid rice[J].Soil&Fertilizer Sciences in China,2016(2):109-113.
[20]UGOCHUKWU U C,JONES M D,HEAD I M,et al.Biodegradation and adsorption of crude oil hydrocarbons supported on“homoionic”montmorillonite clay mineral[J].Applied Clay Science,2014,87(1):81-86.
[21]YOON J,CAO X D,ZHOU Q,et al.Accumulation of Pb,Cu,and Zn in native plants growing on a contaminated Florida[J].Science of the Total Environment,2006,368(2):456-464.
[22]KRISHNA G B,SUSMITA S G.Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite:a review[J].Advances in Colloid and Interface Science,2008,140(2):114-131.
[23]KUMPIENE J,LAGERKVIST A,MAURICE C.Stabilization of As,Cr,Cu,Pb and Zn in soil using amendments-A review[J].Waste Management,2008,28(1):215-225.
[24]MALANDRINO M,ABOLLINO O,GIACOMINO A,et al.Adsorption of heavy metals on vermiculite:influence of pHand organic ligands[J].Journal of Colloid and Interface Science,2006,299(2):537-546.
[25]BOLAN Nanthi,KUNHIKRISHNAN Anitha,THANGA-RAJAN Ramya,et al.Remediation of heavy metals contaminated soils to mobilize or to immobilize[J].Journal of Hazardous Materials,2014,266(15):141-166.
[26]蔡轩,龙新宪,种云霄,等.无机-有机混合改良剂对酸性重金属复合污染土壤的修复效应[J].环境科学学报,2015,35(12):3991-4002.CAI Xuan,LONG Xinxian,CHONG Yunxiao,et al.Inorganic-organic amendments for immobilization of metal contaminants in an acidic soil[J].Acta Scientiae Circumstantiae,2015,35(12):3991-4002.
[27]CHEN Ruishan,YE Chao.Resolving soil pollution in China[J].Nature,2014,23(1):483.
[28]陈银合.化学淋洗和固化/稳定化技术修复重金属污染土壤[J].安徽农业科学,2016,44(1):156-158.CHEN Yinhe.Patent bibliometric analysis on the remediation techniques of soil heavy metal pollution[J].Journal of Anhui Agricultural Sciences,2016,44(1):156-158.
[29]吴耀楣.中国土壤重金属污染修复技术的专利文献计量分析[J].生态环境学报,2013,22(5):901-904.WU Yaomei.Patent bibliometric analysis on the remediation techniques of soil heavy metal pollution[J].Ecology&Environmental Sciences,2013,22(5):901-904.
[30]LIU Y,MOU H,CHEN L,et al.Cr(VI)-contaminated groundwater remediation with simulated permeable reactive barrier(PRB)filled with natural pyrite as reactive material:Environmental factors and effectiveness[J].Journal of Hazardous Materials,2015,298:83-90.
[31]ROJAS C M,TAVOLARO A,MOLINARI A,et al.Use of vegetable fibers for prb to remove heavy metals from contaminated aquifers-comparisons among cabuya fibers,broom fibers and ZVI[J].International Journal of Environmental Research&Public Health,2017,14(7):684.
[32]YANG Y,YAN-MING H E,LUAN J L,et al.Comprehensive analysis on soil remediation technologies of international contaminated sites[J].Environmental Science&Technology,2012,35(10):92-98.
[33]LEBRUN M,MACRI C,MIARD F,et al.Effect of biochar amendments on As and Pb mobility and phytoavailability in contaminated mine technosols phytoremediated by Salix[J].Journal of Geochemical Exploration,2016,182:149-156.
[34]QASIM B,MOTELICA-HEINO M,BOURGERIE S,et al.Rhizosphere effects of Populus euramericana,Dorskamp on the mobility of Zn,Pb and Cd in contaminated technosols[J].Journal of Soils&Sediments,2016,16(3):811-820.
[35]RUTTENS A,ADRIAENSEN K,MEERS E,et al.Longterm sustainability of metal immobilization by soil amendments:cyclonic ashes versus lime addition[J].Environmental Pollution,2010,158(5):1428-1434.
[36]WATERLOT C,PRUVOT C,CIESIELSKI H,et al.Effects of a phosphorus amendment and the pH of water used for watering on the mobility and phytoavailability of Cd,Pb and Zn in highly contaminated kitchen garden soils[J].Ecological Engineering,2011,37(7):1081-1093.
[37]COULON F,JONES K,LI H,et al.China's soil and groundwater management challenges:lessons from the UK's experience and opportunities for China[J].Environment International,2016,91:196-200.
(1)1亩=666.67m~2。
[2]SHAH K.Cadmium metal detoxification and hyperaccumulators[M]∥Detoxification of Heavy Metals.Springer Berlin Heidelberg,2011:181-203.
[3]FARCASANU I C,MATACHE M,IORDACHE V,et al.Hyperaccummulation:a key to heavy metal bioremediation[M]∥Bio-Geo Interactions in Metal-Contaminated Soils.Springer Berlin Heidelberg,2012:251-278.
[4]赵婉雨,杨雨寒.土壤重金属污染修复技术分析[J].高科技与产业化,2015,11(9):64-69.ZHAO Wanyu,YANG Yuhan.Analysis on remediation technology of heavy metal pollution in soil[J].High Technology and Industrialization,2015,11(9):64-69.
[5]任凌伟.典型矿物材料钝化修复重金属污染农田土壤的作用及机理研究[D].杭州:浙江大学,2017.
[6]李宁,任伯帜,周莹莹,等.土壤重金属污染危害及修复方法研究[J].广州化工,2017,45(9):30-32.LI Ning,REN Bozhi,ZHOU Yingying,et al.Study on pollution and remediation of heavy metals in soil[J].Guangzhou Chemical Industry,2017,45(9):30-32.
[7]环境保护部国土资源部.全国土壤污染状况调查公报[R].2014.
[8]闫丰.环境矿物材料改良土壤的研究进展[J].安徽农业科学,2015,43(21):95-96.YAN Feng.Research progress of soil amelioration with environmental mineral materials[J].Journal of Anhui Agricultural Sciences,2015,43(21):95-96.
[9]BOLAN N,KUNHIKRISHNAN A,THANGARAJAN R,et al.Remediation of heavy metals contaminated soils-to mobilize or to immobilize[J].Journal of Hazardous Materials,2014,266(4):141-166.
[10]郝大程,周建强,王闯,等.重金属污染土壤的植物仿生和植物修复比较研究[J].生物技术通报,2017,33(2):66-71.HAO Dacheng,ZHOU Jianqiang,WANG Chuang,et al.Plant bionic remediation and phytoremediation of heavy metalcontaminated soil[J].Biotechnology Bulletin,2017,33(2):66-71.
[11]蒋婷婷.不同改性蒙脱土的制备及其对土壤中重金属的稳定化作用研究[D].上海:华东理工大学,2016.
[12]杨文弢,周航,邓贵友,等.组配改良剂对污染稻田中铅、镉和砷生物有效性的影响[J].环境科学学报,2016,36(1):257-263.YANG Wentao,ZHOU Hang,DENG Guiyou,et al.Effects of combined amendment on bioavailability of Pb,Cd and As in polluted paddy soil[J].Acta Scientiae Circumstantiae,2016,36(1):257-263.
[13]邹紫今,周航,吴玉俊,等.羟基磷灰石+沸石对稻田土壤中铅镉有效性及糙米中铅镉累积的影响[J].农业环境科学学报,2016,35(1):45-52.ZOU Zijin,ZHOU Hang,WU Yujun,et al.Effects of hydroxyapatite plus zeolite on bioavailability and rice bioaccumulation of Pb and Cd in soils[J].Journal of Agro-Environment Science,2016,35(1):45-52.
[14]曾卉,徐超,周航,等.几种固化剂组配修复重金属污染土壤[J].环境化学,2012,31(9):1368-1374.ZENG Hui,XU Chao,ZHOU Hang,et al.Effects of mixed curing agents on the remediation of soils with heavy metal pollution[J].Environmental Chemistry,2012,31(9):1368-1374.
[15]CONCAS A,MONTINARO S,PISU M,et al.Mechanochemical remediation of heavy metals contaminated soils:modelling and experiments[J].Chemical Engineering Science,2007,62(18):5186-5192.
[16]韩君,梁学峰,徐应明,等.黏土矿物原位修复镉污染稻田及其对土壤氮磷和酶活性的影响[J].环境科学学报,2014,34(11):2853-2860.HAN Jun,LIANG Xuefeng,XU Yingming,et al.In-situ remediation of Cd-polluted paddy soil by clay minerals and their effects on nitrogen,phosphorus and enzymatic activities[J].2014,34(11):2853-2860.
[17]孙国红,李剑睿,梁学峰,等.钝化修复对不同水稻品种镉累积效应及土壤特性的影响[J].灌溉排水学报,2017,36(2):25-31.SUN Guohong,LI Jianrui,LIANG Xuefeng,et al.Effects of Immobilization remediation of cadmium contaminated paddy soil on cadmium accumulation and soil properties in different rice varieties[J].Journal of Irrigation and Drainage,2017,36(2):25-31.
[18]SUN Y,SUN G,XU Y,et al.Evaluation of the effectiveness of sepiolite,bentonite,and phosphate amendments on the stabilization remediation of cadmium-contaminated soils[J].Journal of Environmental Management,2016,166(6):204-210.
[19]陈刚,罗志祥,施伏芝,等.一种新型硅肥在两系杂交水稻上的增产效果研究[J].中国土壤与肥料,2016(2):109-113.CHEN Gang,LUO Zhixiang,SHI Fuzhi,et al.Effect of a new type silicon fertilizer application on yield of two-line hybrid rice[J].Soil&Fertilizer Sciences in China,2016(2):109-113.
[20]UGOCHUKWU U C,JONES M D,HEAD I M,et al.Biodegradation and adsorption of crude oil hydrocarbons supported on“homoionic”montmorillonite clay mineral[J].Applied Clay Science,2014,87(1):81-86.
[21]YOON J,CAO X D,ZHOU Q,et al.Accumulation of Pb,Cu,and Zn in native plants growing on a contaminated Florida[J].Science of the Total Environment,2006,368(2):456-464.
[22]KRISHNA G B,SUSMITA S G.Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite:a review[J].Advances in Colloid and Interface Science,2008,140(2):114-131.
[23]KUMPIENE J,LAGERKVIST A,MAURICE C.Stabilization of As,Cr,Cu,Pb and Zn in soil using amendments-A review[J].Waste Management,2008,28(1):215-225.
[24]MALANDRINO M,ABOLLINO O,GIACOMINO A,et al.Adsorption of heavy metals on vermiculite:influence of pHand organic ligands[J].Journal of Colloid and Interface Science,2006,299(2):537-546.
[25]BOLAN Nanthi,KUNHIKRISHNAN Anitha,THANGA-RAJAN Ramya,et al.Remediation of heavy metals contaminated soils to mobilize or to immobilize[J].Journal of Hazardous Materials,2014,266(15):141-166.
[26]蔡轩,龙新宪,种云霄,等.无机-有机混合改良剂对酸性重金属复合污染土壤的修复效应[J].环境科学学报,2015,35(12):3991-4002.CAI Xuan,LONG Xinxian,CHONG Yunxiao,et al.Inorganic-organic amendments for immobilization of metal contaminants in an acidic soil[J].Acta Scientiae Circumstantiae,2015,35(12):3991-4002.
[27]CHEN Ruishan,YE Chao.Resolving soil pollution in China[J].Nature,2014,23(1):483.
[28]陈银合.化学淋洗和固化/稳定化技术修复重金属污染土壤[J].安徽农业科学,2016,44(1):156-158.CHEN Yinhe.Patent bibliometric analysis on the remediation techniques of soil heavy metal pollution[J].Journal of Anhui Agricultural Sciences,2016,44(1):156-158.
[29]吴耀楣.中国土壤重金属污染修复技术的专利文献计量分析[J].生态环境学报,2013,22(5):901-904.WU Yaomei.Patent bibliometric analysis on the remediation techniques of soil heavy metal pollution[J].Ecology&Environmental Sciences,2013,22(5):901-904.
[30]LIU Y,MOU H,CHEN L,et al.Cr(VI)-contaminated groundwater remediation with simulated permeable reactive barrier(PRB)filled with natural pyrite as reactive material:Environmental factors and effectiveness[J].Journal of Hazardous Materials,2015,298:83-90.
[31]ROJAS C M,TAVOLARO A,MOLINARI A,et al.Use of vegetable fibers for prb to remove heavy metals from contaminated aquifers-comparisons among cabuya fibers,broom fibers and ZVI[J].International Journal of Environmental Research&Public Health,2017,14(7):684.
[32]YANG Y,YAN-MING H E,LUAN J L,et al.Comprehensive analysis on soil remediation technologies of international contaminated sites[J].Environmental Science&Technology,2012,35(10):92-98.
[33]LEBRUN M,MACRI C,MIARD F,et al.Effect of biochar amendments on As and Pb mobility and phytoavailability in contaminated mine technosols phytoremediated by Salix[J].Journal of Geochemical Exploration,2016,182:149-156.
[34]QASIM B,MOTELICA-HEINO M,BOURGERIE S,et al.Rhizosphere effects of Populus euramericana,Dorskamp on the mobility of Zn,Pb and Cd in contaminated technosols[J].Journal of Soils&Sediments,2016,16(3):811-820.
[35]RUTTENS A,ADRIAENSEN K,MEERS E,et al.Longterm sustainability of metal immobilization by soil amendments:cyclonic ashes versus lime addition[J].Environmental Pollution,2010,158(5):1428-1434.
[36]WATERLOT C,PRUVOT C,CIESIELSKI H,et al.Effects of a phosphorus amendment and the pH of water used for watering on the mobility and phytoavailability of Cd,Pb and Zn in highly contaminated kitchen garden soils[J].Ecological Engineering,2011,37(7):1081-1093.
[37]COULON F,JONES K,LI H,et al.China's soil and groundwater management challenges:lessons from the UK's experience and opportunities for China[J].Environment International,2016,91:196-200.
(1)1亩=666.67m~2。
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