The Guocun navajoite deposit is located at special border land of Likou tectonic zone and Taiping fault-fold belt in Jiangnan paleouplift in south-east margin Yangtze landmass, and it belongs to southern part of Likou-Yangzhanling anticline. Through the contrast study, the navajoite deposit was divided into four ore layers such as V1, V2, V3 and V4. On the basis of a detailed study on geologic characteristic, ore characteristics and deposit formation cause, the prospecting indicators can be summarized to provide practical experience and theory evidence for navajoite exploration in south Anhui Province.